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Gaseous Rust: Thermochemistry of Neutral and Ionic Iron Oxides and Hydroxides in the Gas Phase
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Electronic Structure Makes a Difference: Cytochrome P-450 Mediated Hydroxylations of Hydrocarbons as a Two-State Reactivity Paradigm
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Reactions of Bare FeO+ with Element Hydrides EHn (E=C, N, O, F, Si, P, S, Cl)
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A Mechanistic Study of the FeO+-Mediated Decomposition Pathways of Phenol, Anisol, and Their Thio Analogues
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A Density-Functional Theory Based Study on the16O/18O-Exchange Reactions of the Prototype Iron-Oxygen Compounds FeO+ and FeOH+ with H218O in the Gas Phase
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Single- and Two-State Reactivity in the Gas-Phase C−H Bond Activation of Norbornane by `Bare' FeO+
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Extreme Differences in the Interactions of `Bare' Fe+ and Fe2+ with Hydrogen Peroxide:Fenton Chemistry in the Gas Phase
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Fe⊕‐Catalyzed Gas‐Phase Oxidation of Ethane by N2O
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Oxidation of Alkanes by [Fe(O)OH]⊕ in the Gas Phase—the Role of Iron Oxidation State in CH Activations
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OH Bond Activation in the Gas Phase: The Reactions of Water and Methanol with [FeCH3]+
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CH and CC Bond Activation by Bare Transition‐Metal Oxide Cations in the Gas Phase
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Coordination of Dioxygen in Three Representative Transition Metal Cations: FeO, CrO, and [CH3Re(O2)2O]+
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Coulomb Explosions and Stability of Multiply Charged Ions in the Gas Phase
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Mass Spectrometric Study of [Fe,C3,H6,O]+ Isomers Relevant in the Gas‐phase Oxidation of Hydrocarbons by “Bare” FeO+
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Redox Properties of the Diatomic Bare Iron Chalcogenides FeO and FeS in the Gas Phase
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Reaction Paths for the Conversion of Methane to Methanol Catalyzed by FeO+
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Innocent and Less‐Innocent Solvent Ligands: A Systematic Investigation of Cationic Iron Chloride/Alcohol Complexes by Electrospray Ionization Mass Spectrometry Complemented by DFT Calculations
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Bond Dissociation Energies of Organic Molecules
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Solvent and Ligand Effects on the Structures of Iron Halide Cations in the Gas Phase
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Dehydration of Alkanones by Bare FeO+ Involves the ω/(ω − 1) Positions: Exclusion of Iron Carbenes as Intermediates. Preliminary Communication
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Benzene Oxidation by ‘Bare’ FeO+ in the Gas Phase
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Highly Selective Benzylic CH Bond Activation of Toluene 1 by ‘Bare’ FeO+ in the Gas Phase. Short communication
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Generation of ‘Bare’ FeF+ by CF Bond Activation in the Gas Phase and Evaluation of Thermochemical Data. Short communication
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exo/endo‐Selectivity in the Reaction of ‘Bare’ FeO+ with Bicyclo[2.2.1]heptane (Norbornane)
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Two‐State Reactivity in Organometallic Gas‐Phase Ion Chemistry
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Gas‐Phase Reactions of Aliphatic Alcohols with ‘Bare’ FeO+
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Insertion of Molecular Oxygen in Transition‐Metal Hydride Bonds, Oxygen‐Bond Activation, and Unimolecular Dissociation of Metal Hydroperoxide Intermediates. Short Communication
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Chiral superbases: the proton affinities of 1‐ and 2‐aza[6]helicene in the gas phase
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Formation and reactivity of metal carbonyl anions in the gas phase
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Gas‐phase reactions of transition metal carbonyl anions and atomic metal anions with nitrous oxide and dioxygen: Oxygen atom transfer and ligand exchange in reactions with nitrous oxide
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Determination of the Dissociation Energies of Gaseous Iron Monoxide and Manganese Monoxide by the Mass Spectrometric Knudsen Cell Method
