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Practical Route to 2-Quinolinones via a Pd-Catalyzed C–H Bond Activation/C–C Bond Formation/Cyclization Cascade Reaction

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Palladium‐Catalyzed Regioselective Mono‐ and Diarylation Reactions of 2‐Phenylphenols and Naphthols with Aryl Halides

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The Catalytic Intermolecular Orthoarylation of Phenols

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Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality

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Ruthenium‐Catalyzed Regioselective Direct Alkylation of Arenes with Unactivated Alkyl Halides through CH Bond Cleavage

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Pd‐Catalyzed Sequential CC and CN Bond Formations for the Synthesis of N‐Heterocycles: Exploiting Protecting Group‐Directed CH Activation under Modified Reaction Conditions

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Synthesis Routes Towards the Farnesyl Protein Transferase Inhibitor ZARNESTRATM

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Synthesis of Substituted Coumarins and 2‐Quinolinones by Cycloisomerisation of (Hydroxy/aminophenyl)propargyl Alcohols

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4-(Aminoalkylamino)-3-benzimidazole-quinolinones as potent CHK-1 inhibitors

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Selective activation of apoptosis by a novel set of 4-aryl-3-(3-aryl-1-oxo-2-propenyl)-2(1H)-quinolinones through a Myc-dependent pathway

inferredcites →https://doi.org/10.1016/j.tetlet.2008.03.144openalex-snapshot

A general synthesis of quinolinones and benzothiazine 1,1-dioxides via ring closing metathesis

inferredcites →https://doi.org/10.1016/s0022-328x(03)00786-1openalex-snapshot

Palladium-catalyzed carbonylative annulation of terminal alkynes: synthesis of coumarins and 2-quinolones

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Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

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Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation

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Direct C−H Transformation via Iron Catalysis

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Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

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Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

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Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

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Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

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C−H Activation for the Construction of C−B Bonds

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Elaboration of Conjugated Alkenes Initiated by Insertion into a Vinylic C-H Bond

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Nybomycin. VII. Preparative routes to nybomycin and deoxynybomycin

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Selective Pd-Catalyzed Oxidative Coupling of Anilides with Olefins through C−H Bond Activation at Room Temperature

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A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Arylboronates: A New Method for the Arylation of Aromatic Compounds via C−H Bond Cleavage

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A RuH 2 (CO)(PPh 3 ) 3 -Catalyzed Regioselective Arylation of Aromatic Ketones with Arylboronates via Carbon−Hydrogen Bond Cleavage

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Scope and Mechanistic Study of the Ruthenium-Catalyzed ortho-C−H Bond Activation and Cyclization Reactions of Arylamines with Terminal Alkynes

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Ortho Arylation of Acetanilides via Pd(II)-Catalyzed C−H Functionalization

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Palladium-Catalyzed Ortho-Arylation of O-Phenylcarbamates with Simple Arenes and Sodium Persulfate

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Iridium-Catalyzed Annulation of N-Arylcarbamoyl Chlorides with Internal Alkynes

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Palladium-Catalyzed Direct Ethynylation of C(sp3)–H Bonds in Aliphatic Carboxylic Acid Derivatives

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Dehydrative C–H Alkylation and Alkenylation of Phenols with Alcohols: Expedient Synthesis for Substituted Phenols and Benzofurans

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Copper-Catalyzed C–H Azidation of Anilines under Mild Conditions

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Palladium(0)-Catalyzed Alkynylation of C(sp3)–H Bonds

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Mechanistic Study of the Oxidative Coupling of Styrene with 2-Phenylpyridine Derivatives Catalyzed by Cationic Rhodium(III) via C–H Activation

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Site-Selective sp2 and Benzylic sp3 Palladium-Catalyzed Direct Arylation

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Palladium-Catalyzed C−H Functionalization of Pyridine N -Oxides: Highly Selective Alkenylation and Direct Arylation with Unactivated Arenes

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Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions

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Pd(OAc)2 Catalyzed Olefination of Highly Electron-Deficient Perfluoroarenes

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Cationic Palladium(II) Catalysis: C−H Activation/Suzuki−Miyaura Couplings at Room Temperature

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Rational Modification of a Candidate Cancer Drug for Use Against Chagas Disease

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Discovery of Inducible Nitric Oxide Synthase (iNOS) Inhibitor Development Candidate KD7332, Part 1: Identification of a Novel, Potent, and Selective Series of Quinolinone iNOS Dimerization Inhibitors that are Orally Active in Rodent Pain Models

