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Kinetics and Mechanism of the Reaction of Cl Atoms with 2-Methyl-1,3-butadiene (Isoprene) at 298 K

https://doi.org/10.1021/jp962786m
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Outgoing claims: the papers this work cites, builds on, or argues with.

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Development and evaluation of a detailed mechanism for the atmospheric reactions of isoprene and NOx
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Activated Monochloroethyl Radicals in the Photochlorination of Ethylene
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FTIR studies of the kinetics and mechanism for the reaction of Cl atom with formylchloride
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An FTIR study of the Cl atom‐initiated oxidation of CH2Cl2 and CH3Cl
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Kinetics of the gas phase reaction of Cl atoms with a series of organics at 296 ± 2 K and atmospheric pressure
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Kinetics of the gas‐phase reactions of Cl atoms with chloroethenes at 298 ± 2 K and atmospheric pressure
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Acuchem: A computer program for modeling complex chemical reaction systems
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Formation of 3‐Methylfuran from the gas‐phase reaction of OH radicals with isoprene and the rate constant for its reaction with the OH radical
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A product study of the gas‐phase reaction of Isoprene with the OH radical in the presence of NOx
inferredcites →https://doi.org/10.1002/kin.550240109openalex-snapshot
Atmospheric photooxidation of isoprene part I: The hydroxyl radical and ground state atomic oxygen reactions
inferredcites →https://doi.org/10.1002/kin.550240110openalex-snapshot
Atmospheric photooxidation of isoprene part II: The ozone‐isoprene reaction
inferredcites →https://doi.org/10.1002/kin.550240406openalex-snapshot
FTIR spectroscopic study of the Cl‐ and Br‐atom initiated oxidation of ethene
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The Tropospheric Chemistry of Ozone in the Polar Regions
inferredcites →https://doi.org/10.1007/bf01055932openalex-snapshot
A study of the atmospheric reactions of 1,3-dichloropropene and other selected organochlorine compounds
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Infrared characteristic group frequencies
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Atmospheric chemistry. Fundamentals and experimental techniques
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Measurement of vertical distribution of isoprene in surface seawater, its chemical fate, and its emission from several phytoplankton monocultures
inferredcites →https://doi.org/10.1016/0960-1686(92)90015-dopenalex-snapshot
Products and mechanisms of the reactions of the nitrate radical (NO3) with isoprene, 1,3-butadiene and 2,3-dimethyl-1,3-butadiene in air
inferredcites →https://doi.org/10.1016/0960-1686(92)90423-iopenalex-snapshot
Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry
inferredcites →https://doi.org/10.1016/1352-2310(95)00385-1openalex-snapshot
The budgets of ethane and tetrachloroethene: Is there evidence for an impact of reactions with chlorine atoms in the troposphere?
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A supplement for the RADM2 chemical mechanism: The photooxidation of isoprene
inferredcites →https://doi.org/10.1016/1352-2310(95)00433-5openalex-snapshot
Emissions of hydrocarbons from marine phytoplankton—Some results from controlled laboratory experiments
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UV absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase
inferredcites →https://doi.org/10.1021/es00009a046openalex-snapshot
Observation of Hydroxycarbonyls from the OH Radical-Initiated Reaction of Isoprene
inferredcites →https://doi.org/10.1021/es00042a004openalex-snapshot
Atmospheric chemistry of isoprene and of its carbonyl products
inferredcites →https://doi.org/10.1021/es00042a008openalex-snapshot
