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From Valence Trapped to Valence Delocalized by Bridge State Modification in Bis(triarylamine) Radical Cations: Evaluation of Coupling Matrix Elements in a Three-Level System

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Optical transitions of symmetrical mixed-valence systems in the Class II–III transition regimeElectronic supplementary information (ESI) is available: derivation of eqn. (39c), table summarizing the relationships between band maxima and band widths predicted by the two-state model and table of…
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Quantum Study of the Absorption Spectroscopy of Bis(triarylamine) Radical Cations
inferred← citeshttps://doi.org/10.1021/jp8107705openalex-snapshot
Electron Paramagnetic Resonance Spectroscopy of Bis(triarylamine) Paracyclophanes as Model Compounds for the Intermolecular Charge-Transfer in Solid State Materials for Optoelectronic Applications
inferred← citeshttps://doi.org/10.1021/jp904799zopenalex-snapshot
Mixed Valence Character of Anionic Linear Beryllium Chains: A CAS-SCF and MR-CI Study
inferred← citeshttps://doi.org/10.1021/ol502594mopenalex-snapshot
Electrochromism of a Fused Acceptor–Donor–Acceptor Triad Covering Entire UV–vis and Near-Infrared Regions
inferred← citeshttps://doi.org/10.1021/om1010534openalex-snapshot
Spectroscopic and Computational Studies of the Ligand Redox Non-Innocence in Mono- and Binuclear Ruthenium Vinyl Complexes
inferred← citeshttps://doi.org/10.1021/om200712mopenalex-snapshot
Orbital Symmetry Control of Electronic Coupling in a Symmetrical, All-Carbon-Bridged “Mixed Valence” Compound: Synthesis, Spectroscopy, and Electronic Structure of [{Mo(dppe)(η-C7H7)}2(μ-C4)]n+ (n = 0, 1, or 2)
inferred← citeshttps://doi.org/10.1021/om4007455openalex-snapshot
Charge and Spin Confinement to the Amine Site in 3-Connected Triarylamine Vinyl Ruthenium Conjugates
inferred← citeshttps://doi.org/10.1021/om500029xopenalex-snapshot
Half-Wave Potential Splittings ΔE1/2as a Measure of Electronic Coupling in Mixed-Valent Systems: Triumphs and Defeats
inferred← citeshttps://doi.org/10.1021/om9002945openalex-snapshot
Charge Delocalization in a Heterobimetallic Ferrocene−(Vinyl)Ru(CO)Cl(PiPr3)2 System†Dedicated to Prof. Dr. Helmut Werner on the occasion of his 75th birthday
inferred← citeshttps://doi.org/10.1039/b604603gopenalex-snapshot
Mulliken–Hush analysis of a bis(triarylamine) mixed-valence system with a N⋯N distance of 28.7 Å
inferred← citeshttps://doi.org/10.1039/b909715eopenalex-snapshot
Mixed-valence interactions in triarylamine–gold–nanoparticle conjugates
inferred← citeshttps://doi.org/10.1039/c0dt01388aopenalex-snapshot
Polynuclear carbon-rich organometallic complexes: clarification of the role of the bridging ligand in the redox properties
inferred← citeshttps://doi.org/10.1039/c1cp21772kopenalex-snapshot
Computational and spectroscopic studies of organic mixed-valence compounds: where is the charge?
inferred← citeshttps://doi.org/10.1039/c1cs15061hopenalex-snapshot
M2δ to ligand π-conjugation: testbeds for current theories of mixed valence in ground and photoexcited states of molecular systems
inferred← citeshttps://doi.org/10.1039/c1jm12566dopenalex-snapshot
Photo-induced charge transfer and nonlinear absorption in dyads composed of a two-photon-absorbing donor and a perylene diimide acceptor
inferred← citeshttps://doi.org/10.1039/c3cs60481kopenalex-snapshot
Quantum-chemical insights into mixed-valence systems: within and beyond the Robin–Day scheme
inferred← citeshttps://doi.org/10.1039/c3sc50844gopenalex-snapshot
Charge transfer through cross-hyperconjugated versus cross-π-conjugated bridges: an intervalence charge transfer study
inferred← citeshttps://doi.org/10.1039/c4cc04885gopenalex-snapshot
A photoinduced mixed-valence state in an organic bis-triarylamine mixed-valence compound with an iridium-metal-bridge
inferred← citeshttps://doi.org/10.1039/c4cp05404kopenalex-snapshot
The influence of bridge-reduced state levels on the electron transfer within the 2,7-dinitroanthracene radical anion
inferred← citeshttps://doi.org/10.1039/c4ra07304eopenalex-snapshot
Acetylene-bridged dyes with high open circuit potential for dye-sensitized solar cells
inferred← citeshttps://doi.org/10.1039/c4ra12603copenalex-snapshot
UV-vis and EPR spectroelectrochemical investigations of triarylamine functionalized arylene bisimides
inferred← citeshttps://doi.org/10.1039/c6dt00109bopenalex-snapshot
Notable differences between oxidized diruthenium complexes bridged by four isomeric diethynyl benzodithiophene ligands
inferred← citeshttps://doi.org/10.1039/c9cp04837eopenalex-snapshot
Electronic couplings and rates of excited state charge transfer processes at poly(thiophene- co -quinoxaline)–PC 71 BM interfaces: two- versus multi-state treatments
inferred← citeshttps://doi.org/10.1039/d0sc02812fopenalex-snapshot
Delocalization tunable by ligand substitution in [L 2 Al] n − complexes highlights a mechanism for strong electronic coupling
inferred← citeshttps://doi.org/10.1039/d1dt02537fopenalex-snapshot
Symmetric and non-symmetric anthracen-diyl bis(alkylidynes)
inferred← citeshttps://doi.org/10.1039/d4se01752hopenalex-snapshot
Light-driven electron transfer in a lipid bilayer with mixed valence molecular wires
inferred← citeshttps://doi.org/10.1063/1.2166232openalex-snapshot
Estimation of electronic coupling in π-stacked donor-bridge-acceptor systems: Correction of the two-state model
inferred← citeshttps://doi.org/10.1063/1.2911699openalex-snapshot
Can the second order multireference perturbation theory be considered a reliable tool to study mixed-valence compounds?
inferred← citeshttps://doi.org/10.1063/1.4824906openalex-snapshot
A multi-state fragment charge difference approach for diabatic states in electron transfer: Extension and automation
inferred← citeshttps://doi.org/10.1071/ch16555openalex-snapshot
In Situ Spectroelectrochemical Investigations of RuII Complexes with Bispyrazolyl Methane Triarylamine Ligands
inferred← citeshttps://doi.org/10.1201/9781420008395.ch5openalex-snapshot
Regulating Ion-Radical Organic Reactions
inferred← citeshttps://doi.org/10.1515/irm-2012-0005openalex-snapshot
Vinylruthenium-triarylamine conjugates as electroswitchable polyelectrochromic NIR dyes
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