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Organometallic Ion Chemistry
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Photofragmentation of hydrated iron ions Fe(H $_{\mathsf 2}$ O) $_\mathsf{n}^\mathsf{+}$ ( $\mathsf{n=1{-}9}$ ) at 532, 355 and 266 nm
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Thermochemistry of molecular FeO, FeO+ and FeO
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Ligand effects as probes for mechanistic aspects of remote CH bond activation by Iron(I) cations in the gas phase
inferredcites →https://doi.org/10.1016/0168-1176(90)80064-aopenalex-snapshot
Ion-molecule clusters involving doubly charged metal ions (M2+)
inferredcites →https://doi.org/10.1016/0168-1176(96)04360-1openalex-snapshot
A neutralization-reionization mass spectrometric study of alkyl hydroperoxide cation radicals and four distinguishable [C,H3,O2]+ isomers
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Ab initio studies on the electronic structure of FeOH
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Double photoionisation of toluene
inferredcites →https://doi.org/10.1016/j.ijms.2004.12.006openalex-snapshot
Ammonia activation by iron: state-specific reactions of Fe+(6D, 4F) with ND3 and the reaction of FeNH+ with D2
inferredcites →https://doi.org/10.1016/j.ijms.2006.04.009openalex-snapshot
Formation of hydrated triply charged metal ions from aqueous solutions using nanodrop mass spectrometry
inferredcites →https://doi.org/10.1016/j.ijms.2006.05.024openalex-snapshot
Electrospray ionization as a convenient new method for the generation of catalytically active iron-oxide ions in the gas phase
inferredcites →https://doi.org/10.1016/j.ijms.2007.02.024openalex-snapshot
Substituent effects on the second ionization energies of hydroxy- and methoxy benzenes
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Open shell organometallics: a general analysis of their electronic structure and reactivity
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Influence of the internal excitation of FeCO+ on its reactivity with O2 observed in Fourier Transform-ICR cell
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Low-lying electronic states and molecular structure of FeO2 and FeO2−
inferredcites →https://doi.org/10.1016/s0009-2614(97)00898-1openalex-snapshot
Equilibrium studies of weakly bound Fe(L)+ complexes with L = Xe, CO2, N2 and CH4
inferredcites →https://doi.org/10.1016/s0009-2614(99)00703-4openalex-snapshot
The crucial role of CO as a ligand in the formation of long-lived neutral iron complexes in the gas phase
inferredcites →https://doi.org/10.1016/s0010-8545(98)00178-7openalex-snapshot
Gas-phase reactivity of ionic iron complexes: comparison with solution chemistry
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A low-energy CAD study of the ions MOH(H2O)+ (M = Mn, Co, Ni, Cu, Zn) and [M(H2,O2)]+ (M = Cr, Fe, La, Pr)
inferredcites →https://doi.org/10.1016/s1387-3806(00)00310-9openalex-snapshot
Kinetic energy dependence of ion–molecule reactions: guided ion beams and threshold measurements
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Dissociation behavior of Cu(urea)+ complexes generated by electrospray ionization
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Thermochemistry of neutral and cationic iron hydroxides Fe(OH)n0/+ (n=1, 2) in the gas phase
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Formation of some transition metal oxide cluster anions and reactivity towards methanol in the gas phase
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Reactivity of High-Valent Iron–Oxo Species in Enzymes and Synthetic Reagents: A Tale of Many States
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Two-State Reactivity as a New Concept in Organometallic Chemistry
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Theoretical Perspective on the Structure and Mechanism of Cytochrome P450 Enzymes
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Density Functional Theory in Transition-Metal Chemistry: Relative Energies of Low-Lying States of Iron Compounds and the Effect of Spatial Symmetry Breaking
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Generation and Characterization of the Anionic, Neutral, and Cationic Iron-Dioxygen Adducts [FeO2] in the Gas Phase
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Interactions of Metal Ions with Water: Ab Initio Molecular Orbital Studies of Structure, Vibrational Frequencies, Charge Distributions, Bonding Enthalpies, and Deprotonation Enthalpies. 2. Monohydroxides
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On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2
