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Conversion of aliphatic amides into amines with [I,I-bis(trifluoroacetoxy)iodo]benzene. 1. Scope of the reaction

https://doi.org/10.1021/jo00196a031
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B
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Iodine(III)-Promoted Ring Contraction of 1,2-Dihydronaphthalenes: A Diastereoselective Total Synthesis of (±)-Indatraline
inferred← citeshttps://doi.org/10.1021/ol101993qopenalex-snapshot
Hofmann Rearrangement of Carboxamides Mediated by Hypervalent Iodine Species Generated in Situ from Iodobenzene and Oxone: Reaction Scope and Limitations
inferred← citeshttps://doi.org/10.1021/ol991264xopenalex-snapshot
The Total Synthesis of Pantocin B
inferred← citeshttps://doi.org/10.1021/op2000207openalex-snapshot
An Efficient Process for the Manufacture of Carmegliptin
inferred← citeshttps://doi.org/10.1038/s41557-025-01848-2openalex-snapshot
Accessing sulfonamides via formal SO2 insertion into C–N bonds
inferred← citeshttps://doi.org/10.1038/s41557-025-01904-xopenalex-snapshot
Carbon-to-nitrogen atom swap enables direct access to benzimidazoles from drug-like indoles
inferred← citeshttps://doi.org/10.1039/a808466aopenalex-snapshot
Novel metal complex synthons for chiral 4-azaleucine, 2,3-diaminopropanoic acid and its elaboration
inferred← citeshttps://doi.org/10.1039/a904126eopenalex-snapshot
New reaction conditions using trifluoroethanol for the E-I Hofmann rearrangement
inferred← citeshttps://doi.org/10.1039/a909898dopenalex-snapshot
Synthetic studies on the pederin family of antitumour agents. Syntheses of mycalamide B, theopederin D and pederin
inferred← citeshttps://doi.org/10.1039/b415543bopenalex-snapshot
Design and synthesis of a new class of arginine analogues with an improved anion binding site in the side chain
inferred← citeshttps://doi.org/10.1039/b801909fopenalex-snapshot
Synthesis of imidazolidin-2-one-4-carboxylate and of (tetrahydro)pyrimidin-2-one-5-carboxylate via an efficient modification of the Hofmann rearrangement
inferred← citeshttps://doi.org/10.1039/b914580jopenalex-snapshot
The coumarin→indole transformation—a method for preparing 4-halo-5-hydroxyindoles from coumarins
inferred← citeshttps://doi.org/10.1039/b922033jopenalex-snapshot
Hypervalent N-sulfonylimino-λ3-bromane: active nitrenoid species at ambient temperature under metal-free conditions
inferred← citeshttps://doi.org/10.1039/c1np00028dopenalex-snapshot
Hypervalent iodine reagents in the total synthesis of natural products
inferred← citeshttps://doi.org/10.1039/c2cc16360hopenalex-snapshot
A catalytic version of hypervalent aryl-λ 3 -iodane-induced Hofmann rearrangement of primary carboxamides: iodobenzene as an organocatalyst and m-chloroperbenzoic acid as a terminal oxidant
inferred← citeshttps://doi.org/10.1039/c3cy00934copenalex-snapshot
Rearrangement of aldoximes to amides in water under air atmosphere catalyzed by water-soluble iridium complex [Cp*Ir(H 2 O) 3 ][OTf] 2
inferred← citeshttps://doi.org/10.1039/c4nj01668hopenalex-snapshot
Synthesis of unsymmetrical phenylurea derivatives via oxidative cross coupling of aryl formamides with amines under metal-free conditions
inferred← citeshttps://doi.org/10.1039/c7cc05160copenalex-snapshot
Iodoarene-catalyzed oxidative transformations using molecular oxygen
inferred← citeshttps://doi.org/10.1039/cc9960001933openalex-snapshot
Synthesis and nucleophilic substitution of allenyl(m-nitrophenyl)iodanes as a new propynyl cation-equivalent species: synthesis of propynyl ethers, esters, and amides
inferred← citeshttps://doi.org/10.1039/d0cc05354fopenalex-snapshot
