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Catalytic Difluorination of Olefins

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/anie.200500115openalex-snapshot
Hypervalent Iodine Chemistry in Synthesis: Scope and New Directions
inferredcites →https://doi.org/10.1002/anie.200901956openalex-snapshot
Synthesis and Structure of Stereoisomeric Multivicinal Hexafluoroalkanes
inferredcites →https://doi.org/10.1002/anie.201102027openalex-snapshot
Fluorine Conformational Effects in Organocatalysis: An Emerging Strategy for Molecular Design
inferredcites →https://doi.org/10.1002/anie.201507151openalex-snapshot
Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes
inferredcites →https://doi.org/10.1002/anie.201507152openalex-snapshot
Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities
inferredcites →https://doi.org/10.1002/anie.201507180openalex-snapshot
Structurally Defined Molecular Hypervalent Iodine Catalysts for Intermolecular Enantioselective Reactions
inferredcites →https://doi.org/10.1002/anie.201510608openalex-snapshot
Synthesis and Biological Evaluation of Bromo‐ and Fluorodanicalipin A
inferredcites →https://doi.org/10.1002/cber.190103402213openalex-snapshot
Ueber Substitution von Sauerstoff durch Flour in den Jodoverbindungen
inferredcites →https://doi.org/10.1002/smll.201001555openalex-snapshot
Fluorographene: A Two‐Dimensional Counterpart of Teflon
inferredcites →https://doi.org/10.1016/0040-4020(95)00362-copenalex-snapshot
Xenon difluoride in synthesis
inferredcites →https://doi.org/10.1016/j.jfluchem.2006.10.019openalex-snapshot
Elemental fluorine in organic chemistry (1997–2006)
inferredcites →https://doi.org/10.1016/s0022-1139(00)00241-4openalex-snapshot
Fluorocyclization of unsaturated alcohols and carboxylic acids by iodotoluene difluoride and amine-HF complexes
inferredcites →https://doi.org/10.1021/acs.jmedchem.5b01455openalex-snapshot
Fluorination Patterning: A Study of Structural Motifs That Impact Physicochemical Properties of Relevance to Drug Discovery
inferredcites →https://doi.org/10.1021/acs.joc.5b01929openalex-snapshot
Hypervalent Iodine-Mediated Fluorination of Styrene Derivatives: Stoichiometric and Catalytic Transformation to 2,2-Difluoroethylarenes
inferredcites →https://doi.org/10.1021/acs.orglett.6b00230openalex-snapshot
The Alga Ochromonas danica Produces Bromosulfolipids
inferredcites →https://doi.org/10.1021/ar50051a003openalex-snapshot
Gauche effect. Stereochemical consequences of adjacent electron pairs and polar bonds
inferredcites →https://doi.org/10.1021/cr500366bopenalex-snapshot
Modern Carbon–Fluorine Bond Forming Reactions for Aryl Fluoride Synthesis
inferredcites →https://doi.org/10.1021/ja00864a023openalex-snapshot
The Trifluoroacetic Acid Catalyzed Reaction of Iodobenzene Dichloride with Ethylenic Compounds
inferredcites →https://doi.org/10.1021/ja045299qopenalex-snapshot
α,β,γ-Trifluoroalkanes: A Stereoselective Synthesis Placing Three Vicinal Fluorines along a Hydrocarbon Chain
inferredcites →https://doi.org/10.1021/ja202555mopenalex-snapshot
Enantioselective Dichlorination of Allylic Alcohols
inferredcites →https://doi.org/10.1021/ja4083182openalex-snapshot
Catalytic Enantioselective Dibromination of Allylic Alcohols
inferredcites →https://doi.org/10.1021/ja505136jopenalex-snapshot
Direct, Catalytic Monofluorination of sp3 C–H Bonds: A Radical-Based Mechanism with Ionic Selectivity
inferredcites →https://doi.org/10.1021/jo00062a023openalex-snapshot
Site-selective fluorination of organic compounds using 1-alkyl-4-fluoro-1,4-diazabicyclo[2.2.2]octane salts (selectfluor reagents)
inferredcites →https://doi.org/10.1021/jo400301uopenalex-snapshot
Exploration of Fluorine Chemistry at the Multidisciplinary Interface of Chemistry and Biology
inferredcites →https://doi.org/10.1021/ol051446topenalex-snapshot
Straightforward Syntheses of Hypervalent Iodine(III) Reagents Mediated by Selectfluor
inferredcites →https://doi.org/10.1038/460197aopenalex-snapshot
Synthesis at the molecular frontier
inferredcites →https://doi.org/10.1038/nchem.2141openalex-snapshot
Catalytic, stereospecific syn-dichlorination of alkenes
inferredcites →https://doi.org/10.1038/nchem.2232openalex-snapshot
All-cis 1,2,3,4,5,6-hexafluorocyclohexane is a facially polarized cyclohexane
inferredcites →https://doi.org/10.1039/b610213copenalex-snapshot
Fluorine in medicinal chemistry
inferredcites →https://doi.org/10.1039/b611336bopenalex-snapshot
Fluorinated organic materials for electronic and optoelectronic applications: the role of the fluorine atom
inferredcites →https://doi.org/10.1039/b711844aopenalex-snapshot
Understanding organofluorine chemistry. An introduction to the C–F bond
inferredcites →https://doi.org/10.1039/b809432bopenalex-snapshot
Multi-vicinal fluoroalkanes: a new class of organofluorine compounds
inferredcites →https://doi.org/10.1039/c39890000881openalex-snapshot