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Surprisingly low reactivity of bare iron monoxide ion (FeO+) in its spin-allowed, highly exothermic reaction with molecular hydrogen to generate iron(1+) and water
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Three methods to measure RH bond energies
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State-Specific Reactions of Fe+(a6D,a4F) with D2O and Reactions of FeO+ with D2
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Gas-phase metal ion ligation: collision-induced dissociation of aquairon (Fe(H2O)x+) and iron-methane (Fe(CH4)x+) (x=1-4)
inferredcites →https://doi.org/10.1021/j100280a054openalex-snapshot
Effect of kinetic and electronic energy on the reactions of iron(1+) with hydrogen, deuterium hydride, and deuterium: state-specific cross sections for Fe+(6D) and Fe+(4F)
inferredcites →https://doi.org/10.1021/j100345a055openalex-snapshot
State-specific reactions of iron(1+)(6D, 4F) with oxygen and oxirane: D.degree.0(iron(1+)-oxygen) and effects of collisional relaxation
inferredcites →https://doi.org/10.1021/j150608a004openalex-snapshot
Oxidation of transition-metal cations in the gas phase. Oxygen bond dissociation energies and formation of an excited-state product
inferredcites →https://doi.org/10.1021/ja00030a014openalex-snapshot
Experimental and theoretical studies toward a characterization of conceivable intermediates involved in the gas-phase oxidation of methane by bare FeO+. Generation of four distinguishable [Fe,C,H4,O]+ isomers
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Energetics and mechanism of the thermal decarboxylation of tetracarbonyl(carboxy)ferrate(1-) in the gas phase
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Determination of metal-hydroxide bond energies in doubly charged scandium hydroxide, iron hydroxide, and cobalt hydroxide ions
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Ion-molecule reaction chemistry of Fe+ with NO: excited-versus ground-state reactions
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Generation, Fragmentation, and Interconversion Processes of [Fe,C6,H6,O]+ Isomers Relevant for the Oxygenation of Aromatic Hydrocarbons
inferredcites →https://doi.org/10.1021/ja00102a043openalex-snapshot
Electronic Structures and Gas-Phase Reactivities of Cationic Late-Transition-Metal Oxides
inferredcites →https://doi.org/10.1021/ja00125a014openalex-snapshot
Ligand Effects in .sigma.-Bond Activation by Transition Metal-Ligand Complexes
inferredcites →https://doi.org/10.1021/ja00156a018openalex-snapshot
Intrinsic Coordination Properties of Iron in FeO+: Kinetics at 294 .+-. 3 K for Gas-Phase Reactions of the Ground States of Fe+ and FeO+ with Inorganic Ligands Containing Hydrogen, Nitrogen, and Oxygen
inferredcites →https://doi.org/10.1021/ja00162a074openalex-snapshot
Production and study in the gas phase of multiply charged solvated or coordinated metal ions
inferredcites →https://doi.org/10.1021/ja00185a013openalex-snapshot
Gas-phase reactions of iron(1-) and cobalt(1-) with simple thiols, sulfides, and disulfides by Fourier-transform mass spectrometry
inferredcites →https://doi.org/10.1021/ja00193a051openalex-snapshot
Gas-phase water and hydroxyl binding energies for monopositive first-row transition metal ions
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Gas-phase chemistry of transition metal-imido and -nitrene ion complexes. Oxidative addition of nitrogen-hydrogen bonds in ammonia and transfer of NH from a metal center to an alkene
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Multi-coordinatively and electronically unsaturated transition-metal complex negative ions: generation and chemistry of (OC)2Fe-.cntdot. and (OC)3Mn-
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Gas-phase reactions of transition-metal ions with methyl nitrite and nitromethane
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Gas phase reactions of Group 8-10 transition-metal ions with nitroalkanes
inferredcites →https://doi.org/10.1021/ja00317a014openalex-snapshot
Gas-phase reactions of oxoiron(1+) ion (FeO+) with hydrocarbons
inferredcites →https://doi.org/10.1021/ja00321a010openalex-snapshot
Properties and reactions of organometallic fragments in the gas phase. Ion beam studies of hydridoiron(1+) ion
inferredcites →https://doi.org/10.1021/ja00395a080openalex-snapshot
Gas-phase oxidation catalysis by transition-metal cations
inferredcites →https://doi.org/10.1021/ja00511a033openalex-snapshot
Reactions of atomic metal ions with alkyl halides and alcohols in the gas phase
inferredcites →https://doi.org/10.1021/ja011267gopenalex-snapshot
Is There a Minimum Size for Aqueous Doubly Charged Metal Cations?
