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Enantioselective Diels–Alder Reactions of Enals and Alkylidene Diketones Catalyzed by N-Heterocyclic Carbenes

https://doi.org/10.1021/ol201917u

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/adsc.200800051openalex-snapshot

Diastereoselective Synthesis of Trifluoromethylated γ‐Butyrolactones via N‐Heterocyclic Carbene‐Catalyzed Conjugated Umpolung of α,β‐Unsaturated Aldehydes

inferredcites →https://doi.org/10.1002/adsc.200800251openalex-snapshot

Stereoselective Synthesis of γ‐Butyrolactones via Organocatalytic Annulations of Enals and Keto Esters

inferredcites →https://doi.org/10.1002/anie.200461572openalex-snapshot

Organocatalyzed Conjugate Umpolung of α,β‐Unsaturated Aldehydes for the Synthesis of γ‐Butyrolactones

inferredcites →https://doi.org/10.1002/anie.200603129openalex-snapshot

Asymmetric Organocatalytic Domino Reactions

inferredcites →https://doi.org/10.1002/anie.200603380openalex-snapshot

N‐Heterocyclic Carbenes as Organocatalysts

inferredcites →https://doi.org/10.1002/anie.200605235openalex-snapshot

A Highly Enantioselective Intramolecular Michael Reaction Catalyzed by N‐Heterocyclic Carbenes

inferredcites →https://doi.org/10.1002/anie.200704684openalex-snapshot

Asymmetric Organocatalysis: From Infancy to Adolescence

inferredcites →https://doi.org/10.1002/anie.200705523openalex-snapshot

Asymmetric Aminocatalysis—Gold Rush in Organic Chemistry

inferredcites →https://doi.org/10.1002/anie.201007144openalex-snapshot

A Highly Regio‐ and Stereoselective Cascade Annulation of Enals and Benzodi(enone)s Catalyzed by N‐Heterocyclic Carbenes

inferredcites →https://doi.org/10.1002/chem.200801165openalex-snapshot

Chiral N‐Heterocyclic Carbene‐Catalyzed Formal [4+2] Cycloaddition of Ketenes with Enones: Highly Enantioselective Synthesis of trans‐ and cis‐δ‐Lactones

inferredcites →https://doi.org/10.1002/chin.200601063openalex-snapshot

Catalytic Generation of Activated Carboxylates from Enals: A Product‐Determining Role for the Base.

inferredcites →https://doi.org/10.1002/chin.200645087openalex-snapshot

N‐Heterocyclic Carbene‐Catalyzed Reaction of Chalcones and Enals via Homoenolate: An Efficient Synthesis of 1,3,4‐Trisubstituted Cyclopentenes.

inferredcites →https://doi.org/10.1021/ar0300468openalex-snapshot

Enamine-Based Organocatalysis with Proline and Diamines: The Development of Direct Catalytic Asymmetric Aldol, Mannich, Michael, and Diels−Alder Reactions

inferredcites →https://doi.org/10.1021/ar030048sopenalex-snapshot

Asymmetric Organic Catalysis with Modified Cinchona Alkaloids

inferredcites →https://doi.org/10.1021/ar2000716openalex-snapshot

Extending NHC-Catalysis: Coupling Aldehydes with Unconventional Reaction Partners

inferredcites →https://doi.org/10.1021/cr068372zopenalex-snapshot

Organocatalysis by N-Heterocyclic Carbenes

inferredcites →https://doi.org/10.1021/cr068373ropenalex-snapshot

Small-Molecule H-Bond Donors in Asymmetric Catalysis

inferredcites →https://doi.org/10.1021/cr068374jopenalex-snapshot

Stronger Brønsted Acids

inferredcites →https://doi.org/10.1021/cr068377wopenalex-snapshot

Asymmetric Catalysis Mediated by Synthetic Peptides

inferredcites →https://doi.org/10.1021/cr068388popenalex-snapshot

Iminium Catalysis

inferredcites →https://doi.org/10.1021/cr0684016openalex-snapshot

Asymmetric Enamine Catalysis

inferredcites →https://doi.org/10.1021/ja044714bopenalex-snapshot

N-Heterocyclic Carbene-Catalyzed Generation of Homoenolates: γ-Butyrolactones by Direct Annulations of Enals and Aldehydes

inferredcites →https://doi.org/10.1021/ja046991oopenalex-snapshot

Conversion of α-Haloaldehydes into Acylating Agents by an Internal Redox Reaction Catalyzed by Nucleophilic Carbenes

inferredcites →https://doi.org/10.1021/ja0625677openalex-snapshot

N-Heterocyclic Carbene-Catalyzed Reaction of Chalcones and Enals via Homoenolate: an Efficient Synthesis of 1,3,4-Trisubstituted Cyclopentenes

inferredcites →https://doi.org/10.1021/ja062707copenalex-snapshot

Highly Enantioselective Azadiene Diels−Alder Reactions Catalyzed by Chiral N-Heterocyclic Carbenes

inferredcites →https://doi.org/10.1021/ja066380ropenalex-snapshot

Chiral N-Heterocyclic Carbene Catalyzed, Enantioselective Oxodiene Diels−Alder Reactions with Low Catalyst Loadings