Observations on the reaction of some electron rich dienes with hypervalent iodoarene difluorides: a novel mechanism for fluorination
inferredcites →https://doi.org/10.1039/c3cc49850fopenalex-snapshot
Halocarbocyclization versus dihalogenation: substituent directed iodine( iii ) catalyzed halogenations
inferredcites →https://doi.org/10.1039/c3cs60193eopenalex-snapshot
The influence of fluorine in asymmetric catalysis
inferredcites →https://doi.org/10.1039/c3sc53261eopenalex-snapshot
A photocatalyzed aliphatic fluorination
inferredcites →https://doi.org/10.1039/c5sc01973gopenalex-snapshot
Unstrained C–C bond activation and directed fluorination through photocatalytically-generated radical cations
inferredcites →https://doi.org/10.1055/s-0033-1339672openalex-snapshot
Facile Synthesis of 2-Fluoro-1,3-dicarbonyl Compounds with Aqueous Hydrofluoric Acid Mediated by Iodosylarenes
inferredcites →https://doi.org/10.1055/s-1998-1714openalex-snapshot
Difluorination of Alkenes with Iodotoluene Difluoride

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4649863openalex-extracted
inferred← citeshttps://doi.org/10.1002/0471264229.os098.01openalex-snapshot
Synthesis of Chiral Organoiodine Catalyst for Enantioselective Oxidative Dearomatization Reactions: N , N '‐(2 S ,2' S )‐(2‐Iodo‐1,3‐phenylene) bis(oxy)bis(propane‐2,1‐diyl)bis(2,4,6‐trimethylbenzamide)
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0948openalex-snapshot
Carbon–Heteroatom Bond Formation Mediated by Hypervalent Iodine
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0949openalex-snapshot
Halogenation and Perfluoroalkylation Chemistry Using Hypervalent Halogen Compounds
inferred← citeshttps://doi.org/10.1002/9781119288657.ch10openalex-snapshot
Addition Reactions
inferred← citeshttps://doi.org/10.1002/9781119736424.ch13openalex-snapshot
ASYMMETRIC CARBON–HALOGEN BOND FORMING REACTIONS (EXCLUDING C–H ACTIVATION PROCESSES)
inferred← citeshttps://doi.org/10.1002/9781119736424.ch7openalex-snapshot
ASYMMETRIC HYPERVALENT IODINE CATALYSIS
inferred← citeshttps://doi.org/10.1002/9783527825158.ch6openalex-snapshot
Fluorination, Trifluoromethylation, and Trifluoromethylthiolation of Alkenes, Cyclopropanes, and Diazo Compounds
inferred← citeshttps://doi.org/10.1002/9783527829569.ch7openalex-snapshot
Design of Chiral Organoiodine(I/ III ) Catalysts for Asymmetric Oxidative Transformations
inferred← citeshttps://doi.org/10.1002/9783527829569.ch9openalex-snapshot
Catalytic Alkene Difunctionalization Reactions
inferred← citeshttps://doi.org/10.1002/adsc.201700321openalex-snapshot
Enantioselective Mannich‐Type Reactions to Construct Trifluoromethylthio‐Containing Tetrasubstituted Carbon Stereocenters via Asymmetric Dual‐Reagent Catalysis
inferred← citeshttps://doi.org/10.1002/adsc.201700393openalex-snapshot
Synthesis of Aryldihalomethanes by Denitrogenative Dihalogenation of Benzaldehyde Hydrazones
inferred← citeshttps://doi.org/10.1002/adsc.201701581openalex-snapshot
Lewis acid‐mediated defluorinative [3+2] cycloaddition/aromatization cascade of 2,2‐difluoroethanol systems with nitriles
inferred← citeshttps://doi.org/10.1002/adsc.201800521openalex-snapshot
Enantioselective Iodine(I/III) Catalysis in Organic Synthesis
inferred← citeshttps://doi.org/10.1002/adsc.201801620openalex-snapshot
Cs2CO3‐Mediated Vicinal Thiosulfonylation of 1,1‐Dibromo‐1‐Alkenes with Thiosulfonates: An Expedient Synthesis of (E)‐1,2‐Thiosulfonylethenes
inferred← citeshttps://doi.org/10.1002/adsc.201900814openalex-snapshot
Enantioselective Fluorocyclizations Mediated by Amino‐Acid‐Derived Phthalazine
inferred← citeshttps://doi.org/10.1002/adsc.202000381openalex-snapshot
Fluorocyclization of N‐Propargyl Carboxamides by λ3‐Iodane Catalysts with Coordinating Substituents
inferred← citeshttps://doi.org/10.1002/adsc.202000750openalex-snapshot
Fluorination and Fluoroalkylation Reactions Mediated by Hypervalent Iodine Reagents
inferred← citeshttps://doi.org/10.1002/adsc.202300265openalex-snapshot
N,N’‐Difluoro‐2,2’‐bipyridinium Bis(tetrafluoroborate): a New Terminal Oxidant for Iodoarene‐catalyzed Fluorination Reactions
inferred← citeshttps://doi.org/10.1002/adsc.202301256openalex-snapshot
Silver‐Catalyzed Decarboxylative Acylfluorination of Two Alkenes with Ketonic Acids
inferred← citeshttps://doi.org/10.1002/ajoc.201600383openalex-snapshot
Catalytic Cycloisomerization–Fluorination Sequence of N‐Propargyl Amides by Iodoarene/HF⋅Pyridine/Selectfluor Systems
inferred← citeshttps://doi.org/10.1002/ajoc.201700099openalex-snapshot
Metal‐Free Hypervalent‐Iodine‐Promoted C3 Difluorination and C2 Oxidation of N‐Substituted Indoles
inferred← citeshttps://doi.org/10.1002/ange.201609110openalex-snapshot
Metal‐Free Enantioselective Oxidative Arylation of Alkenes: Hypervalent‐Iodine‐Promoted Oxidative C−C Bond Formation
inferred← citeshttps://doi.org/10.1002/ange.201609741openalex-snapshot
Hypervalent Iodine(III)‐Mediated Oxidative Fluorination of Alkylsilanes by Fluoride Ions
