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(.eta.5-Indenyl)trichlorotitanium. An improved syndiotactic polymerization catalyst for styrene

https://doi.org/10.1021/ma00073a046
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[Ti{H 5 -1-(Sime3)-3-(R)-C9h5}Cl2(Oet)] Half-Sandwich Complexes: Synthesis, Solid-State Structure, Hirshfeld Surface Analysis and Theoretical Studies
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Syndiospecific polymerization of styrene: Activity enhancement of Ti/MAO catalytic systems in the presence of SnR4 compounds
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Syndiospecific polymerization of styrene using fluorinated indenyltitanium complexes
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Polymerization of styrene with supported half-sandwich complexes
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Single‐Site Catalysts
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Single‐Site Catalysts
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Syndiotactic Polystyrene
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Syndiotactic Polystyrene
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Stereoregular Polymers
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Copolymerization of 1-hexene and ethylene catalyzed by the Ziegler catalyst Cp*TiMe3/B(C6F5)3
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Olefin polymerization with Me 4 Cp–Amido complexes with electron‐withdrawing groups
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Grafting of syndiotactic polystyrene by branched oligoethene using [Ni(?-methallyl)(Br)]2/AlCl3 catalyst
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Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV)
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Transition Metal Catalysts for Syndiotactic Polystyrene
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Structure and Properties of Tetrabenzo[ a,c,g,i ]Fluorenyl‐Based Titanium Catalysts
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Stereospezifische Olefinpolymerisation mit chiralen Metallocenkatalysatoren
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Chain Transfer to Toluene in Styrene Coordination Polymerization
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Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts
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Chain Transfer to Toluene in Styrene Coordination Polymerization
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Syndiotactic polymerization of styrene catalyzed by alkenyl‐substituted cyclopentadienyltitanium trichlorides
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Syndiotactic polymerization of styrene: Study of catalyst components and polymerization conditions
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Comparison of catalytic behaviors of various silica‐supported metallocene catalysts in syndiospecific polymerization of styrene
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A kinetic study of novel bimetallic titanocene catalyst for syndiospecific styrene polymerization
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Catalytic Behavior of Half‐Metallocene Non‐Cp‐Type Group 4 Metal Complexes (M=Zr, Hf) with a Cyclooctatetraenyl Dianion during Olefin Polymerization
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A combined NMR and electron spin resonance investigation of the (C5(CH3)5)Ti(CH2C6H5)3/B(C6F5)3 catalytic system active in the syndiospecific styrene polymerization
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Syndiotactic specific polymerization of styrene: driving energy of the steric control and reaction mechanism
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Syndiotactic polymerization of styrene with cyclopentadienyltribenzyloxytitanium/methylaluminoxane catalyst
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Quantitative Correlation between Steric Defects and Thermal Behavior in Highly Syndiotactic Polystyrene: A Study Based on DSC and 13C NMR Spectroscopy
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Stereochemical Structure of Polypropylene Obtained in the Presence of Half‐Sandwich Titanium Complexes