Measurement technique for inorganic chlorine gases in the marine boundary layer
inferredcites →https://doi.org/10.1021/es00057a025openalex-snapshot
Formation Yields of Methyl Vinyl Ketone and Methacrolein from the Gas-Phase Reaction of O3 with Isoprene
inferredcites →https://doi.org/10.1021/j100035a018openalex-snapshot
Rate Constants for the Reactions of Chlorine Atoms with Some Simple Alkanes at 298 K: Measurement of a Self-Consistent Set Using Both Absolute and Relative Rate Methods
inferredcites →https://doi.org/10.1021/j100372a052openalex-snapshot
Pressure dependence of the reaction of chlorine atoms with ethene and acetylene in air at 295 K
inferredcites →https://doi.org/10.1021/j100378a047openalex-snapshot
Formyl chloride: UV absorption cross sections and rate constants for the reactions with chlorine atom and hydroxyl radical
inferredcites →https://doi.org/10.1021/j100452a002openalex-snapshot
Thermal chlorine-38 reactions with propyne
inferredcites →https://doi.org/10.1021/j100528a001openalex-snapshot
Kinetics and mechanism of recoil chlorine atom reactions with ethylene
inferredcites →https://doi.org/10.1021/j100528a002openalex-snapshot
Thermal chlorine-38 reactions with propene
inferredcites →https://doi.org/10.1021/j100528a004openalex-snapshot
Thermal chlorine-38 atom reactions with ethylene
inferredcites →https://doi.org/10.1021/j100568a002openalex-snapshot
Chlorine-atom sensitized oxidation of dichloromethane and chloromethane
inferredcites →https://doi.org/10.1021/ja00017a004openalex-snapshot
Temperature coefficients of the rates of chlorine atom reactions with C2H6, C2H5, and C2H4. The rates of disproportionation and recombination of ethyl radicals
inferredcites →https://doi.org/10.1021/ja00159a020openalex-snapshot
Kinetics of chlorine atom reactions with ethane, ethyl, and ethylene. Rates of disproportionation and recombination of ethyl radicals
inferredcites →https://doi.org/10.1021/jp953103qopenalex-snapshot
FTIR Spectroscopic Studies of the Mechanisms of the Halogen Atom Initiated Oxidation of Haloacetaldehydes
inferredcites →https://doi.org/10.1021/jp953178uopenalex-snapshot
Kinetics of the Reactions of Chlorine Atoms with C2H4 (k1) and C2H2 (k2): A Determination of ΔHf,298° for C2H3
inferredcites →https://doi.org/10.1021/jp960406ropenalex-snapshot
Pressure Dependence of the Reaction Cl + C3H6
inferredcites →https://doi.org/10.1029/92gl00083openalex-snapshot
Evidence for marine production of isoprene
inferredcites →https://doi.org/10.1029/92jd00062openalex-snapshot
Formation of OH radicals in the gas phase reactions of O 3 with a series of terpenes
inferredcites →https://doi.org/10.1029/92jd01914openalex-snapshot
Development and evaluation of a photooxidation mechanism for isoprene
inferredcites →https://doi.org/10.1029/93gl00047openalex-snapshot
Evidence of inorganic chlorine gases other than hydrogen chloride in marine surface air
inferredcites →https://doi.org/10.1029/93ja02096openalex-snapshot
Planetary wave and solar emission signatures in the equatorial electrojet
inferredcites →https://doi.org/10.1029/94gb03103openalex-snapshot
Tropospheric budget of reactive chlorine
inferredcites →https://doi.org/10.1029/94gl02363openalex-snapshot
Production of isoprene by marine phytoplankton cultures
inferredcites →https://doi.org/10.1029/94jd01334openalex-snapshot
OH radical‐ initiated photooxidation of isoprene: An estimate of global CO production
inferredcites →https://doi.org/10.1029/95jd01028openalex-snapshot
Low ozone in the marine boundary layer of the tropical Pacific Ocean: Photochemical loss, chlorine atoms, and entrainment
inferredcites →https://doi.org/10.1029/95jd02457openalex-snapshot
Hydrocarbon and halocarbon measurements as photochemical and dynamical indicators of atmospheric hydroxyl, atomic chlorine, and vertical mixing obtained during Lagrangian flights
inferredcites →https://doi.org/10.1029/96gl01368openalex-snapshot
Tetrachloroethylene as an indicator of low Cl atom concentrations in the troposphere
inferredcites →https://doi.org/10.1038/334138a0openalex-snapshot
Ozone destruction and photochemical reactions at polar sunrise in the lower Arctic atmosphere