inferred← citeshttps://doi.org/10.1002/ange.201706401openalex-snapshot
Intermolecular Palladium‐Catalyzed Oxidative Fluorocarbonylation of Unactivated Alkenes: Efficient Access to β‐Fluorocarboxylic Esters
inferred← citeshttps://doi.org/10.1002/ange.201706798openalex-snapshot
Fluorinative Rearrangements of Substituted Phenylallenes Mediated by (Difluoroiodo)toluene: Synthesis of α‐(Difluoromethyl)styrenes
inferred← citeshttps://doi.org/10.1002/ange.201802466openalex-snapshot
Hypervalent Iodine(III)‐Catalyzed Balz–Schiemann Fluorination under Mild Conditions
inferred← citeshttps://doi.org/10.1002/ange.201803889openalex-snapshot
Indanol‐Based Chiral Organoiodine Catalysts for Enantioselective Hydrative Dearomatization
inferred← citeshttps://doi.org/10.1002/ange.201810328openalex-snapshot
Enantioselective, Catalytic Vicinal Difluorination of Alkenes
inferred← citeshttps://doi.org/10.1002/ange.201814471openalex-snapshot
Die selektive Arenhydrierung bietet einen direkten Zugang zu gesättigten Carbo‐ und Heterocyclen
inferred← citeshttps://doi.org/10.1002/ange.201901777openalex-snapshot
Organokatalytische, enantioselektive Dichlorierung unfunktionalisierter Alkene
inferred← citeshttps://doi.org/10.1002/ange.201903007openalex-snapshot
Organoiodine‐Catalyzed Enantioselective Alkoxylation/Oxidative Rearrangement of Allylic Alcohols
inferred← citeshttps://doi.org/10.1002/ange.201904662openalex-snapshot
Regioselective Formal [3+2] Cycloadditions of Urea Substrates with Activated and Unactivated Olefins for Intermolecular Olefin Aminooxygenation
inferred← citeshttps://doi.org/10.1002/ange.201905452openalex-snapshot
Inverting Small Molecule–Protein Recognition by the Fluorine Gauche Effect: Selectivity Regulated by Multiple H→F Bioisosterism
inferred← citeshttps://doi.org/10.1002/ange.201906124openalex-snapshot
Positionelle und geometrische Isomerisierung von Alkenen: der Gipfel der Atomökonomie
inferred← citeshttps://doi.org/10.1002/ange.201912119openalex-snapshot
Electrochemical Vicinal Difluorination of Alkenes: Scalable and Amenable to Electron‐Rich Substrates
inferred← citeshttps://doi.org/10.1002/ange.202004902openalex-snapshot
Iodine Catalysis for C(sp3)–H Fluorination with a Nucleophilic Fluorine Source
inferred← citeshttps://doi.org/10.1002/ange.202005181openalex-snapshot
Enantioselektive Synthese von 3‐Fluorchromanen durch Iod(I)/Iod(III)‐Katalyse
inferred← citeshttps://doi.org/10.1002/ange.202005844openalex-snapshot
Photocatalytic Fluoro Sulfoximidations of Styrenes
inferred← citeshttps://doi.org/10.1002/ange.202015946openalex-snapshot
Eine chirale pentafluorierte Isopropylgruppe durch Iod(I)/(III)‐Katalyse
inferred← citeshttps://doi.org/10.1002/ange.202102222openalex-snapshot
Synthese von trifluorierten Tetralinen durch I(I)/I(III)‐katalysierte Ringexpansion: programmieren von Konformationen über [CH2CH2] → [CF2CHF] Isosterismus
inferred← citeshttps://doi.org/10.1002/ange.202205088openalex-snapshot
Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride
inferred← citeshttps://doi.org/10.1002/ange.202205277openalex-snapshot
Stereokontrollierte Synthese von fluorierten Isochromanen durch Iod(I)/Iod(III)‐Katalyse
inferred← citeshttps://doi.org/10.1002/ange.202205508openalex-snapshot
Regio‐ und enantioselektive, intermolekulare Aminofluorierung von Alkenen durch Iod(I)/Iod(III)‐Katalyse**
inferred← citeshttps://doi.org/10.1002/ange.202214906openalex-snapshot
Catalytic, Regioselective 1,4‐Fluorodifunctionalization of Dienes
inferred← citeshttps://doi.org/10.1002/ange.202309789openalex-snapshot
Forging Medium Rings via I(I)/I(III)‐Catalyzed Diene Carbofunctionalization
inferred← citeshttps://doi.org/10.1002/ange.202403957openalex-snapshot
Catalytic Ring Expanding Difluorination: An Enantioselective Platform to Access β,β‐Difluorinated Carbocycles
inferred← citeshttps://doi.org/10.1002/ange.202404666openalex-snapshot
Alkene 1,3‐Difluorination via Transient Oxonium Intermediates
inferred← citeshttps://doi.org/10.1002/ange.202422899openalex-snapshot
Saturated F 2 ‐Rings from Alkenes
inferred← citeshttps://doi.org/10.1002/ange.202514359openalex-snapshot
A Highly Selective Nucleophilic and Radical Relay Difluorination of Cyclopropanes and Alkenes
inferred← citeshttps://doi.org/10.1002/ange.202518520openalex-snapshot
Difluorinative Cyclopropene Rearrangement by I(I)/I(III) Catalysis: Regio‐ and Stereoselective Synthesis of Allyl Difluorides
inferred← citeshttps://doi.org/10.1002/ange.5570530openalex-snapshot
Direct Regioselective para ‐Fluorination via I(I)/I(III) Catalysis
inferred← citeshttps://doi.org/10.1002/ange.7578090openalex-snapshot
Fluorinative Rearrangement of Vinyl Diazo Compounds Enabled by a New Reactivity Mode of Cyclopropanediazonium Ions
inferred← citeshttps://doi.org/10.1002/anie.201609110openalex-snapshot
Metal‐Free Enantioselective Oxidative Arylation of Alkenes: Hypervalent‐Iodine‐Promoted Oxidative C−C Bond Formation