inferredcites →https://doi.org/10.1021/ja0705543openalex-snapshot

Enantioselective, Cyclopentene-Forming Annulations via NHC-Catalyzed Benzoin−Oxy-Cope Reactions

inferredcites →https://doi.org/10.1021/ja0709167openalex-snapshot

Highly Stereoselective Formal [3 + 3] Cycloaddition of Enals and Azomethine Imines Catalyzed by N-Heterocyclic Carbenes

inferredcites →https://doi.org/10.1021/ja073987eopenalex-snapshot

Enantioselective Synthesis of α,α-Disubstituted Cyclopentenes by an N-Heterocyclic Carbene-Catalyzed Desymmetrization of 1,3-Diketones

inferredcites →https://doi.org/10.1021/ja0768136openalex-snapshot

N-Heterocyclic Carbene-Catalyzed Redox Amidations of α-Functionalized Aldehydes with Amines

inferredcites →https://doi.org/10.1021/ja203810bopenalex-snapshot

Catalytic Asymmetric Intermolecular Stetter Reaction of Enals with Nitroalkenes: Enhancement of Catalytic Efficiency through Bifunctional Additives

inferredcites →https://doi.org/10.1021/ja905501zopenalex-snapshot

N-Heterocyclic Carbene-Catalyzed Generation of α,β-Unsaturated Acyl Imidazoliums: Synthesis of Dihydropyranones by their Reaction with Enolates

inferredcites →https://doi.org/10.1021/ja910666nopenalex-snapshot

Cooperative N-Heterocyclic Carbene/Lewis Acid Catalysis for Highly Stereoselective Annulation Reactions with Homoenolates

inferredcites →https://doi.org/10.1021/jo802515gopenalex-snapshot

An Unexpected N-Heterocyclic Carbene-Catalyzed Annulation of Enals and Nitroso Compounds

inferredcites →https://doi.org/10.1021/ol050100fopenalex-snapshot

Conversion of α,β-Unsaturated Aldehydes into Saturated Esters: An Umpolung Reaction Catalyzed by Nucleophilic Carbenes

inferredcites →https://doi.org/10.1021/ol051269wopenalex-snapshot

Catalytic Generation of Activated Carboxylates from Enals: A Product-Determining Role for the Base

inferredcites →https://doi.org/10.1021/ol052826hopenalex-snapshot

Stereoselective Synthesis of (E)-α,β-Unsaturated Esters via Carbene-Catalyzed Redox Esterification

inferredcites →https://doi.org/10.1021/ol052926nopenalex-snapshot

N-Heterocyclic Carbene Catalyzed Reaction of Enals and 1,2-Dicarbonyl Compounds: Stereoselective Synthesis of Spiro γ-Butyrolactones

inferredcites →https://doi.org/10.1021/ol103112vopenalex-snapshot

NHC-Catalyzed/Titanium(IV)−Mediated Highly Diastereo- and Enantioselective Dimerization of Enals

inferredcites →https://doi.org/10.1021/ol800003nopenalex-snapshot

Organocatalytic Synthesis of N-Phenylisoxazolidin-5-ones and a One-Pot Synthesis of β-Amino Acid Esters

inferredcites →https://doi.org/10.1021/ol800006mopenalex-snapshot

Synthesis of an N-Mesityl Substituted Chiral Imidazolium Salt for NHC-Catalyzed Reactions

inferredcites →https://doi.org/10.1021/ol801502hopenalex-snapshot

Chiral NHC-Catalyzed Oxodiene Diels−Alder Reactions with α-Chloroaldehyde Bisulfite Salts

inferredcites →https://doi.org/10.1021/ol8029005openalex-snapshot

NHC-Catalyzed Ring Expansion of Oxacycloalkane-2-carboxaldehydes: A Versatile Synthesis of Lactones

inferredcites →https://doi.org/10.1021/ol901545mopenalex-snapshot

Impact of Solvent Polarity on N-Heterocyclic Carbene-Catalyzed β-Protonations of Homoenolate Equivalents

inferredcites →https://doi.org/10.1038/nature07367openalex-snapshot

The advent and development of organocatalysis

inferredcites →https://doi.org/10.1038/nchem.727openalex-snapshot

Cooperative catalysis by carbenes and Lewis acids in a highly stereoselective route to γ-lactams

inferredcites →https://doi.org/10.1039/b719083mopenalex-snapshot

Recent advances in carbon–carbon bond-forming reactions involving homoenolates generated by NHC catalysis

inferredcites →https://doi.org/10.1039/b800857bopenalex-snapshot

N-Heterocyclic carbene catalysed β-lactam synthesis

inferredcites →https://doi.org/10.1039/b815139copenalex-snapshot

Asymmetric esterification of ketenes catalyzed by an N-heterocyclic carbene

inferredcites →https://doi.org/10.1039/b903816gopenalex-snapshot

Organocatalysis—after the gold rush

inferredcites →https://doi.org/10.1055/s-0029-1218801openalex-snapshot

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

inferredcites →https://doi.org/10.1073/pnas.1007469107openalex-snapshot

Chiral N-heterocyclic carbene-catalyzed generation of ester enolate equivalents from α,β-unsaturated aldehydes for enantioselective Diels–Alder reactions