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Second Generation Analogues of the Cancer Drug Clinical Candidate Tipifarnib for Anti-Chagas Disease Drug Discovery

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Palladium-catalyzed synthesis of 2-quinolone derivatives from 2-iodoanilines

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Synthesis of 2-Quinolones via Palladium-Catalyzed Carbonylative Annulation of Internal Alkynes by N-Substituted o-Iodoanilines

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Alternative to Benzoquinone for Room-Temperature Fujiwara–Moritani Reactions

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Ruthenium Complex Catalyzed Direct Ortho Arylation and Alkenylation of Aromatic Imines with Organic Halides

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Rhodium-Catalyzed Arylation Using Arylboron Compounds: Efficient Coupling with Aryl Halides and Unexpected Multiple Arylation of Benzonitrile

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Direct Lactonization of 2-Arylacetic Acids through Pd(II)-Catalyzed C–H Activation/C–O Formation

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Synthesis of 2(1 H )-Quinolinones via Pd-Catalyzed Oxidative Cyclocarbonylation of 2-Vinylanilines

inferredcites →https://doi.org/10.1021/ol403666sopenalex-snapshot

Ruthenium-Catalyzed Hydroarylation of Anilides with Alkynes: An Efficient Route to Ortho-Alkenylated Anilines

inferredcites →https://doi.org/10.1021/ol501548eopenalex-snapshot

Ruthenium-Catalyzed Cyclization of Anilides with Substituted Propiolates or Acrylates: An Efficient Route to 2-Quinolinones

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New Approach to 2-Quinolinones

inferredcites →https://doi.org/10.1021/ol902115fopenalex-snapshot

Regioselective Ruthenium-Catalyzed Direct Benzylations of Arenes through C−H Bond Cleavages

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Palladium catalyzed synthesis of highly substituted naphthalenes via direct ring construction from amides with alkynes

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Tandem-type Pd(ii)-catalyzed oxidative Heck reaction/intramolecular C–H amidation sequence: a novel route to 4-aryl-2-quinolinones

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Clean and Convenient One-Pot Synthesis of 4-Hydroxycoumarin and 4-Hydroxy-2-quinolinone Derivatives

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Iridium‐ and Rhodium‐Catalyzed Carbocyclization between 2‐Phenylimidazo[1,2‐ a ]pyridine and α‐Diazo Esters

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Synthesis of 4‐Aryl‐2‐Quinolones via Copper‐Catalyzed Hydroarylation of (o‐Aminophenyl)propiolates with Arylboronates

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Iridium‐Catalyzed Carbonylative Synthesis of Halogen‐Containing Quinolin‐2(1H)‐ones from Internal Alkynes and Simple Anilines

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Metal‐Free Synthesis of 4‐Aryl‐2‐quinolone Derivatives by Iodine‐Mediated Intramolecular C−H Amidation

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Metal‐Free Photocyclization/Oxidation Cascade Constructing Quinoline‐2‐ones and Tetrahydrocarbazolones

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A General and Efficient Synthesis of 2‐Pyridones, 2‐Quinolinones, and 1‐Isoquinolinones from Azine N ‐Oxides

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PdCl2‐Catalyzed Oxidative Cyclization of N‐(2’‐Alkynylaryl)‐1,3‐ketoamides: Synthesis of 3,4‐Diacyl‐2‐Quinolones

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Metal‐Free Multifunctionalization of Alkynes Promoted by Acid and Selectfluor

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Kooperative Lewis‐Säure/Cp*CoIII‐katalysierte C‐H‐Bindungsaktivierung zur Synthese von Isochinolin‐3‐onen

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Bio‐Inspired Fragmentations: Rapid Assembly of Indolones, 2‐Quinolinones, and (−)‐Goniomitine

inferred← citeshttps://doi.org/10.1002/anie.201601003openalex-snapshot

Cooperative Lewis Acid/Cp*CoIII Catalyzed C−H Bond Activation for the Synthesis of Isoquinolin‐3‐ones

inferred← citeshttps://doi.org/10.1002/anie.201611830openalex-snapshot

Bio‐Inspired Fragmentations: Rapid Assembly of Indolones, 2‐Quinolinones, and (−)‐Goniomitine

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Palladium‐Catalyzed [3+3] Annulation between Diarylamines and α,β‐Unsaturated Acids through CH Activation: Direct Access to 4‐Substituted 2‐Quinolinones

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From Anilines to Quinolines: Iodide‐ and Silver‐Mediated Aerobic Double C−H Oxidative Annulation–Aromatization

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A Highly Enantio‐ and Diastereoselective Synthesis of Spirocyclic Dihydroquinolones via Domino Michael Addition‐Lactamization of ortho‐Quinone Methide Imines

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A One‐Pot Ring‐Opening/Ring‐Closure Sequence for the Synthesis of Polycyclic Spirooxindoles

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ChemInform Abstract: Practical Route to 2‐Quinolinones via a Pd‐Catalyzed C—H Bond Activation/C—C Bond Formation/Cyclization Cascade Reaction.

