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Synthesis of Heteroaryl Compounds through Cross-Coupling Reaction of Aryl Bromides or Benzyl Halides with Thienyl and Pyridyl Aluminum Reagents

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Extremely Efficient Cross‐Coupling of Benzylic Halides with Aryltitanium Tris(isopropoxide) Catalyzed by Low Loadings of a Simple Palladium(II) Acetate/Tris(p‐tolyl)phosphine System
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Nickel‐Catalyzed Cross‐Coupling of Arene‐ or Heteroarenecarbonitriles with Aryl‐ or Heteroarylmanganese Reagents through CCN Bond Activation
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Iron‐Catalyzed Aryl–Aryl Cross‐Couplings with Magnesium‐Derived Copper Reagents
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A Versatile Method for Suzuki Cross‐Coupling Reactions of Nitrogen Heterocycles
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A Highly Active Catalyst for Suzuki–Miyaura Cross‐Coupling Reactions of Heteroaryl Compounds
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Palladium‐Catalyzed 2‐Pyridylmethyl Transfer from 2‐(2‐Pyridyl)ethanol Derivatives to Organic Halides by Chelation‐Assisted Cleavage of Unstrained CC Bonds
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Highly Enantioselective Aryl Additions of [AlAr3(thf)] to Ketones Catalyzed by a Titanium(IV) Catalyst of (S)‐Binol
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A General and Efficient Method for the Suzuki–Miyaura Coupling of 2‐Pyridyl Nucleophiles
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C(aryl)O Activation of Aryl Carboxylates in Nickel‐Catalyzed Biaryl Syntheses
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Pd‐PEPPSI‐IPent: Low‐Temperature Negishi Cross‐Coupling for the Preparation of Highly Functionalized, Tetra‐ortho‐Substituted Biaryls
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Direct Synthesis of 1,4‐Disubstituted‐5‐alumino‐1,2,3‐triazoles: Copper‐Catalyzed Cycloaddition of Organic Azides and Mixed Aluminum Acetylides
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Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Aryl Alanes to Trisubstituted Enones: Binap as an Effective Ligand in the Formation of Quaternary Stereocenters
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Highly Diastereoselective Iron‐Mediated C(sp2)C(sp3) Cross‐Coupling Reactions between Aryl Grignard Reagents and Cyclic Iodohydrine Derivatives
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Magical Power of Transition Metals: Past, Present, and Future (Nobel Lecture)
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Practical One‐Pot Preparation of Magnesium Di(hetero)aryl‐ and Magnesium Dialkenylboronates for Suzuki–Miyaura Cross‐Coupling Reactions
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Enantioselective Copper‐Catalyzed Conjugate Addition of Trimethylaluminium to β,γ‐Unsaturated α‐Ketoesters
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Improved Air‐Stable Solid Aromatic and Heterocyclic Zinc Reagents by Highly Selective Metalations for Negishi Cross‐Couplings
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Direct Pd‐Catalyzed Cross‐Coupling of Functionalized Organoaluminum Reagents
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Highly Reactive, Single‐Component Nickel Catalyst Precursor for Suzuki–Miyuara Cross‐Coupling of Heteroaryl Boronic Acids with Heteroaryl Halides
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Biaryls Made Easy: PEPPSI and the Kumada–Tamao–Corriu Reaction
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Highly Efficient Suzuki–Miyaura Coupling of Heterocyclic Substrates through Rational Reaction Design
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An Efficient Low‐Temperature Stille–Migita Cross‐Coupling Reaction for Heteroaromatic Compounds by Pd–PEPPSI–IPent
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Kumada–Corriu Cross‐Couplings with 2‐Pyridyl Grignard Reagents
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Recent Progress in Coupling of Two Heteroarenes
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Unusual products from the synthesis of 3‐(2‐phenylethyl)pyridines by the hydrosulfite reduction of nitrosamines
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Organoaluminum Couplings to Carbonyls, Imines, and Halides
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Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex
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Preliminary in vitro studies on two potent, water-soluble trimethoprim analogues with exceptional species selectivity against dihydrofolate reductase from Pneumocystis carinii and Mycobacterium avium
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2-Pyridyl and 3-pyridylzinc bromides: direct preparation and coupling reaction
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Facile synthesis of 3-arylpyridine derivatives by palladacycle-catalyzed Stille cross-coupling reaction
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Negishi coupling of 2-pyridylzinc bromide—paradigm shift in cross-coupling chemistry?
