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Increasing the Density of Adsorbed Hydrogen with Coordinatively Unsaturated Metal Centers in Metal−Organic Frameworks

https://doi.org/10.1021/la703864a
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Quantum-Chemical Characterization of the Properties and Reactivities of Metal–Organic Frameworks
inferred← citeshttps://doi.org/10.1021/ic2021275openalex-snapshot
Triple Framework Interpenetration and Immobilization of Open Metal Sites within a Microporous Mixed Metal–Organic Framework for Highly Selective Gas Adsorption
inferred← citeshttps://doi.org/10.1021/ic4022239openalex-snapshot
Tuning the Host–Guest Interactions in a Phosphine Coordination Polymer through Different Types of post-Synthetic Modification
inferred← citeshttps://doi.org/10.1021/ja1001407openalex-snapshot
Metal−Organic Polyhedral Frameworks: High H2 Adsorption Capacities and Neutron Powder Diffraction Studies
inferred← citeshttps://doi.org/10.1021/ja104923fopenalex-snapshot
Molecular Hydrogen “Pairing” Interaction in a Metal Organic Framework System with Unsaturated Metal Centers (MOF-74)
inferred← citeshttps://doi.org/10.1021/ja2010863openalex-snapshot
Spectroscopic Evidence for the Influence of the Benzene Sites on Tightly Bound H2 in Metal−Organic Frameworks with Unsaturated Metal Centers: MOF-74-Cobalt
inferred← citeshttps://doi.org/10.1021/ja202432xopenalex-snapshot
Hydrogen Confinement in Carbon Nanopores: Extreme Densification at Ambient Temperature
inferred← citeshttps://doi.org/10.1021/ja2071384openalex-snapshot
Metal-Specific Interactions of H2 Adsorbed within Isostructural Metal–Organic Frameworks
inferred← citeshttps://doi.org/10.1021/ja305004aopenalex-snapshot
Structure and Mobility of Metal Clusters in MOFs: Au, Pd, and AuPd Clusters in MOF-74
inferred← citeshttps://doi.org/10.1021/ja310173eopenalex-snapshot
Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of M-BTT Metal–Organic Frameworks
inferred← citeshttps://doi.org/10.1021/ja400754popenalex-snapshot
Water Cluster Confinement and Methane Adsorption in the Hydrophobic Cavities of a Fluorinated Metal–Organic Framework
inferred← citeshttps://doi.org/10.1021/ja402103uopenalex-snapshot
Highly Selective Quantum Sieving of D2 from H2 by a Metal–Organic Framework As Determined by Gas Manometry and Infrared Spectroscopy
inferred← citeshttps://doi.org/10.1021/ja503218jopenalex-snapshot
Structural Complexity in Metal–Organic Frameworks: Simultaneous Modification of Open Metal Sites and Hierarchical Porosity by Systematic Doping with Defective Linkers
inferred← citeshttps://doi.org/10.1021/ja506230ropenalex-snapshot
M 2 ( m -dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H 2 Binding at the Open Metal Sites
inferred← citeshttps://doi.org/10.1021/ja512382fopenalex-snapshot
Water Sensitivity in Zn 4 O-Based MOFs is Structure and History Dependent
inferred← citeshttps://doi.org/10.1021/ja8036096openalex-snapshot
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
inferred← citeshttps://doi.org/10.1021/ja803669wopenalex-snapshot
Reversible Structural Transition in MIL-53 with Large Temperature Hysteresis
inferred← citeshttps://doi.org/10.1021/ja806624jopenalex-snapshot
High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites
inferred← citeshttps://doi.org/10.1021/ja807023qopenalex-snapshot
Enhanced H2 Adsorption in Isostructural Metal−Organic Frameworks with Open Metal Sites: Strong Dependence of the Binding Strength on Metal Ions
inferred← citeshttps://doi.org/10.1021/ja900258topenalex-snapshot
High-Capacity Methane Storage in Metal−Organic Frameworks M2(dhtp): The Important Role of Open Metal Sites
inferred← citeshttps://doi.org/10.1021/ja904782hopenalex-snapshot
Exceptionally High Acetylene Uptake in a Microporous Metal−Organic Framework with Open Metal Sites
inferred← citeshttps://doi.org/10.1021/ja906302topenalex-snapshot