inferredcites →https://doi.org/10.1039/9781847552310-00065openalex-snapshot
Gas phase tropospheric chemistry of organic compounds
inferredcites →https://doi.org/10.1163/156856793x00091openalex-snapshot
Chlorine atoms as a potential tropospheric oxidant in the marine boundary layer
inferredcites →https://doi.org/10.1163/156856794x00388openalex-snapshot
Formation of O(3P) atoms and epoxides from the gas- phase reaction of O3 with isoprene
inferredcites →https://doi.org/10.1201/b17118openalex-snapshot
CRC Handbook of Chemistry and Physics
inferredcites →https://doi.org/10.1364/josa.32.000285openalex-snapshot
Long Optical Paths of Large Aperture
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The Handbook of infrared and Raman characteristic frequencies of organic molecules

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Reaction of Atomic Chlorine with Benzyl Alcohol
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An experimental study of the gas-phase reaction between Cl atoms and trans-2-pentenal: Kinetics, products and SOA formation
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Kinetics of the reaction of chlorine atoms with isoprene (2-methyl 1,3-butadiene, CH2C(CH3)CH CH2) at 297 ± 2 K
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Temperature dependence of the gas-phase reactions of Cl atoms with propene and 1-butene between 285 <T< 313 K
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FTIR gas-phase kinetic study of the reactions of Cl atoms with (CH3)2C CHC(O)H and CH3CH CHC(O)OCH3
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In situ measurement of isoprene in the marine air and surface seawater from the western North Pacific
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Direct evidence for chlorine-enhanced urban ozone formation in Houston, Texas
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Atmospheric Chemistry of 4:2 Fluorotelomer Acrylate [C4F9CH2CH2OC(O)CH═CH2]: Kinetics, Mechanisms, and Products of Chlorine-Atom- and OH-Radical-Initiated Oxidation
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Inverse Kinetic Isotope Effect in the Reaction of Atomic Chlorine with C2H4 and C2D4
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Low-Pressure Study of the Reaction of Cl Atoms with Isoprene
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Laboratory Kinetic Studies of the Reactions of Cl Atoms with Species of Biogenic Origin: δ3-Carene, Isoprene, Methacrolein and Methyl Vinyl Ketone
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A Pulsed Laser Photolysis-Resonance Fluorescence Kinetic Study of the Atmospheric Cl Atom-Initiated Oxidation of Propene and a Series of 3-Halopropenes at Room Temperature
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4‐Chlorocrotonaldehyde as a unique chlorine‐containing compound from the reaction of atomic chlorine with 1,3‐butadiene in air at room temperature
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Unique markers of chlorine atom chemistry in coastal urban areas: The reaction with 1,3‐butadiene in air at room temperature
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An environmental chamber investigation of chlorine‐enhanced ozone formation in Houston, Texas
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Atomic chlorine concentrations derived from ethane and hydroxyl measurements over the equatorial Pacific Ocean: Implication for dimethyl sulfide and bromine monoxide
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Modeling the impact of ClNO 2 on ozone formation in the Houston area
inferred← citeshttps://doi.org/10.1029/97gl01547openalex-snapshot
Unique products of the reaction of isoprene with atomic chlorine: Potential markers of chlorine atom chemistry
inferred← citeshttps://doi.org/10.1029/98jd00528openalex-snapshot
Rate and mechanism of the reactions of OH and Cl with 2‐methyl‐3‐buten‐2‐ol
inferred← citeshttps://doi.org/10.1038/28584openalex-snapshot
Unexpectedly high concentrations of molecular chlorine in coastal air
inferred← citeshttps://doi.org/10.1039/b003394oopenalex-snapshot
