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The osmium-catalyzed asymmetric dihydroxylation: a new ligand class and a process improvement

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Molecular Dynamics-Based Models Explain the Unexpected Diastereoselectivity of the Sharpless Asymmetric Dihydroxylation of Allyl D-Xylosides
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inferred← citeshttps://doi.org/10.1002/(sici)1521-3757(20000117)112:2<342::aid-ange342>3.0.co;2-zopenalex-snapshot
Sauerstoff und Osmium – ein neues Paar für Dihydroxylierungen?
inferred← citeshttps://doi.org/10.1002/(sici)1521-3765(19980515)4:5<950::aid-chem950>3.0.co;2-bopenalex-snapshot
Enantioselective Preparation of C2-Symmetrical Ferrocenyl Ligands for Asymmetric Catalysis
inferred← citeshttps://doi.org/10.1002/(sici)1521-3897(200004)342:4<340::aid-prac340>3.0.co;2-1openalex-snapshot
The Growing Synthetic Utility of Weinreb′s Amide
inferred← citeshttps://doi.org/10.1002/047084289x.rd232openalex-snapshot
Dihydroquinidine Acetate
inferred← citeshttps://doi.org/10.1002/047084289x.rd232.pub2openalex-snapshot
Dihydroquinidine Acetate
inferred← citeshttps://doi.org/10.1002/047084289x.rd233openalex-snapshot
Dihydroquinine Acetate
inferred← citeshttps://doi.org/10.1002/047084289x.rd233.pub2openalex-snapshot
Dihydroquinine Acetate
inferred← citeshttps://doi.org/10.1002/047084289x.rm074.pub2openalex-snapshot
Methanesulfonamide
inferred← citeshttps://doi.org/10.1002/047084289x.rn00057openalex-snapshot
(R,R)-1,2-Diphenyl-1,2-[di(pentafluorophenyl)phosphanoxy]ethane
inferred← citeshttps://doi.org/10.1002/047084289x.rn00163openalex-snapshot
Poly(ethylene glycol)-supported 1,4-phthalazinediyl Diether Hydroquinidine ‘(DHQD)2PHAL’ Ligand
inferred← citeshttps://doi.org/10.1002/047084289x.ro010openalex-snapshot
Osmium Tetroxide-Potassium Ferricyanide
inferred← citeshttps://doi.org/10.1002/047084289x.ro010.pub2openalex-snapshot
Osmium Tetroxide-Potassium Ferricyanide
inferred← citeshttps://doi.org/10.1002/047084289x.rp213.pub2openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/0471227617.eoc184openalex-snapshot
Selective Oxidation – Homogeneous
inferred← citeshttps://doi.org/10.1002/0471238961.0301200104050813.a01.pub2openalex-snapshot
Phase‐Transfer Catalysis
inferred← citeshttps://doi.org/10.1002/0471238961.0301200104050813.a01.pub3openalex-snapshot
Phase Transfer Catalysis
inferred← citeshttps://doi.org/10.1002/0471238961.1612012007090114.a01openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/0471264180.or060.01openalex-snapshot
Epoxide Migration (Payne Rearrangement) and Related Reactions
inferred← citeshttps://doi.org/10.1002/0471264180.or066.02openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/0471264180.or074.02openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/0471264180.or105.01openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/0471264180.or110.02openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/0471264180.os079.11openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/1521-3757(20011105)113:21<4179::aid-ange4179>3.0.co;2-#openalex-snapshot
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Synthesis of the Functionalized Macrocyclic Core of Proteasome Inhibitors TMC-95A and B
inferred← citeshttps://doi.org/10.1002/1521-3773(20011105)40:21<4055::aid-anie4055>3.0.co;2-hopenalex-snapshot
Stereocontrolled Total Synthesis of (+)-Altohyrtin A/Spongistatin 1 Financial support was provided by the EPSRC (GR/L41646), Cambridge Commonwealth Trust (Scholarship to M.J.C.), EC (Marie Curie Postdoctoral Fellowship to J.L.A.), DFG (Postdoctoral Fellowship to T.T.), NSERC-Canada (Postdoctoral…
inferred← citeshttps://doi.org/10.1002/9780470126042.ch16openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/9780470638859.conrr582openalex-snapshot
Sharpless Dihydroxylation
