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Terpene Cyclizations inside a Supramolecular Catalyst: Leaving-Group-Controlled Product Selectivity and Mechanistic Studies
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Supramolecular Activation of Hydrogen Peroxide in the Selective Sulfoxidation of Thioethers by a Self‐Assembled Hexameric Capsule
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Host‐Catalyzed Cyclodehydration–Rearrangement Cascade Reaction of Unsaturated Tertiary Alcohols
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Supramolecular Catalysis in the Synthesis of Substituted 1 H‐Tetrazoles from Isonitriles by a Self‐Assembled Hexameric Capsule
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Functional Molecular Flasks: New Properties and Reactions within Discrete, Self‐Assembled Hosts
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Encapsulated or Not Encapsulated? Mapping Alcohol Sites in Hexameric Capsules of Resorcin[4]arenes in Solution by Diffusion NMR Spectroscopy
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Enzyme Mimics Based Upon Supramolecular Coordination Chemistry
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Iminium Catalysis inside a Self‐Assembled Supramolecular Capsule: Modulation of Enantiomeric Excess
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Supramolecular Encapsulation of Neutral Diazoacetate Esters and Catalyzed 1,3‐Dipolar Cycloaddition Reaction by a Self‐Assembled Hexameric Capsule
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Kinetic Isotope Effects in Asymmetric Reactions
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The Effect of Alcohol Structures on the Interaction Mode with the Hexameric Capsule of Resorcin[4]arene
inferredcites →https://doi.org/10.1002/chem.201600726openalex-snapshot
Advantages of Catalysis in Self‐Assembled Molecular Capsules
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A Switchable Gold Catalyst by Encapsulation in a Self‐Assembled Cage
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A simple, convenient and expeditious approach to cineol
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Zur Kenntnis der Triterpene. 190. Mitteilung. Eine stereochemische Interpretation der biogenetischen Isoprenregel bei den Triterpenen
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Evidence for the ionization steps in monoterpene cyclization reactions using 2-fluorogeranyl and 2-fluorolinalyl pyrophosphates as substrates
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Synthesis of 1,8-cineole and 1,4-cineole by isomerization of α-terpineol catalyzed by heteropoly acid
inferredcites →https://doi.org/10.1016/j.phytochem.2009.07.030openalex-snapshot
Monoterpene and sesquiterpene synthases and the origin of terpene skeletal diversity in plants
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Production of the anticancer drug taxol in Taxus baccata suspension cultures: A review
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Isoprenoid biosynthesis: manifold chemistry catalyzed by similar enzymes
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A Self-Assembled Molecular Cage for Substrate-Selective Epoxidation Reactions in Aqueous Media
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Proton-Mediated Chemistry and Catalysis in a Self-Assembled Supramolecular Host
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Mechanism of the pyrophosphate migration in the enzymic cyclization of geranyl and linalyl pyrophosphates to (+)- and (-)-bornyl pyrophosphates
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Biosynthesis and catabolism of monoterpenoids
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Enzymic formation of sesquiterpenes
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A Case Study in Biomimetic Total Synthesis: Polyolefin Carbocyclizations to Terpenes and Steroids
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Structural Biology and Chemistry of the Terpenoid Cyclases
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Supramolecular Catalysis in Metal–Ligand Cluster Hosts
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Syn Stereochemistry of Cyclic Ether Formation in 1,8-Cineole Biosynthesis Catalyzed by Recombinant Synthase from Salvia officinalis
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Spontaneous Formation of Hexameric Resorcinarene Capsule in Chloroform Solution as Detected by Diffusion NMR
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Kinetics and Thermodynamics of Hexameric Capsule Formation
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Hexameric Resorcinarene Capsule is a Brønsted Acid: Investigation and Application to Synthesis and Catalysis
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Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis
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Permeable Self-Assembled Molecular Containers for Catalyst Isolation Enabling Two-Step Cascade Reactions
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Recent Advances in the Chemistry of Taxol
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The Role of Water Molecules in a Resorcinarene Capsule As Probed by NMR Diffusion Measurements
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Hexameric Capsules of Lipophilic Pyrogallolarene and Resorcinarene in Solutions as Probed by Diffusion NMR: One Hydroxyl Makes the Difference
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Multicatalytic Synthesis of Complex Tetrahydrofurans Involving Bismuth(III) Triflate Catalyzed Intramolecular Hydroalkoxylation of Unactivated Olefins
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A chiral spherical molecular assembly held together by 60 hydrogen bonds
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High-level semi-synthetic production of the potent antimalarial artemisinin
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Synthesis of highly strained terpenes by non-stop tail-to-head polycyclization
inferredcites →https://doi.org/10.1038/nchem.2181openalex-snapshot
Terpene cyclization catalysed inside a self-assembled cavity
inferredcites →https://doi.org/10.1038/nchem.2425openalex-snapshot
Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions
inferredcites →https://doi.org/10.1038/nchem.2452openalex-snapshot
Highly efficient catalysis of the Kemp elimination in the cavity of a cubic coordination cage
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Supramolecular catalysis beyond enzyme mimics
inferredcites →https://doi.org/10.1039/b414252gopenalex-snapshot
Resorcinarene assemblies as synthetic receptors
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Reactivity within a confined self-assembled nanospace
inferredcites →https://doi.org/10.1039/c1cc10150aopenalex-snapshot
Recent advances in hydrogen-bonded hexameric encapsulation complexes
inferredcites →https://doi.org/10.1039/c1np00060hopenalex-snapshot
Sesquiterpene synthases: Passive catalysts or active players?
