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New Methods of Free-Radical Perfluoroalkylation of Aromatics and Alkenes. Absolute Rate Constants and Partial Rate Factors for the Homolytic Aromatic Substitution by n-Perfluorobutyl Radical

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Sulfur-Centered Reactive Intermediates in Chemistry and Biology
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The Invention of Radical Chain Reactions of Value in Organic Synthesis
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Free Radicals in Synthesis and Biology
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Synthetic Applications of the Polar Effects of the Substituents in Free-Radical Reactions
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Recent aspects of homolytic aromatic substitutions
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Recent progress in perfluoroalkylation by radical species with special reference to the use of bis(perfluoroalkanoyl) peroxides
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Synthesis of perfluoroalkylpyrroles by homolytic substitution with perfluoroalkyl radicals
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Structure, Reactivity, and Chemistry of Fluoroalkyl Radicals
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Absolute rate constants for some reactions of perfluoro-n-alkyl radicals in solution
inferredcites →https://doi.org/10.1021/ja00465a030openalex-snapshot
Radicals and scavengers. 7. Diffusion controlled scavenging of phenyl radicals and absolute rate constants of several phenyl radical reactions
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Nucleophilic character of the alkyl radicals. 16. Absolute rate constants and the reactivity-selectivity relationship in the homolytic aromatic alkylation
inferredcites →https://doi.org/10.1021/ja00974a035openalex-snapshot
Homolytic Aromatic Cyclohexylation
inferredcites →https://doi.org/10.1021/ja01505a059openalex-snapshot
PERFLUOROALKYLATION OF AROMATIC COMPOUNDS
inferredcites →https://doi.org/10.1021/jo01329a017openalex-snapshot
Nucleophilic character of alkyl radicals. 18. Absolute rate constants for the addition of primary alkyl radicals to conjugated olefins and 1,4-benzoquinone
inferredcites →https://doi.org/10.1039/c39850000234openalex-snapshot
Perfluoropropylation of aromatic compounds with bis(heptafluorobutyryl) peroxide
inferredcites →https://doi.org/10.1146/annurev.pc.33.100182.002425openalex-snapshot
Hydrocarbon Bond Dissociation Energies

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Synthesis of Proton-Conductive Perfluoro(Benzylphosphoric Acid)S Via Polymer Side Chain Phosphorylation
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Dibenzoyl Peroxide
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Dibenzoyl Peroxide
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Homolytic Aromatic Substitution
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Radical Arylations
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Homolytic Aromatic Substitutions
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Radical‐Based Arylation Methods
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Decarboxylative Perfluoroalkylation of Vinyl Bromides with Copper(I) Perfluorocarboxylato Complexes
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Condensed‐Phase, Halogen‐Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions
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Heterogeneous Platinum‐Catalyzed CH Perfluoroalkylation of Arenes and Heteroarenes
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Perfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl Source
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Direct Arene Trifluoromethylation Enabled by a High‐Valent CuIII−CF3Compound
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Modular Synthesis of Phenanthridine Derivatives by Oxidative Cyclization of 2‐Isocyanobiphenyls with Organoboron Reagents
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Taming Hot CF3 Radicals: Incrementally Tuned Families of Polyarene Electron Acceptors for Air‐Stable Molecular Optoelectronics
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Metal‐Free Photochemical Aromatic Perfluoroalkylation of α‐Cyano Arylacetates
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Condensed‐Phase, Halogen‐Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions
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Heterogeneous Platinum‐Catalyzed CH Perfluoroalkylation of Arenes and Heteroarenes
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Perfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl Source
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Direct Arene Trifluoromethylation Enabled by a High‐Valent CuIII−CF3Compound
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Enhancement of Neighbouring‐Group Participation in Cu0‐Promoted Cross‐Coupling gem‐Difluoromethylenation of Aryl/Alkenyl Halides with 1,3‐Azolic Difluoromethyl Bromides
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Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of CH Bond Functionalization
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Copper Causes Regiospecific Formation of C4F8‐Containing Six‐Membered Rings and their Defluorination/Aromatization to C4F4‐Containing Rings in Triphenylene/1,4‐C4F8I2 Reactions
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Photocatalytic/Cu‐Promoted C−H Activations: Visible‐light‐Induced ortho‐Selective Perfluoroalkylation of Benzamides
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Continuous Flow Homolytic Aromatic Substitution with Electrophilic Radicals: A Fast and Scalable Protocol for Trifluoromethylation
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Direct Perfluoroalkylation of C−H Bonds in (Hetero)arenes
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ChemInform Abstract: New Methods of Free‐Radical Perfluoroalkylation of Aromatics and Alkenes. Absolute Rate Constants and Partial Rate Factors for the Homolytic Aromatic Substitution by n‐Perfluorobutyl Radical.