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Effect of Different Aluminum Alkyls on the Metallocene/Methylaluminoxane Catalyzed Polymerization of Higher α‐Olefins and Styrene
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Stereospecific Styrene Polymerization by Methylalumoxane‐Activated Ti (IV) N‐Trimethylsilylamido Complexes Bearing the N‐Biphenyl or N‐(6‐(2‐(Diethylboryl)phenyl)‐Pyrid‐2‐yl) Motif
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Syndiospecific polymerization of styrene with arene titanium(II) complexes as catalyst precursors
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Amalgamation of ziegler‐natta and metallocene catalysts
inferred← citeshttps://doi.org/10.1002/masy.200851407openalex-snapshot
Comparison of Syndiotactic Polystyrene Morphology Obtained Via Heterogeneous and Homogeneous Polymerization with Metallocene Catalyst
inferred← citeshttps://doi.org/10.1002/pen.22132openalex-snapshot
Polymerization of ethylene using amido functional half‐sandwich complexes of group 4 metals
inferred← citeshttps://doi.org/10.1002/pi.966openalex-snapshot
Polymerization of olefins and polar monomers catalyzed by bis(imino)Ni(II)/dibutylmagnesium/alkylaluminium halide systems
inferred← citeshttps://doi.org/10.1002/pola.10022openalex-snapshot
Syndiospecific living polymerization of 4‐methylstyrene and styrene with (trimethyl)pentamethylcyclopentadienyltitanium/tris(pentafluorophenyl)borane/trioctylaluminum catalytic system
inferred← citeshttps://doi.org/10.1002/pola.10631openalex-snapshot
Copolymerization of styrene and conjugated dienes with half‐sandwich titanium(IV) catalysts: The effect of the ligand structure on the monomer reactivity, monomer sequence distribution, and insertion mode of dienes
inferred← citeshttps://doi.org/10.1002/pola.1159openalex-snapshot
Syndiospecific polymerization of styrene catalyzed by CpTiCl2(OR) complexes
inferred← citeshttps://doi.org/10.1002/pola.20621openalex-snapshot
Syndiospecific polymerization of styrene with Cp*TiCl((OCH(R)CH2)2NAr)/MMAO
inferred← citeshttps://doi.org/10.1002/pola.20715openalex-snapshot
Novel catalyst compositions for the syndiospecific polymerization of styrene prepared by the combination of cyclopentadenyl complexes of group IIA or group IIIA elements with titanium alkoxides
inferred← citeshttps://doi.org/10.1002/pola.20948openalex-snapshot
Consideration of the mechanism of styrene/ethylene copolymerization with half‐titanocene catalysts
inferred← citeshttps://doi.org/10.1002/pola.20970openalex-snapshot
The ligand effect in Ti‐mediated living radical styrene polymerizations initiated by epoxide radical ring opening. 2. Scorpionate and half‐sandwich LTiCl3 complexes
inferred← citeshttps://doi.org/10.1002/pola.21220openalex-snapshot
Ligand effect in Ti‐mediated living radical styrene polymerizations initiated by epoxide radical ring opening. III. Substituted sandwich metallocenes
inferred← citeshttps://doi.org/10.1002/pola.21307openalex-snapshot
Titanium‐mediated living radical styrene polymerizations. V. Cp2TiCl‐catalyzed initiation by epoxide radical ring opening: Effect of solvents and additives
inferred← citeshttps://doi.org/10.1002/pola.21326openalex-snapshot
Titanium‐mediated living radical styrene polymerizations. VI. Cp2TiCl‐catalyzed initiation by epoxide radical ring opening: Effect of the reducing agents, temperature, and titanium/epoxide and titanium/zinc ratios
inferred← citeshttps://doi.org/10.1002/pola.22765openalex-snapshot
Factors affecting product distributions in ethylene/styrene copolymerization by (aryloxo)(cyclopentadienyl)titanium complexes‐MAO catalyst systems
inferred← citeshttps://doi.org/10.1002/zaac.200700127openalex-snapshot
Indenyl‐Titanchloride: Ethen‐Polymerisation und Struktur‐Reaktivitäts‐Untersuchungen
inferred← citeshttps://doi.org/10.1007/978-3-642-36199-9_180-1openalex-snapshot
Coordination Polymerization (Styrene and Polar Vinyl Monomers)
inferred← citeshttps://doi.org/10.1007/978-3-642-60178-1_49openalex-snapshot
Styrene and Conjugated Dienes Polymerization with Half Sandwich Titanocene Catalysts
