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Electronic Structural Analysis of Copper(II)–TEMPO/ABNO Complexes Provides Evidence for Copper(I)–Oxoammonium Character

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/ange.201504813openalex-snapshot

Selective Alcohol Oxidation by a Copper TEMPO Catalyst: Mechanistic Insights by Simultaneously Coupled Operando EPR/UV‐Vis/ATR‐IR Spectroscopy

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A Piece of the Picture—Misunderstanding of Chemical Concepts

inferredcites →https://doi.org/10.1002/anie.201403110openalex-snapshot

Practical Aerobic Oxidations of Alcohols and Amines with Homogeneous Copper/TEMPO and Related Catalyst Systems

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A Bonding Quandary—or—A Demonstration of the Fact That Scientists Are Not Born With Logic

inferredcites →https://doi.org/10.1002/chem.201604402openalex-snapshot

Mechanism of the Copper/TEMPO‐Catalyzed Aerobic Oxidation of Alcohols

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The ORCA program system

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Synthese und Röntgenstrukturanalyse von Bis(2,2,6,6‐tetramethylpiperidin‐1‐oxidato‐O, N)‐molybdän(VI)‐dioxid

inferredcites →https://doi.org/10.1007/bf02578291openalex-snapshot

Crystal chemistry of mixed-ligand coordination compounds with stable nitroxide radicals

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Oxidation states, atomic charges and orbital populations in transition metal complexes

inferredcites →https://doi.org/10.1016/0009-2614(82)85016-1openalex-snapshot

Observation of an electric quadrupole transition in the X-ray absorption spectrum of a Cu(II) complex

inferredcites →https://doi.org/10.1016/0022-328x(83)85163-8openalex-snapshot

Synthesis and x-ray structure of (2,2,6,6-tetramethyl-piperidinyl-1-oxo-O,N)tricarbonylmanganese(0); “side-on” coordination of the nitroxyl radical to manganese

inferredcites →https://doi.org/10.1016/0301-0104(86)80192-6openalex-snapshot

Ligand spin polarization and antiferromagnetic coupling in transition metal dimers

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Definition of corresponding orbitals and the diradical character in broken symmetry DFT calculations on spin coupled systems

inferredcites →https://doi.org/10.1016/j.tetlet.2014.05.085openalex-snapshot

Chemoselective aerobic oxidation catalyzed by a metal/stable organoradical redox conjugate

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Synthesis of 1,2-bis(di-tert-butylphosphino)ethane (dtbpe) complexes of nickel: radical coupling and reduction reactions promoted by the nickel(I) dimer [(dtbpe)NiCl]2

inferredcites →https://doi.org/10.1016/s0040-4039(00)75204-xopenalex-snapshot

Pyridinium chlorochromate. An efficient reagent for oxidation of primary and secondary alcohols to carbonyl compounds

inferredcites →https://doi.org/10.1021/acs.jpca.5b12674openalex-snapshot

The Dimerization of H2NO

inferredcites →https://doi.org/10.1021/ar990125copenalex-snapshot

Ligand K-Edge X-ray Absorption Spectroscopy: A Direct Probe of Ligand−Metal Covalency

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Large-Scale Oxidations in the Pharmaceutical Industry

inferredcites →https://doi.org/10.1021/cs400689aopenalex-snapshot

Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems

inferredcites →https://doi.org/10.1021/ic00023a039openalex-snapshot

Structural and redox properties of the Tempo adducts of copper(II) halides

inferredcites →https://doi.org/10.1021/ic00132a042openalex-snapshot

Structure of chloro(2,2,4,4-tetramethylpiperidinyl-1-oxo-O,N)(triphenylphosphine)palladium(II), a metal complex of a reduced nitroxyl radical

inferredcites →https://doi.org/10.1021/ic00235a022openalex-snapshot

Bis(nitroxyl) adducts of bis(hexafluoroacetylacetonato)manganese(II). Preparation, structures, and magnetic properties

inferredcites →https://doi.org/10.1021/ic060402topenalex-snapshot

Metal and Ligand K-edge XAS of Titanium−TEMPO Complexes: Determination of Oxidation States and Insights into Ti−O Bond Homolysis

inferredcites →https://doi.org/10.1021/ic2005979openalex-snapshot

Redox Noninnocence of Nitrosoarene Ligands in Transition Metal Complexes

inferredcites →https://doi.org/10.1021/ic200725kopenalex-snapshot

Cu(bipy)2+/TEMPO-Catalyzed Oxidation of Alcohols: Radical or Nonradical Mechanism?