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Functional polypyridine ligands from copper-mediated room temperature coupling of 4-chloro-2-trimethylsilylpyridine
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Facile preparation of highly-functionalized, nitrogen-bearing diarylmethanes
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Palladium- or nickel-catalyzed cross coupling. A new selective method for carbon-carbon bond formation
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Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands
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The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)3 and PCy3 as Ligands
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Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds
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Iron-Catalyzed Reactions in Organic Synthesis
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Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners
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Synthetic Principles for Bandgap Control in Linear π-Conjugated Systems
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The First General Method for Palladium-Catalyzed Negishi Cross-Coupling of Aryl and Vinyl Chlorides: Use of Commercially Available Pd(P(t-Bu)3)2as a Catalyst
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A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides
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Pd/P(t-Bu)3: A Mild and General Catalyst for Stille Reactions of Aryl Chlorides and Aryl Bromides
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Room-Temperature Hiyama Cross-Couplings of Arylsilanes with Alkyl Bromides and Iodides
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A Solution to the 2-Pyridyl Organometallic Cross-Coupling Problem: Regioselective Catalytic Direct Arylation of Pyridine N-Oxides
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Remarkably Efficient Enantioselective Titanium(IV)−(R)-H8-BINOLate Catalyst for Arylations to Aldehydes by Triaryl(tetrahydrofuran)aluminum Reagents
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Highly Efficient Monophosphine-Based Catalyst for the Palladium-Catalyzed Suzuki−Miyaura Reaction of Heteroaryl Halides and Heteroaryl Boronic Acids and Esters
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Elements of Regiocontrol in Palladium-Catalyzed Oxidative Arene Cross-Coupling
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Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryl)acetates with Aryl Halides and Triflates
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Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts
inferredcites →https://doi.org/10.1021/ja8056503openalex-snapshot
Biaryl Construction via Ni-Catalyzed C−O Activation of Phenolic Carboxylates
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Hydroxyphosphine Ligand for Nickel-Catalyzed Cross-Coupling through Nickel/Magnesium Bimetallic Cooperation
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Inhibition of Myeloperoxidase Release from Rat Polymorphonuclear Leukocytes by a Series of Azachalcone Derivatives
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Rational Design and Synthesis of Novel Dimeric Diketoacid-Containing Inhibitors of HIV-1 Integrase: Implication for Binding to Two Metal Ions on the Active Site of Integrase
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Structure−Selectivity Investigations of D2-Like Receptor Ligands by CoMFA and CoMSIA Guiding the Discovery of D3Selective PET Radioligands
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Palladium-Catalyzed Aryl−Aryl Cross-Coupling Reaction Using ortho -Substituted Arylindium Reagents †
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Direct Arylation of Arene and N-Heteroarenes with Diaryliodonium Salts without the Use of Transition Metal Catalyst
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One-Pot Synthesis of Symmetrical and Unsymmetrical Diarylmethanes via Diborylmethane