inferredcites →https://doi.org/10.1246/cl.2011.786openalex-snapshot

Dual Activation in N-Heterocyclic Carbene-organocatalysis

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4641471openalex-extracted

inferred← citeshttps://doi.org/10.1002/9781118730379.ch9openalex-snapshot

Catalytic Reactions withN‐Mesityl‐SubstitutedN‐Heterocyclic Carbenes

inferred← citeshttps://doi.org/10.1002/9783527658862.ch38openalex-snapshot

Diels‐Alder and Hetero‐Diels–Alder Reactions

inferred← citeshttps://doi.org/10.1002/9783527809042.ch3openalex-snapshot

N‐Heterocyclic Carbene‐catalyzed S tetter Reaction and Related Chemistry

inferred← citeshttps://doi.org/10.1002/9783527809042.ch8openalex-snapshot

N‐Heterocyclic Carbene‐Catalyzed Reactions via Azolium Enolates and Dienolates

inferred← citeshttps://doi.org/10.1002/adsc.201200031openalex-snapshot

Exploiting Acyl and Enol Azolium Intermediates via N‐Hetero‐ cyclic Carbene‐Catalyzed Reactions of α‐Reducible Aldehydes

inferred← citeshttps://doi.org/10.1002/adsc.201700198openalex-snapshot

Catalytic Generation of Donor‐Acceptor Cyclopropanes under N‐Heterocyclic Carbene Activation and their Stereoselective Reaction with Alkylideneoxindoles

inferred← citeshttps://doi.org/10.1002/adsc.202201036openalex-snapshot

Carbene Catalyzed Asymmetric Synthesis of Selenylated δ‐Lactones via [4+2] Annulation of Selenyl Vinyl Ketones and Enals

inferred← citeshttps://doi.org/10.1002/ajoc.201600419openalex-snapshot

Sequential N‐Heterocyclic Carbene‐Catalyzed Reactions of Enals and Cyclic Aryldiene‐1,3‐Diones: Synthesis of Tricyclic Chromenones and Related Compounds

inferred← citeshttps://doi.org/10.1002/ajoc.201700520openalex-snapshot

N‐Heterocyclic‐Carbene‐Catalyzed Reactions of Nitroalkenes: Synthesizing Important Building Blocks

inferred← citeshttps://doi.org/10.1002/ajoc.201800496openalex-snapshot

Reactivity of N‐Substituted Exo‐oxazolidin‐2‐one Dienes with Naphthalene Chalcones and Cyclic 1,3‐Dicarbonyl Compounds

inferred← citeshttps://doi.org/10.1002/ajoc.201900352openalex-snapshot

para‐Toluenesulfonic Acid‐Catalyzed, Ultrasound‐Promoted, One‐Pot, Three‐Component Coupling of Aldehydes, β‐Dicarbonyls/Amides, and Electron‐Rich Arenes

inferred← citeshttps://doi.org/10.1002/ajoc.202100090openalex-snapshot

NHC‐Catalyzed Oxidative Annulation of α,β‐unsaturated Aldehydes with Benzyl Ketones: Direct Access to 4,5,6‐Trisubstituted Dihydropyranones

inferred← citeshttps://doi.org/10.1002/ajoc.202300341openalex-snapshot

Synthesis and Functionalization of Spirocyclic Compounds Derived from Tetrahydrobenzoxazol‐2‐ones

inferred← citeshttps://doi.org/10.1002/ange.201105812openalex-snapshot

Enantioselective Stetter Reactions of Enals and Modified Chalcones Catalyzed by N‐Heterocyclic Carbenes

inferred← citeshttps://doi.org/10.1002/ange.201206490openalex-snapshot

N‐Heterocyclic‐Carbene‐Catalyzed Asymmetric Oxidative Hetero‐Diels–Alder Reactions with Simple Aliphatic Aldehydes

inferred← citeshttps://doi.org/10.1002/ange.201301304openalex-snapshot

Enantioselective N‐Heterocyclic Carbene Catalyzed Aza‐Benzoin Reaction of Enals with Activated Ketimines

inferred← citeshttps://doi.org/10.1002/ange.201303524openalex-snapshot

Struktur und ambidente Reaktivität von Azolium‐Enolaten

inferred← citeshttps://doi.org/10.1002/ange.201303903openalex-snapshot

N‐Heterocyclic Carbene Catalyzed [4+3] Annulation of Enals and o‐Quinone Methides: Highly Enantioselective Synthesis of Benzo‐ε‐Lactones

inferred← citeshttps://doi.org/10.1002/ange.201305861openalex-snapshot

Functionalization of Benzylic C(sp3)H Bonds of Heteroaryl Aldehydes through N‐Heterocyclic Carbene Organocatalysis

inferred← citeshttps://doi.org/10.1002/ange.201305957openalex-snapshot

Asymmetrische Synthese von Pyrroloindolonen über eine durch N‐heterocyclische Carbene katalysierte [2+3]‐Anellierung von α‐Chloraldehyden mit Nitrovinylindolen

inferred← citeshttps://doi.org/10.1002/ange.201402620openalex-snapshot

Access to Oxoquinoline Heterocycles by N‐Heterocyclic Carbene Catalyzed Ester Activation for Selective Reaction with an Enone

