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Pd-Catalyzed Asymmetric Allylic Alkylation of Indoles and Pyrroles by Chiral Alkene-Phosphine Ligands

https://doi.org/10.1021/ol200602x

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What this work says

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Copper-Catalyzed Asymmetric Yne-Allylic Substitution Using Electron-Rich Arenes

inferred← citeshttps://doi.org/10.1021/acscatal.5c00040openalex-snapshot

Bridging Homogeneous and Heterogeneous Catalysis: Ni@CPOL-dppp&PPh3-Catalyzed Symmetric H-Phosphonate Diester Synthesis from Sodium Hypophosphite

inferred← citeshttps://doi.org/10.1021/acscatal.6b01585openalex-snapshot

Enantioselective Synthesis of Pyrrole-Fused Piperazine and Piperazinone Derivatives via Ir-Catalyzed Asymmetric Allylic Amination

inferred← citeshttps://doi.org/10.1021/acscatal.9b04354openalex-snapshot

Axially Chiral Biaryl Monophosphine Oxides Enabled by Palladium/WJ-Phos-Catalyzed Asymmetric Suzuki–Miyaura Cross-coupling

inferred← citeshttps://doi.org/10.1021/ar500167fopenalex-snapshot

Transition-Metal-Catalyzed Asymmetric Allylic Dearomatization Reactions

inferred← citeshttps://doi.org/10.1021/ja403535aopenalex-snapshot

Enantioselective Functionalization of Indoles and Pyrroles via an in Situ-Formed Spiro Intermediate

inferred← citeshttps://doi.org/10.1021/ja5028138openalex-snapshot

Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles

inferred← citeshttps://doi.org/10.1021/jacs.5c03816openalex-snapshot

Phosphorus(III)-Compatible Asymmetric Suzuki–Miyaura Cross-Coupling (P-ASMC) Reaction

inferred← citeshttps://doi.org/10.1021/jacs.6b11243openalex-snapshot

Planar-Chiral Phosphine-Olefin Ligands Exploiting a (Cyclopentadienyl)manganese(I) Scaffold To Achieve High Robustness and High Enantioselectivity

inferred← citeshttps://doi.org/10.1021/jacs.7b01410openalex-snapshot

Palladium Catalyzed Asymmetric Three-Component Coupling of Boronic Esters, Indoles, and Allylic Acetates

inferred← citeshttps://doi.org/10.1021/jacs.8b06629openalex-snapshot

Tandem Allylation/1,2-Boronate Rearrangement for the Asymmetric Synthesis of Indolines with Adjacent Quaternary Stereocenters

inferred← citeshttps://doi.org/10.1021/jo200925qopenalex-snapshot

Pd-Catalyzed Asymmetric Allylic Etherizations with Oximes by Chiral Alkene-Phosphine Ligands

inferred← citeshttps://doi.org/10.1021/jo300539yopenalex-snapshot

Asymmetric Allylic Alkylation of Pyrroles and 4,7-Dihydroindoles with Alkene–Phosphine Ligands

inferred← citeshttps://doi.org/10.1021/jo5013042openalex-snapshot

Preparation of 2,3-Dihydrofurans via a Double Allylic Substitution Reaction of Allylic Nitro Compounds

inferred← citeshttps://doi.org/10.1021/ol2009494openalex-snapshot

Simple N-Sulfinyl-Based Chiral Sulfur–Olefin Ligands for Rhodium-Catalyzed Asymmetric 1,4-Additions

inferred← citeshttps://doi.org/10.1021/ol202069eopenalex-snapshot

Kinetic Resolution of Hindered Morita–Baylis–Hillman Adducts by Rh(I)-Catalyzed Asymmetric 1,4-Addition/β-Hydroxyelimination

inferred← citeshttps://doi.org/10.1021/ol203238jopenalex-snapshot

Rh(I)-Catalyzed Asymmetric 1,2-Addition to α-Diketones with Chiral Sulfur–Alkene Hybrid Ligands

inferred← citeshttps://doi.org/10.1021/ol300770wopenalex-snapshot

Asymmetric Synthesis of Chiral 9,10-Dihydrophenanthrenes Using Pd-Catalyzed Asymmetric Intramolecular Friedel–Crafts Allylic Alkylation of Phenols

inferred← citeshttps://doi.org/10.1021/ol3032736openalex-snapshot

Pd-Catalyzed Asymmetric Allylic Alkylations of 3-Substituted Indoles Using Chiral P/Olefin Ligands

inferred← citeshttps://doi.org/10.1021/ol400334uopenalex-snapshot

Palladium-Catalyzed Decarboxylative Allylation and Benzylation of N-Alloc and N-Cbz Indoles

