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Crystallization Properties and Polymorphic Behavior of Isotactic Poly(1-Butene) from Metallocene Catalysts: The Crystallization of Form I from the Melt

https://doi.org/10.1021/ma901453x
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The Effect of In Situ Melt Pre-Shear Induced Precursors On the Crystallization of Poly(1-Butene)/Polypropylene Blends
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Influence of Crystal Defects and Structural Disorder on the Physical and Mechanical Properties of Polymeric Materials
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Self‐welding 1‐butene/ethylene copolymers from metallocene catalysts: Structure, morphology, and mechanical properties
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Rheology, polymorphic crystal transformation, thermal, and mechanical properties of long‐chain branched isotactic poly(1‐butene)
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Effect of long‐chain branching structures on supercritical CO2 foaming behavior of iPB ‐1 with different crystalline form ratios
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Crystallization and Phase Transition of 1‐Butene Copolymers with Distinct Cyclic Co‐Units
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Direct Fabrication of Porous Isotactic Poly‐1‐Butene With Form I From the Melt Using CO2
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Dramatically Accelerating II−I Crystal Phase Transition of Polybutene‑1 by In Situ Incorporation of H‐Shape Long‐Chain‐Branching Structures
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Correlation between Orientation of Crystallites and Stress‐Induced Phase Transformations in Copolymers of Isotactic Poly(Butene) with Ethylene
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Crystal structures and polymorphism of polymers: Influence of defects and disorder
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Polymorphism in polymers: A tool to tailor material's properties
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An FTIR and X‐ray diffraction study of the crystal phase transition in isotactic polybutene‐1
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Influence of the Form II/Form I crystal polymorphism of random copolymers of butene‐1 with ethylene or propylene on the peel behavior of peel films
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Stretching‐induced phase transition of the butene‐1/ethylene random copolymer: Orientation and kinetics
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Effect of residue solvent in polybutylene-1 on the following phase transition after solvent vapor annealing for different time
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Mechanism of polymorph selection during crystallization of random butene-1/ethylene copolymer
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Differential Polymorphic Transformation Behavior of Polybutene-1 with Multiple Isotactic Sequences
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The Effect of In situ Melt Pre-shear Induced Oriented Precursors on the Crystallization of Poly(1-butene)/Polypropylene Blends
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Acceleration of Form II-I Transition in Polybutene-1 by H-shape Long-chain Branching: Critical Role of 1,9-Decadiene as Branching Agent and Synergy with Comonomer
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Shear effects on crystallization behaviors and structure transitions of isotactic poly-1-butene
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Effects of zinc isophthalate on the crystallization and crystal transformation behavior of polybutene alloy
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Influence of pre-generated form i polybutylene-1 on form ii/i phase transition during solvent vapor annealing
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Isospecific polymerizations of 1-butene catalyzed by MgCl2/TiCl4/internal donor-AlR3/external donor system
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Heterocycle-fused cyclopentadienyl metal complexes: Heterocene synthesis, structure and catalytic applications
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The irreversible Form II to Form I transformation in random butene-1/ethylene copolymers
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Conformationally disordered crystals and their influence on material properties: The cases of isotactic polypropylene, isotactic poly(1-butene), and poly(l-lactic acid)