inferred← citeshttps://doi.org/10.1007/978-3-642-79136-9_11openalex-snapshot
Advances in Ziegler Catalysts
inferred← citeshttps://doi.org/10.1007/bf00295768openalex-snapshot
Syndiotactic polymerization of styrene with CpTiCl2(OPri)/methylaluminoxane
inferred← citeshttps://doi.org/10.1007/bf03247206openalex-snapshot
Syndiospecific polymerization of styrene using a heterogeneous titanocene catalyst
inferred← citeshttps://doi.org/10.1007/s00289-005-0405-2openalex-snapshot
Styrene Polymerization by TpTiCl2(OR) Precatalysts
inferred← citeshttps://doi.org/10.1007/s10562-011-0706-zopenalex-snapshot
Preparation of Tethered Half-Titanocene Complex on Syndiotactic Poly(styrene-co-p-methylstyrene) for Using in Syndiospecific Polymerization of Styrene
inferred← citeshttps://doi.org/10.1007/s10563-010-9086-4openalex-snapshot
Syndiospecific Styrene Polymerization and Ethylene/Styrene Copolymerization Using Half-Titanocenes: Ligand Effects and Some New Mechanistic Aspects
inferred← citeshttps://doi.org/10.1007/s10965-022-03411-wopenalex-snapshot
Syndiospecific polymerization of styrene by half-metallocene with a naphthoxy group ligand
inferred← citeshttps://doi.org/10.1007/s11224-025-02535-1openalex-snapshot
[Ti{η5-C9H7}Cl2(OR)] half-sandwich complexes: synthesis and theoretical studies on substituent effects on the HOMO − LUMO energy gap
inferred← citeshttps://doi.org/10.1016/0022-328x(94)05094-ropenalex-snapshot
Cyclische amine als intramolekulare hilfsliganden in π-komplexen des titans
inferred← citeshttps://doi.org/10.1016/0022-328x(94)05161-4openalex-snapshot
Monoindenyl halides of zirconium and hafnium. The preparation of [(η5-C9H7)ZrCl3]n and [(η5-C9H7)HfCl2(μ-Cl)]2 and the crystal structure of [(η5-C9H7)HfCl2(μ-Cl)]2
inferred← citeshttps://doi.org/10.1016/0022-328x(94)84087-3openalex-snapshot
Homogeneous group 4 metallocene ziegler-natta catalysts: The influence of cyclopentadienyl-ring substituents
inferred← citeshttps://doi.org/10.1016/0022-328x(95)00111-3openalex-snapshot
Polymerization of norbornene and 1,5-hexadiene by [Cp∗TiMe2][MeB(C6F5)3]
inferred← citeshttps://doi.org/10.1016/0022-328x(95)05590-lopenalex-snapshot
Indenyl effect in d0-transition metal complexes: synthesis, molecular structure and lactone polymerization activity of [Ti(η5-C9H7)Cl2OMe)]
inferred← citeshttps://doi.org/10.1016/0022-328x(95)06084-aopenalex-snapshot
Electrophilic addition of CCl4 to a cyclopentadienyl ligand in the tungstenocene carbonyl [W(η5-C5H5)2(CO)] to give [W(η5-C5H5)(η4-C5H5-exo-CCl3)(CO) Cl]
inferred← citeshttps://doi.org/10.1016/0022-328x(96)06350-4openalex-snapshot
Linked amido-indenyl complexes of titanium
inferred← citeshttps://doi.org/10.1016/0079-6700(95)00016-xopenalex-snapshot
Synthesis of syndiotactic polystyrene: Reaction mechanisms and catalysis
inferred← citeshttps://doi.org/10.1016/b0-08-045047-4/00061-3openalex-snapshot
Complexes of Titanium in Oxidation State iv
inferred← citeshttps://doi.org/10.1016/b0-08-045047-4/00065-0openalex-snapshot
Olefin Polymerizations with Group IV Metal Catalysts
inferred← citeshttps://doi.org/10.1016/j.apcata.2009.02.047openalex-snapshot
Polystyrene with half-titanocene/MAO catalysts: Influence of 2,6-diisopropylphenol
inferred← citeshttps://doi.org/10.1016/j.ccr.2007.12.015openalex-snapshot
Group 3 and 4 single-site catalysts for stereospecific polymerization of styrene
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Novel metallocene catalysts for syndiotactic polystyrene
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2004.01.024openalex-snapshot
Titanium isodicyclopentadienide hemimetallocenes for ethylene/styrene copolymerization
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2004.03.001openalex-snapshot
Various silyl-substituted cyclopentadienyl titanium complexes [CpSi(CH3)2X]TiCl3 as catalysts for syndiotactic polystyrene
inferred← citeshttps://doi.org/10.1016/j.ica.2008.06.019openalex-snapshot
New phospholyl complexes of groups 4 and 6: Syntheses, characterisation and polymerisation studies
inferred← citeshttps://doi.org/10.1016/j.ica.2018.03.003openalex-snapshot
Ti(ƞ5-1-SiMe3-C9H6)(Cl)2(OR): Structure and bonding
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2003.10.005openalex-snapshot