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New, Simple and Selective Synthesis of Perfluoroalkylquinones by Perfluoroalkyl Radicals – Enthalpic and Polar Effects
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Heterogeneous Photoinduced Homolytic Aromatic Substitution of Electron‐Rich Arenes with Perfluoroalkyl Groups in Water and Aqueous Media – A Radical‐Ion Reaction
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A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arenediazonium Salts with RFCu(CH3CN) Complexes
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Understanding Polyarene Trifluoromethylation with Hot CF3 Radicals Using Corannulene
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Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? A Fruitful Interplay Anyway
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Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? – A Fruitful Interplay Anyway
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Thiophene Substitution Chemistry
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Bibliographical Backgrounds
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Fluorinated Thiophenes and Their Analogues
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Recent Advances in the Integrated Microflow Synthesis of Organofluorine Compounds
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Perfluoropolyether-Functionalized Carbon-Based Materials and Their Applications
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Trifluoromethylation of various aromatic compounds by CF3I in the presence of Fe(II) compound, H2O2 and dimethylsulfoxide
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Light-induced iodoperfluoroalkylation reactions of carbon–carbon multiple bonds in water
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Optimization of the synthesis of 4′-nonafluorobutylacetophenone by metal catalysed cross-coupling reaction
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Solution-phase perfluoroalkylation of C60 leads to efficient and selective synthesis of bis-perfluoroalkylated fullerenes
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Design and formulation of nanoemulsions using 2-(poly(hexafluoropropylene oxide)) perfluoropropyl benzene in combination with linear perfluoro(polyethylene glycol dimethyl ether)
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Cation-exchange fluoropolymer membranes with the conjugate acid of 2,3,5,6-tetrafluoroaniline as an alternative proton-exchange group
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Fluorinated Azaacenes: Efficient Syntheses, Structures, and Electrochemical Properties
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Reactions of difluoro-pentafluorosulfanyl-iodomethane (SF5CF2I) with electronically different types of alkenes
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Synthesis and performance comparison of perfluorobenzoic acid and perfluorobenzenesulfonic acid membranes
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Free-radical selective functionalization of 1,4-naphthoquinones by perfluorodiacyl peroxides
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Photochemical direct perfluoroalkylation of phenols
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Photochemical oxyfluoroalkylation of styrenes by the addition of perfluoroalkyl radicals in an atmosphere of oxygen
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Copper-Catalyzed Bromo-cyanomethylative Cyclization of Enynes
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Cu-Catalyzed Multicomponent Reaction of Styrenes, Perfluoroalkyl Halide, Alcohol, and tert-Butyl Hydroperoxide: One-Pot Synthesis of (Z)-β-Alkoxyperfluoroalkenone
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N-Heterocycle-Forming Amino/Carboperfluoroalkylations of Aminoalkenes by Using Perfluoro Acid Anhydrides: Mechanistic Studies and Applications Directed Toward Perfluoroalkylated Compound Libraries
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One-Step Formation of Bifunctionnal Aryl/Alkyl Grafted Films on Conducting Surfaces by the Reduction of Diazonium Salts in the Presence of Alkyl Iodides
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Organic Dye-Catalyzed Atom Transfer Radical Addition–Elimination (ATRE) Reaction for the Synthesis of Perfluoroalkylated Alkenes
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Visible-Light-Mediated Iodoperfluoroalkylation of Alkenes in Flow and Its Application to the Synthesis of a Key Fulvestrant Intermediate
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Highly Hydrophobic Carbon Black Obtained by Covalent Linkage of Perfluorocarbon and Perfluoropolyether Chains on the Carbon Surface
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