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Poly(lactones). 9. Polymerization mechanism of metal alkoxide initiated polymerizations of lactide and various lactones

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Disproportionation, Polycondensation and Cyclization of Poly(L-Lactide) Trifluoro-Ethyl Esters and the Simultaneous Formation of Extended-Chain Crystals and Extended-Ring Crystals
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Lithium chloride as catalyst for the ring-opening polymerization of lactide in the presence of hydroxyl-containing compounds
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Alcoholysis of Aluminum Alkyls Supported by Bulky Phenoxide Ligands: Synthesis, Characterization, and ε-Caprolactone Polymerization Activity of Two Dimeric Aluminum Isopropoxides
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Ring Opening Polymerization
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Zinc(II), Samarium(III) and Tin(II) Complexes Featuring a Tridentate Nitrogen Donor for the Ring-Opening Copolymerization of (D,L)-Lactide and Glycolide
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Metallo-Supramolecular Initiators for the Preparation of Novel Functional Architectures
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General Methodology for Chemical Synthesis of Polyesters
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Aliphatic Polyester Formation, Mechanisms of
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Designing Nanofibrous Scaffolds for Tissue Engineering
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Mechanisms in Heterobimetallic Reactivity
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Interchange Reactions in Condensation Polymers and Their Analysis by NMR Spectroscopy
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Living Ring‐Opening Polymerization of Heterocyclic Monomers
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Biologisch abbaubare Polymere. 2. Mitt.: Zur Homo‐ und Copolymerisation von D,L‐Dilactid
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Biodegradable polymers. 7th comm. On the mechanism of ring‐opening polymerization of cyclic esters of aliphatic hydroxycarboxylic acids by means of different tin compounds
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Recent Advancements and Perspectives of Biodegradable Polymers for Supercapacitors
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Ring‐opening polymerization of rac‐lactide catalyzed by Al(III) and Zn(II) complexes incorporating Schiff base ligands derived from pyrrole‐2‐carboxaldehyde
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Advances in cyclic ester ring‐opening polymerization using heterogeneous catalysts
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Reaction calorimetric investigation of the ring‐opening polymerization of ε‐caprolactone
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The ring‐opening polymerization of D , L ‐lactide catalyzed by new complexes of Cu, Zn, Co, and Ni Schiff base derived from salicylidene and L‐aspartic acid
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Structural and physical properties of biodegradable copolyesters from poly(ethylene terephthalate) and polycaprolactone blends
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Thermal and mechanical properties of plasticized poly( L ‐lactide) nanocomposites with organo‐modified montmorillonites
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Ring‐opening polymerization of lactones using RuCl2(PPh3)3 as initiator: Effect of hydroxylic transfer agents
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Mechanistic study of boron trifluoride catalyzed ε‐caprolactone polymerization in the presence of glycerol
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Highly exfoliated poly(ϵ‐caprolactone)/organomontmorillonite nanocomposites prepared by in situ polymerization
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Continuous polymerization of ε‐caprolactone initiated by titanium phenoxide in a twin‐screw extruder
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Kinetics study of Ti[O(CH2)4OCHCH2]4 initiated ring‐opening polymerization of ε‐caprolactone by differential scanning calorimetry
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Organic acids catalyzed polymerization of ε‐caprolactone: Synthesis and characterization
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Enzymatic degradation of polylactide/layered silicate nanocomposites: Effect of organic modifiers
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Effects of copolymer microstructure on the properties of electrospun poly( l ‐lactide‐co‐ε‐caprolactone) absorbable nerve guide tubes
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Tuning the Properties of Ester‐Based Degradable Polymers by Inserting Epoxides into Poly( ϵ ‐caprolactone)
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Polylactic acid (PLA): Research, development and industrialization