inferredcites →https://doi.org/10.1021/ic2007342openalex-snapshot

Synthesis and Reactivity of a Transition Metal Complex Containing Exclusively TEMPO Ligands: Ni(η2-TEMPO)2

inferredcites →https://doi.org/10.1021/ic2016534openalex-snapshot

The Rhenium Tris(dithiolene) Electron Transfer Series: Calibrating Covalency

inferredcites →https://doi.org/10.1021/ic5018888openalex-snapshot

Oxidation of Alcohols and Activated Alkanes with Lewis Acid-Activated TEMPO

inferredcites →https://doi.org/10.1021/ic802276wopenalex-snapshot

Synthesis and Reactions of Mono- and Dinuclear Ni(I) Thiolate Complexes

inferredcites →https://doi.org/10.1021/ic902155mopenalex-snapshot

Activation of the C−H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)2+/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System

inferredcites →https://doi.org/10.1021/j100084a048openalex-snapshot

Principal Components of Ionicity

inferredcites →https://doi.org/10.1021/ja00060a052openalex-snapshot

Copper L-edge spectral studies: a direct experimental probe of the ground-state covalency in the blue copper site in plastocyanin

inferredcites →https://doi.org/10.1021/ja00164a005openalex-snapshot

The metal-nitroxyl interaction MNO metallacycles (M = copper, palladium). An ab initio SCF/CI study

inferredcites →https://doi.org/10.1021/ja00215a055openalex-snapshot

Three-center binding of a nitroxyl free radical to copper(II) bromide

inferredcites →https://doi.org/10.1021/ja00255a032openalex-snapshot

X-ray absorption edge determination of the oxidation state and coordination number of copper. Application to the type 3 site in Rhus vernicifera laccase and its reaction with oxygen

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Magnetic exchange interactions in nitroxyl biradicals bridged by metal-metal bonded complexes: structural, magnetochemical, and electronic spectral characterization of tetrakis(perfluorocarboxylato)dimetal(II) complexes of rhodium and molybdenum containing axially coordinated nitroxyl radicals

inferredcites →https://doi.org/10.1021/ja00323a064openalex-snapshot

Oxidation of alcohols to aldehydes with oxygen and cupric ion, mediated by nitrosonium ion

inferredcites →https://doi.org/10.1021/ja00330a069openalex-snapshot

Bis(nitroxyl) radical adducts of rhodium(II) and molybdenum(II) carboxylate dimers: magnetic exchange interactions propagated by metal-metal bonds

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Sulfur trioxide in the oxidation of alcohols by dimethyl sulfoxide

inferredcites →https://doi.org/10.1021/ja0615223openalex-snapshot

X-ray Absorption Edge Spectroscopy and Computational Studies on LCuO2 Species: Superoxide−CuII versus Peroxide−CuIII Bonding

inferredcites →https://doi.org/10.1021/ja206230hopenalex-snapshot

Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols

inferredcites →https://doi.org/10.1021/ja3117203openalex-snapshot

Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation

inferredcites →https://doi.org/10.1021/ja409241hopenalex-snapshot

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

inferredcites →https://doi.org/10.1021/ja5070137openalex-snapshot

Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals

inferredcites →https://doi.org/10.1021/ja993134popenalex-snapshot

A Systematic K-edge X-ray Absorption Spectroscopic Study of Cu(III) Sites

inferredcites →https://doi.org/10.1021/jacs.5b10819openalex-snapshot

Spectroscopic Evidence for a 3d 10 Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF 3 ) 4 ] 1–

inferredcites →https://doi.org/10.1021/jo00388a038openalex-snapshot

Fast and selective oxidation of primary alcohols to aldehydes or to carboxylic acids and of secondary alcohols to ketones mediated by oxoammonium salts under two-phase conditions

inferredcites →https://doi.org/10.1021/jp803174mopenalex-snapshot

Prediction of Iron K-Edge Absorption Spectra Using Time-Dependent Density Functional Theory

inferredcites →https://doi.org/10.1021/om900005topenalex-snapshot

Steric Enhancement of Group 12 Metal Hydride Stability and the Reaction of an Arylzinc Hydride with Tetramethylpiperidinyl Oxide (TEMPO)

inferredcites →https://doi.org/10.1021/op900059xopenalex-snapshot

Industrial Oxidations with Organocatalyst TEMPO and Its Derivatives

inferredcites →https://doi.org/10.1038/nature18008openalex-snapshot

Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators

inferredcites →https://doi.org/10.1039/b305941copenalex-snapshot

Cu(ii)-nitroxyl radicals as catalytic galactose oxidase mimics

inferredcites →https://doi.org/10.1039/b508541aopenalex-snapshot

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy

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Aerobic oxidation catalysis with stable radicals

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Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal–ligand interactions

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13. Researches on acetylenic compounds. Part I. The preparation of acetylenic ketones by oxidation of acetylenic carbinols and glycols

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The modern theory of valency

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COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient

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Pyridinium Chlorochromate: A Versatile Oxidant in Organic Synthesis

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On the Use of Stable Organic Nitroxyl Radicals for the Oxidation of Primary and Secondary Alcohols

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Systematic optimization of long-range corrected hybrid density functionals

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Valence bond description of antiferromagnetic coupling in transition metal dimers