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0116openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/9780470682531.pat0131openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/9780470842898.rp213.pub2openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/9780470988619.ch17openalex-snapshot
Nojirimycin
inferred← citeshttps://doi.org/10.1002/9780470988619.ch37openalex-snapshot
(‐)‐Swainsonine
inferred← citeshttps://doi.org/10.1002/9780471264194.fos07484openalex-snapshot
Osmium tetroxide
inferred← citeshttps://doi.org/10.1002/9780471264194.fos07484.pub2openalex-snapshot
Osmium tetroxide
inferred← citeshttps://doi.org/10.1002/9780471264194.fos07484.pub3openalex-snapshot
Osmium Tetroxide
inferred← citeshttps://doi.org/10.1002/9780471264194.fos07484.pub4openalex-snapshot
Osmium Tetroxide
inferred← citeshttps://doi.org/10.1002/9780471264194.fos07484.pub5openalex-snapshot
Osmium tetroxide
inferred← citeshttps://doi.org/10.1002/9780471264194.fos07484.pub6openalex-snapshot
Osmium tetroxide
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(+)‐Intricatetraol
inferred← citeshttps://doi.org/10.1002/9783527613144.ch10openalex-snapshot
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References
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Asymmetric Syntheses
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Special Products: 3.3.1–3.3.6.5
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Asymmetric Dihydroxylation
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Asymmetric Dihydroxylation
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Enantioselectivecis‐Dihydroxylation
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Enantioselectivecis‐Dihydroxylation
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Cinchona‐Derived Chiral Poly(Phase‐Transfer Catalysts) for Asymmetric Synthesis
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Cinchona Alkaloids as Chiral Ligands in Asymmetric Oxidations
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Recent Developments in Metal‐Catalyzed Dihydroxylation of Alkenes
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Cinchona Alkaloids
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Design of Inhibitors of Aspartic Acid Proteases
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Asymmetric Dearomatization with Chiral Auxiliaries and Reagents
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Microencapsulated Osmium Tetroxide‐Catalyzed Asymmetric Dihydroxylation of Olefins in Water without Using Organic Cosolvents
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inferred← citeshttps://doi.org/10.1002/anie.199411821openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.199421901openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.199504121openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.199604481openalex-snapshot
A New Ligand Class for the Asymmetric Dihydroxylation of Olefins
inferred← citeshttps://doi.org/10.1002/anie.199616751openalex-snapshot
The Complete Structure of Maitotoxin, Part II: Configuration of the C135C142 Side Chain and Absolute Configuration of the Entire Molecule
inferred← citeshttps://doi.org/10.1002/anie.199707411openalex-snapshot
Asymmetric Dihydroxylation with MeO‐Polyethyleneglycol‐Bound Ligands
inferred← citeshttps://doi.org/10.1002/anie.199717311openalex-snapshot
Multipolymer‐Supported Substrate and Ligand Approach to the Sharpless Asymmetric Dihydroxylation
inferred← citeshttps://doi.org/10.1002/anie.199727941openalex-snapshot
Synthesis of an ABC Ring Analogue of Kapurimycin A3 as an Effective DNA Alkylating Agent
inferred← citeshttps://doi.org/10.1002/anie.200400663openalex-snapshot
The Quest for Quinine: Those Who Won the Battles and Those Who Won the War
inferred← citeshttps://doi.org/10.1002/anie.200453863openalex-snapshot
Synthesis and Biochemical Properties of Reversible Inhibitors of UDP‐N‐Acetylglucosamine 2‐Epimerase
inferred← citeshttps://doi.org/10.1002/anie.200503982openalex-snapshot
The Solution to a Deep Stereochemical Conundrum: Studies toward the Tetrahydroisoquinoline Alkaloids