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Mechanistic Study of Bu2SnCl2‐Mediated Ring‐Opening Polymerization of ε‐Caprolactone by Multinuclear NMR Spectroscopy
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Ring‐Opening Polymerization of Lactide with Group 3 Metal Complexes Supported by Dianionic Alkoxy‐Amino‐Bisphenolate Ligands: Combining High Activity, Productivity, and Selectivity
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Bis(guanidinate) Alkoxide Complexes of Lanthanides: Synthesis, Structures and Use in Immortal and Stereoselective Ring‐Opening Polymerization of Cyclic Esters
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Lanthanide Borohydride Complexes of Bulky Guanidinate Ligands [(Me3Si)2NC(N‐Cy)2]2Ln(μ‐BH4)2Li(THF)2 (Ln = Nd, Sm, Yb): Synthesis, Structure and Catalytic Activity in Lactide Polymerization
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Lactide Polymerisation with Complexes of Neutral N‐Donors – New Strategies for Robust Catalysts
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Neutral Dimethylzirconocene Complexes as Initiators for the Ring‐Opening Polymerization of ϵ‐Caprolactone
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Lanthanide Borohydrido Complexes Supported by ansa‐Bis(amidinato) Ligands with a Rigid o‐Phenylene Linker: Effect of Ligand Tailoring on Catalytic Lactide Polymerization
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Metal Catalyzed Polymerization: From Stereoregular Poly(α‐olefins) to Tailor‐Made Biodegradable/Biorenewable Polymers and Copolymers
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Chemical synthesis and in vitro biocompatibility tests of poly ( L ‐lactic acid)
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Biodegradable and bioactive porous scaffold structures prepared using fused deposition modeling
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Stereo block copolymers of L ‐ and D ‐lactides
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Polylactones, 19. Anionic polymerization of L ‐lactide in solution
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Coordination polymerization of lactides, 1. Structure determination of obtained polymers
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Coordination polymerization of lactides, 2. Microstructure determination of poly[( L , L ‐lactide)‐ co ‐(ε‐caprolactone)] with 13 C nuclear magnetic resonance spectroscopy
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Polymerization of lactones, 12. Polymerization of L ‐dilactide and L,D ‐dilactide in the presence of potassium methoxide
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Polylactones 26. Lithium alkoxide‐initiated polymerizations of L ‐lactide
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Telechelic and Star‐Shaped Poly(ε‐caprolactone) Functionalized with Triethoxysilyl Groups – New Biodegradable Coatings and Adhesives
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High Molecular Weight Poly(ε‐caprolactone) by Initiation with Triphenyl Bismuth
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The Role of Transesterification in SnOct2‐Catalyzed Polymerizations of Lactides
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Dialkylmagnesium‐Promoted Deprotonation of Protic Precursors for the Activated Anionic Ring‐Opening Polymerization of Epoxides
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Anionic and pseudoanionic polymerization of ϵ‐caprolactone
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Kinetics of ε‐caprolactone polymerization on dialkylaluminum alkoxides
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Cationic polymerization of cyclocarbonates
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Kinetics and mechanisms in anionic ring‐opening polymerization
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Ring‐opening oligomerization reactions using aluminium complexes of schiff's bases as initiators
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Polymerizations with contribution of covalent and ionic species
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Selectivity as a measure of “livingness” of the polymerization of cyclic esters
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Well defined polymer structures by ionic ring‐opening polymerization of cyclic monomers comprising the respective structure
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Microspheres by dispersion polymerization of lactides and ϵ‐caprolactone
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Bulk polymerization of lactides initiated by aluminum isopropoxide. I. Mechanism and kinetics
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Quantitative comparison of selectivities in the polymerization of cyclic esters
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Stereochemical aspects of the controlled ring‐opening polymerization of chiral cyclic esters