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Scope of the Suzuki−Miyaura Cross-Coupling Reactions of Potassium Heteroaryltrifluoroborates
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Highly Enantioselective Arylation of Aldehydes and Ketones Using AlArEt2(THF) as Aryl Sources
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Scandium(III) Triflate-Catalyzed Friedel−Crafts Alkylation Reactions
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Unusual C-6 Lithiation of 2-Chloropyridine-Mediated by BuLi−Me2N(CH2)2OLi. New Access to 6-Functional-2-chloropyridines and Chloro-bis-heterocycles
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inferredcites →https://doi.org/10.1021/ol051929xopenalex-snapshot
Palladium-Catalyzed Cross-Coupling of B-Benzyl-9-borabicyclo[3.3.1]nonane To Furnish Methylene-Linked Biaryls
inferredcites →https://doi.org/10.1021/ol053165ropenalex-snapshot
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inferredcites →https://doi.org/10.1021/ol060591jopenalex-snapshot
Suzuki Coupling of Oxazoles
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Iron-Catalyzed Cross-Coupling of N-Heterocyclic Chlorides and Bromides with Arylmagnesium Reagents
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Some regioselective cross-coupling reactions of halopyridines and halopyrimidines
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Analysis of the reactions used for the preparation of drug candidate molecules
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Synthesis of functionalised diarylmethanes via a cobalt-catalysed cross-coupling of arylzinc species with benzyl chlorides
inferredcites →https://doi.org/10.1039/b818961gopenalex-snapshot
Iron-catalysed Negishi coupling of benzylhalides and phosphates
inferredcites →https://doi.org/10.1039/b903646fopenalex-snapshot
Sterically demanding trialkylphosphines for palladium-catalyzed cross coupling reactions—alternatives to PtBu3
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Iron(iii) chloride in oxidative C–C coupling reactions
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The first iron-catalysed aluminium-variant Negishi coupling: critical effect of co-existing salts on the dynamic equilibrium of arylaluminium species and their reactivity
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Simple and efficient nickel-catalyzed cross-coupling reaction of alkynylalanes with benzylic and aryl bromides
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PdCl2(dppf)-catalyzed in situ coupling of 2-hydroxypyridines with aryl boronic acids mediated by PyBroP and the one-pot chemo- and regioselective construction of two distinct aryl–aryl bonds
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Metal-free arylation of benzene and pyridine promoted by amino-linked nitrogen heterocyclic carbenes
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ZrCl2(η-C5Me5)2-AlHCl2·(THF)2: efficient hydroalumination of terminal alkynes and cross-coupling of the derived alanes
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108. New therapeutic agents of the quinoline series. Part III. Methoxy-, hydroxy-, and alkyl-pyridylquinolines
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Cross-coupling between 3-Pyridylmagnesium Chlorides and Heteroaromatic Halides

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/ejoc.201601257openalex-snapshot
End‐Capping Groups for Small‐Molecule Organic Semiconducting Materials: Synthetic Investigation and Photovoltaic Applications through Direct C–H (Hetero)arylation
inferred← citeshttps://doi.org/10.1002/ejoc.201900130openalex-snapshot
Transition‐Metal‐Free Heterobiaryl Synthesis via Aryne Coupling
inferred← citeshttps://doi.org/10.1002/ejoc.202300594openalex-snapshot
Pyrazine Derivative as Supramolecular Host for Immobilization of Palladium Nanoparticles for Efficient Suzuki Coupling
inferred← citeshttps://doi.org/10.1007/s10562-024-04662-6openalex-snapshot
Nickel (II) imidazol-2-ylidine Complexes Supported Through Internally Functionalized Amido Linkage Synthesis and Catalytic Studies for Suzuki Miyaura Cross Coupling
