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Total Syntheses of (+)- and (−)-Pestalotiopsin A

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/1099-0690(200010)2000:20<3381::aid-ejoc3381>3.0.co;2-qopenalex-snapshot
Uncatalyzed, Solvent-Free [2+2] Cycloaddition of Cyclic Ketene Trimethylsilyl Acetals with Electrophilic Acetylenes
inferredcites →https://doi.org/10.1002/anie.200800253openalex-snapshot
Total Synthesis of (−)‐Pestalotiopsin A
inferredcites →https://doi.org/10.1002/anie.200800574openalex-snapshot
Oxazaborolidines as Catalysts for Enantioselective Cycloadditions: Now [2+2]!
inferredcites →https://doi.org/10.1002/anie.200801900openalex-snapshot
Synthesis and Reactions of the Pestalotiopsin Skeleton
inferredcites →https://doi.org/10.1002/jlac.1992199201186openalex-snapshot
Selective Acetate Hydrolysis of Diastereomers with Porcine Pancreatic lipase (PPL) as an Access to Useful Chiral Building Blocks
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Stable and reactive conformations of N-enoyl-bornane-10.2-sultams in the absence of lewis acids : asymmetric 1.4-hydride additions
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Synthesis of an enantiomerically pure 2,2,4-trisubstituted cyclobutanone building block by zirconocene-promoted deoxygenative ring contraction of structurally modified 4-vinylfuranosides
inferredcites →https://doi.org/10.1016/j.tetlet.2005.06.133openalex-snapshot
Synthetic studies of pestalotiopsin A: asymmetric synthesis of the 2-oxabicyclo[3.2.0]heptane substructure
inferredcites →https://doi.org/10.1016/s0022-328x(00)90476-5openalex-snapshot
ketene bis(trialkylsilyl) acetals: synthesis, pyrolysis and spectral studies
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Metabolites of Pestalotiopsis spp., endophytic fungi of Taxus brevifolia
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Modern methods for the radical deoxygenation of alcohols
inferredcites →https://doi.org/10.1016/s0040-4039(00)82368-0openalex-snapshot
Reaction of ketenealkylsilylacetals with ethyl propiolate
inferredcites →https://doi.org/10.1016/s0040-4039(00)83972-6openalex-snapshot
Efficient asymmetric hydrogenations of camphor-soltam-imide-conjugated alkenes.
inferredcites →https://doi.org/10.1016/s0040-4039(00)85046-7openalex-snapshot
Asymmetric induction at C(β) and C(α) of N-enoyl sultams by 1,4-hydride addition/enolate trapping
inferredcites →https://doi.org/10.1016/s0040-4039(00)93615-3openalex-snapshot
Reductive displacement of allylic acetates by hydride transfer via catalytic activation by palladium(0) complexes
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Palladium catalyzed selective formation of homogannular conjugated dienes from allylic esters in decalin derivatives. And its application to the synthesis of 1-α-hydroxy-provitamin D3.
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Conformational aspects of caryophyllene. Population of stable conformers and ring inversion barrier of trans cyclononene ring portion
inferredcites →https://doi.org/10.1016/s0957-4166(97)00167-5openalex-snapshot
A convenient preparation of N-(2-alkynoyl) derivatives of chiral oxazolidin-2-ones and bornane-10,2-sultam
inferredcites →https://doi.org/10.1021/cr00032a009openalex-snapshot
Catalytic Asymmetric Dihydroxylation
inferredcites →https://doi.org/10.1021/cr010010yopenalex-snapshot
The Application of Cyclobutane Derivatives in Organic Synthesis
inferredcites →https://doi.org/10.1021/cr010013aopenalex-snapshot
Enantiomerically Pure Cyclobutane Derivatives and Their Use in Organic Synthesis
inferredcites →https://doi.org/10.1021/cr9703360openalex-snapshot
Carbon−Carbon Bond Formations Involving Organochromium(III) Reagents
inferredcites →https://doi.org/10.1021/cr9902695openalex-snapshot
Metal-Catalyzed Hydrostannations
inferredcites →https://doi.org/10.1021/ja00019a027openalex-snapshot
A useful 12-I-5 triacetoxyperiodinane (the Dess-Martin periodinane) for the selective oxidation of primary or secondary alcohols and a variety of related 12-I-5 species
inferredcites →https://doi.org/10.1021/ja00198a045openalex-snapshot
Palladium-catalyzed selective hydrogenolysis of alkenyloxiranes with formic acid. Stereoselectivity and synthetic utility
