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Direct and Catalyst-Free Ester Metathesis Reaction for Covalent Adaptable Networks

https://doi.org/10.1021/jacs.3c06262
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Colorless, Transparent, Robust, and Fast Scratch‐Self‐Healing Elastomers via a Phase‐Locked Dynamic Bonds Design
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Superstretchable Dynamic Polymer Networks
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Toward Stimuli‐Responsive Dynamic Thermosets through Continuous Development and Improvements in Covalent Adaptable Networks (CANs)
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Strong and Tough Supramolecular Covalent Adaptable Networks with Room‐Temperature Closed‐Loop Recyclability
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Thermally Adjustable Dynamic Disulfide Linkages Mediated by Highly Air‐Stable 2,2,6,6‐Tetramethylpiperidine‐1‐sulfanyl (TEMPS) Radicals
inferredcites →https://doi.org/10.1002/anie.201813525openalex-snapshot
Dynamic Covalent Bonds in Polymeric Materials
inferredcites →https://doi.org/10.1002/anie.201903726openalex-snapshot
The Persistent Radical Effect in Organic Synthesis
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Thiol–Anhydride Dynamic Reversible Networks
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Diels–Alder Polymer Networks with Temperature‐Reversible Cross‐Linking‐Induced Emission
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Mechanochromic, Shape‐Programmable and Self‐Healable Cholesteric Liquid Crystal Elastomers Enabled by Dynamic Covalent Boronic Ester Bonds
inferredcites →https://doi.org/10.1002/anie.202303841openalex-snapshot
Non‐activated Esters as Reactive Handles in Direct Post‐Polymerization Modification
inferredcites →https://doi.org/10.1002/pol.20220013openalex-snapshot
Functionalization of poly(methyl acrylate) with formate esters and polyester through ester‐ester exchange reaction
inferredcites →https://doi.org/10.1016/j.polymer.2020.122392openalex-snapshot
Recent development of repairable, malleable and recyclable thermosetting polymers through dynamic transesterification
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Spin Trapping: ESR parameters of spin adducts 1474 1528V
inferredcites →https://doi.org/10.1021/acs.chemrev.0c00938openalex-snapshot
Dynamic Covalent Polymer Networks: A Molecular Platform for Designing Functions beyond Chemical Recycling and Self-Healing
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Room-Temperature Self-Healing Polymers Based on Dynamic-Covalent Boronic Esters
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Selenium-Containing Polymers: Perspectives toward Diverse Applications in Both Adaptive and Biomedical Materials
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Closed-Loop Polymer Upcycling by Installing Property-Enhancing Comonomer Sequences and Recyclability
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Reprocessable, Self-Healing, Thermadapt Shape Memory Polycaprolactone via Robust Ester–Ester Interchanges Toward Kirigami-Tailored 4D Medical Devices
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Single Electron Transfer-Induced Redox Processes Involving N-(Acyloxy)phthalimides
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Catalytic Ester Metathesis Reaction and Its Application to Transfer Hydrogenation of Esters
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Reprocessing Postconsumer Polyurethane Foam Using Carbamate Exchange Catalysis and Twin-Screw Extrusion
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Reprocessable Cross-Linked Polymer Networks: Are Associative Exchange Mechanisms Desirable?