inferred← citeshttps://doi.org/10.1002/ange.201408604openalex-snapshot

β‐Functionalization of Carboxylic Anhydrides with β‐Alkyl Substituents through Carbene Organocatalysis

inferred← citeshttps://doi.org/10.1002/ange.201702881openalex-snapshot

N‐Heterocyclic Carbene Catalyzed [4+2] Annulation of Enals via a Double Vinylogous Michael Addition: Asymmetric Synthesis of 3,5‐Diaryl Cyclohexenones

inferred← citeshttps://doi.org/10.1002/ange.201704210openalex-snapshot

Switchable Access to Different Spirocyclopentane Oxindoles by N‐Heterocyclic Carbene Catalyzed Reactions of Isatin‐Derived Enals and N‐Sulfonyl Ketimines

inferred← citeshttps://doi.org/10.1002/ange.201800483openalex-snapshot

Access to Enantioenriched Organosilanes from Enals and β‐Silyl Enones: Carbene Organocatalysis

inferred← citeshttps://doi.org/10.1002/anie.201105812openalex-snapshot

Enantioselective Stetter Reactions of Enals and Modified Chalcones Catalyzed by N‐Heterocyclic Carbenes

inferred← citeshttps://doi.org/10.1002/anie.201206490openalex-snapshot

N‐Heterocyclic‐Carbene‐Catalyzed Asymmetric Oxidative Hetero‐Diels–Alder Reactions with Simple Aliphatic Aldehydes

inferred← citeshttps://doi.org/10.1002/anie.201301304openalex-snapshot

Enantioselective N‐Heterocyclic Carbene Catalyzed Aza‐Benzoin Reaction of Enals with Activated Ketimines

inferred← citeshttps://doi.org/10.1002/anie.201303524openalex-snapshot

Structures and Ambident Reactivities of Azolium Enolates

inferred← citeshttps://doi.org/10.1002/anie.201303903openalex-snapshot

N‐Heterocyclic Carbene Catalyzed [4+3] Annulation of Enals and o ‐Quinone Methides: Highly Enantioselective Synthesis of Benzo‐ε‐Lactones

inferred← citeshttps://doi.org/10.1002/anie.201305861openalex-snapshot

Functionalization of Benzylic C(sp3)H Bonds of Heteroaryl Aldehydes through N‐Heterocyclic Carbene Organocatalysis

inferred← citeshttps://doi.org/10.1002/anie.201305957openalex-snapshot

Asymmetric Synthesis of Pyrroloindolones by N‐Heterocyclic Carbene Catalyzed [2+3] Annulation of α‐Chloroaldehydes with Nitrovinylindoles

inferred← citeshttps://doi.org/10.1002/anie.201402620openalex-snapshot

Access to Oxoquinoline Heterocycles by N‐Heterocyclic Carbene Catalyzed Ester Activation for Selective Reaction with an Enone

inferred← citeshttps://doi.org/10.1002/anie.201408604openalex-snapshot

β‐Functionalization of Carboxylic Anhydrides with β‐Alkyl Substituents through Carbene Organocatalysis

inferred← citeshttps://doi.org/10.1002/anie.201702881openalex-snapshot

N‐Heterocyclic Carbene Catalyzed [4+2] Annulation of Enals via a Double Vinylogous Michael Addition: Asymmetric Synthesis of 3,5‐Diaryl Cyclohexenones

inferred← citeshttps://doi.org/10.1002/anie.201704210openalex-snapshot

Switchable Access to Different Spirocyclopentane Oxindoles by N‐Heterocyclic Carbene Catalyzed Reactions of Isatin‐Derived Enals and N‐Sulfonyl Ketimines

inferred← citeshttps://doi.org/10.1002/anie.201800483openalex-snapshot

Access to Enantioenriched Organosilanes from Enals and β‐Silyl Enones: Carbene Organocatalysis

inferred← citeshttps://doi.org/10.1002/asia.201500907openalex-snapshot

Enantioselective Synthesis of 3,5,6‐Substituted Dihydropyranones and Dihydropyridinones using Isothiourea‐Mediated Catalysis

inferred← citeshttps://doi.org/10.1002/asia.201500959openalex-snapshot

An Upstream By‐product from Ester Activation via NHC‐Catalysis Catalyzes Downstream Sulfonyl Migration Reaction

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Insights into the N‐Heterocyclic Carbene (NHC)‐Catalyzed Intramolecular Cyclization of Aldimines: General Mechanism and Role of Catalyst