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Pd( II )‐Catalyzed Selective [4+2] Benzannulations of Pyridones with Alkenes: Diversity‐Oriented Synthesis of a Novel Fluorescent Quinolinone

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Quinolone as a Privileged Scaffold: A Brief Overview on Early Classical and Recent Advanced Synthetic Pathways, Innovative Neuroprotective Potential, and Structure‐Activity Relationships

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Unusual Regioselectivity in Palladium‐Catalyzed Tandem C−H Arylation and C−H Amidation of cis‐Cinnamyl Hydroxamates: Facile Synthesis of 3‐Aryl‐2‐quinolones

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Pd‐Catalyzed Cyclization of o‐Iodoanilines with Acrylates or Acrylic Acids: A Convenient One‐Step Route to 2‐Quinolinones

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Synthesis of Multisubstituted Pyridin‐2(3H)‐ones via Nickel‐Catalyzed Intermolecular Condensation of β‐Ketobutylanilides

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Silver‐Promoted Coupling of Carbon Dioxide, o ‐Alkynylanilines and Diaryliodonium Salts: Straightforward Access to 4‐Aryloxy‐2‐quinolinones

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Rapid Access to Functionalized 2‐Quinolinones and Coumarins by Direct Coupling of 2‐Alkynyl‐anilines/phenols and Diazo Ketones

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Novel synthesis of quinoline chalcone derivatives - Design, synthesis, characterization and antimicrobial activity

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Cobalt-catalyzed carbonylative cyclization of N-(2-Vinylphenyl)nicotinamides to access (NH)-quinolin-2(1H)-ones

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A imple oute to 7-ubstituted Quinolin-2()-ones from -ubstituted nilines

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Heterogeneous Pd/C-catalyzed oxidative annulation of anilines toward 2-quinolinones

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Pd(II)-catalyzed cascade Heck/intramolecular C(sp)–H amidation reaction: An efficient route to 4-aryl-2-quinolinones

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Cationic Pd(II)-catalyzed arylative cyclization of N-(2-formylaryl)alkynamides: An efficient route to 2-quinolinones

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Cationic Pd(II) catalyzed regioselective intramolecular hydroarylation for the efficient synthesis of 4-aryl-2-quinolones

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Transition metal-catalyzed synthesis of N, O−Heterocycles via C–H functionalization

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Ir(III)-catalyzed C–H alkenylation/annulation of N-iminopyridinium ylides with acrylates and alkynes

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A facile and environmental friendly strategy for the synthesis of N-methoxyquinolin-2(1H)-ones

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Palladium-catalyzed arylation/cyclization/desulfonation cascades toward 4-aryl quinolin-2(1 H )-ones with diaryliodonium salts

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Transition-metal-free direct cross-dehydrogenative coupling reactions of quinolinones with ethers

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HFIP-mediated strategy towards β-oxo amides and subsequent Friedel-Craft type cyclization to 2‑quinolinones using recyclable catalyst

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One-pot approach: Tandem consecutive Ugi-4CR/ACM-type reaction towards the synthesis of functionalised quinoline-2(1H)-one scaffolds

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Palladium catalysed hydrolysis-free arylation of aliphatic nitriles for the synthesis of 4-arylquinolin-2-one/pyrazolone derivatives

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Selective C–H acylation of quinolin-2(1H)-one with α-oxocarboxylic acids at the C3 position by sliver catalysis and its application in the synthesis of palbociclib

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Palladium-catalyzed oxidative arene C–H alkenylation reactions involving olefins

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Ring Expansion of Isatins via 1,2-Phospha-Brook Rearrangement: A Route to the Synthesis of 2-Quinolinone-Derived p-Quinone Methides

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Intramolecular Palladium(II)-Catalyzed Regioselective 6-endo or 6-exo C–H Benzannulation: An Approach for the Diversity-Oriented Synthesis of Quinolinone Derivatives from Pyridones

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Beyond a Protecting Reagent: DMAP-Catalyzed Cyclization of Boc-Anhydride with 2-Alkenylanilines