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The outlined polymorph selection of iPB-1 revealing by incorporation of a dentritic polymer
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CO2-induced polymorphous phase transition of isotactic poly-1-butene with form III upon annealing
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Direct melt-crystallization of isotactic poly-1-butene with form I′ using high-pressure CO2
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Morphological and kinetic partitioning of comonomer in random propylene 1-butene copolymers
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Controlling crystal phase transition from form II to I in isotactic poly-1-butene using CO2
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Transition from two-stage to direct melt-crystallization in isotactic random butene-1/propene copolymers
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Accelerating crystal–crystal transition in poly(1-butene) with two-step crystallization: An in-situ microscopic infrared imaging and microbeam X-ray diffraction study
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On cross- and self-nucleation in seeded crystallization of isotactic poly(1-butene)
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Self-nucleation of isotactic poly(1-butene) in the trigonal modification
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Crystallization behavior and mechanical properties of copolymers of isotactic poly(1-butene) with 1-octene from metallocene catalysts
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Interfacial nucleation in iPP/PB-1 blends promotes the formation of polybutene-1 trigonal crystals
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Acceleration of crystal transformation from crystal form II to form I in Polybutene-1 induced by nanoparticles
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Direct formation of form I’ crystals in polybutene-1/polypropylene blend enhanced by cold crystallization
inferred← citeshttps://doi.org/10.1016/j.polymer.2018.10.045openalex-snapshot
Crystallization and mechanical properties of metallocene made 1-butene-pentene and 1-butene-hexene isotactic copolymers
inferred← citeshttps://doi.org/10.1016/j.polymer.2019.04.050openalex-snapshot
Effects of molecular weight on polybutene-1 cold crystallization from polybutene-1/polypropylene blend
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Investigation on phase transition from flow-induced oriented form II to I in isotactic polybutene-1 with in-situ microbeam X-ray diffraction technique
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Transformation from form II to form I accelerated by oriented lamellae in Polybutene-1
inferred← citeshttps://doi.org/10.1016/j.polymer.2020.122169openalex-snapshot
Rapid phase transition of polybutene-1 from form II to form I induced by pressure
inferred← citeshttps://doi.org/10.1016/j.polymer.2020.122293openalex-snapshot
Formation and stabilization of crystal nuclei in isotactic polybutene-1 aged below glass transition temperature
inferred← citeshttps://doi.org/10.1016/j.polymer.2020.122425openalex-snapshot
Hierarchical structure of polybutene-1 in crystal blocks resulting from the form II to I solid-to-solid transition as revealed by small-angle X-ray scattering
inferred← citeshttps://doi.org/10.1016/j.polymer.2020.122460openalex-snapshot
Polymorphism and form II – form I transformation in Ziegler-Natta isotactic 1-butene-ethylene copolymers having a multiblock molecular structure
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Influence of melt structure on Form II to I phase transition of Polybutene-1 under shear flow
inferred← citeshttps://doi.org/10.1016/j.polymer.2020.123355openalex-snapshot
Change of lamellar morphology upon polymorphic transition of form II to form I crystals in isotactic Polybutene-1 and its copolymer
inferred← citeshttps://doi.org/10.1016/j.polymer.2021.123408openalex-snapshot
Mechanical properties of isotactic 1-butene-ethylene copolymers from Ziegler-Natta catalyst
inferred← citeshttps://doi.org/10.1016/j.polymer.2021.123763openalex-snapshot
Reexamining the role of intercrystalline links in the II-I phase transition of Poly(1-butene)
inferred← citeshttps://doi.org/10.1016/j.polymer.2022.125008openalex-snapshot
Investigation on the accelerating effect of two-dimensional boron nitride on the phase transition from form II to I in isotactic polybutene-1
inferred← citeshttps://doi.org/10.1016/j.polymer.2022.125276openalex-snapshot
Melt pre-shear induced orientation crystallization of PB and PB/HMwPB blend