Titanium ketimide complexes as α-olefin homo- and copolymerisation catalysts. X-ray diffraction structures of [TiCp′(NC Bu2)Cl2] (Cp′=Ind, Cp*)
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2004.01.031openalex-snapshot
Synthesis of new substituted cyclopentadienyl titanium monomethoxydifluorides with BF3· OEt2 as fluorinating reagent and their use in syndiotactic polymerization of styrene
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2008.02.005openalex-snapshot
Synthesis, characterization, and catalytic activities in syndiospecific polymerization of styrene for half-sandwich titanium complexes with non-Cp tridentate dianionic ligands MeN(CH2CR2O−)2
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2008.09.015openalex-snapshot
Synthesis, characterization, and polymerization activity of (pentamethylcyclopentadienyl)titanatranes containing {(O-2,4-Me2C6H2-6-CH2) N(CH2CH2O)3−}3− (n= 0–2) or {N(C6H4-2-O)3}3−
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2010.12.010openalex-snapshot
Synthesis, X-ray structures, and syndiospecific polymerization behavior of styrene of new (pentamethylcyclopentadientyl) titanatranes containing modified tetradentate triethanolamine ligands
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2016.10.035openalex-snapshot
Titanium(IV) complexes bearing the (CpC)− ligand
inferred← citeshttps://doi.org/10.1016/j.molcata.2003.07.002openalex-snapshot
Synthesis and polymerization behavior of various substituted half-sandwich titanium complexes Cp′TiCl2(OR∗) as catalysts for syndiotactic polystyrene
inferred← citeshttps://doi.org/10.1016/j.molcata.2005.05.032openalex-snapshot
Effect of the alkoxyl ligands on ethylene polymerization by TpTiCl2(OR) complexes
inferred← citeshttps://doi.org/10.1016/j.molcata.2006.08.076openalex-snapshot
Styrene polymerization with half-sandwiched titanocene trichloride catalysts combined with alkylaluminum-Ph3CB(C6F5)4 cocatalyst systems
inferred← citeshttps://doi.org/10.1016/j.molcata.2010.01.001openalex-snapshot
Preparation of tethered half-titanocene complex on cross-linked polystyrene beads for using in syndiospecific polymerization of styrene
inferred← citeshttps://doi.org/10.1016/j.molcata.2013.11.032openalex-snapshot
(ArO)TiR3 complexes for highly syndiospecific styrene polymerization
inferred← citeshttps://doi.org/10.1016/j.molstruc.2024.138510openalex-snapshot
[Ti{η5-1-(SiMe3)-3-(R)-C9H5}Cl2(OEt)] half-sandwich complexes: Synthesis, solid-state structure, hirshfeld surface analysis and theoretical studies
inferred← citeshttps://doi.org/10.1016/j.poly.2006.03.006openalex-snapshot
Diphenyl substituted cyclopentadienyl titanium trichloride derivatives: Synthesis, crystal structure and properties as catalysts for styrene polymerization
inferred← citeshttps://doi.org/10.1016/j.poly.2011.10.021openalex-snapshot
Tris(4-hydroxy-3,5-diisopropylbenzyl)amine as a new bridging ligand for novel trinuclear titanium complexes
inferred← citeshttps://doi.org/10.1016/j.polymdegradstab.2005.01.053openalex-snapshot
Thermal degradation of poly(vinyl chloride) synthesized with a titanocene catalyst
inferred← citeshttps://doi.org/10.1016/j.polymdegradstab.2005.03.020openalex-snapshot
Poly(vinyl alcohol) obtained by hydrolysis of poly(vinyl silyl ethers) and poly(vinyl ethers) synthesized with indenyltitanium trichloride
inferred← citeshttps://doi.org/10.1016/s0014-3057(02)00045-9openalex-snapshot
Syndiotactic polymerization of styrene by 1-(Me)IndTiCl2(OR)/MAO system
inferred← citeshttps://doi.org/10.1016/s0014-3057(98)00137-2openalex-snapshot
Syndiotactic polymerization of styrene with half-sandwich titanocenes
inferred← citeshttps://doi.org/10.1016/s0020-1693(02)01240-9openalex-snapshot
Bridged and unbridged substituted indenyl complexes of titanium and zirconium as catalysts for homogeneous and heterogeneous homo- and copolymerization of olefins
inferred← citeshttps://doi.org/10.1016/s0022-328x(01)00781-1openalex-snapshot
Amido functionalized ansa half-sandwich dichloride complexes of titanium, zirconium and hafnium with alkyl and ω-alkenyl substituents as homogeneous and self-immobilizing catalyst precursors for ethylene polymerization