inferredcites →https://doi.org/10.1021/ja077286topenalex-snapshot
Probing the Compound I-like Reactivity of a Bare High-Valent Oxo Iron Porphyrin Complex: The Oxidation of Tertiary Amines
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“Bare” Iron Methoxide Cation: A Simple Model To Probe the Mechanism of β-Hydrogen Transfer in Organometallic Compounds
inferredcites →https://doi.org/10.1021/ja953338fopenalex-snapshot
Reactions of Laser-Ablated Iron Atoms with Oxygen Molecules: Matrix Infrared Spectra and Density Functional Calculations of OFeO, FeOO, and Fe(O2)
inferredcites →https://doi.org/10.1021/ja954153bopenalex-snapshot
Observation and Photoelectron Spectroscopic Study of Novel Mono- and Diiron Oxide Molecules: FeO y - ( y = 1−4) and Fe 2 O y - ( y = 1−5)
inferredcites →https://doi.org/10.1021/ja960157kopenalex-snapshot
Chromium Dioxide Cation OCrO+ in the Gas Phase: Structure, Electronic States, and the Reactivity with Hydrogen and Hydrocarbons1
inferredcites →https://doi.org/10.1021/ja981525iopenalex-snapshot
Reaction Pathway for the Direct Benzene Hydroxylation by Iron−Oxo Species
inferredcites →https://doi.org/10.1021/ja984469uopenalex-snapshot
Reactivity of Cr+(6S,4D), Mn+(7S,5S), and Fe+(6D,4F): Reaction of Cr+, Mn+, and Fe+ with Water
inferredcites →https://doi.org/10.1021/ja993232aopenalex-snapshot
Regioselective Activation of Ipso and Ortho Positions in Chlorobenzene by FeO+
inferredcites →https://doi.org/10.1021/jp0012552openalex-snapshot
Reaction Pathways for the Oxidation of Methanol to Formaldehyde by an Iron−Oxo Species
inferredcites →https://doi.org/10.1021/jp002252sopenalex-snapshot
Systematic Study of Oxo, Peroxo, and Superoxo Isomers of 3d-Metal Dioxides and Their Anions
inferredcites →https://doi.org/10.1021/jp011324sopenalex-snapshot
Theoretical Study of the Reaction Mechanism of Fe Atoms with H2O, H2S, O2 and H+
inferredcites →https://doi.org/10.1021/jp0122225openalex-snapshot
Mechanism for the Formaldehyde to Formic Acid and the Formic Acid to Carbon Dioxide Conversions Mediated by an Iron-Oxo Species
inferredcites →https://doi.org/10.1021/jp020694topenalex-snapshot
Metal Ion Solvation in the Gas Phase: The Quest for Higher Oxidation States
inferredcites →https://doi.org/10.1021/jp0222088openalex-snapshot
Oxidative Degradation of Small Cationic Vanadium Clusters by Molecular Oxygen: On the Way from Vn+ (n = 2−5) to VOm+ (m = 1, 2)
inferredcites →https://doi.org/10.1021/jp025833lopenalex-snapshot
Reaction Path Sampling of the Reaction between Iron(II) and Hydrogen Peroxide in Aqueous Solution
inferredcites →https://doi.org/10.1021/jp036558lopenalex-snapshot