inferredcites →https://doi.org/10.1021/ja00540a022openalex-snapshot
Total synthesis of (R)-glycerol acetonide and the antiepileptic and hypotensive drug (-)-.gamma.-amino-.beta.-hydroxybutyric acid (GABOB): use of vitamin C as a chiral starting material
inferredcites →https://doi.org/10.1021/ja00886a037openalex-snapshot
Total Synthesis of d,l-Caryophyllene and d,l-Isocaryophyllene
inferredcites →https://doi.org/10.1021/ja01057a040openalex-snapshot
Total Synthesis of d,l-Caryophyllene and d,l-Isocaryophyllene
inferredcites →https://doi.org/10.1021/ja01148a002openalex-snapshot
Ketene Acetals. XXIII. Dealcoholation of Orthoesters with Aluminum t-Butoxide
inferredcites →https://doi.org/10.1021/ja066336bopenalex-snapshot
Total Synthesis of Antheliolide A
inferredcites →https://doi.org/10.1021/ja8003705openalex-snapshot
An Unconventional Approach to the Enantioselective Synthesis of Caryophylloids
inferredcites →https://doi.org/10.1021/jo00062a040openalex-snapshot
An improved procedure for the preparation of the Dess-Martin periodinane
inferredcites →https://doi.org/10.1021/jo00170a070openalex-snapshot
Readily accessible 12-I-5 oxidant for the conversion of primary and secondary alcohols to aldehydes and ketones
inferredcites →https://doi.org/10.1021/jo00187a006openalex-snapshot
Medium-ring ketone synthesis. Total syntheses of (.+-.)-isocaryophyllene and (.+-.)-caryophyllene
inferredcites →https://doi.org/10.1021/jo00293a035openalex-snapshot
Palladium- and molybdenum-catalyzed hydrostannation of alkynes. A novel access to regio- and stereodefined vinylstannanes
inferredcites →https://doi.org/10.1021/jo00369a043openalex-snapshot
Regioselective removal of allylic nitro groups via hydride transfer
inferredcites →https://doi.org/10.1021/jo026827oopenalex-snapshot
The Remarkable Effect of Cosolvent on a Samarium(II)-Mediated 4-exo-trig Cyclization: Further Synthetic Studies on Pestalotiopsin A
inferredcites →https://doi.org/10.1021/jo070861ropenalex-snapshot
Pestalotiopsin A. Enantioselective Construction of Potential Building Blocks Derived from Antipodal Cyclobutanol Intermediates
inferredcites →https://doi.org/10.1021/jo070862jopenalex-snapshot
Pestalotiopsin A. Side Chain Installation and Exhaustive Probing of Olefin Metathesis as a Possible Tool for Elaborating the Cyclononene Ring
inferredcites →https://doi.org/10.1021/jo951736vopenalex-snapshot
Pestalotiopsins A and B: New Caryophyllenes from an Endophytic Fungus of Taxus brevifolia
inferredcites →https://doi.org/10.1021/jo9621581openalex-snapshot
Efficient and Facile Glycol Cleavage Oxidation Using Improved Silica Gel-Supported Sodium Metaperiodate
inferredcites →https://doi.org/10.1021/jo9710339openalex-snapshot
Radical Hydrostannylation, Pd(0)-Catalyzed Hydrostannylation, Stannylcupration of Propargyl Alcohols and Enynols: Regio- and Stereoselectivities
inferredcites →https://doi.org/10.1021/ol015976aopenalex-snapshot
Samarium(II)-Mediated 4-exo-trig Cyclization. A Stereocontrolled Approach to the Core of Pestalotiopsin A
inferredcites →https://doi.org/10.1021/ol020063hopenalex-snapshot
Diastereoselectivity Control in the Zirconocene-Mediated Ring Contraction of 4-Vinylfuranosides to Enantiopure Multiply Functionalized Cyclobutanes
inferredcites →https://doi.org/10.1039/a815187yopenalex-snapshot
Recent advances in the chemistry of caryophyllene
inferredcites →https://doi.org/10.1039/b209066jopenalex-snapshot
The first synthetic studies on pestalotiopsin A. A stereocontrolled approach to the functionalised bicyclic coreElectronic supplementary information (ESI) available: crystal structure analysis of 18a. See http://www.rsc.org/suppdata/ob/b2/b209066j/
inferredcites →https://doi.org/10.1039/b600677aopenalex-snapshot
Stereoselective synthesis of bicyclic lactones by annelation with functionalised orthoesters
inferredcites →https://doi.org/10.1039/c39890001344openalex-snapshot
Asymmetric construction of optically active 3-hydroxyalkyne functionalities
inferredcites →https://doi.org/10.1039/p19750001574openalex-snapshot
A new method for the deoxygenation of secondary alcohols
inferredcites →https://doi.org/10.1055/s-1989-27182openalex-snapshot
The Synthesis ofO-Silyl Ketene Acetals from α-Haloesters