inferred← citeshttps://doi.org/10.1016/s0022-328x(01)00937-8openalex-snapshot
Ferrocenes derived from cyclopenta[l]phenanthrene: dibenzindene–metal complexes that resist haptotropic shifts
inferred← citeshttps://doi.org/10.1016/s0022-328x(01)01105-6openalex-snapshot
New half-sandwich metallocene catalysts for polyethylene and polystyrene
inferred← citeshttps://doi.org/10.1016/s0022-328x(02)01555-3openalex-snapshot
Syndiotactic polystyrene with very high molecular weight produced by sterically and electronically modified catalyst
inferred← citeshttps://doi.org/10.1016/s0022-328x(96)06153-0openalex-snapshot
Alkyl-substituted indenyl titanium precursors for syndiospecific ziegler-natta polymerization of styrene
inferred← citeshttps://doi.org/10.1016/s0022-328x(96)06481-9openalex-snapshot
Unverbrückte (Pentamethylcyclopentadienyl)(fluorenyl)-Komplexe des zirconiums und hafniums. Die molekülstrukturen von (C5Me5) (2,7-Me2C13H7)MCl2 (M Zr, Hf)
inferred← citeshttps://doi.org/10.1016/s0022-328x(96)06607-7openalex-snapshot
Synthesis and polymerization behavior of various substituted indenyl titanium complexes as catalysts for syndiotactic polystyrene
inferred← citeshttps://doi.org/10.1016/s0022-328x(96)06622-3openalex-snapshot
The formation and structures of the methyl-bridged complexes Cp∗TiMe2(μ-Me)B(C6F5)3 and [Cp∗TiMe2(μ-Me)TiMe2Cp∗][MeB(C6F5)3]
inferred← citeshttps://doi.org/10.1016/s0022-328x(96)06625-9openalex-snapshot
The synthesis and polymerization behavior of methoxy-substituted (indenyl) trichlorotitanium complexes
inferred← citeshttps://doi.org/10.1016/s0022-328x(97)00251-9openalex-snapshot
Cyclopenta[l]phenanthrene titanium trichloride derivatives: syntheses, crystal structure and properties as catalysts for styrene polymerization
inferred← citeshttps://doi.org/10.1016/s0022-328x(97)00258-1openalex-snapshot
Titanium-catalysed formation of high molecular weight elastomeric polypropene: evidence for living propene polymerisation
inferred← citeshttps://doi.org/10.1016/s0022-328x(97)00443-9openalex-snapshot
Synthesis and reactivity of new silyl substituted monocyclopentadienyl zirconium complexes. X-ray molecular structure of [Zrη5-C5H4 (SiMe2CH2Ph)(CH2Ph)3]
inferred← citeshttps://doi.org/10.1016/s0022-328x(98)00361-1openalex-snapshot
Binuclear monoindenyl–titanium(IV) complexes. Synthesis and styrene polymerization catalysis
inferred← citeshttps://doi.org/10.1016/s0022-328x(98)00388-xopenalex-snapshot
Siloxy-substituted tetramethylcyclopentadienyl and indenyl trichlorotitanium complexes for syndiospecific polymerization of styrene
inferred← citeshttps://doi.org/10.1016/s0022-328x(98)01209-1openalex-snapshot
Ethylene and propylene polymerization by cationic monocyclopentadienyl titanium catalysts containing the weakly coordinating anion [B(C6F5)4]−
inferred← citeshttps://doi.org/10.1016/s0032-3861(00)00607-8openalex-snapshot
Isospecific polymerization of styrene with modified ziegler-type catalysts
inferred← citeshttps://doi.org/10.1016/s0040-4020(98)01208-3openalex-snapshot
Preparation of bifluorenes via the synthesis and thermal decomposition of fluorenyltitanium(IV) trichlorides. Molecular and crystal structure of 9,9′-bis(trimethylsilyl)-bi-9,9′-fluorene
inferred← citeshttps://doi.org/10.1016/s0079-6700(01)00014-4openalex-snapshot
Recent developments in olefin polymerizations with transition metal catalysts
inferred← citeshttps://doi.org/10.1016/s0079-6700(02)00026-6openalex-snapshot
Syndiotactic polystyrene catalysts and polymerization
inferred← citeshttps://doi.org/10.1016/s1381-1169(01)00082-6openalex-snapshot
Steric and electronic effects of the R in IndTiCl 2 (OR) catalysts on the syndiospecific polymerization of styrene
inferred← citeshttps://doi.org/10.1016/s1381-1169(01)00219-9openalex-snapshot
Amido functionalized ansa fluorenylidene half-sandwich complexes of zirconium as catalyst precursors for homogeneous ethylene polymerization
inferred← citeshttps://doi.org/10.1016/s1381-1169(02)00223-6openalex-snapshot
Effect of ligand in ethylene/styrene copolymerization by [Me2Si(C5Me4)(NR)]TiCl2 (R = tert-Bu, cyclohexyl) and (1,3-Me2C5H3)TiCl2(O-2,6- Pr2C6H3)-MAO catalyst system