Theoretical Study of Two-State Reactivity of Transition Metal Cations: The “Difficult” Case of Iron Ion Interacting with Water, Ammonia, and Methane
inferredcites →https://doi.org/10.1021/jp047912yopenalex-snapshot
Introduction to Active Thermochemical Tables: Several “Key” Enthalpies of Formation Revisited
inferredcites →https://doi.org/10.1021/jp0539223openalex-snapshot
Density Functionals for Inorganometallic and Organometallic Chemistry
inferredcites →https://doi.org/10.1021/jp0624698openalex-snapshot
Infrared Spectra of M(OH)1,2,3 (M = Mn, Fe, Co, Ni) Molecules in Solid Argon and the Character of First Row Transition Metal Hydroxide Bonding
inferredcites →https://doi.org/10.1021/jp953198wopenalex-snapshot
Reactions of Laser-Ablated Iron Atoms with Oxygen Molecules in Condensing Argon. Infrared Spectra and Density Functional Calculations of Iron Oxide Product Molecules
inferredcites →https://doi.org/10.1021/jp953329topenalex-snapshot
Gas-Phase Ion Dynamics and Chemistry
inferredcites →https://doi.org/10.1021/jp962535dopenalex-snapshot
Performance of the B3LYP/ECP DFT Calculations of Iron-Containing Compounds
inferredcites →https://doi.org/10.1021/jp9842749openalex-snapshot
Gas-Phase Thermochemistry of Iron Oxides and Hydroxides: Portrait of a Super-Efficient Flame Suppressant
inferredcites →https://doi.org/10.1021/jp9909006openalex-snapshot
Electronic Structure and Properties of FeOn and FeOn- Clusters
inferredcites →https://doi.org/10.1021/jp991332xopenalex-snapshot
Generation, Stability, and Reactivity of Small, Multiply Charged Ions in the Gas Phase
inferredcites →https://doi.org/10.1021/jp994389sopenalex-snapshot
Second Ionization Energies of Gaseous Iron Oxides and Hydroxides: The FeOmHn2+ Dications (m = 1, 2; n ≤ 4)
inferredcites →https://doi.org/10.1021/om00016a064openalex-snapshot
Gas-Phase Generation and Structural Characterization of the Fe(CO2)+ Cluster
inferredcites →https://doi.org/10.1021/om000811bopenalex-snapshot
Regioselectivity in 2-Methylbutane Hydroxylation Mediated by FeO+ and FeO2+
inferredcites →https://doi.org/10.1021/om020893zopenalex-snapshot
Fe+-Mediated Interconversion of n- and i-C3H7OH Preceding Their Gas-Phase Dehydrations: Experimental and Computational Evidence for Memory Effects and Inherent Asymmetry of Constitutionally Equivalent Methyl Groups,
inferredcites →https://doi.org/10.1021/om030094wopenalex-snapshot
Fe+-Mediated Interconversion of n- and i-C3H7OH Preceding Their Gas-Phase Dehydrations: Experimental and Computational Evidence for Memory Effects and Inherent Asymmetry of Constitutionally Equivalent Methyl Groups.
