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Mechanistic Studies on Ring-Opening Polymerization of Benzoxazines: A Mechanistically Based Catalyst Design
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Molecular origin of unusual physical and mechanical properties in novel phenolic materials based on benzoxazine chemistry
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Modification of Polymer Substrates with Low Surface Free Energy Material by Low‐Temperature Cured Polybenzoxazine
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Photoinitiated cationic polymerization of monofunctional benzoxazine
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Ring Opening Polymerization of Benzoxazines — A New Route to Phenolic Resins
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Selective Formation of Poly(N,O-acetal) by Polymerization of 1,3-Benzoxazine and Its Main Chain Rearrangement
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Sustainable furfural bis-thymol based benzoxazines: Superhydrophobic, aggregation induced emission and corrosion resistant properties
inferred← citeshttps://doi.org/10.1016/j.mtchem.2026.103819openalex-snapshot
The molecular origin of unusual and advantageous properties of benzoxazine monomers and polybenzoxazines: Comprehensive review on fundamentals and application of inter- and intra-molecular hydrogen bonding for advanced material design
inferred← citeshttps://doi.org/10.1016/j.mtcomm.2019.100568openalex-snapshot
A fully bio-based benzoxazine as latent catalyst for bisphenol A/aniline-based benzoxazine
inferred← citeshttps://doi.org/10.1016/j.mtcomm.2019.100629openalex-snapshot
Influence of natural substituents in the polymerization behavior of novel bio-based benzoxazines
inferred← citeshttps://doi.org/10.1016/j.polymer.2012.07.033openalex-snapshot
The structural transformation during polymerization of benzoxazine/FeCl3 and the effect on the thermal stability
inferred← citeshttps://doi.org/10.1016/j.polymer.2013.03.063openalex-snapshot
Catalyst effects on the ring-opening polymerization of 1,3-benzoxazine and on the polymer structure
inferred← citeshttps://doi.org/10.1016/j.polymer.2014.02.017openalex-snapshot
A pair of benzoxazine isomers from o-allylphenol and 4,4′-diaminodiphenyl ether: Synthesis, polymerization behavior, and thermal properties
inferred← citeshttps://doi.org/10.1016/j.polymer.2016.04.005openalex-snapshot
Spectral and thermal studies on the synthesis and catalyzed oligomerization of novel cardanol-based benzoxazines
inferred← citeshttps://doi.org/10.1016/j.polymer.2016.07.056openalex-snapshot
Study on synthesis and the reaction mechanism of polybenzoxazine-silica nanocomposites provided from perhydropolysilazane
inferred← citeshttps://doi.org/10.1016/j.polymer.2017.05.061openalex-snapshot
Innovative approach using aminomaleimide for unlocking phenolic diversity in high-performance maleimidobenzoxazine resins
inferred← citeshttps://doi.org/10.1016/j.polymer.2017.06.077openalex-snapshot
Ammonium salt catalyzed ring-opening polymerization of 1,3-benzoxazines
inferred← citeshttps://doi.org/10.1016/j.polymer.2018.01.084openalex-snapshot
Enhancing the processibility of high temperature polymerizing cardanol derived benzoxazines using eco-friendly curing accelerators
inferred← citeshttps://doi.org/10.1016/j.polymer.2018.09.061openalex-snapshot
Non-flammable thiazole-functional monobenzoxazines: Synthesis, polymerization, thermal and thermomechanical properties, and flammability studies
inferred← citeshttps://doi.org/10.1016/j.polymer.2018.12.024openalex-snapshot
Facile preparation of polybenzoxazine/graphene nanocomposites for electromagnetic interference shielding
inferred← citeshttps://doi.org/10.1016/j.polymer.2019.01.048openalex-snapshot
Synthesis, dynamic mechanical properties, and shape memory effect of polybenzoxazines based on monofluorophenol isomers and polyetheramines