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Macrocyclic polymerization ‐ a new approach to molecular engineering
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Direct condensation polymerization of lactic acid
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Kinetic Study of the Al‐Schiff's Base Initiated Polymerization of ε‐caprolactone and Synthesis of Graft Poly(methylmethacrylate‐g‐caprolactone)
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Influence of the Operative Conditions on the Characteristics of Poly(D,L‐lactide‐co‐glycolide) Synthesized in Supercritical Carbon Dioxide
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Synthesis of Polylactide under Inert Atmosphere and Vacuum
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Electrospinning and cutting of ultrafine bioerodible poly(lactide‐co‐ethylene oxide) tri‐ and multiblock copolymer fibers for inhalation applications
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Benzoxazole phenoxide ligand supported group IV catalysts and their application for the ring‐opening polymerization of rac‐lactide and ε‐caprolactone
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Novel polylactide/vermiculite nanocomposites by in situ intercalative polymerization. I. Preparation, characterization, and properties
inferred← citeshttps://doi.org/10.1002/pen.11085openalex-snapshot
Biodegradable polyester layered silicate nanocomposites based on poly(ϵ‐caprolactone)
inferred← citeshttps://doi.org/10.1002/pen.22165openalex-snapshot
Crystallization behavior of poly(ϵ‐caprolactone)/Tio2 nanocomposites obtained by in situ polymerization
inferred← citeshttps://doi.org/10.1002/pi.1183openalex-snapshot
Ring‐opening polymerization of lactones initiated by diphenylzinc–coinitiator systems
inferred← citeshttps://doi.org/10.1002/pi.1426openalex-snapshot
Influence of the chemical structure of transfer agents in coordinated anionic ring‐opening polymerization: application to one‐step functional oligomerization of ε‐caprolactone
inferred← citeshttps://doi.org/10.1002/pi.2531openalex-snapshot
Heterogeneous ring‐opening polymerization of lactones for biomedical applications
inferred← citeshttps://doi.org/10.1002/pi.4450openalex-snapshot
Catecholate complexes of zirconium: synthesis, spectroscopic characterization and polymerization studies
inferred← citeshttps://doi.org/10.1002/pi.6361openalex-snapshot
Investigation of initiator metal efficiency in the ring‐opening polymerization of lactones: an experimental and computational study
inferred← citeshttps://doi.org/10.1002/pi.70003openalex-snapshot
Bulk ring‐opening polymerization of l ‐lactide with an effective liquid tin( II ) n ‐butoxide initiator for biomedical applications: a comparative kinetics study
inferred← citeshttps://doi.org/10.1002/pola.10003openalex-snapshot
Stannous(II) trifluoromethane sulfonate: a versatile catalyst for the controlled ring‐opening polymerization of lactides: Formation of stereoregular surfaces from polylactide “brushes”
inferred← citeshttps://doi.org/10.1002/pola.10013openalex-snapshot
Synthesis of phosphate end‐functional polymers and application to thermally latent polymeric initiators
inferred← citeshttps://doi.org/10.1002/pola.10222openalex-snapshot
Synthesis of biodegradable copolymers with low‐toxicity zirconium compounds. II. Copolymerization of glycolide with ϵ‐caprolactone initiated by zirconium(IV) acetylacetonate and zirconium(IV) chloride
inferred← citeshttps://doi.org/10.1002/pola.10448openalex-snapshot
Soluble tin(II) macroinitiator adducts for the controlled ring‐opening polymerization of lactones and cyclic carbonates
inferred← citeshttps://doi.org/10.1002/pola.10740openalex-snapshot
Strontium‐based initiator system for ring‐opening polymerization of cyclic esters
inferred← citeshttps://doi.org/10.1002/pola.10814openalex-snapshot
Ring‐opening polymerization and block copolymerization of L ‐lactide with divalent samarocene complex
inferred← citeshttps://doi.org/10.1002/pola.10849openalex-snapshot
Modified poly(ϵ‐caprolactone)s and their use for drug‐encapsulating nanoparticles
inferred← citeshttps://doi.org/10.1002/pola.10887openalex-snapshot
Use of germanium initiators in ring‐opening polymerization of L ‐lactide
inferred← citeshttps://doi.org/10.1002/pola.1184openalex-snapshot
Novel approach to well‐defined polyester by living anionic alternating copolymerization of ethylphenylketene with 4‐methoxybenzaldehyde
inferred← citeshttps://doi.org/10.1002/pola.1994.080320207openalex-snapshot
Synthesis of copolymers of 1,3‐dioxan‐2‐one and oxepan‐2‐one using coordination catalysts
inferred← citeshttps://doi.org/10.1002/pola.1994.080320401openalex-snapshot
Ring‐Opening polymerization of ε‐caprolactone by rare earth coordination catalysts. I. Characteristics, kinetics, and mechanism of ε‐caprolactone polymerization with nd(acac)3.3H2O‐ALET3 system
inferred← citeshttps://doi.org/10.1002/pola.1994.080321519openalex-snapshot