inferred← citeshttps://doi.org/10.1016/j.polymer.2023.125846openalex-snapshot
Influence of self-nucleation on phase transition in poly(1-butene)
inferred← citeshttps://doi.org/10.1016/j.polymer.2025.128165openalex-snapshot
Investigation on the polymorph selection during recrystallization of isotactic Polybutene-1 homopolymer
inferred← citeshttps://doi.org/10.1016/j.polymer.2025.128530openalex-snapshot
Melting and transition of isotactic polybutene-1 precipitated from solutions
inferred← citeshttps://doi.org/10.1016/j.polymer.2025.128683openalex-snapshot
Melt-memory effect in copolymers of isotactic poly(butene) with 1-pentene and 1-hexene: the role of defects excluded or included into crystals
inferred← citeshttps://doi.org/10.1016/j.polymer.2025.129088openalex-snapshot
Synthesis and performance study of Polybutene-1 synergistically engineered via H-Shaped long-chain-branching and ethylene co-monomer incorporation
inferred← citeshttps://doi.org/10.1016/j.polymer.2025.129133openalex-snapshot
Isotactic copolymerization of but-1-ene with polar vinyl monomers: the effect of ω-alken-1-ol comonomer content on phase behavior, melt rheology, mechanical and adhesive properties of functionalized poly(but-1-ene)s
inferred← citeshttps://doi.org/10.1016/j.polymer.2025.129458openalex-snapshot
Effect of crystallisation conditions on physical structures and mechanical properties of isotactic polybutene-1
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Revealing the crystal transition of isotactic polybutene-1 via in situ Raman spectroscopy
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In situ binary modification of isotactic polybutene-1 by propylene co-unit and H-shape long-chain-branching: Synergism rendering reconciliation of fast crystalline phase transition kinetics and high physical properties
inferred← citeshttps://doi.org/10.1016/j.polymertesting.2023.108295openalex-snapshot
Accelerated crystallization and crystal-crystal transition of PB induced by PP with optimized content
inferred← citeshttps://doi.org/10.1021/acs.iecr.9b00178openalex-snapshot
High-Performance Isotactic Poly(1-butene)/Isotactic Polypropylene Alloys with in-Situ-Synthesized Poly(propylene-co-butene)
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Influence of Steric Norbornene Co-units on the Crystallization and Memory Effect of Polybutene-1 Copolymers
inferred← citeshttps://doi.org/10.1021/acs.macromol.0c00414openalex-snapshot
Real-Space in Situ Study of the II–I Phase Transition of Isotactic Poly(1-butene)
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Propylene–Butene Copolymers: Tailoring Mechanical Properties from Isotactic Polypropylene to Polybutene
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Nucleation Mechanism for Form II to I Polymorphic Transformation in Polybutene-1
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Flow-Induced Crystallization in Butene-1/1,5-Hexadiene Copolymers: Mutual Effects of Molecular Factor and Flow Stimuli
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Regulating Two Distinct Formation Pathways of the Thermodynamically Stable Phase to Tune Crystal Polymorphism: The Case of Butene/Pentene Copolymers
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Cooling Condition Determines the Transition Degree at Saturation of Form II in Isotactic Polybutene-1 Confined within Nanopores
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Stretching-Induced Melting and Recrystallization Polymorphism Revealed in Polybutene-1
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Equilibrium Melting Temperature of the Hexagonal Crystals of Polybutene-1 and Its Copolymer
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Chain Trajectory and Crystallization Mechanism of a Semicrystalline Polymer in Melt- and Solution-Grown Crystals As Studied Using 13 C– 13 C Double-Quantum NMR
inferred← citeshttps://doi.org/10.1021/acs.macromol.5b02161openalex-snapshot
Mixing Assisted Direct Formation of Isotactic Poly(1-butene) Form I′ Crystals from Blend Melt of Isotactic Poly(1-butene)/Polypropylene
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c00152openalex-snapshot
Mechanism of Fast Phase Transition from Form II to Form I of Polybutene‑1 during Solvent Vapor Annealing
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c01958openalex-snapshot
The Role of Stretching-Induced Phase Transformations in the Mechanical Properties of Isotactic 1-Butene-ethylene Copolymers from Ziegler–Natta Catalyst
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c03047openalex-snapshot
Enhanced Mechanical Performance of Polybutene-1 Terpolymers via Crystallization Modulation