inferred← citeshttps://doi.org/10.1016/j.polymer.2020.122552openalex-snapshot
A tetraphenylethylene-functionalized benzoxazine and copper(II) acetylacetonate form a high-performance polybenzoxazine
inferred← citeshttps://doi.org/10.1016/j.polymer.2021.123573openalex-snapshot
Preparation of low temperature cure polybenzoxazine coating with enhanced thermal stability and mechanical properties by combustion synthesis approach
inferred← citeshttps://doi.org/10.1016/j.polymer.2022.125156openalex-snapshot
Melamine modified phthalonitrile resins: Synthesis, polymerization and properties
inferred← citeshttps://doi.org/10.1016/j.polymer.2024.127801openalex-snapshot
Bio-inspired sustainable benzoxazine based composites containing aniline derivatives: A comprehensive study on anti-microbial, advanced coatings, oil-water separation and electronic utilizations
inferred← citeshttps://doi.org/10.1016/j.polymer.2025.128180openalex-snapshot
Biobased polybenzoxazine containing acetal structures: Adhesion, rebonding, and degradation properties
inferred← citeshttps://doi.org/10.1016/j.polymer.2025.128596openalex-snapshot
High performance combustion synthesis-based low-temperature curing of benzoxazine
inferred← citeshttps://doi.org/10.1016/j.porgcoat.2014.11.004openalex-snapshot
Thermal curing study of bisphenol A benzoxazine for barrier coating applications on 1050 aluminum alloy
inferred← citeshttps://doi.org/10.1016/j.porgcoat.2016.03.026openalex-snapshot
Thermal curing of para -phenylenediamine benzoxazine for barrier coating applications on 1050 aluminum alloys
inferred← citeshttps://doi.org/10.1016/j.porgcoat.2024.108506openalex-snapshot
Progress on the simulation, synthesis, processing and application of high performance thermosetting polybenzoxazine resin and its composites: A review
inferred← citeshttps://doi.org/10.1016/j.porgcoat.2026.110158openalex-snapshot
Synergistic “repel-and-kill” strategy in bio-based polybenzoxazine coatings for high-efficiency marine antifouling and anticorrosion
inferred← citeshttps://doi.org/10.1016/j.progpolymsci.2020.101353openalex-snapshot
Advances in sustainable thermosetting resins: From renewable feedstock to high performance and recyclability
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2016.03.010openalex-snapshot
Shape memory polybenzoxazines based on polyetheramine
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2017.06.004openalex-snapshot
Curing behaviour and properties of a novel benzoxazine resin via catalysis of 2-phenyl-1,3,2-benzodioxaborole
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2017.10.020openalex-snapshot
Meta-phenylenediamine formaldehyde oligomer: A new accelerator for benzoxazine resin
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2019.03.016openalex-snapshot
Controlled polymerization of 3,4-dihydro-2H-1,3-benzoxazine and its properties tailored by Lewis acids
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2020.104716openalex-snapshot
Unique self-catalyzed bio-benzoxazine derived from novel renewable acid-containing diamines based on levulinic acid and furfurylamine: Synthesis, curing behaviors and properties
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2023.105680openalex-snapshot
Synthesis of phosphaphenanthrene-functional monobenzoxazine for enhancing thermal properties of polybenzoxazine thermosets
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2024.105880openalex-snapshot
Studies on catalyst assisted low-temperature curing of benzoxazines
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2025.106491openalex-snapshot
Rational design and synthesis of novel benzoxazine resins with excellent thermal and flame - Retardant properties
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2026.106726openalex-snapshot
Effect of built-in quaternary ammonium structures on the curing behaviour and kinetics of benzoxazine resins