Multiroute Synthesis of Porous Anionic Frameworks and Size-Tunable Extraframework Organic Cation-Controlled Gas Sorption Properties
inferred← citeshttps://doi.org/10.1021/ja908817nopenalex-snapshot
Interaction of Molecular Hydrogen with Microporous Metal Organic Framework Materials at Room Temperature
inferred← citeshttps://doi.org/10.1021/jacs.5b13038openalex-snapshot
In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework
inferred← citeshttps://doi.org/10.1021/jacs.7b07925openalex-snapshot
Exploiting Diffusion Barrier and Chemical Affinity of Metal–Organic Frameworks for Efficient Hydrogen Isotope Separation
inferred← citeshttps://doi.org/10.1021/jacs.7b13825openalex-snapshot
Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks
inferred← citeshttps://doi.org/10.1021/jacs.9b05967openalex-snapshot
Preserving Porosity of Mesoporous Metal–Organic Frameworks through the Introduction of Polymer Guests
inferred← citeshttps://doi.org/10.1021/jp104175nopenalex-snapshot
Origin of the Enhanced Interaction of Molecular Hydrogen with Extraframework Cu+ and FeO+ Cations in Zeolite Hosts. A Periodic DFT Study
inferred← citeshttps://doi.org/10.1021/jp1055039openalex-snapshot
Probing the Room Temperature Spatial Distribution of Hydrogen in Nanoporous Carbon by Use of Small-Angle Neutron Scattering
inferred← citeshttps://doi.org/10.1021/jp200638nopenalex-snapshot
Neutron Scattering and Spectroscopic Studies of Hydrogen Adsorption in Cr3(BTC)2—A Metal−Organic Framework with Exposed Cr2+ Sites
inferred← citeshttps://doi.org/10.1021/jp2010937openalex-snapshot
Structural Study of D2 within the Trimodal Pore System of a Metal Organic Framework
inferred← citeshttps://doi.org/10.1021/jp208529popenalex-snapshot
Site-Specific CO 2 Adsorption and Zero Thermal Expansion in an Anisotropic Pore Network
inferred← citeshttps://doi.org/10.1021/jp308066eopenalex-snapshot
Dehydrogenation of Ammonia Borane Confined by Low-Density Porous Aromatic Framework
inferred← citeshttps://doi.org/10.1021/jp308176fopenalex-snapshot
Evaluation of the Thermodynamic Properties of H2 Binding in Solid State Dihydrogen Complexes [M(η2-H2)(CO)dppe2][BArF24] (M = Mn, Tc, Re): An Experimental and First Principles Study
inferred← citeshttps://doi.org/10.1021/jp510253mopenalex-snapshot
Understanding the H2 Sorption Trends in the M-MOF-74 Series (M = Mg, Ni, Co, Zn)
inferred← citeshttps://doi.org/10.1021/jp5104356openalex-snapshot
Insights into the Anomalous Vibrational Frequency Shifts of CO2 Adsorbed to Metal Sites in Microporous Frameworks
inferred← citeshttps://doi.org/10.1021/jp803714jopenalex-snapshot
Hydrogen Storage in Copper Prussian Blue Analogues: Evidence of H 2 Coordination to the Copper Atom
inferred← citeshttps://doi.org/10.1021/jp8106588openalex-snapshot
Multiadsorption and Coadsorption of Hydrogen on Model Conjugated Systems
inferred← citeshttps://doi.org/10.1021/jp9031767openalex-snapshot
Spectroscopic Study of the Benchmark Mn+−H2 Complex
inferred← citeshttps://doi.org/10.1021/jp907921qopenalex-snapshot
An Ab Initio Force Field for Predicting Hydrogen Storage in IRMOF Materials
inferred← citeshttps://doi.org/10.1021/jp910544jopenalex-snapshot
Structure of Porous Copper Prussian Blue Analogues: Nature of Their High H2 Storage Capacity
inferred← citeshttps://doi.org/10.1021/jz100558ropenalex-snapshot
Adsorption Sites and Binding Nature of CO2 in Prototypical Metal−Organic Frameworks: A Combined Neutron Diffraction and First-Principles Study
inferred← citeshttps://doi.org/10.1021/la200547kopenalex-snapshot
Effect of Humidity on the Performance of Microporous Coordination Polymers as Adsorbents for CO2 Capture
inferred← citeshttps://doi.org/10.1021/la4043556openalex-snapshot
Microporous Coordination Polymers as Efficient Sorbents for Air Dehumidification
inferred← citeshttps://doi.org/10.1021/nn405420topenalex-snapshot
Highly Effective Hydrogen Isotope Separation in Nanoporous Metal–Organic Frameworks with Open Metal Sites: Direct Measurement and Theoretical Analysis