Mechanism of lactide polymerization in the presence of stannous octoate: The effect of hydroxy and carboxylic acid substances
inferred← citeshttps://doi.org/10.1002/pola.1995.080331313openalex-snapshot
Polymers of carbonic acid. XIV. High molecular weight poly(trimethylene carbonate) by ring‐opening polymerization with butyltin chlorides as initiators
inferred← citeshttps://doi.org/10.1002/pola.20028openalex-snapshot
Tetrakis Sn(IV) alkoxides as novel initiators for living ring‐opening polymerization of lactides
inferred← citeshttps://doi.org/10.1002/pola.20261openalex-snapshot
Biodegradable polymers with variable architectures via ring‐expansion polymerization
inferred← citeshttps://doi.org/10.1002/pola.20429openalex-snapshot
Stereoselective polymerization of rac‐lactide with a bulky aluminum/Schiff base complex
inferred← citeshttps://doi.org/10.1002/pola.20474openalex-snapshot
Ring‐opening polymerization of L ‐lactide by rare‐earth tris(4‐tert‐butylphenolate) single‐component initiators
inferred← citeshttps://doi.org/10.1002/pola.20795openalex-snapshot
Copolymerization of ε‐caprolactone and glycolide—A comparison of bismuth(III) hexanoate and tin(II) octanoate as initiators
inferred← citeshttps://doi.org/10.1002/pola.20815openalex-snapshot
Syntheses of trimethoxysilyl‐endcapped polylactones via 3‐mercaptopropyl trimethoxysilane
inferred← citeshttps://doi.org/10.1002/pola.21415openalex-snapshot
Ring‐opening polymerization of ε‐caprolactone via the bismuth‐2‐mercaptoethanol complex
inferred← citeshttps://doi.org/10.1002/pola.22070openalex-snapshot
Sugars‐grafted aliphatic biodegradable poly( L ‐lactide‐co‐carbonate)s by click reaction and their specific interaction with lectin molecules
inferred← citeshttps://doi.org/10.1002/pola.22250openalex-snapshot
Synthesis, characterization, and thermal degradation mechanism of fast biodegradable PPSu/PCL copolymers
inferred← citeshttps://doi.org/10.1002/pola.22315openalex-snapshot
Yttrium bis(alkyl) and bis(amido) complexes bearing N,O multidentate ligands. Synthesis and catalytic activity towards ring‐opening polymerization of L ‐lactide
inferred← citeshttps://doi.org/10.1002/pola.22429openalex-snapshot
Ultra‐high molecular weight poly(ε‐caprolactone) by means of diphenyl bismuth bromide
inferred← citeshttps://doi.org/10.1002/pola.22466openalex-snapshot
Precision synthesis of microstructures in star‐shaped copolymers of ϵ‐caprolactone, L ‐lactide, and 1,5‐dioxepan‐2‐one
inferred← citeshttps://doi.org/10.1002/pola.22621openalex-snapshot
Living ring‐opening polymerization of ϵ‐caprolactone with Ti alkoxides derived from the Cp2TiCl‐catalyzed SET reduction of aldehydes
inferred← citeshttps://doi.org/10.1002/pola.22849openalex-snapshot
Ring‐opening polymerization of 1,4‐dioxan‐2‐one initiated by lanthanum isopropoxide in bulk
inferred← citeshttps://doi.org/10.1002/pola.23079openalex-snapshot
Synthesis, kinetic study, and application of Ti[O(CH2)4OCHCH2]4 in ring‐opening polymerization of ε‐caprolactone and radical polymerization
inferred← citeshttps://doi.org/10.1002/pola.23253openalex-snapshot
Synthesis and rheology of biodegradable poly(glycolic acid) prepared by melt ring‐opening polymerization of glycolide
inferred← citeshttps://doi.org/10.1002/pola.23544openalex-snapshot
Tridentate anilido‐aldimine magnesium and zinc complexes as efficient catalysts for ring‐opening polymerization of ε‐caprolactone and L ‐lactide
inferred← citeshttps://doi.org/10.1002/pola.23755openalex-snapshot
Cyclic polymers: Synthetic strategies and physical properties
inferred← citeshttps://doi.org/10.1002/pola.23864openalex-snapshot
Titanium‐mediated [CpTiCl2(OEt)] ring‐opening polymerization of lactides: A novel route to well‐defined polylactide‐based complex macromolecular architectures
inferred← citeshttps://doi.org/10.1002/pola.23886openalex-snapshot
Titanium complexes of dialkanolamine ligands as initiators for living ring‐opening polymerization of ε‐caprolactone
inferred← citeshttps://doi.org/10.1002/pola.24133openalex-snapshot
Magnesium complexes incorporated by sulfonate phenoxide ligands as efficient catalysts for ring‐opening polymerization of ε‐caprolactone and trimethylene carbonate
inferred← citeshttps://doi.org/10.1002/pola.24399openalex-snapshot
Rapid ring‐opening polymerization of 1,4‐dioxan‐2‐one initiated by titanium alkoxides
inferred← citeshttps://doi.org/10.1002/pola.24447openalex-snapshot
Ring‐opening polymerization of cyclic esters promoted by phosphido‐diphosphine pincer group 3 complexes
inferred← citeshttps://doi.org/10.1002/pola.24502openalex-snapshot
Boron‐functionalized poly(3‐hydroxybutyrate)s from hydroboration of poly(allyl‐β‐hydroxyalkanoate)s: Synthesis and insights into the microstructure
inferred← citeshttps://doi.org/10.1002/pola.24637openalex-snapshot
Ring‐opening polymerization of ε‐caprolactone catalyzed by Yttrium trisphenolate in the presence of 1,2‐propanediol. Do both primary and secondary hydroxyl groups initiate polymerization?