inferredcites →https://doi.org/10.1039/c1np00063bopenalex-snapshot
Isoprenoids in three-dimensional space: the stereochemistry of terpene biosynthesis
inferredcites →https://doi.org/10.1039/c2cc36363aopenalex-snapshot
Metal–organic container molecules through subcomponent self-assembly
inferredcites →https://doi.org/10.1039/c3cc42233jopenalex-snapshot
Efficient isonitrile hydration through encapsulation within a hexameric self-assembled capsule and selective inhibition by a photo-controllable competitive guest
inferredcites →https://doi.org/10.1039/c3cs60037hopenalex-snapshot
Supramolecular catalysis. Part 2: artificial enzyme mimics
inferredcites →https://doi.org/10.1039/c3cs60358jopenalex-snapshot
Organic cage compounds – from shape-persistency to function
inferredcites →https://doi.org/10.1039/c3cs60473jopenalex-snapshot
Self-assembled coordination cages based on banana-shaped ligands
inferredcites →https://doi.org/10.1039/c3np70045copenalex-snapshot
Functional diversity of organic molecule enzyme cofactors
inferredcites →https://doi.org/10.1039/c4cc08211gopenalex-snapshot
Intramolecular hydroalkoxylation catalyzed inside a self-assembled cavity of an enzyme-like host structure
inferredcites →https://doi.org/10.1039/c4cs00065jopenalex-snapshot
Soft templates in encapsulation complexes
inferredcites →https://doi.org/10.1039/c4cs00165fopenalex-snapshot
Molecular containers in complex chemical systems
inferredcites →https://doi.org/10.1039/c4cs00191eopenalex-snapshot
Molecular containers assembled through the hydrophobic effect
inferredcites →https://doi.org/10.1039/c4cs00192copenalex-snapshot
Transition metal catalysis in confined spaces
inferredcites →https://doi.org/10.1039/c6cy00307aopenalex-snapshot
Hydration of aromatic alkynes catalyzed by a self-assembled hexameric organic capsule
inferredcites →https://doi.org/10.1039/c6ra20271copenalex-snapshot
Efficient epoxide isomerization within a self-assembled hexameric organic capsule
inferredcites →https://doi.org/10.1039/c6sc04565kopenalex-snapshot
To catalyze or not to catalyze: elucidation of the subtle differences between the hexameric capsules of pyrogallolarene and resorcinarene
inferredcites →https://doi.org/10.1055/s-0035-1560362openalex-snapshot
Self-Assembled Supramolecular Structures as Catalysts for Reactions Involving Cationic Transition States
inferredcites →https://doi.org/10.1073/pnas.0604757103openalex-snapshot
Resorcinarenes are hexameric capsules in solution
inferredcites →https://doi.org/10.1073/pnas.141226898openalex-snapshot
Reversible encapsulation by self-assembling resorcinarene subunits
inferredcites →https://doi.org/10.1246/bcsj.20100035openalex-snapshot
Development of Unique Chemical Phenomena within Nanometer-Sized, Self-Assembled Coordination Hosts
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Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Electric‐Field Catalysis on Carbon Nanotubes in Electromicrofluidic Reactors: Monoterpene Cyclizations
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Multipoint Coordinative Capture of Olefinic Substrates Utilizing Metal‐Carbon Bonds by Macrocyclic Complex
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Non‐Dilute Synthesis of Macrodiolides and Macrotetrolides Enabled by Confinement Catalysis
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A Chalcogen Bonding Catalysis Platform for Isoprenoid Cyclization: Broad Scope and Diverse Product Frameworks
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Utilization of Donor–Acceptor Interactions for the Catalytic Acceleration of Nucleophilic Additions to Aromatic Carbonyl Compounds
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Brønsted Acid‐Catalyzed Carbonyl‐Olefin Metathesis inside a Self‐Assembled Supramolecular Host
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Mild Friedel–Crafts Reactions inside a Hexameric Resorcinarene Capsule: C−Cl Bond Activation through Hydrogen Bonding to Bridging Water Molecules
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Enantioselective Tail-to-Head Cyclizations Catalyzed by Dual-Hydrogen-Bond Donors
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inferred← citeshttps://doi.org/10.1021/jacs.5c17872openalex-snapshot
Attractive Noncovalent Interactions versus Steric Confinement in Asymmetric Supramolecular Catalysis
inferred← citeshttps://doi.org/10.1021/jacs.7b08976openalex-snapshot
Iminium Catalysis inside a Self-Assembled Supramolecular Capsule: Scope and Mechanistic Studies
inferred← citeshttps://doi.org/10.1021/jacs.8b00113openalex-snapshot