inferred← citeshttps://doi.org/10.1002/anie.201609741openalex-snapshot
Hypervalent Iodine(III)‐Mediated Oxidative Fluorination of Alkylsilanes by Fluoride Ions
inferred← citeshttps://doi.org/10.1002/anie.201706401openalex-snapshot
Intermolecular Palladium‐Catalyzed Oxidative Fluorocarbonylation of Unactivated Alkenes: Efficient Access to β‐Fluorocarboxylic Esters
inferred← citeshttps://doi.org/10.1002/anie.201706798openalex-snapshot
Fluorinative Rearrangements of Substituted Phenylallenes Mediated by (Difluoroiodo)toluene: Synthesis of α‐(Difluoromethyl)styrenes
inferred← citeshttps://doi.org/10.1002/anie.201802466openalex-snapshot
Hypervalent Iodine(III)‐Catalyzed Balz–Schiemann Fluorination under Mild Conditions
inferred← citeshttps://doi.org/10.1002/anie.201803889openalex-snapshot
Indanol‐Based Chiral Organoiodine Catalysts for Enantioselective Hydrative Dearomatization
inferred← citeshttps://doi.org/10.1002/anie.201810328openalex-snapshot
Enantioselective, Catalytic Vicinal Difluorination of Alkenes
inferred← citeshttps://doi.org/10.1002/anie.201814471openalex-snapshot
Selective Arene Hydrogenation for Direct Access to Saturated Carbo‐ and Heterocycles
inferred← citeshttps://doi.org/10.1002/anie.201901777openalex-snapshot
Organocatalytic, Enantioselective Dichlorination of Unfunctionalized Alkenes
inferred← citeshttps://doi.org/10.1002/anie.201903007openalex-snapshot
Organoiodine‐Catalyzed Enantioselective Alkoxylation/Oxidative Rearrangement of Allylic Alcohols
inferred← citeshttps://doi.org/10.1002/anie.201904662openalex-snapshot
Regioselective Formal [3+2] Cycloadditions of Urea Substrates with Activated and Unactivated Olefins for Intermolecular Olefin Aminooxygenation
inferred← citeshttps://doi.org/10.1002/anie.201905452openalex-snapshot
Inverting Small Molecule–Protein Recognition by the Fluorine Gauche Effect: Selectivity Regulated by Multiple H→F Bioisosterism
inferred← citeshttps://doi.org/10.1002/anie.201906124openalex-snapshot
Positional and Geometrical Isomerisation of Alkenes: The Pinnacle of Atom Economy
inferred← citeshttps://doi.org/10.1002/anie.201912119openalex-snapshot
Electrochemical Vicinal Difluorination of Alkenes: Scalable and Amenable to Electron‐Rich Substrates
inferred← citeshttps://doi.org/10.1002/anie.202004902openalex-snapshot
Iodine Catalysis for C(sp3)–H Fluorination with a Nucleophilic Fluorine Source
inferred← citeshttps://doi.org/10.1002/anie.202005181openalex-snapshot
Enantioselective Synthesis of 3‐Fluorochromanes via Iodine(I)/Iodine(III) Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202005844openalex-snapshot
Photocatalytic Fluoro Sulfoximidations of Styrenes
inferred← citeshttps://doi.org/10.1002/anie.202015946openalex-snapshot
A Chiral Pentafluorinated Isopropyl Group via Iodine(I)/(III) Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202102222openalex-snapshot
Trifluorinated Tetralins via I(I)/I(III)‐Catalysed Ring Expansion: Programming Conformation by [CH 2 CH 2 ] → [CF 2 CHF] Isosterism
inferred← citeshttps://doi.org/10.1002/anie.202205088openalex-snapshot
Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride
inferred← citeshttps://doi.org/10.1002/anie.202205277openalex-snapshot
Stereocontrolled Synthesis of Fluorinated Isochromans via Iodine(I)/Iodine(III) Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202205508openalex-snapshot
Regio‐ and Enantioselective Intermolecular Aminofluorination of Alkenes via Iodine(I)/Iodine(III) Catalysis**
inferred← citeshttps://doi.org/10.1002/anie.202214906openalex-snapshot
Catalytic, Regioselective 1,4‐Fluorodifunctionalization of Dienes
inferred← citeshttps://doi.org/10.1002/anie.202309789openalex-snapshot
Forging Medium Rings via I(I)/I(III)‐Catalyzed Diene Carbofunctionalization
inferred← citeshttps://doi.org/10.1002/anie.202403957openalex-snapshot
Catalytic Ring Expanding Difluorination: An Enantioselective Platform to Access β,β‐Difluorinated Carbocycles
inferred← citeshttps://doi.org/10.1002/anie.202404666openalex-snapshot
Alkene 1,3‐Difluorination via Transient Oxonium Intermediates
inferred← citeshttps://doi.org/10.1002/anie.202422899openalex-snapshot
Saturated F 2 ‐Rings from Alkenes
inferred← citeshttps://doi.org/10.1002/anie.202514359openalex-snapshot
A Highly Selective Nucleophilic and Radical Relay Difluorination of Cyclopropanes and Alkenes
inferred← citeshttps://doi.org/10.1002/anie.202518520openalex-snapshot
Difluorinative Cyclopropene Rearrangement by I(I)/I(III) Catalysis: Regio‐ and Stereoselective Synthesis of Allyl Difluorides
inferred← citeshttps://doi.org/10.1002/anie.5570530openalex-snapshot
Direct Regioselective para ‐Fluorination via I(I)/I(III) Catalysis
inferred← citeshttps://doi.org/10.1002/asia.201800647openalex-snapshot
Transition‐Metal‐Catalyzed Three‐Component Difunctionalizations of Alkenes
inferred← citeshttps://doi.org/10.1002/asia.202300476openalex-snapshot
