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Cyclic Guanidines as Efficient Organocatalysts for the Synthesis of Polyurethanes

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Catalytic mechanisms of triphenyl bismuth, dibutyltin dilaurate, and their combination in polyurethane-forming reaction
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Efficient organotin catalysts for urethanes: kinetic and mechanistic investigations
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1,8-Bis(tetramethylguanidino)naphthalene (TMGN): A New, Superbasic and Kinetically Active “Proton Sponge”
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New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization
inferredcites →https://doi.org/10.1002/9780470740859.ch4openalex-snapshot
Guanidines in Organic Synthesis
inferredcites →https://doi.org/10.1002/ange.19470590901openalex-snapshot
Das Di‐Isocyanat‐Polyadditionsverfahren (Polyurethane)
inferredcites →https://doi.org/10.1002/ange.19600722403openalex-snapshot
Das Aufbauprinzip der Urethan‐Elastomeren „Vulkollan”
inferredcites →https://doi.org/10.1002/anie.200800490openalex-snapshot
Harnessing the Potential of N‐Heterocyclic Carbenes for the Rejuvenation of Group‐Transfer Polymerization of (Meth)Acrylics
inferredcites →https://doi.org/10.1002/anie.201001035openalex-snapshot
An Isolated CO2 Adduct of a Nitrogen Base: Crystal and Electronic Structures
inferredcites →https://doi.org/10.1002/anie.201105516openalex-snapshot
A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2
inferredcites →https://doi.org/10.1002/chem.200800346openalex-snapshot
Monomer versus Alcohol Activation in the 4‐Dimethylaminopyridine‐Catalyzed Ring‐Opening Polymerization of Lactide and Lactic O‐Carboxylic Anhydride
inferredcites →https://doi.org/10.1002/chem.200802670openalex-snapshot
CO2 and SnII Adducts of N‐Heterocyclic Carbenes as Delayed‐Action Catalysts for Polyurethane Synthesis
inferredcites →https://doi.org/10.1002/ejic.200801161openalex-snapshot
CO 2 , Magnesium, Aluminum, and Zinc Adducts of N‐Heterocyclic Carbenes as (Latent) Catalysts for Polyurethane Synthesis
inferredcites →https://doi.org/10.1002/marc.201100223openalex-snapshot
Well‐defined Biobased Segmented Polyureas Synthesis via a TBD‐catalyzed Isocyanate‐free Route
inferredcites →https://doi.org/10.1002/prac.19883300406openalex-snapshot
Kinetics and mechanism of isocyanate reactions. II. Reactions of Aryl Isocyanates with Alcohols in the presence ob tertiary amines
inferredcites →https://doi.org/10.1007/978-94-011-2924-4openalex-snapshot
Polyurethane Elastomers
inferredcites →https://doi.org/10.1016/j.tet.2008.08.008openalex-snapshot
Study of the carbon dioxide chemical fixation—activation by guanidines
inferredcites →https://doi.org/10.1016/j.tet.2009.10.047openalex-snapshot
Catalytic reaction of methyl formate with amines to formamides
inferredcites →https://doi.org/10.1016/s0040-4039(00)89893-7openalex-snapshot
Über additionen von isocyanaten an N-substituierte guanidine
inferredcites →https://doi.org/10.1016/s0040-4039(03)00424-6openalex-snapshot
Cycloaddition of CO2 to epoxides over both homogeneous and silica-supported guanidine catalysts
inferredcites →https://doi.org/10.1021/bm100233vopenalex-snapshot
Synthesis of Biobased Polyurethane from Oleic and Ricinoleic Acids as the Renewable Resources via the AB-Type Self-Condensation Approach
inferredcites →https://doi.org/10.1021/cr020037xopenalex-snapshot
Asymmetric Alcoholysis of Cyclic Anhydrides
inferredcites →https://doi.org/10.1021/cr068415bopenalex-snapshot
Organocatalytic Ring-Opening Polymerization
inferredcites →https://doi.org/10.1021/ja0764411openalex-snapshot
The Reaction Mechanism for the Organocatalytic Ring-Opening Polymerization of l -Lactide Using a Guanidine-Based Catalyst: Hydrogen-Bonded or Covalently Bound?