Hypervalent iodine reagent-mediated reactions involving rearrangement processes
inferred← citeshttps://doi.org/10.1039/d0ce00368aopenalex-snapshot
A crystalline solid adduct of sulfathiazole–amantadine: the first dual-drug molecular salt containing both antiviral and antibacterial ingredients
inferred← citeshttps://doi.org/10.1039/d1ce00382hopenalex-snapshot
Molecular adduct of amantadine ferulate presents a pathway for slowing in vitro / vivo releases and raising synergistic antiviral effects via dual optimization salification strategy
inferred← citeshttps://doi.org/10.1039/d1nj03160kopenalex-snapshot
Synthesis of unsymmetrical urea from aryl- or pyridyl carboxamides and aminopyridines using PhI(OAc) 2 via in situ formation of aryl- or pyridyl isocyanates
inferred← citeshttps://doi.org/10.1039/d3ob01964kopenalex-snapshot
Phenyliodine bis(trifluoroacetate) as a sustainable reagent: exploring its significance in organic synthesis
inferred← citeshttps://doi.org/10.1039/d5qo00173kopenalex-snapshot
Iron-catalyzed regioselective carboazidation of alkenes for the synthesis of multi-substituted cyclobutylamines
inferred← citeshttps://doi.org/10.1039/p19920002633openalex-snapshot
Synthesis of two 6′α-fluorocarbocyclic nucleosides and incorporation into short segments of DNA
inferred← citeshttps://doi.org/10.1055/s-0040-1707103openalex-snapshot
A Straightforward Synthesis of N-Substituted Ureas from Primary Amides
inferred← citeshttps://doi.org/10.1080/00397910701877608openalex-snapshot
Fast and Efficient Access to a Family of Multifunctional 1,3,5-Trisubstituted Piperidines
inferred← citeshttps://doi.org/10.1080/00397910802398256openalex-snapshot
Novel Route toN-Acyl-N′-formyl Aminal
inferred← citeshttps://doi.org/10.1080/00397910903097229openalex-snapshot
Convenient, Solvent-Free Method for Preparation of [Hydroxy(phosphoryloxy)iodo]arenes
inferred← citeshttps://doi.org/10.1080/00397918808081322openalex-snapshot
Synthesis of Aliphatic Amines Related to Monodansylcadaverine Via the Oxidative Rearrangement of Aliphatic Amides with Phenyl Iodosyl Bis(Trifluoroacetate)
inferred← citeshttps://doi.org/10.1080/07328319008045192openalex-snapshot
5′-C-Chain-Extended Adenosine Derivatives Related to Sinefungin. Synthesis and Biological Activity
inferred← citeshttps://doi.org/10.1080/07328319608007381openalex-snapshot
Relationship Between Chemical Structure and Antileishmanial Effect of Sinefungine Analogues
inferred← citeshttps://doi.org/10.1081/scc-120021988openalex-snapshot
Conversion of a Ketone to a Geminal Bisacetamide: Synthesis of 1,1-Bisacetamidocyclohexane
inferred← citeshttps://doi.org/10.1111/j.1399-3011.1990.tb01300.xopenalex-snapshot
Cyclic hexapeptides related to somatostatin Synthesis and biological testing
inferred← citeshttps://doi.org/10.1111/j.1399-3011.2005.00224.xopenalex-snapshot
Exploring the stereochemical requirements for protease inhibition by ureidopeptides
inferred← citeshttps://doi.org/10.1246/bcsj.79.142openalex-snapshot
Direct and Convenient Synthesis of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes
inferred← citeshttps://doi.org/10.24820/ark.5550190.p010.975openalex-snapshot
Iodonium imides in organic synthesis
inferred← citeshttps://doi.org/10.3390/molecules16119421openalex-snapshot
Indatraline: Synthesis and Effect on the Motor Activity of Wistar Rats
inferred← citeshttps://doi.org/10.3987/com-18-s(f)43openalex-snapshot
[Bis(trifluoroacetoxy)iodo]p-nitrobenzene and [Bis(trifluoroacetoxy)iodo]pentafluorobenzene as Lead Reagents for the Direct Ring Contraction of Lactams to Pyrrolidines
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