inferredcites →https://doi.org/10.1055/s-1995-3847openalex-snapshot
Synthesis of Optically Active β,γ-Unsaturated α-Amino Acids and of α,β-Unsaturated γ-Amino Acids. SN2- vs. SN2’-Dichotomy of the Mitsunobu Amination of Allylic Alcohols
inferredcites →https://doi.org/10.1055/s-1996-4175openalex-snapshot
Palladium-Catalyzed Hydrogenolysis of Allylic and Propargylic Compounds with Various Hydrides
inferredcites →https://doi.org/10.1055/s-1999-3672openalex-snapshot
Recent Advances in Chromium(II)- and Chromium(III)-Mediated Organic Synthesis
inferredcites →https://doi.org/10.1126/science.8097061openalex-snapshot
Taxol and Taxane Production by Taxomyces andreanae , an Endophytic Fungus of Pacific Yew
inferredcites →https://doi.org/10.1246/bcsj.68.1683openalex-snapshot
Reaction of Ketene Alkyl Trimethylsilyl Acetals with Dimethyl Acetylenedicarboxylate Catalyzed with Zirconium Tetrachloride
inferredcites →https://doi.org/10.1515/znc-2003-5-605openalex-snapshot
Three Highly Oxygenated Caryophyllene Sesquiterpenes from Pestalotiopsis sp., a Fungus Isolated from Bark of Pinus taeda
inferredcites →https://doi.org/10.15227/orgsyn.072.0001openalex-snapshot
L-(S)-GLYCERALDEHYDE ACETONIDE
inferredcites →https://doi.org/10.3987/com-06-s(k)12openalex-snapshot
An Example of Overriding Cyanation during Reaction of a Primary Alcohol with o-Nitrophenyl Selenocyanate

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.1016/j.phytochem.2022.113569zenodo-depositor-declared
Caryophyllene sesquiterpenoids with various ring systems from the fungus Pestalotiopsis chamaeropis
inferred← citeshttps://doi.org/10.1002/9783527828166.ch4openalex-snapshot
Miscellaneous Reactions
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A Chiral N,N′‐Dioxide–ZnII Complex Catalyzes the Enantioselective [2+2] Cycloaddition of Alkynones with Cyclic Enol Silyl Ethers
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Total Syntheses of (+)‐Aquatolide and Related Humulanolides
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Die Totalsynthese von Isoxeniolid A**
inferred← citeshttps://doi.org/10.1002/anie.201600801openalex-snapshot
A Chiral N,N′‐Dioxide–ZnII Complex Catalyzes the Enantioselective [2+2] Cycloaddition of Alkynones with Cyclic Enol Silyl Ethers
inferred← citeshttps://doi.org/10.1002/anie.201904404openalex-snapshot
Total Syntheses of (+)‐Aquatolide and Related Humulanolides
inferred← citeshttps://doi.org/10.1002/anie.202315423openalex-snapshot
Total Synthesis of Isoxeniolide A**
inferred← citeshttps://doi.org/10.1002/asia.201800492openalex-snapshot
Nickel‐Catalyzed Asymmetric [2+2] Cycloaddition Reaction of Hetero‐Bicyclic Alkenes with Internal Alkynes
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9‐Membered Carbocycles: Strategies and Tactics for their Synthesis
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Five-Membered Ring Systems: With N and S (Se) Atoms
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ChemInform Abstract: Total Syntheses of (+)‐ and (‐)‐Pestalotiopsin A (I).
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Pericyclische Reaktionen
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Pericyclic Reactions
inferred← citeshttps://doi.org/10.1007/978-981-97-1619-7_13openalex-snapshot
Total Syntheses of (+)-Aquatolide and Related Humulanolides
inferred← citeshttps://doi.org/10.1007/s13659-012-0018-zopenalex-snapshot
Cytosporinols A-C, new caryophyllene sesquiterpenoids from Cytospora sp.
inferred← citeshttps://doi.org/10.1016/b978-0-08-096805-6.00009-7openalex-snapshot
Five-Membered Ring Systems
inferred← citeshttps://doi.org/10.1016/b978-0-12-417034-6.00009-8openalex-snapshot
Conjugate Addition III
inferred← citeshttps://doi.org/10.1016/b978-0-444-62615-8.00005-9openalex-snapshot
Recent Advances in the Synthetic Studies of Pestalotiopsin A and Related Caryophyllene-Type Sesquiterpenoids
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Cr(II)-promoted internal cyclization of acyclic enediynes fused to benzo[b]thiophene core: Macrocycles versus 2-methylenecycloalkan-1-ols formation
inferred← citeshttps://doi.org/10.1016/j.fitote.2015.12.003openalex-snapshot
Caryophyllene sesquiterpenoids from the endophytic fungus, Pestalotiopsis sp.