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Scalable and Practical Synthesis of Halo Quinolin-2(1 H )-ones and Quinolines

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Palladium(II)-Catalyzed C–H Bond Activation/C–C Coupling/Intramolecular Tsuji–Trost Reaction Cascade: Facile Access to 2H-Pyranonaphthoquinones

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Gold-Catalyzed Synthesis of (Dihydro)quinolones by Cyclization of Benzaldehyde-Tethered Ynamides and Anilines

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“One-Pot” Approach to 8-Acylated 2-Quinolinones via Palladium-Catalyzed Regioselective Acylation of Quinoline N-Oxides

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CO 2 -Driven C(sp 2 )–H Lactamization to 2-Quinolinones

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Ir(III)-Catalyzed Carbonylative Cyclization of 2-Alkenyl Anilines via ex situ Generation of CO: Access to 2-Quinolone Derivatives

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Traceless Directing-Group Strategy in the Ru-Catalyzed, Formal [3 + 3] Annulation of Anilines with Allyl Alcohols: A One-Pot, Domino Approach for the Synthesis of Quinolines

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Visible-Light-Photocatalyzed Synthesis of Phenanthridinones and Quinolinones via Direct Oxidative C–H Amidation

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Exceedingly Fast, Direct Access to Dihydroisoquinolino[1,2-b]quinazolinones through a Ruthenium(II)-Catalyzed Redox-Neutral C–H Allylation/Hydroamination Cascade

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Camphorsulfonic Acid-Mediated One-Pot Tandem Consecutive via the Ugi Four-Component Reaction for the Synthesis of Functionalized Indole and 2‑Quinolone Derivatives by Switching Solvents

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Weak Base-Promoted Lactamization under Microwave Irradiation: Synthesis of Quinolin-2(1 H )-ones and Phenanthridin-6(5 H )-ones

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Metal-Catalyst-Free Radical Cyclization of 1,6-Enynes for the Selective and Switchable Synthesis of Lactams in Water

inferred← citeshttps://doi.org/10.1021/acssuschemeng.7b02442openalex-snapshot

Fast, Base-Free and Aqueous Synthesis of Quinolin-2(1H)-ones under Ambient Conditions

inferred← citeshttps://doi.org/10.1021/jacs.3c12119openalex-snapshot

Regiodivergent Ring-Expansion of Oxindoles to Quinolinones

inferred← citeshttps://doi.org/10.1021/jacs.5b05843openalex-snapshot

Rh-Catalyzed Construction of Quinolin-2(1H)-ones via C–H Bond Activation of Simple Anilines with CO and Alkynes

inferred← citeshttps://doi.org/10.1039/c6cc02600aopenalex-snapshot

A palladium-catalyzed intramolecular carbonylative annulation reaction for the synthesis of 4,5-fused tricyclic 2-quinolones

inferred← citeshttps://doi.org/10.1039/c7cc07180aopenalex-snapshot

Cu/Pd cooperatively catalyzed tandem intramolecular anti-Markovnikov hydroarylation of unsaturated amides: facile construction of 3,4-dihydroquinolinones via borylation/intramolecular C(sp 3 )–C(sp 2 ) cross coupling

inferred← citeshttps://doi.org/10.1039/c7sc02181jopenalex-snapshot

Rh-catalyzed aerobic oxidative cyclization of anilines, alkynes, and CO

inferred← citeshttps://doi.org/10.1039/c8cc08708copenalex-snapshot

Computational and experimental studies on copper-mediated selective cascade C–H/N–H annulation of electron-deficient acrylamide with arynes

inferred← citeshttps://doi.org/10.1039/c8ob01882kopenalex-snapshot

Synthesis of 3-substituted quinolin-2(1 H )-ones via the cyclization of o -alkynylisocyanobenzenes

inferred← citeshttps://doi.org/10.1039/c8ob01994kopenalex-snapshot

Step-economical synthesis of 3-amido-2-quinolones by dendritic copper powder-mediated one-pot reaction

inferred← citeshttps://doi.org/10.1039/c9ra03146dopenalex-snapshot

One-pot construction of diverse and functionalized isochromenoquinolinediones by Rh( iii )-catalyzed annulation of unprotected arylamides with 3-diazoquinolinediones and their application for fluorescence sensor

inferred← citeshttps://doi.org/10.1039/d0cy00789gopenalex-snapshot

Palladium-catalysed Heck-type alkenylation reactions in the synthesis of quinolines. Mechanistic insights and recent applications