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2026.106784openalex-snapshot
Structure-property relationships in resorcinol-based bifunctional polybenzoxazines: Comprehensive coating and corrosion protections studies
inferred← citeshttps://doi.org/10.1016/j.seppur.2021.119562openalex-snapshot
Polybenzoxazines in fabrication of separation membranes: A review
inferred← citeshttps://doi.org/10.1016/j.susmat.2025.e01387openalex-snapshot
Research progress on properties and applications of bio-based polybenzoxazine materials
inferred← citeshttps://doi.org/10.1016/j.tca.2022.179254openalex-snapshot
Kinetics of benzoxazine and epoxy oligomer copolymerization
inferred← citeshttps://doi.org/10.1016/j.tca.2025.179984openalex-snapshot
Isoconversional kinetic analysis of bisphenol A benzoxazine cure
inferred← citeshttps://doi.org/10.1016/j.tetlet.2012.07.141openalex-snapshot
Macromolecular polyyne-containing benzoxazines for cross-linked polymerization
inferred← citeshttps://doi.org/10.1021/acs.biomac.1c00981openalex-snapshot
Self-Polymerization Promoting Monomers: In Situ Transformation of Disulfide-Linked Benzoxazines into the Thiazolidine Structure
inferred← citeshttps://doi.org/10.1021/acs.chemmater.3c00341openalex-snapshot
EDTA-Assisted Synthesis of Nitrogen-Doped Carbon Nanospheres with Uniform Sizes for Photonic and Electrocatalytic Applications
inferred← citeshttps://doi.org/10.1021/acs.iecr.3c01289openalex-snapshot
Kinetic Modeling of Ring-Opening Polymerization of Benzoxazines Using MIL-53-Al as a Potent Catalyst
inferred← citeshttps://doi.org/10.1021/acs.iecr.8b01997openalex-snapshot
Magnesium Thiodialkanoates: Dually-Functional Additives to Organic Coatings
inferred← citeshttps://doi.org/10.1021/acs.joc.6b02727openalex-snapshot
Insight into the Mechanism of Reversible Ring-Opening of 1,3-Benzoxazine with Thiols
inferred← citeshttps://doi.org/10.1021/acs.macromol.0c00192openalex-snapshot
Formaldehyde-Free Polybenzoxazines for High Performance Thermosets
inferred← citeshttps://doi.org/10.1021/acs.macromol.0c00225openalex-snapshot
Advanced Polymers from Simple Benzoxazines and Phenols by Ring-Opening Addition Reactions
inferred← citeshttps://doi.org/10.1021/acs.macromol.0c00947openalex-snapshot
Implementation of meta-Positioning in Tetrafunctional Benzoxazines: Synthesis, Properties, and Differences in the Polymerized Structure
inferred← citeshttps://doi.org/10.1021/acs.macromol.0c02036openalex-snapshot
N-Activated 1,3-Benzoxazine Monomer as a Key Agent in Polybenzoxazine Synthesis
inferred← citeshttps://doi.org/10.1021/acs.macromol.2c01216openalex-snapshot
Crown Ether- and Benzoxazine-Linked Porous Organic Polymers Displaying Enhanced Metal Ion and CO 2 Capture through Solid-State Chemical Transformation
inferred← citeshttps://doi.org/10.1021/acs.macromol.3c00028openalex-snapshot
Phosphaphenanthrene-Functionalized Benzoxazines Bearing Intramolecularly Hydrogen-Bonded Phenolic Hydroxyl: Synthesis, Structural Characterization, Polymerization Mechanism, and Property Investigation
inferred← citeshttps://doi.org/10.1021/acs.macromol.3c01515openalex-snapshot
Thiophene-Rich Benzoxazines with an Amide Moiety: Integration of Structural and Hydrogen Bonding Influence on the Polymerization Mechanism by Experimental and Computational Studies
inferred← citeshttps://doi.org/10.1021/acs.macromol.3c02454openalex-snapshot
Hydrogen Bonding-Guided Strategies for Thermal Performance Modulation in Biobased Oxazine Ring-Substituted Benzoxazine Thermosets
inferred← citeshttps://doi.org/10.1021/acs.macromol.4c00829openalex-snapshot
Oxazine Ring-Containing Polycyclic Monomers: A Class of Benzoxazine Thermosetting Resins with Intrinsically Low Curing Temperature
inferred← citeshttps://doi.org/10.1021/acs.macromol.4c01664openalex-snapshot
Polymerization Case with Hydroxybenzoxazines: What Is the Role of the Hydroxy Group, Does It Act as a Self-Catalyst or a Modifier of the Polymer Structure?