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2015.01.009openalex-snapshot
Nickel-catalyzed one-pot synthesis of biaryls from phenols and arylboronic acids via C–O activation using TCT reagent
inferred← citeshttps://doi.org/10.1016/j.tet.2016.02.005openalex-snapshot
PBr3-mediated unexpected reductive deoxygenation of α-aryl-pyridinemethanols: synthesis of arylmethylpyridines
inferred← citeshttps://doi.org/10.1016/j.tet.2016.02.030openalex-snapshot
An approach to heterodiarylmethanes via sp2–sp3 Suzuki−Miyaura cross-coupling
inferred← citeshttps://doi.org/10.1016/j.tet.2017.06.004openalex-snapshot
Nickel-catalyzed cross-coupling of aryl or 2-menaphthyl quaternary ammonium triflates with organoaluminum reagents
inferred← citeshttps://doi.org/10.1016/j.tet.2018.08.050openalex-snapshot
Highly efficient synthesis of 1,2-disubstituted acetylenes derivatives from the cross-coupling reactions of 1-bromoalkynes with organoalane reagents
inferred← citeshttps://doi.org/10.1016/j.tet.2021.132549openalex-snapshot
Simple and efficient nickel-catalyzed cross-coupling reaction of alkenylalanes with alkynyl halides for synthesis of conjugated enynes
inferred← citeshttps://doi.org/10.1016/j.tet.2021.132564openalex-snapshot
Cross-coupling reaction of organoalane reagents with 2-mercaptobenzo-5-membered heterocycles for efficient synthesis of benzo-5-membered heterocycle sulfides
inferred← citeshttps://doi.org/10.1016/j.tet.2024.133850openalex-snapshot
Copper-assisted palladium catalyzed the cross-coupling reaction of Alknylalane reagents with 2-Thiobenzo[d]thiazoles via C–S bond cleavage
inferred← citeshttps://doi.org/10.1016/j.tet.2024.134089openalex-snapshot
Synthesis of the 2-alkynyl benzo[b]furanes/benzo[b]thiophenes from the cross-coupling reaction of benzo[b]furanyl/ benzo[b]thiophene aluminum reagents with gem-dibromoolefin derivatives catalyzed by palladium
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.05.083openalex-snapshot
Synthesis and structural characterization of a highly substituted triazine ring comprising a sterically flexible methylene linker and coordinating substituents
inferred← citeshttps://doi.org/10.1016/j.tetlet.2021.153516openalex-snapshot
Copper-catalyzed sp3-sp3 cross-coupling of turbo grignards with benzyl halides
inferred← citeshttps://doi.org/10.1016/j.tetlet.2024.155249openalex-snapshot
Coinage metal-catalyzed or-mediated oxidative heteroarylation of arenes
inferred← citeshttps://doi.org/10.1021/acs.joc.4c00252openalex-snapshot
Palladium-Catalyzed/Copper-Mediated Decarbonylative Cross-Coupling of S-Pyrimidyl Thioesters for Biaryl Synthesis
inferred← citeshttps://doi.org/10.1021/acs.joc.5b00767openalex-snapshot
Copper-Catalyzed Electrophilic Amination of Organoaluminum Nucleophiles with O-Benzoyl Hydroxylamines
inferred← citeshttps://doi.org/10.1021/acs.joc.5b01410openalex-snapshot
Asymmetric Addition of Pyridyl Aluminum Reagents to Aldehydes Catalyzed by a Titanium(IV) Catalytic System of (R)-H8-BINOLate
inferred← citeshttps://doi.org/10.1021/acs.joc.5b02077openalex-snapshot
General Copper-Catalyzed Coupling of Alkyl-, Aryl-, and Alkynylaluminum Reagents with Organohalides
inferred← citeshttps://doi.org/10.1021/acs.joc.5b02689openalex-snapshot
Synthesis of Benzothiadiazole Derivatives by Applying C–C Cross-Couplings
inferred← citeshttps://doi.org/10.1021/acs.joc.5c01924openalex-snapshot
Copper Catalyzed the Cross-Coupling Reaction of Arylthioaluminum Reagents with Alkynyl Bromides/Terminal Alkynes
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02498openalex-snapshot
Nickel-Catalyzed Cyanation of Phenol Derivatives with Zn(CN)2 Involving C–O Bond Cleavage
inferred← citeshttps://doi.org/10.1021/acs.joc.9b01103openalex-snapshot
Palladium-Catalyzed Decarbonylative Suzuki–Miyaura Coupling of Amides To Achieve Biaryls via C–N Bond Cleavage
inferred← citeshttps://doi.org/10.1021/acs.oprd.7b00185openalex-snapshot
Kumada–Corriu Heteroaryl Cross-Coupling for Synthesis of a Pharmaceutical Intermediate: Comparison of Batch Versus Continuous Reaction Modes
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c04175openalex-snapshot