inferred← citeshttps://doi.org/10.1016/s1381-1169(02)00412-0openalex-snapshot
Syndiospecific polymerization of styrene catalyzed in situ by alkoxyl substituted half-sandwich titanocene and BF3·Et2O
inferred← citeshttps://doi.org/10.1016/s1381-1169(97)00169-6openalex-snapshot
Olefin polymerisation promoted by monodicarbollide complexes of group 4 metals
inferred← citeshttps://doi.org/10.1016/s1381-1169(97)00171-4openalex-snapshot
Syndiospecific polymerization of styrene
inferred← citeshttps://doi.org/10.1016/s1381-1169(98)00227-1openalex-snapshot
Butadiene polymerization with various half-titanocenes
inferred← citeshttps://doi.org/10.1016/s1387-7003(01)00364-1openalex-snapshot
A 2-indenyl-amido-bridged titanium complex with Cs-symmetry
inferred← citeshttps://doi.org/10.1016/s1387-7003(99)00022-2openalex-snapshot
Preparation of a new type of half-sandwich (alkoxylalkylcyclopentadienyl)titanium trichloride complex and X-ray structural characterization of (CH3OCH2CH(CH3)C5H4)TiCl3
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b01707openalex-snapshot
Syndioselective Polymerization of a BN Aromatic Vinyl Monomer
inferred← citeshttps://doi.org/10.1021/acscatal.5b02334openalex-snapshot
Nature of the Entire Range of Rare Earth Metal-Based Cationic Catalysts for Highly Active and Syndioselective Styrene Polymerization
inferred← citeshttps://doi.org/10.1021/cr980462jopenalex-snapshot
Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships
inferred← citeshttps://doi.org/10.1021/ic970178vopenalex-snapshot
Preparation and Molecular Structure of the Unconventional Tantalum Chloride Complex [(η5-C9H7)2TaCl2][TaCl6]
inferred← citeshttps://doi.org/10.1021/ja077272nopenalex-snapshot
Syndiotactic Polystyrene Nanofibrils in Silica Nanotube Reactors: Understanding of Synthesis with Ultrahigh Molecular Weight
inferred← citeshttps://doi.org/10.1021/ja973769topenalex-snapshot
Sterically Encumbered (Perfluoroaryl) Borane and Aluminate Cocatalysts for Tuning Cation−Anion Ion Pair Structure and Reactivity in Metallocene Polymerization Processes. A Synthetic, Structural, and Polymerization Study
inferred← citeshttps://doi.org/10.1021/ja990617kopenalex-snapshot
Silicon-Modified Ziegler−Natta Polymerization. Catalytic Approaches to Silyl-Capped and Silyl-Linked Polyolefins Using “Single-Site” Cationic Ziegler−Natta Catalysts
inferred← citeshttps://doi.org/10.1021/ma011813qopenalex-snapshot
Neutral Olefin Polymerization Activators as Highly Active Catalysts for ROP of Heterocyclic Monomers and for Polymerization of Styrene
inferred← citeshttps://doi.org/10.1021/ma900041copenalex-snapshot
Half-Titanocene-Based Catalysts in the Syndiospecific Polymerization of Styrenes: Possible Oxidation States of the Titanium Species and Geometries of the Active Sites
inferred← citeshttps://doi.org/10.1021/ma9604294openalex-snapshot
{[2-(Dimethylamino)ethyl]cyclopentadienyl}titanium Complexes. Influence of the Dimethylamino Group in Ziegler−Natta Polymerization Catalysis
inferred← citeshttps://doi.org/10.1021/ma9605863openalex-snapshot
Synthesis and Mechanism of Formation of Syndiotactic Polystyrene Using a (tert-Butylcyclopentadienyl)titanium Complex
inferred← citeshttps://doi.org/10.1021/ma961504dopenalex-snapshot
Syndiospecific Styrene Polymerization Promoted by Half-Titanocene Catalysts: A Kinetic Investigation Providing a Closer Insight to the Active Species
inferred← citeshttps://doi.org/10.1021/ma9712763openalex-snapshot
Cationic Titanocene Catalysts for Syndiospecific Polymerization of Styrene
inferred← citeshttps://doi.org/10.1021/ma980324wopenalex-snapshot
Polymerization of Isobutylene and the Copolymerization of Isobutylene and Isoprene Initiated by the Metallocene Derivative Cp*TiMe2(μ-Me)B(C6F5)3
inferred← citeshttps://doi.org/10.1021/ma991036iopenalex-snapshot
Synthesis and Characterization of Poly(styrene-co-4-[(tert-butyldimethylsilyl)oxy]styrene) as a Precursor of Hydroxyl-Functionalized Syndiotactic Polystyrene
inferred← citeshttps://doi.org/10.1021/ma992011mopenalex-snapshot
Syndiospecific Polymerization of Styrene with Half-Sandwich Titanocene Catalysts. Influence of Ligand Pattern on Polymerization Behavior