inferred← citeshttps://doi.org/10.1021/acs.macromol.4c02616openalex-snapshot
Design and Synthesis of Flavonoid-Based Mono-, Bis-, and Tri-Benzoxazines: Toward Elucidating Roles of Oxazine Ring Number and Hydrogen Bonding on Their Polymerization Mechanisms and Thermal Properties
inferred← citeshttps://doi.org/10.1021/acs.macromol.5b00334openalex-snapshot
Origin of the Rapid Trimerization of Cyanate Ester in a Benzoxazine/Cyanate Ester Blend
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c03014openalex-snapshot
Poly(methylene)s Bearing Pendant Benzoxazines via C1 Polymerization: Maximizing Functional Group Density for Enhanced Cross-Linking
inferred← citeshttps://doi.org/10.1021/acs.macromol.6c00027openalex-snapshot
A Fully Biobased Benzoxazine-Modified Waterborne Two-Component Polyurethane with High Adhesion, Self-Healing, and Hydrophobic Properties
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b00171openalex-snapshot
Photochemical Polymerization of N -Phenyl Mono-1,3-benzoxazines in Aqueous Media
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b00218openalex-snapshot
Phenolic Naphthoxazines as Curing Promoters for Benzoxazines
inferred← citeshttps://doi.org/10.1021/acs.macromol.9b02519openalex-snapshot
Crown Ether-Functionalized Polybenzoxazine for Metal Ion Adsorption
inferred← citeshttps://doi.org/10.1021/acsapm.1c00637openalex-snapshot
Catalyzing the Ring-Opening Polymerization of 1,3-Benzoxazines via Thioamide from Renewable Sources
inferred← citeshttps://doi.org/10.1021/acsapm.1c01164openalex-snapshot
Understanding the Origin of the Low Cure Shrinkage of Polybenzoxazine Resin by Computational Simulation
inferred← citeshttps://doi.org/10.1021/acsapm.1c01679openalex-snapshot
Chrysin-Based Bio-Benzoxazine: A Copolymerizable Green Additive for Lowering Curing Temperatures and Improving Thermal Properties of Various Thermosetting Resins
inferred← citeshttps://doi.org/10.1021/acsapm.3c00196openalex-snapshot
Mechanically Interlocked Vitrimer Based on Polybenzoxazine and Polyrotaxane
inferred← citeshttps://doi.org/10.1021/acsapm.3c01107openalex-snapshot
Design of a Low-Temperature Ring-Opening Benzoxazine System Using a Supramolecular Hydrogen-Bond Structure
inferred← citeshttps://doi.org/10.1021/acsapm.3c01902openalex-snapshot
Catalytic Role of Nanoconfinement inside MIL-125 (Ti) on the Ring-Opening Polymerization of Simple Benzoxazines
inferred← citeshttps://doi.org/10.1021/acsapm.3c02221openalex-snapshot
Properties and Curing Kinetics of a Processable Binary Benzoxazine Blend
inferred← citeshttps://doi.org/10.1021/acsapm.4c00404openalex-snapshot
Multifunctional Biobased Benzoxazines: Synthesis, Copolymerization, and Thermal Stability Studies
inferred← citeshttps://doi.org/10.1021/acsapm.4c03222openalex-snapshot
Advancing Renewable Amines: Furan-Derived Polybenzoxazines
inferred← citeshttps://doi.org/10.1021/acsapm.5c03369openalex-snapshot
Designing Biobased Sulfur-Modified Benzoxazines for Enhanced Performance in Antimicrobials, Anticorrosion, and Dielectrics
inferred← citeshttps://doi.org/10.1021/acsmacrolett.9b00083openalex-snapshot
Unexpected Healability of an ortho-Blocked Polybenzoxazine Resin
inferred← citeshttps://doi.org/10.1021/acsomega.8b01297openalex-snapshot
Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
inferred← citeshttps://doi.org/10.1021/acssuschemeng.0c02773openalex-snapshot
Advanced Thermosets from Sulfur and Renewable Benzoxazine and Ionones via Inverse Vulcanization
inferred← citeshttps://doi.org/10.1021/acssuschemeng.1c01266openalex-snapshot
Understanding the Stereochemical Effect on the Properties of Emerging Thermosets: Sustainable Polybenzoxazines