Divergent Fluorinations of Vinylcyclopropanes: Ring‐Opening 1,5‐Hydrofluorination and Ring‐Retaining 1,2‐Difluorination
inferred← citeshttps://doi.org/10.1002/asia.202400053openalex-snapshot
Decennary Update on Oxidative‐Rearrangement Involving 1,2‐Aryl C−C Migration Around Alkenes: Synthetic and Mechanistic Insights
inferred← citeshttps://doi.org/10.1002/chem.201604632openalex-snapshot
Emulating Natural Product Conformation by Cooperative, Non‐Covalent Fluorine Interactions
inferred← citeshttps://doi.org/10.1002/chem.201905445openalex-snapshot
Fluorohalogenation of gem‐Difluoroalkenes: Synthesis and Applications of α‐Trifluoromethyl Halides
inferred← citeshttps://doi.org/10.1002/chem.202000178openalex-snapshot
Polar Organofluorine Substituents: Multivicinal Fluorines on Alkyl Chains and Alicyclic Rings
inferred← citeshttps://doi.org/10.1002/chem.202001355openalex-snapshot
Understanding the Conformational Behavior of Fluorinated Piperidines: The Origin of the Axial‐F Preference
inferred← citeshttps://doi.org/10.1002/chem.202003176openalex-snapshot
Enantioselective Dihalogenation of Alkenes
inferred← citeshttps://doi.org/10.1002/chem.202102819openalex-snapshot
Janus All‐Cis 2,3,4,5,6‐Pentafluorocyclohexyl Building Blocks Applied to Medicinal Chemistry and Bioactives Discovery Chemistry
inferred← citeshttps://doi.org/10.1002/chem.71441openalex-snapshot
Synthesis and Structures of Novel Chiral Cyclic Hypervalent Iodine(III) Reagents for Metal‐Free Ligand‐Transfer Reactions
inferred← citeshttps://doi.org/10.1002/chin.201640053openalex-snapshot
ChemInform Abstract: Catalytic Difluorination of Olefins.
inferred← citeshttps://doi.org/10.1002/ejoc.201800389openalex-snapshot
Transition‐Metal‐Free Regioselective C–H Bond Fluorination of 8‐Amidoquinolines with Selectfluor
inferred← citeshttps://doi.org/10.1002/ejoc.202100364openalex-snapshot
Recent Developments in Enantioselective Organocatalytic Cascade Reactions for the Construction of Halogenated Ring Systems
inferred← citeshttps://doi.org/10.1002/ejoc.202300383openalex-snapshot
Asymmetric Synthesis of Monofluorinated Carbocyclic Alcohols and Vicinal Difluorinated Heterocycles and Carbocycles
inferred← citeshttps://doi.org/10.1002/ejoc.202400351openalex-snapshot
Streamlined Electrochemical Dihalogenation (F, Cl, and Br) of gem‐Difluoroalkenes Using Hydrogen Halides as Reagents
inferred← citeshttps://doi.org/10.1002/ejoc.202500264openalex-snapshot
Electrochemical Fluorination of Proline Derivatives
inferred← citeshttps://doi.org/10.1002/ejoc.202500995openalex-snapshot
The Difluorinative Acetonylation of Imidazopyridine Using Acetophenone and Selectfluor
inferred← citeshttps://doi.org/10.1002/hlca.202200183openalex-snapshot
Fluorocyclisation of Oximes to Isoxazolines Through I(I)/I(III) Catalysis
inferred← citeshttps://doi.org/10.1002/ijch.201600038openalex-snapshot
The Fluorine Gauche Effect: A Brief History
inferred← citeshttps://doi.org/10.1002/jhet.4416openalex-snapshot
Trifluorodiazoethane: A versatile building block to access trifluoromethylated heterocycles
inferred← citeshttps://doi.org/10.1002/nadc.20164054979openalex-snapshot
Notizen aus der Chemie
inferred← citeshttps://doi.org/10.1002/tcr.201800053openalex-snapshot
Recent Advances in the Intermolecular Oxidative Difunctionalization of Alkenes
inferred← citeshttps://doi.org/10.1002/tcr.202200285openalex-snapshot
Asymmetric Fluorofunctionalizations with Carboxylate‐Based Phase‐Transfer Catalysts
inferred← citeshttps://doi.org/10.1002/tcr.202300231openalex-snapshot
Iodine(III)‐Mediated Migratory gem‐Difluorinations: Synthesis of β Transformable Functionality Substituted gem‐Difluoroalkanes
inferred← citeshttps://doi.org/10.1007/978-3-662-65244-2_3openalex-snapshot
Aufbau und Derivatisierung von CC-Mehrfachbindungen
inferred← citeshttps://doi.org/10.1007/978-3-662-70963-4_3openalex-snapshot
Synthesis and Derivatization of Alkenes and Alkynes
inferred← citeshttps://doi.org/10.1007/978-981-10-1855-8_26-1openalex-snapshot
Et3N·3HF Complex Fluorination for Preparing Alkyl Fluorides
inferred← citeshttps://doi.org/10.1007/978-981-10-1855-8_36-1openalex-snapshot
Olah’s Reagent Fluorination for Preparing Alkyl Fluorides
inferred← citeshttps://doi.org/10.1007/978-981-10-1855-8_39-1openalex-snapshot
Hypervalent Iodine Fluorination for Preparing Alkyl Fluorides (Stoichiometrically and Catalytically)
inferred← citeshttps://doi.org/10.1007/978-981-10-1855-8_5-1openalex-snapshot
Fluorination of Alkenes and Alkynes for Preparing Alkyl Fluorides
inferred← citeshttps://doi.org/10.1007/978-981-10-3896-9_26openalex-snapshot
Et3N·3HF Complex Fluorination for Preparing Alkyl Fluorides
inferred← citeshttps://doi.org/10.1007/978-981-10-3896-9_36openalex-snapshot
Olah’s Reagent Fluorination for Preparing Alkyl Fluorides
inferred← citeshttps://doi.org/10.1007/978-981-10-3896-9_39openalex-snapshot
Hypervalent Iodine Fluorination for Preparing Alkyl Fluorides (Stoichiometrically and Catalytically)