inferred← citeshttps://doi.org/10.1021/ol4016578openalex-snapshot

Ruthenium-Catalyzed Intramolecular Allylic Dearomatization Reaction of Indole Derivatives

inferred← citeshttps://doi.org/10.1021/ol402577popenalex-snapshot

Pd(II)-Catalyzed Ph2(O)P-Directed C–H Olefination toward Phosphine–Alkene Ligands

inferred← citeshttps://doi.org/10.1021/ol4027717openalex-snapshot

Highly Enantioselective Synthesis of Tetrahydrocarbolines via Iridium-Catalyzed Intramolecular Friedel–Crafts Type Allylic Alkylation Reactions

inferred← citeshttps://doi.org/10.1021/ol502535zopenalex-snapshot

Brønsted Acid Accelerated Pd-Catalyzed Direct Asymmetric Allylic Alkylation of Azlactones with Simple Allylic Alcohols: A Practical Access to Quaternary Allylic Amino Acid Derivatives

inferred← citeshttps://doi.org/10.1021/om200999nopenalex-snapshot

(Cycloheptadienyl)diphenylphosphine: A Versatile Hybrid Ligand

inferred← citeshttps://doi.org/10.1021/om400110topenalex-snapshot

N-Heterocyclic Carbene C,S Palladium(II) π-Allyl Complexes: Synthesis, Characterization, and Catalytic Application In Allylic Amination Reactions

inferred← citeshttps://doi.org/10.1038/s41929-020-0494-1openalex-snapshot

Construction of axial chirality via palladium/chiral norbornene cooperative catalysis

inferred← citeshttps://doi.org/10.1038/srep36211openalex-snapshot

Rational Design and Synthesis of [5]Helicene-Derived Phosphine Ligands and Their Application in Pd-Catalyzed Asymmetric Reactions

inferred← citeshttps://doi.org/10.1039/9781782621966-00214openalex-snapshot

Asymmetric Friedel–Crafts Alkylation Reactions

inferred← citeshttps://doi.org/10.1039/9781849737708-00001openalex-snapshot

Phosphines and related P–C‐bonded compounds

inferred← citeshttps://doi.org/10.1039/c1ob05803gopenalex-snapshot

Highly effective chiral phosphorus amidite–olefin ligands for palladium-catalyzed asymmetric allylic substitutions

inferred← citeshttps://doi.org/10.1039/c1ob05971hopenalex-snapshot

Chiral N-tert-butanesulfinyl α,β-unsaturated ketimine: a simple and highly effective olefin/sulfinimide hybrid ligand for asymmetric 1,4-additions

inferred← citeshttps://doi.org/10.1039/c1sc00517kopenalex-snapshot

Asymmetric dearomatization of pyrrolesviaIr-catalyzed allylic substitution reaction: enantioselective synthesis of spiro-2H-pyrroles

inferred← citeshttps://doi.org/10.1039/c2sc21085aopenalex-snapshot

Diversity oriented synthesis of indole-based peri-annulated compounds via allylic alkylation reactions

inferred← citeshttps://doi.org/10.1039/c3cc42673dopenalex-snapshot

Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(i) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

inferred← citeshttps://doi.org/10.1039/c3cs60116aopenalex-snapshot

Synthesis of binaphthyl based phosphine and phosphite ligands

inferred← citeshttps://doi.org/10.1039/c4ob01087fopenalex-snapshot

Asymmetric synthesis of axially chiral anilides by Pd-catalyzed allylic substitutions with P/olefin ligands

inferred← citeshttps://doi.org/10.1039/c4qo00135dopenalex-snapshot

Design of a new series of chiral phosphite–olefin ligands and their application in asymmetric catalysis

inferred← citeshttps://doi.org/10.1039/c5cc00685fopenalex-snapshot

H 8 -BINOL chiral imidodiphosphoric acid catalyzed highly enantioselective aza-Friedel–Crafts reactions of pyrroles and enamides/imines

inferred← citeshttps://doi.org/10.1039/c5ob00663eopenalex-snapshot

Palladium-catalyzed asymmetric allylic amination of racemic butadiene monoxide with isatin derivatives

inferred← citeshttps://doi.org/10.1039/c6ob01354fopenalex-snapshot

Chiral N-1-adamantyl-N-trans-cinnamylaniline type ligands: synthesis and application to palladium-catalyzed asymmetric allylic alkylation of indoles

inferred← citeshttps://doi.org/10.1039/c6qo00227gopenalex-snapshot

Highly enantioselective Pd-catalyzed indole allylic alkylation using binaphthyl-based phosphoramidite-thioether ligands