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Chalcones, a Privileged Scaffold: Highly Versatile Molecules in [4+2] Cycloadditions

inferred← citeshttps://doi.org/10.1002/cctc.201701119openalex-snapshot

Recent Advances on Computational Investigations of N ‐Heterocyclic Carbene Catalyzed Cycloaddition/Annulation Reactions: Mechanism and Origin of Selectivities

inferred← citeshttps://doi.org/10.1002/cctc.202200099openalex-snapshot

Progress in Organocatalytic Dearomatization Reactions Catalyzed by N‐Heterocyclic Carbenes

inferred← citeshttps://doi.org/10.1002/chem.201203707openalex-snapshot

Catalysis with N‐Heterocyclic Carbenes under Oxidative Conditions

inferred← citeshttps://doi.org/10.1002/chem.201204539openalex-snapshot

N‐Heterocyclic Carbene Catalyzed [4+2] Cycloaddition of Nitroalkenes with Oxodienes

inferred← citeshttps://doi.org/10.1002/chem.201301996openalex-snapshot

Recent Advances in Organocatalytic Methods for Asymmetric CC Bond Formation

inferred← citeshttps://doi.org/10.1002/chem.201500661openalex-snapshot

NHC‐Catalyzed Asymmetric Synthesis of Functionalized Succinimides from Enals and α‐Ketoamides

inferred← citeshttps://doi.org/10.1002/chem.201503308openalex-snapshot

Stereo‐ and Chemodivergent NHC‐Promoted Functionalisation of Arylalkylketenes with Chloral

inferred← citeshttps://doi.org/10.1002/chem.201504256openalex-snapshot

Enantioselective NHC‐Catalyzed Redox [2+2] Cycloadditions with Perfluoroketones: A Route to Fluorinated Oxetanes

inferred← citeshttps://doi.org/10.1002/chem.201601626openalex-snapshot

A Catalyst‐Enabled Diastereodivergent Aza‐Diels–Alder Reaction: Complementarity of N‐Heterocyclic Carbenes and Chiral Amines

inferred← citeshttps://doi.org/10.1002/chin.201201115openalex-snapshot

ChemInform Abstract: Enantioselective Diels—Alder Reactions of Enals and Alkylidene Diketones Catalyzed by N‐Heterocyclic Carbenes.

inferred← citeshttps://doi.org/10.1002/cjoc.201400381openalex-snapshot

N‐Heterocyclic Carbene‐catalyzed Reactions of o‐Aminonitriles with Carbonyl Compounds Approach to 2,3‐Dihydroquinazolin‐4(1H)‐ones

inferred← citeshttps://doi.org/10.1002/cjoc.201400411openalex-snapshot

N‐Heterocyclic Carbene‐Catalyzed All Carbon‐[4+2] Cyclocondensation of α,β‐Unsaturated Acyl Chlorides with 3‐Alkylenyloxindoles

inferred← citeshttps://doi.org/10.1002/ejoc.201403395openalex-snapshot

N‐Heterocyclic Carbene Catalyzed Generation and [4+2] Annulation of Unsubstituted Dienolate – Enantioselective Synthesis of Spirocyclic Oxindolodihydropyranones

inferred← citeshttps://doi.org/10.1002/ejoc.201600172openalex-snapshot

Studies on Pumiliotoxin A Alkaloids: An Approach to Preparing the Indolizidinic Core by Intramolecular Diastereoselective N‐Heterocyclic Carbene Catalyzed Benzoin Reaction

inferred← citeshttps://doi.org/10.1002/ejoc.201900087openalex-snapshot

Mechanisms and Stereoselectivities of NHC‐Catalyzed [3 + 4] Cycloaddition Reaction between Isatin‐Derived Enal and N‐(ortho‐Chloromethyl)aryl Amide

inferred← citeshttps://doi.org/10.1002/jhet.4075openalex-snapshot

Regioselective aza‐Michael additions of 2‐arylidene ‐1,3‐diphenylpropan‐1,3‐diones with isatins: Synthesis of N‐diketone ‐functionalized isatins

inferred← citeshttps://doi.org/10.1002/tcr.202200054openalex-snapshot

N‐Heterocyclic Carbene (NHC)‐Catalyzed Transformations Involving Azolium Enolates

inferred← citeshttps://doi.org/10.1002/tcr.202500231openalex-snapshot

Organocatalytic Strategies for Higher‐Order Cycloadditions: A Review of Substrate Activation and Enantiocontrol

inferred← citeshttps://doi.org/10.1007/978-981-10-2899-1_1openalex-snapshot

Introduction

inferred← citeshttps://doi.org/10.1007/s12039-020-1749-8openalex-snapshot

Lewis acid catalyst system for Diels–Alder reaction

inferred← citeshttps://doi.org/10.1016/b978-0-08-096807-0.00008-7openalex-snapshot

Five-Membered Ring Systems: With More than One N Atom

inferred← citeshttps://doi.org/10.1016/b978-0-08-096807-0.00015-4openalex-snapshot

Six-Membered Ring Systems: With O and/or S Atoms

inferred← citeshttps://doi.org/10.1016/b978-0-08-100017-5.00015-7openalex-snapshot

Six-Membered Ring Systems

inferred← citeshttps://doi.org/10.1016/b978-0-12-819962-6.00001-4openalex-snapshot

N-Heterocyclic Carbene (NHC)-Catalyzed Transformations for the Synthesis of Heterocycles

inferred← citeshttps://doi.org/10.1016/b978-0-12-821216-5.00005-4openalex-snapshot

Chemistry of isolated 2-pyranones

inferred← citeshttps://doi.org/10.1016/b978-0-32-390644-9.00045-7openalex-snapshot