A General and Selective Synthesis of Methylmonochlorosilanes from Di-, Tri-, and Tetrachlorosilanes
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b02323openalex-snapshot
Selective and Serial Suzuki–Miyaura Reactions of Polychlorinated Aromatics with Alkyl Pinacol Boronic Esters
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b02933openalex-snapshot
Transmetal-Catalyzed Enantioselective Cross-Coupling Reaction of Racemic Secondary Benzylic Bromides with Organoaluminum Reagents
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b02923openalex-snapshot
Palladium-Catalyzed Carbonylative Coupling of Aryl Iodides with Alkenylaluminum Reagents
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b04117openalex-snapshot
Continuous Flow Enables Metallaphotoredox Catalysis in a Medicinal Chemistry Setting: Accelerated Optimization and Library Execution of a Reductive Coupling between Benzylic Chlorides and Aryl Bromides
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b04414openalex-snapshot
Palladium-Catalyzed Synthesis of 1,2-Diketones from Aryl Halides and Organoaluminum Reagents Using tert-Butyl Isocyanide as the CO Source
inferred← citeshttps://doi.org/10.1021/acscatal.0c02805openalex-snapshot
N -(Hetero)arylations with Metalated (Hetero)aryls: Recent Advances in First-Row Transition-Metal-Mediated Cross-Couplings
inferred← citeshttps://doi.org/10.1021/acscatal.7b01058openalex-snapshot
Revisitation of Organoaluminum Reagents Affords a Versatile Protocol for C–X (X = N, O, F) Bond-Cleavage Cross-Coupling: A Systematic Study
inferred← citeshttps://doi.org/10.1021/jacs.1c06112openalex-snapshot
The Versatile Reaction Chemistry of an Alpha-Boryl Diazo Compound
inferred← citeshttps://doi.org/10.1021/ol503560eopenalex-snapshot
Nickel-Catalyzed One-Pot Deoxygenation and Reductive Homocoupling of Phenols via C–O Activation Using TCT Reagent
inferred← citeshttps://doi.org/10.1039/c5ra09257dopenalex-snapshot
An efficient and metal free synthesis of benzylpyridines using HI through the deoxygenation reaction
inferred← citeshttps://doi.org/10.1039/c6nj02560aopenalex-snapshot
Benzylation of heterocyclic N-oxides via direct oxidative cross-dehydrogenative coupling with toluene derivatives
inferred← citeshttps://doi.org/10.1039/c7cc00997fopenalex-snapshot
Exhaustive Suzuki–Miyaura reactions of polyhalogenated heteroarenes with alkyl boronic pinacol esters
inferred← citeshttps://doi.org/10.1039/c8ra07013jopenalex-snapshot
l -Proline catalyzed one-pot synthesis of polysubstituted pyridine system incorporating benzothiazole moiety via sustainable sonochemical approach
inferred← citeshttps://doi.org/10.1039/d0ra02984jopenalex-snapshot
Palladium-catalyzed cross-coupling reaction of alkenyl aluminums with 2-bromobenzo[ b ]furans
inferred← citeshttps://doi.org/10.1039/d3nj02026fopenalex-snapshot
The cross-coupling reaction of organoalane reagents with 2-methylthiobenzo[ d ]thiazoles via C–S bond cleavage catalyzed by nickel
inferred← citeshttps://doi.org/10.1126/science.aac6936openalex-snapshot
Sustainable Fe–ppm Pd nanoparticle catalysis of Suzuki-Miyaura cross-couplings in water
inferred← citeshttps://doi.org/10.1134/s1070363218040333openalex-snapshot
Arylation of Pyridine with 9,10-Dioxoanthracenyl-1(2)-diazonium Hydrosulfates
inferred← citeshttps://doi.org/10.3390/catal9030300openalex-snapshot
Suzuki–Miyaura Coupling Using Monolithic Pd Reactors and Scaling-Up by Series Connection of the Reactors
inferred← citeshttps://doi.org/10.3390/molecules29030576openalex-snapshot
Recent Progress on the Synthesis of Bipyridine Derivatives
inferred← citeshttps://doi.org/10.3762/bjoc.11.226openalex-snapshot
Copper-mediated synthesis of N -alkenyl-α,β-unsaturated nitrones and their conversion to tri- and tetrasubstituted pyridines
inferred← citeshttps://doi.org/10.3762/bjoc.11.261openalex-snapshot
Copper-catalyzed arylation of alkyl halides with arylaluminum reagents
inferred← citeshttps://doi.org/10.3762/bjoc.12.10openalex-snapshot
Hydroquinone–pyrrole dyads with varied linkers
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