inferred← citeshttps://doi.org/10.1039/c6ra09657copenalex-snapshot

Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions with structurally diverse nucleophiles: scope and limitations

inferred← citeshttps://doi.org/10.1039/c7ob00413copenalex-snapshot

Recent progress in transition-metal-catalyzed enantioselective indole functionalizations

inferred← citeshttps://doi.org/10.1039/c7qo00815eopenalex-snapshot

Enantioselective palladium-catalyzed C–H functionalization of pyrroles using an axially chiral 2,2′-bipyridine ligand

inferred← citeshttps://doi.org/10.1039/c8ob02600aopenalex-snapshot

An enantioselective synthesis of α-alkylated pyrroles via cooperative isothiourea/palladium catalysis

inferred← citeshttps://doi.org/10.1039/c8sc01595copenalex-snapshot

Rhodium-catalyzed asymmetric hydroamination and hydroindolation of keto-vinylidenecyclopropanes

inferred← citeshttps://doi.org/10.1039/c9ob00075eopenalex-snapshot

Synthesis and application of P,olefin type axially chiral ligands with sec -alkyl groups

inferred← citeshttps://doi.org/10.1039/d0cc04145aopenalex-snapshot

Evolution of phosphorus–thioether ligands for asymmetric catalysis

inferred← citeshttps://doi.org/10.1039/d0qo00699hopenalex-snapshot

Regio- and enantioselective ring-opening reaction of vinylcyclopropanes with indoles under cooperative catalysis

inferred← citeshttps://doi.org/10.1039/d1cc01929eopenalex-snapshot

Enantioselective synthesis of polycyclic pyrrole derivatives by iridium-catalyzed asymmetric allylic dearomatization and ring-expansive migration reactions

inferred← citeshttps://doi.org/10.1039/d1cc03968gopenalex-snapshot

Iridium-catalyzed C3-selective asymmetric allylation of 7-azaindoles with secondary allylic alcohols

inferred← citeshttps://doi.org/10.1039/d3gc01017aopenalex-snapshot

Alkylation of amines with allylic alcohols and deep eutectic solvents as metal-free and green promoters

inferred← citeshttps://doi.org/10.1039/d4cc03601hopenalex-snapshot

Synthesis of chiral systems featuring the pyrrole unit: a review

inferred← citeshttps://doi.org/10.1039/d4qo01638fopenalex-snapshot

Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution

inferred← citeshttps://doi.org/10.1039/d4qo01671hopenalex-snapshot

Iridium-catalyzed asymmetric allenylic substitution of tertiary racemic allenylic alcohols with indoles

inferred← citeshttps://doi.org/10.1055/a-1920-3041openalex-snapshot

A Three-Component Approach to (Hetero)arenes with Two N-Containing Heterocycle Motifs

inferred← citeshttps://doi.org/10.1055/sos-sd-131-00192openalex-snapshot

31.41.3 Arylphosphine Oxides and Heteroatom Derivatives (Update 2015)

inferred← citeshttps://doi.org/10.1070/rc2012v081n09abeh004305openalex-snapshot

Asymmetric induction in reactions catalyzed by metal complexes

inferred← citeshttps://doi.org/10.1093/nsr/nwx064openalex-snapshot

Chiral ligands designed in China

inferred← citeshttps://doi.org/10.1248/yakushi.17-00151openalex-snapshot

Development of New Chiral Phosphine Ligands with Helical Environments and Their Application in Asymmetric Catalytic Reactions

inferred← citeshttps://doi.org/10.3390/catal10020193openalex-snapshot

Friedel–Crafts-Type Alkylation of Indoles in Water Using Amphiphilic Resin-Supported 1,10-Phenanthroline–Palladium Complex under Aerobic Conditions

inferred← citeshttps://doi.org/10.3390/molecules24081575openalex-snapshot

Spiro Indane-Based Phosphine-Oxazolines as Highly Efficient P,N Ligands for Enantioselective Pd-Catalyzed Allylic Alkylation of Indoles and Allylic Etherification

inferred← citeshttps://doi.org/10.3762/bjoc.10.215openalex-snapshot

P(O)R2-directed Pd-catalyzed C–H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands

inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.78.770openalex-snapshot

Design and Synthesis of Internal-Edge-Substituted Helicenes

inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.78.943openalex-snapshot

Asymmetric Synthesis of Chiral Heterocyclic Compounds via Intramolecular Dehydrative Allylation Catalyzed by a Cp-ruthenium-Brønsted Acid Combined Catalyst

inferred← citeshttps://doi.org/10.6023/cjoc202209002openalex-snapshot

Pd/Novel Axially Chiral Phosphine-Alkene Ligands Catalyzed Asymmetric Allylic Alkylation of Indoles

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