inferred← citeshttps://doi.org/10.1002/anie.200601963openalex-snapshot
Gold(I)‐Catalyzed Bis‐Spiroketalization: Synthesis of the Trioxadispiroketal‐Containing A–D Rings of Azaspiracid
inferred← citeshttps://doi.org/10.1002/anie.200602507openalex-snapshot
Formal Total Synthesis of (+)‐Zaragozic Acid C through an Ireland–Claisen Rearrangement
inferred← citeshttps://doi.org/10.1002/anie.200803271openalex-snapshot
Total Synthesis of Thuggacin B
inferred← citeshttps://doi.org/10.1002/anie.200900264openalex-snapshot
Total Synthesis of Sporolide B
inferred← citeshttps://doi.org/10.1002/anie.201007644openalex-snapshot
Total Syntheses of Guanacastepenes N and O
inferred← citeshttps://doi.org/10.1002/anie.201101562openalex-snapshot
Total Synthesis of Bryostatin 1: A Short Route
inferred← citeshttps://doi.org/10.1002/anie.201101741openalex-snapshot
Total Synthesis of Dinophysistoxin‐2 and 2‐epi‐Dinophysistoxin‐2 and Their PPase Inhibition
inferred← citeshttps://doi.org/10.1002/anie.201103293openalex-snapshot
Amino Acid‐Based Reoxidants for Aminohydroxylation: Application to the Construction of Amino Acid–Amino Alcohol Conjugates
inferred← citeshttps://doi.org/10.1002/anie.201106205openalex-snapshot
Enantioselective Total Syntheses of Communesins A and B
inferred← citeshttps://doi.org/10.1002/anie.201203176openalex-snapshot
Total Synthesis of (−)‐Jiadifenin
inferred← citeshttps://doi.org/10.1002/anie.201208103openalex-snapshot
Combinatorial Nucleoside‐Deletion‐Scanning Mutagenesis of Functional DNA
inferred← citeshttps://doi.org/10.1002/anie.201501505openalex-snapshot
Tandem Z‐Selective Cross‐Metathesis/Dihydroxylation: Synthesis of anti‐1,2‐Diols
inferred← citeshttps://doi.org/10.1002/anie.201507304openalex-snapshot
A Concise and Highly Enantioselective Total Synthesis of (+)‐anti‐ and (−)‐syn‐Mefloquine Hydrochloride: Definitive Absolute Stereochemical Assignment of the Mefloquines
inferred← citeshttps://doi.org/10.1002/anie.201608752openalex-snapshot
Catalytic Enantioselective and Diastereoselective Allylic Alkylation with Fluoroenolates: Efficient Access to C3‐Fluorinated and All‐Carbon Quaternary Oxindoles
inferred← citeshttps://doi.org/10.1002/anie.201609253openalex-snapshot
Stereocontrolled Total Syntheses of (−)‐Rotenone and (−)‐Dalpanol by 1,2‐Rearrangement and SNAr Oxycyclizations
inferred← citeshttps://doi.org/10.1002/anie.201708435openalex-snapshot
Asymmetric Intermolecular Heck Reaction of Propargylic Acetates and Cycloalkenes to Access Fused Cyclobutenes
inferred← citeshttps://doi.org/10.1002/anie.201812284openalex-snapshot
External Reversal of Chirality Transfer in Photoswitches
inferred← citeshttps://doi.org/10.1002/anie.201906872openalex-snapshot
Total Synthesis of 1‐Hydroxytaxinine
inferred← citeshttps://doi.org/10.1002/anie.201914101openalex-snapshot
Triple‐Helix‐Stabilizing Effects in Collagen Model Peptides Containing PPII‐Helix‐Preorganized Diproline Modules
inferred← citeshttps://doi.org/10.1002/anie.202002484openalex-snapshot
Catalytic Behavior of Mono‐N‐Protected Amino‐Acid Ligands in Ligand‐Accelerated C−H Activation by Palladium(II)
inferred← citeshttps://doi.org/10.1002/anie.202002866openalex-snapshot
Iron‐Catalyzed Highly Enantioselective cis‐Dihydroxylation of Trisubstituted Alkenes with Aqueous H2O2
inferred← citeshttps://doi.org/10.1002/anie.202203239openalex-snapshot
Total Synthesis of Starfish Cyclic Steroid Glycosides
inferred← citeshttps://doi.org/10.1002/anie.202204907openalex-snapshot
Total Synthesis of Complex Peptidyl Nucleoside Antibiotics: Asymmetric De Novo Syntheses of Miharamycin B and Its Biosynthetic Precursor
inferred← citeshttps://doi.org/10.1002/aoc.5669openalex-snapshot
Oxidation of benzyl alcohol by novel peripherally and non‐peripherally modular C2‐symmetric diol substituted cobalt (II) phthalocyanines
inferred← citeshttps://doi.org/10.1002/asia.200600310openalex-snapshot
Total Synthesis of Lactacystin and Salinosporamide A