inferred← citeshttps://doi.org/10.1007/978-981-10-3896-9_5openalex-snapshot
Fluorination of Alkenes and Alkynes for Preparing Alkyl Fluorides
inferred← citeshttps://doi.org/10.1007/s11426-021-9965-9openalex-snapshot
Hypervalent iodine-mediated gem-difluorination of vinyl halides enabled by exclusive 1,2-halo migration
inferred← citeshttps://doi.org/10.1016/b978-0-12-812733-9.00001-5openalex-snapshot
Emerging fluorination methods in organic chemistry relevant for life science application
inferred← citeshttps://doi.org/10.1016/b978-0-323-96025-0.00002-8openalex-snapshot
Synthesis of Fluorides
inferred← citeshttps://doi.org/10.1016/j.chempr.2024.08.024openalex-snapshot
Convergent synthesis and protein binding of vicinal difluorides by stereodivergent C–C bond formation
inferred← citeshttps://doi.org/10.1016/j.coelec.2021.100719openalex-snapshot
Recent progress in the electrochemistry of hypervalent iodine compounds
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2017.07.006openalex-snapshot
Geminal difluorination of α,α’- disubstituted styrenes using fluoro-benziodoxole reagent. Migration aptitude of the α-substituents
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2024.110336openalex-snapshot
Dimethyl sulfoxide-mediated dibromination of gem-difluoroalkenes with hydrobromic acid as reagent
inferred← citeshttps://doi.org/10.1016/j.mcat.2025.114944openalex-snapshot
Recent advances in organocatalytic enantioselective syntheses of β-fluoroamine compounds
inferred← citeshttps://doi.org/10.1016/j.polymdegradstab.2022.110144openalex-snapshot
Synthesis of a phosphorus-based epoxy reactive flame retardant analog to diglycidyl ether of bisphenol A (DGEBA) and its behavior as a matrix in a carbon fiber composite
inferred← citeshttps://doi.org/10.1016/j.rechem.2023.101284openalex-snapshot
Synthesis and pharmacological evaluation of fluoro/chloro-substituted acetyl and benzoyl esters of quinine as antimalarial agents
inferred← citeshttps://doi.org/10.1016/j.tchem.2023.100052openalex-snapshot
Catalytic, dearomative 2,3-difluorination of indoles
inferred← citeshttps://doi.org/10.1016/j.tet.2019.06.008openalex-snapshot
Asymmetric syntheses and applications of planar chiral hypervalent iodine(V) reagents with crown ether backbones
inferred← citeshttps://doi.org/10.1016/j.tet.2022.132925openalex-snapshot
Cyclopropene activation via I(I)/I(III) catalysis: Proof of principle and application in direct tetrafluorination
inferred← citeshttps://doi.org/10.1016/j.tet.2025.134611openalex-snapshot
Imidazole-mediated defluorosulfonylation of N-(fluorosulfonyl)oxazolidinones accessed by an organoiodine(I/III)-catalyzed oxyamination
inferred← citeshttps://doi.org/10.1016/j.tetlet.2016.10.016openalex-snapshot
Facile synthesis of amino acid-derived novel chiral hypervalent iodine(V) reagents and their applications
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.02.040openalex-snapshot
Theoretical study of Lewis acid activation models for hypervalent fluoroiodane reagent: The generality of “F-coordination” activation model
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.10.019openalex-snapshot
Mechanistic aspects of alkene oxidation using chiral hypervalent iodine reagents
inferred← citeshttps://doi.org/10.1021/acs.accounts.8b00192openalex-snapshot
Informing Molecular Design by Stereoelectronic Theory: The Fluorine Gauche Effect in Catalysis
inferred← citeshttps://doi.org/10.1021/acs.chemrev.4c00661openalex-snapshot
Nitrogen-Based Organofluorine Functional Molecules: Synthesis and Applications
inferred← citeshttps://doi.org/10.1021/acs.chemrev.5c00363openalex-snapshot
Selective Fluorination of Complex Molecules: Late-Stage Functionalization
inferred← citeshttps://doi.org/10.1021/acs.chemrev.9b00338openalex-snapshot
Chiral Hypervalent Iodines: Active Players in Asymmetric Synthesis
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.0c00648openalex-snapshot
Validating the 1,2-Difluoro Motif As a Hybrid Bioisostere of CF 3 and Et Using Matrix Metalloproteinases As Structural Probes
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.8b01210openalex-snapshot
Ligand-Based Fluorine NMR Screening: Principles and Applications in Drug Discovery Projects
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.9b01172openalex-snapshot
Systematic Investigation of Lipophilicity Modulation by Aliphatic Fluorination Motifs
inferred← citeshttps://doi.org/10.1021/acs.joc.0c02047openalex-snapshot
Iodoarene-Catalyzed Oxyamination of Unactivated Alkenes to Synthesize 5-Imino-2-Tetrahydrofuranyl Methanamine Derivatives
inferred← citeshttps://doi.org/10.1021/acs.joc.1c00578openalex-snapshot
Iodine(III)-Mediated Fluorination/Semipinacol Rearrangement Cascade of 2-Alkylidenecyclobutanol Derivatives: Access to β-Monofluorinated Cyclopropanecarbaldehydes
inferred← citeshttps://doi.org/10.1021/acs.joc.1c01946openalex-snapshot
Intramolecular Alkene Fluoroarylation of Phenolic Ethers Enabled by Electrochemically Generated Iodane