inferred← citeshttps://doi.org/10.1002/pola.24854openalex-snapshot
Polyester from dimethylketene and acetaldehyde: Direct copolymerization and β‐lactone ring‐opening polymerization
inferred← citeshttps://doi.org/10.1002/pola.24926openalex-snapshot
A novel use of Ti‐POSS as initiator of L ‐lactide ring‐opening polymerization
inferred← citeshttps://doi.org/10.1002/pola.24986openalex-snapshot
Titanium complexes based on aminodiol ligands for the ring‐opening polymerization of ε‐caprolactone, rac‐β‐butyrolactone, and trimethylene carbonate
inferred← citeshttps://doi.org/10.1002/pola.26479openalex-snapshot
Ring‐opening polymerization of L ‐lactide using half‐titanocene complexes of the ATiCl2Nu type: Synthesis, characterization, and thermal properties
inferred← citeshttps://doi.org/10.1002/pola.26925openalex-snapshot
Ring‐opening polymerization of rac‐ and meso‐lactide initiated by indium bis(phenolate) isopropoxy complexes
inferred← citeshttps://doi.org/10.1002/pola.27022openalex-snapshot
Highly efficient metal-free organic catalysts to design new Environmentally-friendly starch-based blends
inferred← citeshttps://doi.org/10.1002/pola.27544openalex-snapshot
Synthesis of ultra-small branched star poly(ε-caprolactone)s and their high end group concentration effects on crystallization
inferred← citeshttps://doi.org/10.1002/pola.29077openalex-snapshot
About formation of cycles in Sn(II) octanoate‐catalyzed polymerizations of lactides
inferred← citeshttps://doi.org/10.1002/pola.29184openalex-snapshot
Employing (half‐)titanocene complexes as initiators for the synthesis of end‐functionalized polylactides by coordination polymerization
inferred← citeshttps://doi.org/10.1002/pola.29347openalex-snapshot
Cyclic poly(lactide)s via the ROPPOC method catalyzed by alkyl‐ or aryltin chlorides
inferred← citeshttps://doi.org/10.1002/polb.10133openalex-snapshot
Ring‐opening polymerization of ϵ‐caprolactone by iodine charge‐transfer complex
inferred← citeshttps://doi.org/10.1002/polb.22060openalex-snapshot
Characterization of PBT/POSS nanocomposites prepared by in situ polymerization of cyclic poly(butylene terephthalate) initiated by functionalized POSS
inferred← citeshttps://doi.org/10.1002/psc.3626openalex-snapshot
Ring‐opening polymerization of lactide catalyzed using metal‐coordinated enzyme‐like amino acid assemblies
inferred← citeshttps://doi.org/10.1002/slct.201701602openalex-snapshot
Homoleptic Zr and Hf Complexes of Imino/Bis(imino)phenoxide Scaffolds: Synthesis, Structural Characterization and Their Catalytic Activity in the ROP of Cyclic Esters
inferred← citeshttps://doi.org/10.1002/slct.202502025openalex-snapshot
Influence of Transesterification Reaction on the Molecular Weight and Crystallization Kinetics of the High Molecular Weight Poly(L‐lactide‐co‐ε‐caprolactone) Used in Biomedical Application
inferred← citeshttps://doi.org/10.1002/zaac.201300119openalex-snapshot
Synthesis and Single Crystal X‐ray Structures of Cationic Zinc β‐Diketiminate Complexes
inferred← citeshttps://doi.org/10.1002/zaac.201500814openalex-snapshot
Bismuth(III) Complexes Based on Bis(triazol) Ligands: Effect of Fluorine Substitution on the Structure and Catalysis for the Polymerization of Glycolide
inferred← citeshttps://doi.org/10.1007/12_2011_127openalex-snapshot
Poly(3-Hydroxybutyrate) from Carbon Monoxide
inferred← citeshttps://doi.org/10.1007/12_2011_156openalex-snapshot
Recent Developments in Metal-Catalyzed Ring-Opening Polymerization of Lactides and Glycolides: Preparation of Polylactides, Polyglycolide, and Poly(lactide-co-glycolide)
inferred← citeshttps://doi.org/10.1007/12_2017_20openalex-snapshot
Catalytic Systems for the Production of Poly(lactic acid)
inferred← citeshttps://doi.org/10.1007/3-540-45734-8_1openalex-snapshot
Aliphatic Polyesters: Synthesis, Properties and Applications
inferred← citeshttps://doi.org/10.1007/3-540-45734-8_2openalex-snapshot
Controlled Ring-Opening Polymerization: Polymers with designed Macromolecular Architecture
inferred← citeshttps://doi.org/10.1007/3-540-49424-3_2openalex-snapshot
Polymerization by Metalloporphyrin and Related Complexes
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