inferredcites →https://doi.org/10.1021/jo048252wopenalex-snapshot
Extension of the Self-Consistent Spectrophotometric Basicity Scale in Acetonitrile to a Full Span of 28 p K a Units: Unification of Different Basicity Scales
inferredcites →https://doi.org/10.1021/jo902369gopenalex-snapshot
Cyclic Guanidine Organic Catalysts: What Is Magic About Triazabicyclodecene?
inferredcites →https://doi.org/10.1021/ma0619381openalex-snapshot
Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic Esters
inferredcites →https://doi.org/10.1021/ma900679popenalex-snapshot
Group Transfer Polymerization of (Meth)acrylic Monomers Catalyzed by N-Heterocyclic Carbenes and Synthesis of All Acrylic Block Copolymers: Evidence for an Associative Mechanism
inferredcites →https://doi.org/10.1021/ma901776xopenalex-snapshot
Acyclic Guanidines as Organic Catalysts for Living Polymerization of Lactide
inferredcites →https://doi.org/10.1021/op060032sopenalex-snapshot
Some Items of Interest to Process R&D Chemists and Engineers
inferredcites →https://doi.org/10.1039/b008241oopenalex-snapshot
Hydrogen-bonded complexes of pentaalkyl guanidines
inferredcites →https://doi.org/10.1039/b901940eopenalex-snapshot
Bicyclic-guanidines, -guanidinates and -guanidinium salts: wide ranging applications from a simple family of molecules
inferredcites →https://doi.org/10.1039/c0gc00371aopenalex-snapshot
Solubility in CO2 and carbonation studies of epoxidized fatty acid diesters: towards novel precursors for polyurethane synthesis
inferredcites →https://doi.org/10.1039/jr9470000713openalex-snapshot
135. The mechanism of aromatic side-chain reactions with special reference to the polar effects of substituents. Part XIII. Kinetic examination of the reaction of aryl isocyanates with methyl alcohol
inferredcites →https://doi.org/10.1039/p29940000599openalex-snapshot
Three fundamental mechanisms of base-catalysed reactions of isocyanates with hydrogen-acidic compounds
inferredcites →https://doi.org/10.1080/00222337008059519openalex-snapshot
On the Mechanism of Polyurethane Formation Catalyzed by Metal Chelates and Organotin Compounds
inferredcites →https://doi.org/10.1080/15583727008085365openalex-snapshot
Catalysis in Isocyanate Reactions
inferredcites →https://doi.org/10.1081/cr-120027049openalex-snapshot
Recent Developments in Polyurethane Catalysis: Catalytic Mechanisms Review

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Aminolysis of Five-Membered Cyclic Carbonate Catalyzed by Guanidines: Solvent Effects on the Formation of Guanidine Dimers
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Selective Electrocatalytic Degradation of Ether‐Containing Polymers
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Selective Electrocatalytic Degradation of Ether‐Containing Polymers
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Polyurea‐urethane Temperature‐responsive Hydrogels for Sustained Delivery of Anti‐VEGF Therapeutics
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Insights into the Organocatalyzed Synthesis of Urethanes in Supercritical Carbon Dioxide: An In Situ FTIR Spectroscopic Kinetic Study
inferred← citeshttps://doi.org/10.1002/chem.201804016openalex-snapshot
Mechanistic Analysis and Characterization of Intermediates in the Phosphane‐Catalyzed Oligomerization of Isocyanates
inferred← citeshttps://doi.org/10.1002/chem.202300924openalex-snapshot
“Catch‐Store‐Release” Strategy for the Stabilization of 4,4′‐Methylene Diphenyl Diisocyanate (4,4′‐MDI)
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Reactivity and Structural Diversity in the Reaction of Guanidine 1,5,7‐Triazabicyclo[4.4.0]dec‐5‐ene with CO2, CS2, and Other Heterocumulenes