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02422openalex-snapshot
Iodine-Mediated Fluorination of Alkenes with an HF Reagent: Regioselective Synthesis of 2-Fluoroalkyl Iodides
inferred← citeshttps://doi.org/10.1021/acs.joc.2c01886openalex-snapshot
An Electrochemical Approach to Directed Fluorination
inferred← citeshttps://doi.org/10.1021/acs.joc.4c00179openalex-snapshot
Molecular Iodine as a Catalyst for Alkene Difluorination
inferred← citeshttps://doi.org/10.1021/acs.joc.6b01642openalex-snapshot
Mechanism and Origin of the Unexpected Chemoselectivity in Fluorocyclization of o-Styryl Benzamides with a Hypervalent Fluoroiodane Reagent
inferred← citeshttps://doi.org/10.1021/acs.joc.6c00562openalex-snapshot
Trifluorination of 1,1-Diarylethenes Using Selectfluor/HF Reagent and Experimental Evidence for a Single Electron Transfer Mechanism
inferred← citeshttps://doi.org/10.1021/acs.joc.6c00780openalex-snapshot
Internally Directed Stereochemical Alteration of Alkene Dihalogenation
inferred← citeshttps://doi.org/10.1021/acs.joc.7b01671openalex-snapshot
Deconstructing the Catalytic, Vicinal Difluorination of Alkenes: HF-Free Synthesis and Structural Study of p-TolIF2
inferred← citeshttps://doi.org/10.1021/acs.joc.7b01941openalex-snapshot
Chiral Hypervalent Organoiodine-Catalyzed Enantioselective Oxidative Spirolactonization of Naphthol Derivatives
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02473openalex-snapshot
Difluorination of Functionalized Aromatic Olefins Using Hypervalent Iodine/HF Reagents
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02741openalex-snapshot
Mechanism of Hypervalent Iodine Promoted Fluorocyclization of Unsaturated Alcohols: Metathesis via Double Acids Activation
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02920openalex-snapshot
Synthesis and Conformational Properties of 3,4-Difluoro- l -prolines
inferred← citeshttps://doi.org/10.1021/acs.jpcb.1c00100openalex-snapshot
Polarity Matters: Dielectric Relaxation in All-cis-Multifluorinated Cycloalkanes
inferred← citeshttps://doi.org/10.1021/acs.oprd.0c00180openalex-snapshot
Practical and Scalable Synthesis of a Glucokinase Activator via One-Pot Difluorination and Julia Olefination
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c00405openalex-snapshot
Electrophilic Hypervalent Trifluoromethylthio-Iodine(III) Reagent
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c02252openalex-snapshot
Deciphering the Keys for High Enantioselectivity in Hypervalent Iodine-Catalyzed 1,2-Difunctionalization: Improved Synthesis of Ishihara–Muñiz Precatalysts
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c02872openalex-snapshot
Lewis Base Catalyzed Dioxygenation of Olefins with Hypervalent Iodine Reagents
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c00518openalex-snapshot
Enantioselective Cu-Catalyzed Nucleophilic Addition of Fluorinated Reagents: C–C Bond Formation for the Synthesis of Chiral Vicinal Difluorides
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01150openalex-snapshot
Oxidative Fluoroarylation of Benzylidenecyclopropanes with HF·Py and Aryl Iodides via Iodonio-[3,3]-Rearrangement
inferred← citeshttps://doi.org/10.1021/acs.orglett.3c02379openalex-snapshot
Oxidative Cycloaddition Reactions of Arylboron Reagents via a One-pot Formal Dehydroboration Sequence
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c04501openalex-snapshot
Stereodivergent Synthesis of the Vicinal Difluorinated Tetralin of Casdatifan Enabled by Ru-Catalyzed Transfer Hydrogenation
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b03134openalex-snapshot
Mechanism of Silver-Mediated Geminal Difluorination of Styrenes with a Fluoroiodane Reagent: Insights into Lewis-Acid-Activation Model
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c00557openalex-snapshot
A Sequential Iodination–Fluorodeiodination of the Cubane Scaffold
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c03313openalex-snapshot
Unified Copper-Catalyzed Stereoselective Addition: Construction of Vicinal F/CF x -Containing Stereocenters
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b00887openalex-snapshot
Ionic Liquid-Mediated Hydrofluorination of o-Azaxylylenes Derived from 3-Bromooxindoles
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b01366openalex-snapshot
Copper-Catalyzed, Stereoselective Bis-trifluoromethylthiolation of Propiolic Acid Derivatives with AgSCF3
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b02479openalex-snapshot
Hypervalent-Iodine-Mediated Ring-Contraction Monofluorination Affording Monofluorinated Five-Membered Ring-Fused Oxazolines
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b03371openalex-snapshot
Photoredox Divergent 1,2-Difunctionalization of Alkenes with gem-Dibromides
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b03794openalex-snapshot