inferred← citeshttps://doi.org/10.1021/ma992121topenalex-snapshot
Syntheses of syndiotactic-Polystyrene-graft-poly(methyl methacrylate), syndiotactic-Polystyrene-graft-poly(methyl acrylate), and syndiotactic-Polystyrene-graft-atactic-polystyrene with Defined Structures by Atom Transfer Radical Polymerization
inferred← citeshttps://doi.org/10.1021/om010459hopenalex-snapshot
Chelating Aryloxide Ligands in the Synthesis of Titanium, Niobium, and Tantalum Compounds: Electrochemical Studies and Styrene Polymerization Activities
inferred← citeshttps://doi.org/10.1021/om0109197openalex-snapshot
New Titanatranes: Characterization and Styrene Polymerization Behavior
inferred← citeshttps://doi.org/10.1021/om030211nopenalex-snapshot
Insertion of Isocyanides into Group 4 Metal−Carbon and Metal−Nitrogen Bonds. Syntheses and DFT Calculations
inferred← citeshttps://doi.org/10.1021/om0400898openalex-snapshot
Trimethylsilyl-Substituted Indenyl-TiCl3 Half-Sandwich Complexes: Synthesis, Solid-State Structure, and Analysis of Substituent Effects
inferred← citeshttps://doi.org/10.1021/om0602613openalex-snapshot
Tetrabenzo[a,c,g,i]fluorenyllithium and η5-Tetrabenzo[a,c,g,i]fluorenyltitanium Complexes
inferred← citeshttps://doi.org/10.1021/om060909bopenalex-snapshot
Preparation and X-ray Structures of Alkyl−Titanium(IV) Complexes Stabilized by Indenyl Ligands with a Pendant Ether or Amine Substituent and Their Use in the Catalytic Hydroamination of Alkynes
inferred← citeshttps://doi.org/10.1021/om0609564openalex-snapshot
Efficient Direct Synthesis of Tropidinyl Titanium and Zirconium Complexes by Allylic CH-Activation of 8-Methyl-8-azabicyclo[3.2.1]oct-2-ene (Tropidine)
inferred← citeshttps://doi.org/10.1021/om1000265openalex-snapshot
Stereoselective Polymerization of Styrene with Cationic Scandium Precursors Bearing Quinolyl Aniline Ligands
inferred← citeshttps://doi.org/10.1021/om7012293openalex-snapshot
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
inferred← citeshttps://doi.org/10.1021/om9501945openalex-snapshot
Ethylene, Styrene, and α-Methylstyrene Polymerization by Mono(pentamethylcyclopentadienyl) (Cp*) Complexes of Titanium, Zirconium, and Hafnium: Roles of Cationic Complexes of the Type [Cp*MR2]+ (R = Alkyl) as both Coordination Polymerization Catalysts and Carbocationic Polymerization Initiators
inferred← citeshttps://doi.org/10.1021/om950666fopenalex-snapshot
Reductive Decomposition of Cationic Half-Titanocene(IV) Complexes, Precursors of the Active Species in Syndiospecific Styrene Polymerization
inferred← citeshttps://doi.org/10.1021/om950990aopenalex-snapshot
Highly Stable Catalysts for the Stereospecific Polymerization of Styrene
inferred← citeshttps://doi.org/10.1021/om960475sopenalex-snapshot
[1-(2-Phenylethyl)-2,3,4,5-tetramethylcyclopentadienyl]- titanium Compounds. Synthesis and Their Use for the Syndiospecific Polymerization of Styrene
inferred← citeshttps://doi.org/10.1021/om980118copenalex-snapshot
Pendent Aminoalkyl-Substituted Monocyclopentadienyltitanium Compounds and Their Polymerization Behavior
inferred← citeshttps://doi.org/10.1021/om9805382openalex-snapshot
Oxidation States of Active Species for Syndiotactic-Specific Polymerization of Styrene
inferred← citeshttps://doi.org/10.1021/om980784dopenalex-snapshot
(Pentamethylcyclopentadienyl)titanatrane: A New Class of Catalyst for Syndiospecific Polymerization of Styrene
inferred← citeshttps://doi.org/10.1023/a:1007093825712openalex-snapshot
Ethene polymerization with mixed-ring metallocene catalysts, Cp′Cp″MCl2, M = Ti and Zr
inferred← citeshttps://doi.org/10.1023/a:1019072829203openalex-snapshot
inferred← citeshttps://doi.org/10.1039/a605470fopenalex-snapshot
Cyclopentadienyl, indenyl and bis(cyclopentadienyl) titanium imido compounds
inferred← citeshttps://doi.org/10.1039/a703192kopenalex-snapshot
Zirconium and hafnium diene and dienyl half-sandwich complexes: synthesis, polymerization catalysis and deactivation pathways. The molecular structures of [M(η3-C3H5)(2,3-Me2 C4H4){η-C5H 3(SiMe3)2-1,3}] (M = Zr or Hf ) and [Hf(η3-C3H5){ η3-CH2CMeCMeCH2B(C6 F5)3}{η-C5 H3(SiMe2)-1,3}]
inferred← citeshttps://doi.org/10.1039/a908435eopenalex-snapshot