inferred← citeshttps://doi.org/10.1021/acssuschemeng.1c01338openalex-snapshot
Multifunctional Biobased Benzoxazines Blended with an Epoxy Resin for Tunable High-Performance Properties
inferred← citeshttps://doi.org/10.1021/acssuschemeng.8b03631openalex-snapshot
Harvesting the Benefits of Inherent Reactive Functionalities in Fully Biosourced Isomeric Benzoxazines
inferred← citeshttps://doi.org/10.1021/acssuschemeng.8b06515openalex-snapshot
Sustainable Framework of Chitosan–Benzoxazine with Mutual Benefits: Low Curing Temperature and Improved Thermal and Mechanical Properties
inferred← citeshttps://doi.org/10.1021/bm4002014openalex-snapshot
Biobased Chitosan/Polybenzoxazine Cross-Linked Films: Preparation in Aqueous Media and Synergistic Improvements in Thermal and Mechanical Properties
inferred← citeshttps://doi.org/10.1021/cm403483popenalex-snapshot
Polybenzoxazine Aerogels. 1. High-Yield Room-Temperature Acid-Catalyzed Synthesis of Robust Monoliths, Oxidative Aromatization, and Conversion to Microporous Carbons
inferred← citeshttps://doi.org/10.1021/cr300195nopenalex-snapshot
On the Versatility of Urethane/Urea Bonds: Reversibility, Blocked Isocyanate, and Non-isocyanate Polyurethane
inferred← citeshttps://doi.org/10.1021/ma200542popenalex-snapshot
Top-Down Multidimensional Mass Spectrometry Methods for Synthetic Polymer Analysis
inferred← citeshttps://doi.org/10.1021/ma201414topenalex-snapshot
Cationic Polybenzoxazines. A Novel Polyelectrolyte Class with Adjustable Solubility and Unique Hydrogen-Bonding Capabilities
inferred← citeshttps://doi.org/10.1021/ma301963dopenalex-snapshot
Mechanistic Pathways for the Polymerization of Methylol-Functional Benzoxazine Monomers
inferred← citeshttps://doi.org/10.1021/ma401756dopenalex-snapshot
Steric Hindrance Control Synthesis of Primary Amine-Containing Benzoxazines and Properties of the Resulting Poly(benzoxazine imide) Thermosetting Films
inferred← citeshttps://doi.org/10.1021/ma502336jopenalex-snapshot
Study on the Ring-Opening Polymerization of Benzoxazine through Multisubstituted Polybenzoxazine Precursors
inferred← citeshttps://doi.org/10.1039/c2gc35796hopenalex-snapshot
Synthesis and copolymerization of fully bio-based benzoxazines from guaiacol, furfurylamine and stearylamine
inferred← citeshttps://doi.org/10.1039/c3gc41811aopenalex-snapshot
Matrices from vegetable oils, cashew nut shell liquid, and other relevant systems for biocomposite applications
inferred← citeshttps://doi.org/10.1039/c4cp02053gopenalex-snapshot
Influence of substituent on equilibrium of benzoxazine synthesis from Mannich base and formaldehyde
inferred← citeshttps://doi.org/10.1039/c4nj02047bopenalex-snapshot
New benzoxazines containing polyhedral oligomeric silsesquioxane from eugenol, guaiacol and vanillin
inferred← citeshttps://doi.org/10.1039/c4ra08381dopenalex-snapshot
Azopyridine-functionalized benzoxazine with Zn(ClO 4 ) 2 form high-performance polybenzoxazine stabilized through metal–ligand coordination
inferred← citeshttps://doi.org/10.1039/c4ra16582aopenalex-snapshot
A curing system of benzoxazine with amine: reactivity, reaction mechanism and material properties
inferred← citeshttps://doi.org/10.1039/c5py01397fopenalex-snapshot
A study on the chain propagation of benzoxazine
inferred← citeshttps://doi.org/10.1039/c5ra02839fopenalex-snapshot
A novel high performance oxazine derivative: design of tetrafunctional monomer, step-wise ring-opening polymerization, improved thermal property and broadened processing window
inferred← citeshttps://doi.org/10.1039/c5ra06413aopenalex-snapshot
Fabrication of highly durable hydrophobic PBZ/SiO 2 surfaces
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