NXS, Morpholine, and HFIP: The Ideal Combination for Biomimetic Haliranium-Induced Polyene Cyclizations
inferred← citeshttps://doi.org/10.1021/jacs.8b10522openalex-snapshot
Enantioselective Conversion of Oligoprenol Derivatives to Macrocycles in the Germacrene, Cembrene, and 18-Membered Cyclic Sesterterpene Series
inferred← citeshttps://doi.org/10.1021/jacs.8b13411openalex-snapshot
Discovering Monoterpene Catalysis Inside Nanocapsules with Multiscale Modeling and Experiments
inferred← citeshttps://doi.org/10.1021/jacs.9b00131openalex-snapshot
Site-Selective Functionalization of Linear Diterpenoids through U-Shaped Folding in a Confined Artificial Cavity
inferred← citeshttps://doi.org/10.1021/jacs.9b05604openalex-snapshot
A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length
inferred← citeshttps://doi.org/10.1021/jacs.9b13239openalex-snapshot
Requirements for Terpene Cyclizations inside the Supramolecular Resorcinarene Capsule: Bound Water and Its Protonation Determine the Catalytic Activity
inferred← citeshttps://doi.org/10.1021/jacsau.4c00097openalex-snapshot
Window[1]resorcin[3]arenes: A Novel Macrocycle Able to Self-Assemble to a Catalytically Active Hexameric Cage
inferred← citeshttps://doi.org/10.1021/jacsau.5c00492openalex-snapshot
Expanding Meroterpenoid Chemical Space Via Intermolecular Trapping of Cationic Cyclization Intermediates
inferred← citeshttps://doi.org/10.1038/s41467-019-14251-6openalex-snapshot
Interplay of water and a supramolecular capsule for catalysis of reductive elimination reaction from gold
inferred← citeshttps://doi.org/10.1038/s41467-023-36157-0openalex-snapshot
Enzyme-like polyene cyclizations catalyzed by dynamic, self-assembled, supramolecular fluoro alcohol-amine clusters
inferred← citeshttps://doi.org/10.1038/s41557-020-0419-2openalex-snapshot
Coordination cages as permanently porous ionic liquids
inferred← citeshttps://doi.org/10.1038/s41596-023-00919-3openalex-snapshot
Biomimetic tail-to-head terpene cyclizations using the resorcin[4]arene capsule catalyst
inferred← citeshttps://doi.org/10.1038/s41929-018-0115-4openalex-snapshot
Sesquiterpene cyclizations catalysed inside the resorcinarene capsule and application in the short synthesis of isolongifolene and isolongifolenone
inferred← citeshttps://doi.org/10.1038/s41929-020-00528-3openalex-snapshot
Advances in supramolecular host-mediated reactivity
inferred← citeshttps://doi.org/10.1039/9781788019705-00133openalex-snapshot
Reactivity in a Self-assembled Organic Host
inferred← citeshttps://doi.org/10.1039/c7qo00942aopenalex-snapshot
The hexameric resorcinarene capsule as an artificial enzyme: ruling the regio and stereochemistry of a 1,3-dipolar cycloaddition between nitrones and unsaturated aldehydes
inferred← citeshttps://doi.org/10.1039/c8se00390dopenalex-snapshot
Computational design of biofuels from terpenes and terpenoids
inferred← citeshttps://doi.org/10.1039/c9cc01611bopenalex-snapshot
Cyclizations catalyzed inside a hexameric resorcinarene capsule
inferred← citeshttps://doi.org/10.1039/c9cc03151kopenalex-snapshot
Water plays a diverse role in a hydrogen-bonded, hexameric supramolecular assembly
inferred← citeshttps://doi.org/10.1039/c9cp06874kopenalex-snapshot
Water plays a dynamical role in a hydrogen-bonded, hexameric supramolecular assembly
inferred← citeshttps://doi.org/10.1039/c9np00003hopenalex-snapshot
En route to terpene natural products utilizing supramolecular cyclase mimetics
inferred← citeshttps://doi.org/10.1039/c9np00051hopenalex-snapshot
Terpene synthases in disguise: enzymology, structure, and opportunities of non-canonical terpene synthases
inferred← citeshttps://doi.org/10.1039/c9np00055kopenalex-snapshot
Nature-driven approaches to non-natural terpene analogues
inferred← citeshttps://doi.org/10.1039/c9qo00182dopenalex-snapshot
Binding properties and supramolecular polymerization of a water-soluble resorcin[4]arene
inferred← citeshttps://doi.org/10.1039/c9qo00329kopenalex-snapshot
Diffusion NMR for the characterization, in solution, of supramolecular systems based on calixarenes, resorcinarenes, and other macrocyclic arenes
inferred← citeshttps://doi.org/10.1039/d0cc05765gopenalex-snapshot
Selective, cofactor-mediated catalytic oxidation of alkanethiols in a self-assembled cage host
inferred← citeshttps://doi.org/10.1039/d0dt01485kopenalex-snapshot
Anion-mediated encapsulation-induced emission enhancement of an Ir III complex within a resorcin[4]arene hexameric capsule
inferred← citeshttps://doi.org/10.1039/d1cc02906aopenalex-snapshot
Solution NMR of synthetic cavity containing supramolecular systems: what have we learned on and from?