Chlorine: the only green element – towards a wider acceptance of its role in natural cycles
inferred← citeshttps://doi.org/10.1039/b007244nopenalex-snapshot
Reactions of acrolein, crotonaldehyde and pivalaldehyde with Cl atoms: structure–activity relationship and comparison with OH and NO3 reactions
inferred← citeshttps://doi.org/10.1039/b101380gopenalex-snapshot
Kinetics of the gas-phase reaction of atomic chlorine with selected monoterpenes
inferred← citeshttps://doi.org/10.1039/b211185copenalex-snapshot
Theoretical study of the initial reaction between OH and isoprene in tropospheric conditions
inferred← citeshttps://doi.org/10.1039/c6ra11892eopenalex-snapshot
Kinetic investigations of chlorine atom initiated photo oxidation reactions of 2,3-dimethyl-1,3-butadiene in the gas phase: an experimental and theoretical study
inferred← citeshttps://doi.org/10.1039/d5ea00091bopenalex-snapshot
Comparison of oxidation products generated from the reaction of α-pinene with hydroxyl radicals, chlorine atoms, and bromine atoms measured using ammonium adduct chemical ionization mass spectrometry
inferred← citeshttps://doi.org/10.1039/d5ea00142kopenalex-snapshot
Quantification, diel variation and photochemistry of inorganic chlorine trace gases in continental Germany
inferred← citeshttps://doi.org/10.1063/1.1531660openalex-snapshot
C–C bond fission pathways of chloroalkenyl alkoxy radicals
inferred← citeshttps://doi.org/10.1063/1.1792593openalex-snapshot
The dynamics of the Cl+n-C4H10→HCl (v′,j′)+C4H9 reaction at 0.32 eV
inferred← citeshttps://doi.org/10.1063/1.3473049openalex-snapshot
Imaging the dynamics of chlorine atom reactions with alkenes
inferred← citeshttps://doi.org/10.1063/1.481782openalex-snapshot
Chlorine atom addition reaction to isoprene: A theoretical study
inferred← citeshttps://doi.org/10.1071/en04045openalex-snapshot
Atmospheric Oxidation Mechanism of Isoprene
inferred← citeshttps://doi.org/10.1071/en13026openalex-snapshot
Chlorine chemistry in urban atmospheres: a review
inferred← citeshttps://doi.org/10.1080/10426500802625719openalex-snapshot
Chemoselective Synthesis of Stable Phosphorus Ylides from 6-Azauracil and Mechanistic Investigation of the Reaction by UV Spectrophotometry
inferred← citeshttps://doi.org/10.1080/10426507.2020.1833330openalex-snapshot
Kinetics and a mechanistic investigation of 2H-thiopyrano [2, 3-b] quinoline-2, 3-dicarboxylates from 2-mercaptoquinoline-3-carbaldehydes, dialkyl acetylenedicarboxylates and triphenylphosphine: Empirical approach
inferred← citeshttps://doi.org/10.1088/1674-0068/22/02/134-138openalex-snapshot
Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2
inferred← citeshttps://doi.org/10.3184/007967405777874877openalex-snapshot
Kinetic Investigation of the Reactions between Triphenylphosphine, Dialkyl Acetylenedicarboxylates and Sh-Acid Such as 2-Thiazoline-2-Thiol or 2-Mercaptobenzoxazole by Uv Spectrophotometry
inferred← citeshttps://doi.org/10.3390/atmos6101487openalex-snapshot
Inland Concentrations of Cl2 and ClNO2 in Southeast Texas Suggest Chlorine Chemistry Significantly Contributes to Atmospheric Reactivity
inferred← citeshttps://doi.org/10.3390/molecules29133124openalex-snapshot
Chemical Transformations of Benzyl Alcohol Caused by Atomic Chlorine
inferred← citeshttps://doi.org/10.5194/acp-17-13491-2017openalex-snapshot
Secondary organic aerosol from chlorine-initiated oxidation of isoprene
inferred← citeshttps://doi.org/10.5194/acp-23-15165-2023openalex-snapshot
Box Modelling of Gas-Phase Atmospheric Chlorine Chemistry
inferred← citeshttps://doi.org/10.5194/acp-25-11247-2025openalex-snapshot
Formation of chlorinated organic compounds from Cl atom-initiated reactions of aromatics and their detection in suburban Shanghai
inferred← citeshttps://doi.org/10.5194/acpd-13-13685-2013-supplementopenalex-snapshot
Supplementary material to "Evaluating evidence for Cl sources and oxidation chemistry in a coastal, urban environment"
inferred← citeshttps://doi.org/10.70675/8029769ezcad4z4e50z8982z0700adbc11ceopenalex-snapshot
Atmospheric degradation of oxygenated Volatile Organic Compounds
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