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Light-Controlled Triple-Shape-Memory, High-Permittivity Dynamic Elastomer for Wearable Multifunctional Information Encoding Devices
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“New” Catalysts for the Ester-Interchange Reaction: The Role of Alkali-Metal Alkoxide Clusters in Achieving Unprecedented Reaction Rates
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Boronic Ester Based Vitrimers with Enhanced Stability via Internal Boron–Nitrogen Coordination
inferredcites →https://doi.org/10.1021/jacs.1c03316openalex-snapshot
Covalent Adaptable Networks Using β-Amino Esters as Thermally Reversible Building Blocks
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Covalent Adaptable Liquid Crystal Networks Enabled by Reversible Ring-Opening Cascades of Cyclic Disulfides
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Reprocessing of Covalent Adaptable Polyamide Networks through Internal Catalysis and Ring-Size Effects
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Disulfide-Mediated Reversible Polymerization toward Intrinsically Dynamic Smart Materials
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Superior Hard but Quickly Reversible Si–O–Si Network Enables Scalable Fabrication of Transparent, Self-Healing, Robust, and Programmable Multifunctional Nanocomposite Coatings
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1,2-Disubstituted 1,2-Dihydro-1,2,4,5-tetrazine-3,6-dione as a Dynamic Covalent Bonding Unit at Room Temperature
inferredcites →https://doi.org/10.1021/jacs.2c03525openalex-snapshot
Intrinsically Re-curable Photopolymers Containing Dynamic Thiol-Michael Bonds
inferredcites →https://doi.org/10.1021/jacs.3c00774openalex-snapshot
Spiroborate-Linked Ionic Covalent Adaptable Networks with Rapid Reprocessability and Closed-Loop Recyclability
inferredcites →https://doi.org/10.1021/jacs.5b02653openalex-snapshot
Reprocessing and Recycling of Highly Cross-Linked Ion-Conducting Networks through Transalkylation Exchanges of C–N Bonds
inferredcites →https://doi.org/10.1021/jacs.7b03967openalex-snapshot
Oxime-Based and Catalyst-Free Dynamic Covalent Polyurethanes
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Silyl Ether as a Robust and Thermally Stable Dynamic Covalent Motif for Malleable Polymer Design
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Poly(oxime–ester) Vitrimers with Catalyst-Free Bond Exchange
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Adaptable Crosslinks in Polymeric Materials: Resolving the Intersection of Thermoplastics and Thermosets
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Chemically Triggered Synthesis, Remodeling, and Degradation of Soft Materials
inferredcites →https://doi.org/10.1021/ma902596sopenalex-snapshot
Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
inferredcites →https://doi.org/10.1038/nchem.2730openalex-snapshot
Macromolecular metamorphosis via stimulus-induced transformations of polymer architecture
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Dynamic urea bond for the design of reversible and self-healing polymers
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Closed-loop chemical recycling of cross-linked polymeric materials based on reversible amidation chemistry
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Closed-loop recycling of plastics enabled by dynamic covalent diketoenamine bonds
inferredcites →https://doi.org/10.1038/s41557-022-01046-4openalex-snapshot
Recyclable and malleable thermosets enabled by activating dormant dynamic linkages
inferredcites →https://doi.org/10.1038/s41578-021-00412-xopenalex-snapshot
Dynamic and reconfigurable materials from reversible network interactions
inferredcites →https://doi.org/10.1038/s41586-020-2495-2openalex-snapshot
Cleavable comonomers enable degradable, recyclable thermoset plastics
inferredcites →https://doi.org/10.1039/c3py00246bopenalex-snapshot
N-Acetoxy-phthalimide (NAPI) as a new H-abstracting agent at high temperature: application to the melt functionalization of polyethylene
inferredcites →https://doi.org/10.1039/c5sc02223aopenalex-snapshot
Vitrimers: permanent organic networks with glass-like fluidity
inferredcites →https://doi.org/10.1039/c9py01891copenalex-snapshot
Structural tuning of polycaprolactone based thermadapt shape memory polymer
inferredcites →https://doi.org/10.1039/d2cc04747kopenalex-snapshot
Dynamic covalent polymers enabled by reversible isocyanate chemistry
inferredcites →https://doi.org/10.1080/00222337608061220openalex-snapshot
The Kinetics of Ester-Ester Exchange Reactions by Mass Spectrometry
inferredcites →https://doi.org/10.1080/10236669508233869openalex-snapshot
Multinuclear NMR Characterization of Co-cross-linking of Ethylene-co-vinylacetate and Ethylene-co-methylacrylate Polymer Blends in the Presence of Dibutyltin Oxide
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Silica-Like Malleable Materials from Permanent Organic Networks
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High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Design of covalent adaptable networks with intrinsic flame retardancy
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Research progress on crosslinked polymer-based dielectrics for thin film capacitors
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New Advances in Covalent Network Polymers via Dynamic Covalent Chemistry
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Strengthening and Toughening Dynamic Covalent Thermosets via Hydrogen-Bonded Cross-Links
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