inferred← citeshttps://doi.org/10.1038/ncomms13871openalex-snapshot
Trapping gases in metal-organic frameworks with a selective surface molecular barrier layer
inferred← citeshttps://doi.org/10.1038/s41467-024-45082-9openalex-snapshot
Experimentally validated design principles of heteroatom-doped-graphene-supported calcium single-atom materials for non-dissociative chemisorption solid-state hydrogen storage
inferred← citeshttps://doi.org/10.1038/s41598-019-51344-0openalex-snapshot
Investigation of Ionic Liquid interaction with ZnBDC-Metal Organic Framework through Scanning EXAFS and Inelastic Neutron Scattering
inferred← citeshttps://doi.org/10.1039/9781849737586-00143openalex-snapshot
Characterization of MOFs. 2. Long and Local Range Order Structural Determination of MOFs by Combining EXAFS and Diffraction Techniques
inferred← citeshttps://doi.org/10.1039/b802256aopenalex-snapshot
Hydrogen storage in metal–organic frameworks
inferred← citeshttps://doi.org/10.1039/b808322nopenalex-snapshot
The current status of hydrogen storage in metal–organic frameworks
inferred← citeshttps://doi.org/10.1039/b814155jopenalex-snapshot
Enhancement of H2 adsorption in Li+-exchanged co-ordination framework materials
inferred← citeshttps://doi.org/10.1039/b815583fopenalex-snapshot
Adsorption and desorption of hydrogen on metal–organic framework materials for storage applications: comparison with other nanoporous materials
inferred← citeshttps://doi.org/10.1039/b818951jopenalex-snapshot
Hydrogen storage materials: present scenarios and future directions
inferred← citeshttps://doi.org/10.1039/b911242aopenalex-snapshot
Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide
inferred← citeshttps://doi.org/10.1039/b916295jopenalex-snapshot
Gas storage in porous metal–organic frameworks for clean energy applications
inferred← citeshttps://doi.org/10.1039/b920995fopenalex-snapshot
An unusual case of symmetry-preserving isomerism
inferred← citeshttps://doi.org/10.1039/b921442aopenalex-snapshot
Ammonia dynamics in magnesium ammine from DFT and neutron scattering
inferred← citeshttps://doi.org/10.1039/c0cc00091dopenalex-snapshot
Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)
inferred← citeshttps://doi.org/10.1039/c0cc03453copenalex-snapshot
Hydrogen storage properties and neutron scattering studies of Mg 2 (dobdc)—a metal–organic framework with open Mg 2+ adsorption sites
inferred← citeshttps://doi.org/10.1039/c0ce00122hopenalex-snapshot
Dense and homogeneous coatings of CPO-27-M type metal–organic frameworks on alumina substrates
inferred← citeshttps://doi.org/10.1039/c0ee00700eopenalex-snapshot
Carbon capture in metal–organic frameworks—a comparative study
inferred← citeshttps://doi.org/10.1039/c0sc00179aopenalex-snapshot
Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal–organic framework (Fe-BTT) discovered via high-throughput methods
inferred← citeshttps://doi.org/10.1039/c1cp21865dopenalex-snapshot
From microscopic insights of H2 adsorption to uptake estimations in MOFs
inferred← citeshttps://doi.org/10.1039/c1ee01720aopenalex-snapshot
Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
inferred← citeshttps://doi.org/10.1039/c1gc15726dopenalex-snapshot
Near-critical water, a cleaner solvent for the synthesis of a metal–organic framework
inferred← citeshttps://doi.org/10.1039/c2cc37793dopenalex-snapshot
Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO2
inferred← citeshttps://doi.org/10.1039/c2cp23146hopenalex-snapshot
Confinement effects in the hydrogen adsorption on paddle wheel containing metal–organic frameworks
inferred← citeshttps://doi.org/10.1039/c2cs35251fopenalex-snapshot
Methane storage in advanced porous materials
inferred← citeshttps://doi.org/10.1039/c2dt12138gopenalex-snapshot
Hydrogen adsorption in the metal–organic frameworks Fe2(dobdc) and Fe2(O2)(dobdc)
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