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The Influence of The Alcohol's Acidity on Organo‐Base Catalyzed Carbamate Formation From Aliphatic Isocyanates
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Organocatalysts for the Synthesis of Poly(ethylene terephthalate‐ co ‐isosorbide terephthalate): A Combined Experimental and DFT Study
inferred← citeshttps://doi.org/10.1002/marc.201300503openalex-snapshot
Renewable Non‐Isocyanate Based Thermoplastic Polyurethanes via Polycondensation of Dimethyl Carbamate Monomers with Diols
inferred← citeshttps://doi.org/10.1002/marc.201300898openalex-snapshot
Latent and Delayed Action Polymerization Systems
inferred← citeshttps://doi.org/10.1002/marc.201500247openalex-snapshot
Thermoresponsive Random Poly(ether urethanes) with Tailorable LCSTs for Anticancer Drug Delivery
inferred← citeshttps://doi.org/10.1002/pol.20230643openalex-snapshot
Triazabicyclodecene: A versatile catalyst for polymer synthesis
inferred← citeshttps://doi.org/10.1002/pola.26951openalex-snapshot
Synthesis and polymerization of styrene monomer carrying isothiocyanate moiety and its copolymerization with HEMA based on chemo-selectivity to nucleophiles
inferred← citeshttps://doi.org/10.1002/pola.29203openalex-snapshot
Synthesis of polymers having zwitterionic structure via the radical polymerization of 4‐vinylphenyl isothiocyanate/cyclic amidine adduct
inferred← citeshttps://doi.org/10.1016/b978-0-12-409547-2.14958-3openalex-snapshot
Bicyclic 6-6 Systems With One Bridgehead (Ring Junction) Nitrogen Atom: Three Extra Heteroatoms (2:1)
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Advances in Polyurethane Synthesis, From 2010 to 2025
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Guanidines from ‘toxic substances’ to compounds with multiple biological applications – Detailed outlook on synthetic procedures employed for the synthesis of guanidines
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2016.08.008openalex-snapshot
Biocompatibility and hemocompatibility evaluation of polyether urethanes synthesized using DBU organocatalyst
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2017.07.001openalex-snapshot
Synthesis of antithrombotic poly(carbonate-urethane)s through a sequential process of ring-opening polymerization and polyaddition facilitated by organocatalysts
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2017.09.032openalex-snapshot
Reactivity and kinetics of HDI-iminooxadiazinedione: Application to polyurethane synthesis
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2025.113909openalex-snapshot
From betulin potentially bioproduced from plastics wastes to sustainable and high-performance cycloaliphatic polyurethanes: Towards a Biotech-Chem approach
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Development of new high-throughput screening method to compare and to detect efficient catalysts for adhesive materials
inferred← citeshttps://doi.org/10.1016/j.jcat.2019.12.002openalex-snapshot
Copper (II) as catalyst for intramolecular cyclization and oxidation of (1,4-phenylene)bisguanidines to benzodiimidazole-diylidenes
inferred← citeshttps://doi.org/10.1016/j.jcat.2019.12.014openalex-snapshot
Investigations of FeCl3 adducted N-heterocyclic carbene complex as curing-delayed action catalyst for polyurethane polymerization
inferred← citeshttps://doi.org/10.1016/j.molstruc.2024.140299openalex-snapshot
Aminolysis of five-membered cyclic carbonate catalyzed by guanidines: Solvent effects on the formation of guanidine dimers
inferred← citeshttps://doi.org/10.1016/j.polymer.2026.130789openalex-snapshot