inferredcites →https://doi.org/10.1021/om950573yopenalex-snapshot
Gas-Phase Chemistry of Hydrogen Peroxide and Alkyl Hydroperoxides with “Bare” First-Row Transition-Metal Cations Cr+−Co+. Generation of MO+ Cations Using H2O2 as Oxidant
inferredcites →https://doi.org/10.1021/om950837gopenalex-snapshot
Sequential Iron(I)-Mediated Homologization of Olefins by Methanol and Methyl Halides in the Gas Phase
inferredcites →https://doi.org/10.1039/a605415copenalex-snapshot
Collisions of Fe+ ions, clusters and hydroxides ligated by water molecules
inferredcites →https://doi.org/10.1039/a805140bopenalex-snapshot
A study of the reactions of Fe+ with O3, O2 and N2
inferredcites →https://doi.org/10.1039/b000877jopenalex-snapshot
The reactions of FeO with O3, H2, H2O, O2 and CO2
inferredcites →https://doi.org/10.1039/b207188fopenalex-snapshot
Structure and thermochemistry of Fe 2 S 2 −/0/+ gas phase clusters and their fragments. B3LYP calculations
inferredcites →https://doi.org/10.1039/b508922kopenalex-snapshot
A kinetic study of the reactions of Fe + with N 2 O, N 2 , O 2 , CO 2 and H 2 O, and the ligand-switching reactions Fe + ·X + Y → Fe + ·Y + X (X = N 2 , O 2 , CO 2 ; Y = O 2 , H 2 O)
inferredcites →https://doi.org/10.1039/b518155kopenalex-snapshot
A kinetic study of the reactions FeO + + O, Fe + ·N 2 + O, Fe + ·O 2 + O and FeO + + CO: implications for sporadic E layers in the upper atmosphere
inferredcites →https://doi.org/10.1039/b609123gopenalex-snapshot
Probing the intrinsic features and environmental stabilization of multiply charged anions
inferredcites →https://doi.org/10.1039/b614390copenalex-snapshot
Understanding the kinetics of spin-forbidden chemical reactions
inferredcites →https://doi.org/10.1039/b615648gopenalex-snapshot
Bond-formation versuselectron transfer: C–C-coupling reactions of hydrocarbon dications with benzene
inferredcites →https://doi.org/10.1039/f19736901448openalex-snapshot
Iron compounds in flames. Relative stabilities of Fe, FeO, FeOH and Fe(OH)2
inferredcites →https://doi.org/10.1039/ft9949000031openalex-snapshot
Kinetic study of the reaction between Fe and O3 under mesospheric conditions
inferredcites →https://doi.org/10.1039/ft9949000395openalex-snapshot
Experimental and theoretical study of the reaction Fe + O2+ N2? FeO2+ N2
inferredcites →https://doi.org/10.1039/ft9969204371openalex-snapshot
A kinetic study of the reactions of Fe(a 5 D) and Fe + (a 6 D) with N 2 O over the temperature range 294–850 K
inferredcites →https://doi.org/10.1039/jr9650004490openalex-snapshot
830. The vapour-phase reaction of iron pentacarbonyl with nitrogen dioxide; iron(III) oxide nitrate
inferredcites →https://doi.org/10.1063/1.1448489openalex-snapshot
Electronic spectroscopy of intermediates involved in the conversion of methane to methanol by FeO+
inferredcites →https://doi.org/10.1063/1.1731972openalex-snapshot
Double and Triple Ionization in Molecules Induced by Electron Impact
inferredcites →https://doi.org/10.1063/1.1856916openalex-snapshot
Revision of the second ionization energy of toluene
inferredcites →https://doi.org/10.1063/1.2032947openalex-snapshot
Direct determination of the ionization energies of FeO and CuO with VUV radiation
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inferredcites →https://doi.org/10.1063/1.457434openalex-snapshot
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inferredcites →https://doi.org/10.1063/1.474622openalex-snapshot
Mass selected anion-zero kinetic energy photoelectron spectroscopy (anion-ZEKE): Ground and low excited states of FeO
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Electronic State-Specific Transition Metal ION Chemistry
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Compound Database for Gaseous Metal Hydroxides and Oxyhydroxides
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Mass Spectrometry for Ion Chemistry and Links from the Gas Phase to “Real” Processes
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Thermal Activation of Ammonia by Transition‐Metal Hydroxide Cations
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Ion-mobility mass spectrometry of complexes of nickel and acetonitrile
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