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c03108openalex-snapshot
Quantitative Correlation between Mechanical Behaviors and Free Volume of Oriented Polyethylene Terephthalate: an In Situ PALS Study
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c03636openalex-snapshot
Melt Memory in Propene–Butene Isotactic Copolymers: The Case of Defects Hosted in the Crystals and of Isodimorphism in Olefin Copolymers
inferred← citeshttps://doi.org/10.1021/acs.macromol.6b00862openalex-snapshot
Kinetics of Nucleation and Growth of Form II to I Polymorphic Transition in Polybutene-1 as Revealed by Stepwise Annealing
inferred← citeshttps://doi.org/10.1021/acs.macromol.6b01457openalex-snapshot
Featured Crystallization Polymorphism and Memory Effect in Novel Butene-1/1,5-Hexadiene Copolymers Synthesized by Post-Metallocene Hafnium Catalyst
inferred← citeshttps://doi.org/10.1021/acs.macromol.6c00424openalex-snapshot
Mechanistic Insights into Isotactic 1-Butene Polymerization: Accessing Novel Microstructures with Nonmetallocene Pyridylamido-Hf Catalysts
inferred← citeshttps://doi.org/10.1021/acs.macromol.6c01764openalex-snapshot
Form II to Form I Transition in Butene-1/Ethylene Copolymer at Isothermal Crystallization Temperatures
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b02481openalex-snapshot
Retardance of Form II to Form I Transition in Polybutene-1 at Late Stage: A Proposal of a New Mechanism
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b01313openalex-snapshot
Promotion of Self-Nucleation with Latent Form I Nuclei in Polybutene-1 and Its Copolymer
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b01795openalex-snapshot
Spontaneous Form II to I Transition in Low Molar Mass Polybutene-1 at Crystallization Temperature Reveals Stabilization Role of Intercrystalline Links and Entanglements for Metastable Form II Crystals
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b02600openalex-snapshot
Phase Transition from Tetragonal Form II to Hexagonal Form I of Butene-1/4-Methyl-1-pentene Random Copolymers: Molecular Factor versus Stretching Stimuli
inferred← citeshttps://doi.org/10.1021/acs.macromol.9b00627openalex-snapshot
Epitaxial Recrystallization of IPBu in Form II on an Oriented IPS Film Initially Induced by Oriented Form I IPBu
inferred← citeshttps://doi.org/10.1021/acs.macromol.9b01570openalex-snapshot
Crystallization Behavior of Copolymers of Isotactic Poly(1-butene) with Ethylene from Ziegler–Natta Catalyst: Evidence of the Blocky Molecular Structure
inferred← citeshttps://doi.org/10.1021/acs.macromol.9b01574openalex-snapshot
Morphological Evidence for the Two-Step II–I Phase Transition of Isotactic Polybutene-1
inferred← citeshttps://doi.org/10.1021/acs.macromol.9b02023openalex-snapshot
Direct High-Temperature Form I Crystallization of Isotactic Poly(1-butene) Assisted by Oriented Isotactic Polypropylene
inferred← citeshttps://doi.org/10.1021/acs.macromol.9b02463openalex-snapshot
Interplay between Macroscopic Stretching and Microscopic Phase Transition Revealed in Butene-1/1,5-Hexadiene Random Copolymers
inferred← citeshttps://doi.org/10.1021/acsapm.5c02453openalex-snapshot
Machine Learning-Based Prediction Model for the Stretching-Induced II–I Phase Transition of Polybutene-1
inferred← citeshttps://doi.org/10.1021/jacs.8b02963openalex-snapshot
Synthesis of Semicrystalline Polyolefin Materials: Precision Methyl Branching via Stereoretentive Chain Walking
inferred← citeshttps://doi.org/10.1021/ma102534fopenalex-snapshot
Crystallization Behavior of Propylene−Butene Copolymers: The Trigonal Form of Isotactic Polypropylene and Form I of Isotactic Poly(1-butene)
inferred← citeshttps://doi.org/10.1021/ma200988yopenalex-snapshot
CO2-Induced Phase Transition of Isotactic Poly-1-butene with Form III upon Heating
inferred← citeshttps://doi.org/10.1021/ma2026513openalex-snapshot
Stretch-Induced Crystal–Crystal Transition of Polybutene-1: An in Situ Synchrotron Radiation Wide-Angle X-ray Scattering Study
inferred← citeshttps://doi.org/10.1021/ma402239kopenalex-snapshot
Mechanical Properties and Stress-Induced Phase Transformations of Metallocene Isotactic Poly(1-butene): The Influence of Stereodefects
inferred← citeshttps://doi.org/10.1021/ma500088aopenalex-snapshot
Polymorphic Behavior and Mechanical Properties of Isotactic 1-Butene–Ethylene Copolymers from Metallocene Catalysts
inferred← citeshttps://doi.org/10.1021/ma500281fopenalex-snapshot
Kinetics of the Polymorphic Transition in Isotactic Poly(1-butene) under Uniaxial Extension. New Insights From Designed Mechanical histories.