Engineering highly flexural-resistant and antibacterial polyurethane elastomers via coordinated catalyst mediated crosslinking
inferred← citeshttps://doi.org/10.1016/j.progpolymsci.2015.12.001openalex-snapshot
Update and challenges in organo-mediated polymerization reactions
inferred← citeshttps://doi.org/10.1016/j.progpolymsci.2018.11.003openalex-snapshot
Opportunities for organocatalysis in polymer synthesis via step-growth methods
inferred← citeshttps://doi.org/10.1016/j.saa.2017.07.032openalex-snapshot
Synthesis, vibrational spectrometry and thermal characterizations of coordination polymers derived from divalent metal ions and hydroxyl terminated polyurethane as ligand
inferred← citeshttps://doi.org/10.1021/acs.iecr.6b00484openalex-snapshot
Efficient Catalysis of Calcium Carbide for the Synthesis of Isophorone from Acetone
inferred← citeshttps://doi.org/10.1021/acs.joc.4c02668openalex-snapshot
Pyridinamide Ion Pairs: Design Principles for Super-Nucleophiles in Apolar Organic Solvents
inferred← citeshttps://doi.org/10.1021/acs.joc.6b02423openalex-snapshot
Nickel-Catalyzed Aerobic Oxidative Isocyanide Insertion: Access to Benzimidazoquinazoline Derivatives via a Sequential Double Annulation Cascade (SDAC) Strategy
inferred← citeshttps://doi.org/10.1021/acs.joc.9b01319openalex-snapshot
Design Principles for Rational Polyurethane Catalyst Development
inferred← citeshttps://doi.org/10.1021/acs.langmuir.6c00770openalex-snapshot
Effects of Catalyst Complex on In Situ Polymerization and Formation Processes of Reactive Polyurethane Coatings
inferred← citeshttps://doi.org/10.1021/acs.macromol.1c02491openalex-snapshot
Harnessing Catalysis Selectivity and Isophorone Diisocyanate Asymmetry for Tailored Polyurethane Prepolymers and Networks
inferred← citeshttps://doi.org/10.1021/acs.macromol.4c01431openalex-snapshot
Tackling the Thermodynamic Stability of Low-Ceiling Temperature Polymers for the Preparation of Tough and Chemically Recyclable Thermoplastic Polyurethane-Urea Elastomers
inferred← citeshttps://doi.org/10.1021/acs.macromol.5b00384openalex-snapshot
Synthesis of Polyurethanes Using Organocatalysis: A Perspective
inferred← citeshttps://doi.org/10.1021/acs.macromol.5b02531openalex-snapshot
Tunable Thermoplastic Poly(ester–urethane)s Based on Modified Serinol Extenders
inferred← citeshttps://doi.org/10.1021/acs.macromol.6b01542openalex-snapshot
Base-to-Base Organocatalytic Approach for One-Pot Construction of Poly(ethylene oxide)-Based Macromolecular Structures
inferred← citeshttps://doi.org/10.1021/acs.macromol.9b02648openalex-snapshot
Thioxanthone-Based Photobase Generators for the Synthesis of Polyurethanes via the Photopolymerization of Polyols and Polyisocyanates
inferred← citeshttps://doi.org/10.1021/acscatal.3c03293openalex-snapshot
O-Methyl-N-nitroisourea as a NCO Surrogate in Cu-Catalyzed Alkane C–H Amidination. A Masked Isocyanate Strategy
inferred← citeshttps://doi.org/10.1021/acssuschemeng.7b01110openalex-snapshot
Application of Modified Amino Acid-Derived Diols as Chain Extenders in the Synthesis of Novel Thermoplastic Polyester–Urethane Elastomers
inferred← citeshttps://doi.org/10.1021/ja408641gopenalex-snapshot
Organic Acid-Catalyzed Polyurethane Formation via a Dual-Activated Mechanism: Unexpected Preference of N-Activation over O-Activation of Isocyanates
inferred← citeshttps://doi.org/10.1021/jacs.5b02879openalex-snapshot
Imidazolium Cations with Exceptional Alkaline Stability: A Systematic Study of Structure–Stability Relationships
inferred← citeshttps://doi.org/10.1021/jo400481bopenalex-snapshot
Synthesis of Differentially Substituted 2-Aminoimidazolidines via a Microwave-Assisted Tandem Staudinger/Aza-Wittig Cyclization