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Density functional calculations of molecular hyperfine interactions in the zero order regular approximation for relativistic effects

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Molecular density functional calculations in the regular relativistic approximation: Method, application to coinage metal diatomics, hydrides, fluorides and chlorides, and comparison with first-order relativistic calculations

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RECENT APPLICATIONS OF OXOCHROMIUMAMINE COMPLEXES AS OXIDANTS IN ORGANIC SYNTHESIS. A REVIEW

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Quantum Theory of Many-Particle Systems. I. Physical Interpretations by Means of Density Matrices, Natural Spin-Orbitals, and Convergence Problems in the Method of Configurational Interaction

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Handbook of X-Ray Spectrometry

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SIXPack a Graphical User Interface for XAS Analysis Using IFEFFIT

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Experimental and Theoretical Spin Densities in Two Alkyl Nitroxides

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TEMPO (2,2,6,6-tetramethylpiperidine-N-oxyl) an Important Reagent in Alcohol Oxidation and its Application in Synthesis of Natural Products

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4640633openalex-extracted

inferred← citeshttps://doi.org/10.1002/ajoc.70256openalex-snapshot

ABNO‐Catalyzed Oxidative Dehydrogenation of N ‐Heterocycles in the Synthesis of N ‐Heteroarenes

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Boosting Hydrogen Production by Anodic Oxidation of Primary Amines over a NiSe Nanorod Electrode

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Methyl‐Selective α‐Oxygenation of Tertiary Amines to Formamides by Employing Copper/Moderately Hindered Nitroxyl Radical (DMN‐AZADO or 1‐Me‐AZADO)

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Boosting Hydrogen Production by Anodic Oxidation of Primary Amines over a NiSe Nanorod Electrode

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Methyl‐Selective α‐Oxygenation of Tertiary Amines to Formamides by Employing Copper/Moderately Hindered Nitroxyl Radical (DMN‐AZADO or 1‐Me‐AZADO)

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Three copper(II) complexes derived from 2‐methylquinoline and cyclic secondary amines: Synthesis and catalytic application in C—N bond forming reactions

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Molecular Electrocatalytic Hydrogenation of Carbonyls and Dehydrogenation of Alcohols

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Multivariate Analysis of Coupled Operando EPR/XANES/EXAFS/UV–Vis/ATR‐IR Spectroscopy: A New Dimension for Mechanistic Studies of Catalytic Gas‐Liquid Phase Reactions

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Copper Pyrithione (CuPT)-Catalyzed Oxidation of Secondary and Primary Benzyl Alcohols with Molecular oxygen or Air Under Mild Conditions

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Structural studies of nitroxyl ([TEMPO]n, [ABNO]n (n = 0,1)) ligation to iron reveal diversity in bonding (η1 vs. η2), oxygen atom transfer and aggregation

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Copper/TEMPO Redox Redux: Analysis of PCET Oxidation of TEMPOH by Copper(II) and the Reaction of TEMPO with Copper(I)

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Copper-Mediated Single-Electron Approach to Indoline Amination: Scope, Mechanism, and Total Synthesis of Asperazine A

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Cu/TEMPO Alcohol Oxidation Follows an Open-Shell HAT Mechanism

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Crown-hydroxylamines are pH-dependent chelating N,O-ligands with a potential for aerobic oxidation catalysis

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Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes

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Mechanistic studies on Cu(NO 3 ) 2 /TEMPO-catalyzed aerobic oxidation of alcohols to carboxylic acids

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Leveraging ligand-based proton and electron transfer for aerobic reactivity and catalysis

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Sizing up a supercharged ferryl

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A cobalt adduct of an N-hydroxy-piperidinium cation

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Synthesis of a copper-supported triplet nitrene complex pertinent to copper-catalyzed amination

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Catalytic Magnesium-Oppenauer Oxidation of Alcohols

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The histidine-brace active site of a copper monooxygenase is redox active and forms part of an in-built enzyme repair mechanism

inferred← citeshttps://doi.org/10.26434/chemrxiv.12924005openalex-snapshot

Chromium–Salen Complex / Nitroxyl Radical Cooperative Catalysis:A New Combination for Aerobic Intramolecular Dearomative Coupling of Phenols

inferred← citeshttps://doi.org/10.3390/catal9050395openalex-snapshot

Biomimetic Cu/Nitroxyl Catalyst Systems for Selective Alcohol Oxidation

inferred← citeshttps://doi.org/10.3390/molecules24010100openalex-snapshot

Electrochemical Performance of ABNO for Oxidation of Secondary Alcohols in Acetonitrile Solution

inferred← citeshttps://doi.org/10.3390/molecules25030748openalex-snapshot

Recent Advances in Copper Catalyzed Alcohol Oxidation in Homogeneous Medium

inferred← citeshttps://doi.org/10.3762/bjoc.16.77openalex-snapshot

Copper catalysis with redox-active ligands

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