inferred← citeshttps://doi.org/10.1016/j.phytol.2016.05.001openalex-snapshot
New punctaporonins from two fungicolous isolates of Pestalotiopsis sp.
inferred← citeshttps://doi.org/10.1016/j.tchem.2024.100066openalex-snapshot
Inverse electron demand Diels-Alder reaction in total synthesis of bioactive natural products
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Synthesis of rumphellaone A via epoxy nitrile cyclization
inferred← citeshttps://doi.org/10.1016/s0959-6380(11)22009-9openalex-snapshot
Five-Membered Ring Systems
inferred← citeshttps://doi.org/10.1016/s1875-5364(20)30032-7openalex-snapshot
Caryophyllene-type sesquiterpenoids and α-furanones from the plant endophytic fungus Pestalotiopsis theae
inferred← citeshttps://doi.org/10.1021/acs.jnatprod.0c00501openalex-snapshot
Highly Oxygenated Caryophyllene-Type Sesquiterpenes from a Plant-Associated Fungus, Pestalotiopsis hainanensis, and Their Biosynthetic Gene Cluster
inferred← citeshttps://doi.org/10.1021/acs.jnatprod.2c01159openalex-snapshot
Caryophyllene Sesquiterpenes from a Chaetomium globosum Endophyte of the Canadian Medicinal Plant Empetrum nigrum
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00086openalex-snapshot
Total Synthesis of (+)-Vibsanin A
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b02080openalex-snapshot
Pestaloporonins: Caryophyllene-Derived Sesquiterpenoids from a Fungicolous Isolate of Pestalotiopsis sp.
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Enantioselective Construction of 6–10-Membered Cyclic Allylic Alcohols Containing Exocyclic Alkenes by Synergistic Photoredox/Cobalt-Catalyzed Intramolecular Alkenylation of Aldehydes
inferred← citeshttps://doi.org/10.1021/jacs.5b11438openalex-snapshot
Total Synthesis of (+)-Cytosporolide A via a Biomimetic Hetero-Diels–Alder Reaction
inferred← citeshttps://doi.org/10.1021/jacs.5c15423openalex-snapshot
Concise Enantioselective Total Synthesis of (+)-Punctaporonin U
inferred← citeshttps://doi.org/10.1021/np500110zopenalex-snapshot
Caryophyllene Sesquiterpenes from the Marine-Derived Fungus Ascotricha sp. ZJ-M-5 by the One Strain–Many Compounds Strategy
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Siloxy(trialkoxy)ethene undergoes regioselective [2+2] cycloaddition to ynones and ynoates en route to functionalized cyclobutenediones
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Asymmetric synthesis of potent chroman-based Rho kinase (ROCK-II) inhibitors
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Natural sesquiterpenoids
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The taxonomy, biology and chemistry of the fungal Pestalotiopsis genus
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Synthesis of chiral cyclobutanes via rhodium/diene-catalyzed asymmetric 1,4-addition: a dramatic ligand effect on the diastereoselectivity
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Tandem Prins/Wagner/Ritter process for the stereoselective synthesis of (3-oxabicyclo[4.2.0]octanyl)amide and (1-(5-aryltetrahydrofuran-3-yl)cyclobutyl)amide derivatives
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Recent advances in the application of Diels–Alder reactions involving o -quinodimethanes, aza- o -quinone methides and o -quinone methides in natural product total synthesis
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Naturally occurring [4 + 2] type terpenoid dimers: sources, bioactivities and total syntheses
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Synthetic Studies of Polycyclic Polyprenylated Acylphloroglucinols: Asymmetric Construction of a Cyclohexanone Moiety
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Sesquiterpenes: A Terpene Subclass with Multifaceted Bioactivities
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BIOLOGICALLY ACTIVE ALCOHOLS: CYCLIC ALCOHOLS
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New Bioactive Sesquiterpeniods From the Plant Endophytic Fungus Pestalotiopsis theae
inferred← citeshttps://doi.org/10.3389/fmicb.2023.1248896openalex-snapshot
Caryophyllene-type sesquiterpenes from the endophytic fungus Pestalotiopsis lespedezae through an OSMAC approach
inferred← citeshttps://doi.org/10.3390/molecules171113330openalex-snapshot
Asymmetric Construction of All-Carbon Quaternary Stereocenters by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol
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Challenges to the Synthesis of Structurally Unique Cyclic Skeletons and Application to Biologically Intriguing Natural Product Synthesis
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