[4 + 2] Cycloadditions Catalyzed by Nucleophilic Catalysts

inferred← citeshttps://doi.org/10.1016/j.mcat.2023.113135openalex-snapshot

Mechanisms and origins of stereoselectivity involved in NHC-catalyzed [3 + 3] Annulation of 2-bromoenals and β-ketothioamides: A DFT study

inferred← citeshttps://doi.org/10.1016/j.mcat.2024.114538openalex-snapshot

Uncovering a general oxidation model of nitrogen-containing oxidant in N-heterocyclic carbene (NHC) catalyzed oxidative reactions of aldehydes

inferred← citeshttps://doi.org/10.1016/j.tet.2019.03.007openalex-snapshot

Enantioselective synthesis of fused dihydropyranones via squaramide-catalyzed Michael addition/lactonization cascade reaction

inferred← citeshttps://doi.org/10.1016/j.tet.2024.133941openalex-snapshot

Iodine-promoted metal-free synthesis of mono- / di- and tri-substituted aryl sulfides / selenides in aqueous medium

inferred← citeshttps://doi.org/10.1016/j.tetlet.2011.08.157openalex-snapshot

N-Heterocyclic carbene (NHC) catalyzed annulation of enals and vinyl ketones: a novel synthesis of [2H]-pyranones

inferred← citeshttps://doi.org/10.1016/j.tetlet.2013.01.100openalex-snapshot

NHC-catalysed annulation of enals to ene-1,4-diones: stereoselective synthesis of 1,3-diaryl-4-acyl cyclopentenes

inferred← citeshttps://doi.org/10.1016/j.tetlet.2015.03.101openalex-snapshot

The first NHC-induced regioselective introduction of C- and N-nucleophiles in to Baylis–Hillman enals

inferred← citeshttps://doi.org/10.1021/acs.chemrev.7b00322openalex-snapshot

Forty Years after “Heterodiene Syntheses with α,β-Unsaturated Carbonyl Compounds”: Enantioselective Syntheses of 3,4-Dihydropyran Derivatives

inferred← citeshttps://doi.org/10.1021/acs.joc.1c00782openalex-snapshot

Annulation of Enals with Carbamoylpropiolates via NHC-Catalyzed Enolate Pathway: Access to Functionalized Maleimides/Iso-maleimides and Synthesis of Aspergillus FH-X-213

inferred← citeshttps://doi.org/10.1021/acs.joc.1c01517openalex-snapshot

A General Method for α-Oxyacylation of Vinyl Ketones Using Koser’s Reagent

inferred← citeshttps://doi.org/10.1021/acs.joc.2c01894openalex-snapshot

N -Heterocyclic Carbene-Catalyzed Enantioselective [3 + 2] Annulation of Enals with Vinyl Ketones

inferred← citeshttps://doi.org/10.1021/acs.joc.5b02439openalex-snapshot

DFT Study on the Mechanism and Stereoselectivity of NHC-Catalyzed Synthesis of Substituted Trifluoromethyl Dihydropyranones with Contiguous Stereocenters

inferred← citeshttps://doi.org/10.1021/acs.joc.6b01152openalex-snapshot

N-Heterocyclic Carbene/Lewis Acid Catalyzed Enantioselective Aerobic Annulation of α,β-Unsaturated Aldehydes with 1,3-Dicarbonyl Compounds

inferred← citeshttps://doi.org/10.1021/acs.joc.6c01483openalex-snapshot

NHC-Catalyzed Asymmetric [4 + 2] Annulation of 2-Methylindole-3-Carbaldehydes to Spiro Indole-Fused Heterocycles

inferred← citeshttps://doi.org/10.1021/acs.joc.8b01425openalex-snapshot

Enantioselective Formal [4 + 2] Annulation of ortho-Quinone Methides with ortho-Hydroxyphenyl α,β-Unsaturated Compounds

inferred← citeshttps://doi.org/10.1021/acs.orglett.5b01827openalex-snapshot

γ-Carbon Activation through N-Heterocyclic Carbene/Brønsted Acids Cooperative Catalysis: A Highly Enantioselective Route to δ-Lactams

inferred← citeshttps://doi.org/10.1021/acs.orglett.6b01191openalex-snapshot

Electrophilic Reaction of 2,2,2-Trifluorodiazoethane with the in Situ Generated N-Heterocyclic Carbenes: Access to N-Aminoguanidines

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b02889openalex-snapshot

An N-Heterocyclic Carbene-Mediated, Enantioselective and Multicatalytic Strategy to Access Dihydropyranones in a Sequential Three-Component One-Pot Reaction

inferred← citeshttps://doi.org/10.1021/acs.orglett.8b03892openalex-snapshot

Facile Synthesis of 2,2-Diacyl Spirocyclohexanones via an N-Heterocyclic Carbene-Catalyzed Formal [3C + 3C] Annulation

inferred← citeshttps://doi.org/10.1021/acscatal.1c03390openalex-snapshot

Enantioselective Inverse-Electron Demand Aza-Diels–Alder Reaction: ipso,α-Selectivity of Silyl Dienol Ethers

inferred← citeshttps://doi.org/10.1021/cs500667gopenalex-snapshot

Asymmetric Synthesis of Tri- and Tetrasubstituted Trifluoromethyl Dihydropyranones from α-Aroyloxyaldehydes via NHC Redox Catalysis