Catalytic Geminal Difluorination of Styrenes for the Construction of Fluorine-rich Bioisosteres
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b00938openalex-snapshot
Catalytic, Enantioselective 1,2-Difluorination of Cinnamamides
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b02662openalex-snapshot
Stereocontrolled Synthesis of Tetrafluoropentanols: Multivicinal Fluorinated Alkane Units for Drug Discovery
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b03381openalex-snapshot
Silver-Catalyzed Decarboxylative Alkylfluorination of Alkenes
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b03593openalex-snapshot
Transformation of Alkynes into α- or β-Difluorinated Alkyl Azides by an Efficient One-Pot Two-Step Procedure
inferred← citeshttps://doi.org/10.1021/acsami.7b13138openalex-snapshot
Solid-State Fluorescence of Fluorine-Modified Carbon Nanodots Aggregates Triggered by Poly(ethylene glycol)
inferred← citeshttps://doi.org/10.1021/acscatal.2c04511openalex-snapshot
Skeletal Ring Contractions via I(I)/I(III) Catalysis: Stereoselective Synthesis of cis-α,α-Difluorocyclopropanes
inferred← citeshttps://doi.org/10.1021/acscatal.6b02155openalex-snapshot
Catalytic, Vicinal Difluorination of Olefins: Creating a Hybrid, Chiral Bioisostere of the Trifluoromethyl and Ethyl Groups
inferred← citeshttps://doi.org/10.1021/acscatal.6b03380openalex-snapshot
Enantioselective Synthesis of Masked Benzoquinones Using Designer Chiral Hypervalent Organoiodine(III) Catalysis
inferred← citeshttps://doi.org/10.1021/acscatal.7b00975openalex-snapshot
Hypercoordinate Iodine Catalysts in Enantioselective Transformation: The Role of Catalyst Folding in Stereoselectivity
inferred← citeshttps://doi.org/10.1021/acscatal.7b03118openalex-snapshot
Metal-Free Catalytic Asymmetric Fluorination of Keto Esters Using a Combination of Hydrogen Fluoride (HF) and Oxidant: Experiment and Computation
inferred← citeshttps://doi.org/10.1021/acscatal.8b00667openalex-snapshot
Mechanisms of Rh-Catalyzed Oxyfluorination and Oxytrifluoromethylation of Diazocarbonyl Compounds with Hypervalent Fluoroiodine
inferred← citeshttps://doi.org/10.1021/acscatal.9b02313openalex-snapshot
Catalytic Vicinal Dichlorination of Unactivated Alkenes
inferred← citeshttps://doi.org/10.1021/acscentsci.4c00819openalex-snapshot
Nickel-Catalyzed Enantio- and Diastereoselective Synthesis of Fluorine-Containing Vicinal Stereogenic Centers
inferred← citeshttps://doi.org/10.1021/acsmedchemlett.9b00287openalex-snapshot
Fluorinated Analogues of the Histone Deacetylase Inhibitor Vorinostat (Zolinza): Validation of a Chiral Hybrid Bioisostere, BITE
inferred← citeshttps://doi.org/10.1021/acsomega.2c01791openalex-snapshot
Catalytic Synthesis of 5-Fluoro-2-oxazolines: Using BF3·Et2O as the Fluorine Source and Activating Reagent
inferred← citeshttps://doi.org/10.1021/jacs.0c07004openalex-snapshot
Carbonyl-Directed Aliphatic Fluorination: A Special Type of Hydrogen Atom Transfer Beats Out Norrish II
inferred← citeshttps://doi.org/10.1021/jacs.0c07043openalex-snapshot
Catalytic Enantioselective Synthesis of Difluorinated Alkyl Bromides
inferred← citeshttps://doi.org/10.1021/jacs.0c08150openalex-snapshot
Enantioselective Aryl-Iodide-Catalyzed Wagner–Meerwein Rearrangements
inferred← citeshttps://doi.org/10.1021/jacs.0c09323openalex-snapshot
Enantioselective Construction of Tertiary Fluoride Stereocenters by Organocatalytic Fluorocyclization
inferred← citeshttps://doi.org/10.1021/jacs.0c11440openalex-snapshot
Organoiodine-Catalyzed Enantioselective Intermolecular Oxyamination of Alkenes
inferred← citeshttps://doi.org/10.1021/jacs.1c06783openalex-snapshot
Structure Dependence in Asymmetric Deprotonative Fluorination and Fluorocyclization Reactions of Allylamine Derivatives with Linked Binaphthyl Dicarboxylate Phase-Transfer Catalyst
inferred← citeshttps://doi.org/10.1021/jacs.4c02344openalex-snapshot
Determination of the Hammett Acidity of HF/Base Reagents
inferred← citeshttps://doi.org/10.1021/jacs.4c03826openalex-snapshot
Silver-Catalyzed ( Z )-β-Fluoro-vinyl Iodonium Salts from Alkynes: Efficient and Selective Syntheses of Z -Monofluoroalkenes
inferred← citeshttps://doi.org/10.1021/jacs.5c05472openalex-snapshot
Non-Aqueous Binary and Ternary nHF·Base Fluoride Reagents: Characterization of Structure, Properties, and Reactivity
inferred← citeshttps://doi.org/10.1021/jacs.6b07221openalex-snapshot
Iron(II)-Catalyzed Intermolecular Aminofluorination of Unfunctionalized Olefins Using Fluoride Ion
inferred← citeshttps://doi.org/10.1021/jacs.6b09499openalex-snapshot
Enantioselective, Catalytic Fluorolactonization Reactions with a Nucleophilic Fluoride Source
inferred← citeshttps://doi.org/10.1021/jacs.7b01443openalex-snapshot
Catalytic Asymmetric Diamination of Styrenes
inferred← citeshttps://doi.org/10.1021/jacs.7b05160openalex-snapshot
Catalytic 1,3-Difunctionalization via Oxidative C–C Bond Activation
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