inferred← citeshttps://doi.org/10.1021/ma5009868openalex-snapshot
A New ε Crystal Modification Found in Stereodefective Isotactic Polypropylene Samples
inferred← citeshttps://doi.org/10.1021/ma501272aopenalex-snapshot
Molecular Weight Dependency of Crystallization Line, Recrystallization Line, and Melting Line of Polybutene-1
inferred← citeshttps://doi.org/10.1021/ma5019796openalex-snapshot
Direct Formation of Different Crystalline Forms in Butene-1/Ethylene Copolymer via Manipulating Melt Temperature
inferred← citeshttps://doi.org/10.1038/pj.2011.66openalex-snapshot
Critical roles of molecular dynamics in the superior mechanical properties of isotactic-poly(1-butene) elucidated by solid-state NMR
inferred← citeshttps://doi.org/10.1039/c5ce01727kopenalex-snapshot
The morphology and polymorphism of self-nucleated trigonal isotactic poly(1-butene) studied by synchrotron IR microspectroscopy
inferred← citeshttps://doi.org/10.1039/c7sm00107jopenalex-snapshot
Structural and morphological transitions in extension-induced crystallization of poly(1-butene) melt
inferred← citeshttps://doi.org/10.1039/c7sm01366copenalex-snapshot
Rapid assessment of crystal orientation in semi-crystalline polymer films using rotational zone annealing and impact of orientation on mechanical properties
inferred← citeshttps://doi.org/10.1039/c8sm01793jopenalex-snapshot
Controlling crystal polymorphism of isotactic poly(1-butene) by incorporating long chain branches
inferred← citeshttps://doi.org/10.1039/c9ce02010aopenalex-snapshot
A new perspective to enhance the II–I transition of polybutene-1
inferred← citeshttps://doi.org/10.1039/c9py01485copenalex-snapshot
The blocky structure of Ziegler–Natta “random” copolymers: myths and experimental evidence
inferred← citeshttps://doi.org/10.1039/d0sm00572jopenalex-snapshot
Formation of fibrillar crystals strongly accelerates the form II to I transformation of polybutene-1
inferred← citeshttps://doi.org/10.1039/d1ce01612aopenalex-snapshot
Effect of an additive TAB-1 on crystallization behaviors and tensile properties of iPB-1
inferred← citeshttps://doi.org/10.1039/d2ce00765gopenalex-snapshot
Chain dimension and crystallization temperature affect the II – I transition of isotactic polybutene-1
inferred← citeshttps://doi.org/10.1039/d2sm00841fopenalex-snapshot
Investigation of the synergistic effect of melt-extension and nanofiller on the crystal–crystal phase transition from form II to I of isotactic polybutene-1
inferred← citeshttps://doi.org/10.1039/d3ce00008gopenalex-snapshot
Crystallization and phase transition of butene/propylene copolymers
inferred← citeshttps://doi.org/10.1039/d3ce00584dopenalex-snapshot
Retarding crystal transitions of polybutene-1 in blends
inferred← citeshttps://doi.org/10.1039/d3ce01131copenalex-snapshot
Utilizing 3-methyl-1-butene co-units to tailor phase transition behavior in butene-1 copolymers
inferred← citeshttps://doi.org/10.1039/d3ce01303kopenalex-snapshot
Effects of nucleating agents on the II–I transition of iPB-1
inferred← citeshttps://doi.org/10.1039/d3py00028aopenalex-snapshot
Recent developments in catalyst systems for selective oligomerization and polymerization of higher α-olefins
inferred← citeshttps://doi.org/10.1039/d4sm00369aopenalex-snapshot
Transition of iPB-1 with low molecular weight crystallized from solutions
inferred← citeshttps://doi.org/10.1039/d5ce00329fopenalex-snapshot
In situ Raman scattering investigation of crystal phase transition in isotactic polybutene-1
inferred← citeshttps://doi.org/10.1063/1.4937318openalex-snapshot
The irreversible tetragonal to trigonal transformation in random butene-1/ethylene copolymers
inferred← citeshttps://doi.org/10.1122/1.5021000openalex-snapshot
Stability of flow-induced precursors in poly-1-butene and copolymer of 1-butene and ethylene
inferred← citeshttps://doi.org/10.3139/217.3205openalex-snapshot
Study on Crystal Form Transition and Non-Isothermal Crystallization of Glycidyl Methacrylate Grafted Isotactic Polybutene-1
inferred← citeshttps://doi.org/10.3139/217.3248openalex-snapshot
The Three-Phase Structure of Random Butene-1/Ethylene Copolymers
inferred← citeshttps://doi.org/10.3389/fchem.2024.1377740openalex-snapshot
Mechanistic insights on 1-butene polymerization catalyzed by homogeneous single-site catalysts: a DFT computational study
inferred← citeshttps://doi.org/10.3390/polym10050556openalex-snapshot
Polymorphic Behavior and Phase Transition of Poly(1-Butene) and Its Copolymers
inferred← citeshttps://doi.org/10.3390/polym11050837openalex-snapshot
Thermal Analysis of Crystallization and Phase Transition in Novel Polyethylene Glycol Grafted Butene-1 Copolymers
inferred← citeshttps://doi.org/10.3390/polym11071133openalex-snapshot
Poly (1-butene-ran-ethylene) Monomodal Copolymers from Metallocene Catalysts: Structural and Morphological Differences with Increasing Ethylene Content
inferred← citeshttps://doi.org/10.3390/polym13081315openalex-snapshot
The II–I Phase Transition Behavior of Butene-1 Copolymers with Hydroxyl Groups
inferred← citeshttps://doi.org/10.48084/etasr.9421openalex-snapshot
Effect of Iron Loading on Quiescent Crystallization of Syndiotactic Polypropylene/Iron Composites
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