inferred← citeshttps://doi.org/10.1038/s41428-019-0246-8openalex-snapshot
Low-temperature amino-based catalyst activation for on-demand polyurethane synthesis
inferred← citeshttps://doi.org/10.1039/9781788015738-00121openalex-snapshot
Base Catalysts for Organopolymerization
inferred← citeshttps://doi.org/10.1039/9781788015738-00531openalex-snapshot
Organocatalyzed Step-growth Polymerization
inferred← citeshttps://doi.org/10.1039/c2py21006aopenalex-snapshot
Latent catalysts based on guanidine templates for polyurethane synthesis
inferred← citeshttps://doi.org/10.1039/c3gc40319jopenalex-snapshot
Homogeneous isocyanate- and catalyst-free synthesis of polyurethanes in aqueous media
inferred← citeshttps://doi.org/10.1039/c3gc40440dopenalex-snapshot
Sustainable routes to polyurethane precursors
inferred← citeshttps://doi.org/10.1039/c3gc41217bopenalex-snapshot
Synthesis of polyurethane particles in supercritical carbon dioxide using organocatalysts or organocatalytic surfactants
inferred← citeshttps://doi.org/10.1039/c3py01639kopenalex-snapshot
Ring-opening metathesis polymerization of cyclooctene derivatives with chain transfer agents derived from glycerol carbonate
inferred← citeshttps://doi.org/10.1039/c4gc01032aopenalex-snapshot
Rational investigations in the ring opening of cyclic carbonates by amines
inferred← citeshttps://doi.org/10.1039/c4py00262hopenalex-snapshot
Highly tunable polyurethanes: organocatalyzed polyaddition and subsequent post-polymerization modification of pentafluorophenyl ester sidechains
inferred← citeshttps://doi.org/10.1039/c4py01002gopenalex-snapshot
Thermally cleavable imine base/isocyanate adducts and oligomers suitable as initiators for radical homo- and copolymerization
inferred← citeshttps://doi.org/10.1039/c4py01455copenalex-snapshot
Polyurethane-coated silica particles with broad-spectrum antibacterial properties
inferred← citeshttps://doi.org/10.1039/c4sc03804eopenalex-snapshot
Development of solvent-free synthesis of hydrogen-bonded supramolecular polyurethanes
inferred← citeshttps://doi.org/10.1039/c5np00108kopenalex-snapshot
The chemistry and biology of guanidine natural products
inferred← citeshttps://doi.org/10.1039/c5py02032hopenalex-snapshot
Bio-based difuranic polyol monomers and their derived linear and cross-linked polyurethanes
inferred← citeshttps://doi.org/10.1039/c8py00485dopenalex-snapshot
Ultrafast and efficient aza- and thiol-Michael reactions on a polyester scaffold with internal electron deficient triple bonds
inferred← citeshttps://doi.org/10.1039/c8ra07677dopenalex-snapshot
Poly(styrene)-supported N-heterocyclic carbene coordinated iron chloride as a catalyst for delayed polyurethane polymerization
inferred← citeshttps://doi.org/10.1039/c9nj05189aopenalex-snapshot
A facile preparation strategy of polycaprolactone (PCL)-based biodegradable polyurethane elastomer with a highly efficient shape memory effect
inferred← citeshttps://doi.org/10.1039/d0ma00734jopenalex-snapshot
Zinc diethyldithiocarbamate as a catalyst for synthesising biomedically-relevant thermogelling polyurethanes
inferred← citeshttps://doi.org/10.1039/d0py00864hopenalex-snapshot
Identifying competitive tin- or metal-free catalyst combinations to tailor polyurethane prepolymer and network properties
inferred← citeshttps://doi.org/10.1039/d1gc00446hopenalex-snapshot
Heterobimetallic complexes composed of bismuth and lithium carboxylates as polyurethane catalysts – alternatives to organotin compounds
inferred← citeshttps://doi.org/10.1039/d2cc03155hopenalex-snapshot
Photocatalyzed decarboxylation of oxamic acids under near-infrared conditions