Trichloro monophenoxide complexes of titanium(IV)
inferred← citeshttps://doi.org/10.1039/b006889fopenalex-snapshot
Titanium indenyldimethylamido complexes: synthesis, characterisation and theoretical calculations. Crystal structure of [Ti(η5-Ind)(NMe2)Cl2]
inferred← citeshttps://doi.org/10.1039/b506074popenalex-snapshot
Self-immobilizing catalysts and cocatalysts for olefin polymerization
inferred← citeshttps://doi.org/10.1039/b701003fopenalex-snapshot
Tuning the active species from syndiospecific styrene polymerisation to ethylene/styrene copolymerisation by (aryloxo)(cyclopentadienyl)titanium complexes–MAO catalysts
inferred← citeshttps://doi.org/10.1039/c1dt10607dopenalex-snapshot
Indenyl ring slippage in crown thioether complexes [IndMo(CO)2L]+ and C–S activation of trithiacyclononane: Experimental and theoretical studies
inferred← citeshttps://doi.org/10.1039/c1py00245gopenalex-snapshot
Synthesis of highly syndiotactic polymers by discrete catalysts or initiators
inferred← citeshttps://doi.org/10.1039/c39950001065openalex-snapshot
The first example of polymerization of isobutylene induced by a metallocene-like initiator, [(η 5 -C 5 Me 5 )TiMe 2 [(µ-Me)B(C 6 F 5 ) 3 ]
inferred← citeshttps://doi.org/10.1039/c8py01796dopenalex-snapshot
Group 4 permethylindenyl complexes for slurry-phase polymerisation of ethylene
inferred← citeshttps://doi.org/10.1039/d1dt02622dopenalex-snapshot
Polymerisation of styrene using pincer type amine functionalized azo aromatic complexes of Co( ii ) as catalysts
inferred← citeshttps://doi.org/10.1039/d3nj02625fopenalex-snapshot
DFT studies on the effect of additives on stereoselectivity in the polymerization of styrene catalyzed by rare-earth metal complexes
inferred← citeshttps://doi.org/10.1039/d5ra00389jopenalex-snapshot
Syndiospecific polymerization of styrene with half-titanocene catalysts containing fluorinated phenoxy ligands
inferred← citeshttps://doi.org/10.1080/15533170600862481openalex-snapshot
Synthesis and Characterization of Cyclopentadienyl Titanium Trichloride and Indenyltitanium Trichloride; Monocyclictitanium Trihalide Complexes
inferred← citeshttps://doi.org/10.1134/s1560090410030036openalex-snapshot
Syndiospecific polymerization of styrene in the presence of new titanium complexes with dialkanolamines: Titanocanes and bistitanocanes
inferred← citeshttps://doi.org/10.1135/cccc20011359openalex-snapshot
Synthesis of Trichloro(η5-alkenyltetramethylcyclopentadienyl)titanium(IV) Complexes and Their Activity in Styrene Polymerization
inferred← citeshttps://doi.org/10.1139/v02-170openalex-snapshot
Synthesis and characterization of titanium complexes containing phosphinimido and tropidinyl ligands: Crystal structure of (trop)(t-Bu3PN)TiCl2
inferred← citeshttps://doi.org/10.1201/9781420017083-21openalex-snapshot
Tactic Polystyrene and Styrene Copolymers
inferred← citeshttps://doi.org/10.1201/9781420017083.ch14openalex-snapshot
Tactic Polystyrene and Styrene Copolymers
inferred← citeshttps://doi.org/10.1295/polymj.29.182openalex-snapshot
A Catalyst for Syndiotactic Polymerization of Styrene
inferred← citeshttps://doi.org/10.1515/epoly-2014-0030openalex-snapshot
Syndiospecific polymerization of styrene by half-titanocene catalysts with the sulfur-containing donor ligand
inferred← citeshttps://doi.org/10.1557/opl.2016.24openalex-snapshot
Synthesis of Biodegradable Copolymer of Poly(isobutyl vinyl ether)-co-Poly(ε-Caprolactone) using Half-Sandwich Metallocene Catalyst and their Application as Plasticizer for Poly(Vinyl Chloride)
inferred← citeshttps://doi.org/10.3390/catal3010157openalex-snapshot
Half-Titanocenes Containing Anionic Ancillary Donor Ligands: Effective Catalyst Precursors for Ethylene/Styrene Copolymerization
inferred← citeshttps://doi.org/10.3390/molecules28196792openalex-snapshot
High-Efficiency Mono-Cyclopentadienyl Titanium and Rare-Earth Metal Catalysts for the Production of Syndiotactic Polystyrene
inferred← citeshttps://doi.org/10.5012/bkcs.2004.25.11.1648openalex-snapshot
Syndiotactic Polymerization of Amino-functionalized Styrenes Using (Pentamethylcyclopentadienyl)titanatrane/MMAO Catalyst System
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