inferred← citeshttps://doi.org/10.1021/ja303618zopenalex-snapshot

Oxidative γ-Addition of Enals to Trifluoromethyl Ketones: Enantioselectivity Control via Lewis Acid/N-Heterocyclic Carbene Cooperative Catalysis

inferred← citeshttps://doi.org/10.1021/ja510737nopenalex-snapshot

N-Heterocyclic Carbene Catalyzed Switchable Reactions of Enals with Azoalkenes: Formal [4 + 3] and [4 + 1] Annulations for the Synthesis of 1,2-Diazepines and Pyrazoles

inferred← citeshttps://doi.org/10.1021/jacs.8b00868openalex-snapshot

Highly Enantioselective [5 + 2] Annulations through Cooperative N-Heterocyclic Carbene (NHC) Organocatalysis and Palladium Catalysis

inferred← citeshttps://doi.org/10.1021/jo401433qopenalex-snapshot

Stereospecific Asymmetric N-Heterocyclic Carbene (NHC)-Catalyzed Redox Synthesis of Trifluoromethyl Dihydropyranones and Mechanistic Insights

inferred← citeshttps://doi.org/10.1021/jo500194dopenalex-snapshot

DFT Study on the Mechanisms and Stereoselectivities of the [4 + 2] Cycloadditions of Enals and Chalcones Catalyzed by N-Heterocyclic Carbene

inferred← citeshttps://doi.org/10.1021/jo502668copenalex-snapshot

N-Heterocyclic Carbene-Catalyzed Diastereoselective and Enantioselective Reaction of 2-Aroylvinylcinnamaldehydes with α,β-Unsaturated Imines: Complete Control and Switch of Diastereoselectivity by N-Substituents of Catalysts

inferred← citeshttps://doi.org/10.1021/ol202108aopenalex-snapshot

Highly Stereoselective Synthesis of 1,2,3-Trisubstituted Indanes via Oxidative N-Heterocyclic Carbene-Catalyzed Cascades

inferred← citeshttps://doi.org/10.1021/ol202250sopenalex-snapshot

Formal Diels–Alder Reactions of Chalcones and Formylcyclopropanes Catalyzed by Chiral N-Heterocyclic Carbenes

inferred← citeshttps://doi.org/10.1021/ol300676wopenalex-snapshot

Enantioselective Activation of Stable Carboxylate Esters as Enolate Equivalents via N-Heterocyclic Carbene Catalysts

inferred← citeshttps://doi.org/10.1021/ol301175zopenalex-snapshot

N-Heterocyclic Carbene (NHC)-Catalyzed Highly Diastereo- and Enantioselective Oxo-Diels–Alder Reactions for Synthesis of Fused Pyrano[2,3-b]indoles

inferred← citeshttps://doi.org/10.1021/ol3013588openalex-snapshot

Enantioselective Intramolecular Formal [2 + 4] Annulation of Acrylates and α,β-Unsaturated Imines Catalyzed by Amino Acid Derived Phosphines

inferred← citeshttps://doi.org/10.1021/ol303035ropenalex-snapshot

Direct α-Functionalization of Simple Aldehydes via Oxidative N-Heterocyclic Carbene Catalysis

inferred← citeshttps://doi.org/10.1021/ol4021805openalex-snapshot

Organocatalytic Activation of Alkylacetic Esters as Enolate Precursors to React with α,β-Unsaturated Imines

inferred← citeshttps://doi.org/10.1021/ol4024985openalex-snapshot

N-Heterocyclic Carbene-Catalyzed Stereoselective Cascade Reaction: Synthesis of Functionalized Tetrahydroquinolines

inferred← citeshttps://doi.org/10.1021/ol402877nopenalex-snapshot

Asymmetric Access to the Smallest Enolate Intermediate via Organocatalytic Activation of Acetic Ester

inferred← citeshttps://doi.org/10.1021/ol4030748openalex-snapshot

N-Heterocyclic Carbene Catalyzed Reaction of Cinnamils Leading to the Formation of 2,3,8-Triaryl Vinyl Fulvenes: An Uncommon Transformation

inferred← citeshttps://doi.org/10.1021/ol500830aopenalex-snapshot

Catalytic Asymmetric α-Aldol Reaction of Vinylogous N-Heterocyclic Carbene Enolates: Formation of Quaternary and Labile Tertiary Stereocenters

inferred← citeshttps://doi.org/10.1021/ol501286eopenalex-snapshot

N-Heterocyclic Carbene-Catalyzed Chemoselective Cross-Aza-Benzoin Reaction of Enals with Isatin-Derived Ketimines: Access to Chiral Quaternary Aminooxindoles

inferred← citeshttps://doi.org/10.1021/ol5021509openalex-snapshot

N-Heterocyclic Carbene-Promoted Annulation Reaction of Allenals with Chalcones: Synthesis of Polysubstituted Pyranyl Aldehydes

inferred← citeshttps://doi.org/10.1039/9781782621966-00283openalex-snapshot

N-Heterocyclic Carbene-Catalyzed Asymmetric Functionalization of Aldehyde C–H Bonds

inferred← citeshttps://doi.org/10.1039/c2cc36564bopenalex-snapshot

Controlled β-protonation and [4+2] cycloaddition of enals and chalconesvia N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control