inferred← citeshttps://doi.org/10.1039/d3ra02157bopenalex-snapshot
Injectable and photocurable macromonomers synthesized using a heterometallic magnesium–titanium metal–organic catalyst for elastomeric polymer networks
inferred← citeshttps://doi.org/10.1039/d6ob00116eopenalex-snapshot
N–N ring opening of diazabicyclo[3.1.0]hexanes with aryl isocyanates and isothiocyanates
inferred← citeshttps://doi.org/10.1039/d6ra03376hopenalex-snapshot
UV photocatalyzed polyurethane formulations for controlled foam generation
inferred← citeshttps://doi.org/10.1055/s-0037-1612425openalex-snapshot
Synthesis of Sterically Congested Carbamates of Carbohydrates through Organic Base Catalysis
inferred← citeshttps://doi.org/10.1055/sos-sd-118-00435openalex-snapshot
18.16.20 Other Tetraheterosubstituted Methanes (Update 2014)
inferred← citeshttps://doi.org/10.1080/15685551.2016.1152545openalex-snapshot
Novel nucleophilic/basic and acidic organocatalysts for reaction between poorly reactive diisocyanate and diols
inferred← citeshttps://doi.org/10.1155/adv/9666254openalex-snapshot
Dual‐Cation Fe/Zn Complexes and Their Catalysis Effects on Polyurethane Synthesis
inferred← citeshttps://doi.org/10.3390/catal11050614openalex-snapshot
DBU-Intercalated α-Zirconium Phosphates as Latent Thermal Catalysts in the Reaction of Hexamethylene Diisocyanate and Phenol
inferred← citeshttps://doi.org/10.3390/molecules28207133openalex-snapshot
Paving the Way towards Sustainability of Polyurethanes: Synthesis and Properties of Terpene-Based Diisocyanate
inferred← citeshttps://doi.org/10.3390/molecules29235569openalex-snapshot
DABCO-Intercalated α-Zirconium Phosphate as a Latent Thermal Catalyst in the Reaction of Urethane Synthesis
inferred← citeshttps://doi.org/10.3390/polym17131749openalex-snapshot
Biocompatible Glues: Recent Progress and Emerging Frontiers in Surgical Adhesion
inferred← citeshttps://doi.org/10.3390/polym17182548openalex-snapshot
Catalyst Selection for Body-Temperature Curable Polyurethane Networks from Poly(δ-Decalactone) and Lysine Diisocyanate
inferred← citeshttps://doi.org/10.58837/chula.the.2018.398openalex-snapshot
Preparation of polyurethane and polyisocyanurate foams catalyzed by metal acetate-ammonia complexes
inferred← citeshttps://doi.org/10.70675/282e9acbze50fz4468z8afezd78fd0df0510openalex-snapshot
Développement de méthodes de criblages et d'analyses en parallèle appliquées aux polymères modifiés silanes
inferred← citeshttps://doi.org/10.70675/39f705a7zbf24z4d60za254z29f3ec2151cbopenalex-snapshot
Sustainable polymers and additives from waste plastics using a hybrid “chem-biotech” approach
inferred← citeshttps://doi.org/10.70675/6546aa5bzf91dz4988za7d0z01d67ebec869openalex-snapshot
Nouveaux catalyseurs et systèmes catalytiques appliqués à la synthèse du polyuréthane via la réaction isocyanate – alcool
inferred← citeshttps://doi.org/10.70675/7560a3b3z41afz4e5fz838cz8550975e925dopenalex-snapshot
Réactions d’interconversion catalytiques entre composés C1 : CO2, CO, acide formique, méthanol, méthane et dérivés
inferred← citeshttps://doi.org/10.70675/a5ad76afz65ddz433bz87cbz8557eff4e7c2openalex-snapshot
Organopolymérisations du méthacrylate de méthyle induites par les carbène N-hétérocycliques et par des paires de Lewis organiques
inferred← citeshttps://doi.org/10.70675/b75ffe81z010bz41fdz8234z767f7353746fopenalex-snapshot
New challenges in the synthesis of non-isocyanate polyurethanes
inferred← citeshttps://doi.org/10.70675/e8e48c65z9f28z44f3z9c60z90234f767393openalex-snapshot
Influence et sélection de systèmes catalytiques pour la synthèse et la réticulation de prépolymères polyuréthanes
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