inferred← citeshttps://doi.org/10.1039/d0qo01335hopenalex-snapshot

Ring expansion and ring opening of 3-halooxindoles with N -alkoxycarbonyl- O -tosylhydroxylamines for divergent access to 4-aminoquinolin-2-ones and N -Cbz- N’ -arylureas

inferred← citeshttps://doi.org/10.1039/d0ra01352hopenalex-snapshot

One-pot copper-catalyzed three-component reaction: a modular approach to functionalized 2-quinolones

inferred← citeshttps://doi.org/10.1039/d1gc01460aopenalex-snapshot

Efficient visible light mediated synthesis of quinolin-2(1 H )-ones from quinoline N -oxides

inferred← citeshttps://doi.org/10.1039/d2cc05514gopenalex-snapshot

Expedient delivery of quinolinone drugs via a traceless N -nitroso enabled oxidative Heck/amidation cascade

inferred← citeshttps://doi.org/10.1039/d3sc02992aopenalex-snapshot

Rhodium( i )-catalyzed cascade C(sp 2 )–H bond alkylation – amidation of anilines: phosphorus as traceless directing group

inferred← citeshttps://doi.org/10.1039/d4ob00649fopenalex-snapshot

Iron-catalyzed synthesis of substituted 3-arylquinolin-2(1 H )-ones via an intramolecular dehydrogenative coupling of amido-alcohols

inferred← citeshttps://doi.org/10.1039/d5nj03991fopenalex-snapshot

HCO 2 H-promoted hydrolysis of 2-chloroquinolines to quinolones

inferred← citeshttps://doi.org/10.1039/d5qo00337gopenalex-snapshot

Hypervalent iodine-mediated one-pot synthesis of C3,6-dithioquinolin-2-ones

inferred← citeshttps://doi.org/10.1039/d5ra03124aopenalex-snapshot

Frontiers in bond construction: innovative approaches to C–C and carbon–heteroatom (C–S, C–N, C–O, C–Se, C–P) transformations-a review

inferred← citeshttps://doi.org/10.1039/d6cc02257jopenalex-snapshot

Carbocyclization-oximation of alkenes via boryl radical-mediated halogen atom transfer to access fluorinated 4-(carbaldehyde oxime)quinolinones

inferred← citeshttps://doi.org/10.1055/a-2799-0275openalex-snapshot

Synthesis of 2-Quinolinones through Direct Annulation: A Tandem Suzuki Coupling-Cyclization Strategy

inferred← citeshttps://doi.org/10.2174/1570193x20666230821102422openalex-snapshot

Recent Advances in Transition Metal Catalyzed Synthesis of C3-Substitution-free 2-Oxindole Derivatives

inferred← citeshttps://doi.org/10.3390/antibiotics11020148openalex-snapshot

Insulinotropic Potential of Moxifloxacin and Gemifloxacin: An In Vivo Rabbits Model Study Followed by Randomized Phase I Clinical Trial

inferred← citeshttps://doi.org/10.3390/molecules21040268openalex-snapshot

The Current Case of Quinolones: Synthetic Approaches and Antibacterial Activity

inferred← citeshttps://doi.org/10.3390/molecules24020228openalex-snapshot

Palladium-Catalysed Synthesis and Transformation of Quinolones

inferred← citeshttps://doi.org/10.3390/molecules25225450openalex-snapshot

Recent Advances in One-Pot Modular Synthesis of 2-Quinolones

inferred← citeshttps://doi.org/10.3390/molecules27238112openalex-snapshot

Synthesis, In Silico and In Vivo Toxicity Assessment of Functionalized Pyridophenanthridinones via Sequential MW-Assisted Intramolecular Friedel-Crafts Alkylation and Direct C–H Arylation

inferred← citeshttps://doi.org/10.3762/bjoc.14.234openalex-snapshot

Gold-catalyzed post-Ugi alkyne hydroarylation for the synthesis of 2-quinolones

inferred← citeshttps://doi.org/10.3987/rev-19-914openalex-snapshot

Recent Advances in Transition-Metal-Catalyzed Synthesis of 3- and/or 4-Aryl-2(1H)-Quinolones

inferred← citeshttps://doi.org/10.70675/1519c358z70f3z4f8czacfeze5254832762copenalex-snapshot

Rhodium-catalyzed cascade C–H bond functionalization for the synthesis of nitrogen-containing heterocycles

inferred← citeshttps://doi.org/10.70675/cf06a882zbf56z4a9bzb6edz75c8062f2098openalex-snapshot

Nouvelles méthodes de synthèse et de fonctionnalisation d'hétérocycles par catalyse photorédox et organocatalyse

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