inferred← citeshttps://doi.org/10.1039/d1cs00175bopenalex-snapshot
New horizons for catalysis disclosed by supramolecular chemistry
inferred← citeshttps://doi.org/10.1039/d2qo00011copenalex-snapshot
Frustrated behavior of Lewis/Brønsted pairs inside molecular cages
inferred← citeshttps://doi.org/10.1039/d2qo01002jopenalex-snapshot
Leaving-group controlled N- or C-cyclization of azadienes via domino sequences: synthesis, mechanism, and chemoselectivity
inferred← citeshttps://doi.org/10.1039/d5cc06590aopenalex-snapshot
Bridging the hydrophobic gap: visible-light-driven photocatalysis of organic reactions in water with soft-matter nanoreactors
inferred← citeshttps://doi.org/10.1039/d5sc07390aopenalex-snapshot
Exploring the formation of medium-sized cyclic amines within self-assembled yoctoliter inner-spaces
inferred← citeshttps://doi.org/10.1039/d6ra01475eopenalex-snapshot
Stability and compatibility of resorcin[4]arene hexamer cages with amphiphilic random copolymers in organic solvents
inferred← citeshttps://doi.org/10.1107/s2052520620009944openalex-snapshot
C60in a peptidic cage: a case of symmetry mismatch studied by crystallography and solid-state NMR
inferred← citeshttps://doi.org/10.1186/s42833-019-0007-1openalex-snapshot
Emerging functional materials based on chemically designed molecular recognition
inferred← citeshttps://doi.org/10.1246/bcsj.20230187openalex-snapshot
Controlled Chemical Construction in Nature: Unified Biogenesis Accounting for Synthesis of Fungal Dimeric Anhydrides
inferred← citeshttps://doi.org/10.12677/hjcet.2023.132014openalex-snapshot
Catalytic Acetal Hydrolysis and Asymmetric Transfer Hydrogenation Reaction of Resorcinolcalix[4]arene Hexamer
inferred← citeshttps://doi.org/10.2139/ssrn.5248356openalex-snapshot
Study on the Aroma Formation Pathways in Huajiao Oil During the Frying Process: Instrumental, Sensory, and Correlation Analysis
inferred← citeshttps://doi.org/10.2533/chimia.2020.561openalex-snapshot
Molecular Capsule Catalysis: Ready to Address Current Challenges in Synthetic Organic Chemistry?
inferred← citeshttps://doi.org/10.26434/chemrxiv.9891341openalex-snapshot
Four-Step Access to the Sesquiterpene Natural Product Presilphiperfolan-1β-ol and Unnatural Derivatives via Supramolecular Catalysis
inferred← citeshttps://doi.org/10.3389/fchem.2018.00084openalex-snapshot
Supramolecular Organocatalysis in Water Mediated by Macrocyclic Compounds
inferred← citeshttps://doi.org/10.3389/fchem.2019.00687openalex-snapshot
The Hexameric Resorcinarene Capsule as a Brønsted Acid Catalyst for the Synthesis of Bis(heteroaryl)methanes in a Nanoconfined Space
inferred← citeshttps://doi.org/10.3390/molecules29204861openalex-snapshot
Cyclization Strategies in Carbonyl–Olefin Metathesis: An Up-to-Date Review
inferred← citeshttps://doi.org/10.3762/bjoc.20.211openalex-snapshot
HFIP as a versatile solvent in resorcin[ n ]arene synthesis
inferred← citeshttps://doi.org/10.6023/cjoc202303028openalex-snapshot
Research Progress on Organic Cation Receptors Based on Molecular Containers
inferred← citeshttps://doi.org/10.70675/7379abe3z0530z4227zbbf0z6fa7a386484fopenalex-snapshot
Conception et synthèse d'azacryptophanes. Influence des atomes d'azote sur les propriétés d'encapsulation du xénon
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