inferred← citeshttps://doi.org/10.1002/asia.200900634openalex-snapshot
New Approaches to the Total Synthesis of the Bryostatin Antitumor Macrolides
inferred← citeshttps://doi.org/10.1002/asia.201601487openalex-snapshot
High‐Throughput Synthetic Chemistry Enabled by Organic Solvent Disintegrating Tablet
inferred← citeshttps://doi.org/10.1002/cber.19961290113openalex-snapshot
Synthesis of Novel Tridentate N,O,S and N,N,O Ligands of the Tripod Type in Racemic and Enantiomerically Pure Form
inferred← citeshttps://doi.org/10.1002/cbic.201402339openalex-snapshot
Polymer Enzyme Conjugates as Chiral Ligands for Sharpless Dihydroxylation of Alkenes in Organic Solvents
inferred← citeshttps://doi.org/10.1002/cbic.201800587openalex-snapshot
Design and Synthesis of Metabolically Stable tRNA Synthetase Inhibitors Derived from Cladosporin
inferred← citeshttps://doi.org/10.1002/cbic.202100250openalex-snapshot
Chemical Synthesis of Side‐Chain‐Hydroxylated Vitamin D3 Derivatives and Their Metabolism by CYP27B1
inferred← citeshttps://doi.org/10.1002/cbic.202500200openalex-snapshot
Diversity of ThDP‐Dependent Enzymes Forming Chiral Tertiary Alcohols
inferred← citeshttps://doi.org/10.1002/cctc.201000295openalex-snapshot
Chemoenzymatic One‐Pot Synthesis of both (R)‐ and (S)‐Aryl‐1,2‐ethanediols
inferred← citeshttps://doi.org/10.1002/cctc.201300880openalex-snapshot
Whole‐Cell Teabag Catalysis for the Modularisation of Synthetic Enzyme Cascades in Micro‐Aqueous Systems
inferred← citeshttps://doi.org/10.1002/cctc.201501083openalex-snapshot
Optimization of and Mechanistic Considerations for the Enantioselective Dihydroxylation of Styrene Catalyzed by Osmate‐Laccase‐Poly(2‐Methyloxazoline) in Organic Solvents
inferred← citeshttps://doi.org/10.1002/cctc.201901189openalex-snapshot
One‐Pot Three‐Step Consecutive Transformation of L‐α‐Amino Acids to (R)‐ and (S)‐Vicinal 1,2‐Diols via Combined Chemical and Biocatalytic Process
inferred← citeshttps://doi.org/10.1002/cctc.202000959openalex-snapshot
Transformations of bio‐sourced 4‐hydroxyphenylpropanoids based on olefin metathesis
inferred← citeshttps://doi.org/10.1002/chem.19950010106openalex-snapshot
Studies of Allylic Substitution Catalysed by a Palladium Complex of a C2‐Symmetric Bis(aziridine): Preparation and NMR Spectroscopic Investigation of a Chiral π‐Allyl Species
inferred← citeshttps://doi.org/10.1002/chem.19950010712openalex-snapshot
Synthesis of Zaragozic Acid A/Squalestatin S1
inferred← citeshttps://doi.org/10.1002/chem.19970031123openalex-snapshot
Asymmetric Addition Reactions with Optimized Selenium Electrophiles
inferred← citeshttps://doi.org/10.1002/chem.200304828openalex-snapshot
MTO and OsO4: An Efficient Catalytic Couple for Mild H2O2‐Based Asymmetric Dihydroxylation of Olefins
inferred← citeshttps://doi.org/10.1002/chem.200400904openalex-snapshot
A General Method for the Synthesis of Bastaranes and Isobastaranes: First Total Synthesis of Bastadins 5, 10, 12, 16, 20, and 21
inferred← citeshttps://doi.org/10.1002/chem.200500095openalex-snapshot
An Electrophilic Cleavage Procedure for the Asymmetric Dihydroxylation: Direct Enantioselective Synthesis of Cyclic Boronic Esters from Olefins
inferred← citeshttps://doi.org/10.1002/chem.200501274openalex-snapshot
Total Synthesis and NMR Investigations of Cylindramide
inferred← citeshttps://doi.org/10.1002/chem.200801656openalex-snapshot
Total Synthesis of Rapamycin
inferred← citeshttps://doi.org/10.1002/chem.201001085openalex-snapshot
A Synthetic Entry into the Taiwaniaquinoids Based on a Biogenetic Hypothesis: Total Synthesis of (−)‐Taiwaniaquinone H
inferred← citeshttps://doi.org/10.1002/chem.201002898openalex-snapshot
Total Synthesis of Bryostatins: The Development of Methodology for the Atom‐Economic and Stereoselective Synthesis of the Ring C Subunit
inferred← citeshttps://doi.org/10.1002/chem.201003320openalex-snapshot
Synthesis and Conformational Analysis of α,β‐Difluoro‐γ‐amino Acid Derivatives
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