inferred← citeshttps://doi.org/10.1039/c3ob42008fopenalex-snapshot

NHC-catalyzed oxidative γ-addition of α,β-unsaturated aldehydes to isatins: a high-efficiency synthesis of spirocyclic oxindole-dihydropyranones

inferred← citeshttps://doi.org/10.1039/c4cc04047copenalex-snapshot

Synthesis of 3,3-disubstituted indoline-2-thiones catalysed by an N-heterocyclic carbene

inferred← citeshttps://doi.org/10.1039/c4cc07788aopenalex-snapshot

Stereoselective synthesis of ε-lactones or spiro-heterocycles through NHC-catalyzed annulation: divergent reactivity by catalyst control

inferred← citeshttps://doi.org/10.1039/c4cc09308aopenalex-snapshot

Functionalized cyclopentenes through a tandem NHC-catalyzed dynamic kinetic resolution and ambient temperature decarboxylation: mechanistic insight and synthetic application

inferred← citeshttps://doi.org/10.1039/c4ob01706dopenalex-snapshot

N-heterocyclic carbene-catalyzed [4 + 2] cyclization of 2-bromo-2-enal with 3-alkylenyloxindoles: efficient assembly of spirocarbocyclic oxindole

inferred← citeshttps://doi.org/10.1039/c4ob02330gopenalex-snapshot

N-heterocyclic carbene-catalyzed cyclocondensation of 2-aryl carboxylic acids and enones: highly enantioselective synthesis of δ-lactones

inferred← citeshttps://doi.org/10.1039/c4sc00317aopenalex-snapshot

Catalytic kinetic resolution of a dynamic racemate: highly stereoselective β-lactone formation by N-heterocyclic carbene catalysis

inferred← citeshttps://doi.org/10.1039/c5qo00121hopenalex-snapshot

A quantum mechanical study of the mechanism and stereoselectivity of the N-heterocyclic carbene catalyzed [4 + 2] annulation reaction of enals with azodicarboxylates

inferred← citeshttps://doi.org/10.1039/c5qo00338eopenalex-snapshot

DFT perspective toward [3 + 2] annulation reaction of enals with α-ketoamides through NHC and Brønsted acid cooperative catalysis: mechanism, stereoselectivity, and role of NHC

inferred← citeshttps://doi.org/10.1039/c5sc01027fopenalex-snapshot

Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediates

inferred← citeshttps://doi.org/10.1039/c6ob00363jopenalex-snapshot

N-Heterocyclic carbene-triggered transition-metal-free synthesis of 2,3-disubstituted benzofuran derivatives

inferred← citeshttps://doi.org/10.1039/c8qo01370eopenalex-snapshot

Insights into highly selective ring expansion of oxaziridines under Lewis base catalysis: a DFT study

inferred← citeshttps://doi.org/10.1039/c8ra10262gopenalex-snapshot

Mechanism and stereoselectivity in NHC-catalyzed β-functionalization of saturated carboxylic ester

inferred← citeshttps://doi.org/10.1039/c8sc04601hopenalex-snapshot

A tandem dearomatization/rearomatization strategy: enantioselective N-heterocyclic carbene-catalyzed α-arylation

inferred← citeshttps://doi.org/10.1039/c9cy00526aopenalex-snapshot

Insights into NHC-catalyzed oxidative α-C(sp 3 )–H activation of aliphatic aldehydes and cascade [2 + 3] cycloaddition with azomethine imines

inferred← citeshttps://doi.org/10.1039/d0cc03204bopenalex-snapshot

Access to enantioenriched 4-phosphorylated δ-lactones from β-phosphorylenones and enals via carbene organocatalysis

inferred← citeshttps://doi.org/10.1055/a-1514-1049openalex-snapshot

Organocatalyzed Oxa-Diels–Alder Reactions: Recent Progress

inferred← citeshttps://doi.org/10.1055/a-2718-1886openalex-snapshot

N-Heterocyclic Carbene-Catalyzed Acylalkylation of Indole via C–C Bond Cleavage/Dearomatization to Access the Multisubstituted Benzopyrrolizidinones

inferred← citeshttps://doi.org/10.1055/s-0034-1379369openalex-snapshot

Asymmetric N-Heterocyclic Carbene Catalyzed Annulation of 2-Alkenylbenzothiazoles with α-Chloro Aldehydes

inferred← citeshttps://doi.org/10.1177/1747519819880693openalex-snapshot

Chemoselective aza-Michael addition of indoles to 2-aroyl-1,3-diarylenones

inferred← citeshttps://doi.org/10.1515/hc-2013-0075openalex-snapshot

Heterocyclic synthesis via catalysis of N -heterocyclic carbenes: very classical and very modern chemical species

inferred← citeshttps://doi.org/10.24820/ark.5550190.p010.404openalex-snapshot

Synthesis of dihydropyranones and dihydropyrano[2,3-d][1,3]dioxine-diones by cyclization reaction of Meldrum’s acid with arylaldehydes and 1,3-dicarbonyls under thermal and ultrasound irradiation

inferred← citeshttps://doi.org/10.6023/cjoc202401009openalex-snapshot

N-Heterocyclic Carbene Catalyzed the Umpolung of Aldehyde Compounds

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