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Chemoselective Oxygen-Centered Radical Cyclizations onto Silyl Enol Ethers

https://doi.org/10.1021/ol802142k
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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On the SelectiveO-Alkylation of Ambident Nucleophiles – The Synthesis of Thiohydroxamic AcidO-Esters by Phase-Transfer Reactions
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Ring Closure Reactions of Disubstituted 4-Penten-1-oxyl Radicals − Towards a Stereoselective Synthesis ofallo-Muscarine
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Stereoselective Construction of the Tetrahydrofuran Nucleus by Alkoxyl Radical Cyclizations
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5‐exo or 6‐endo? Exploring Transition State Structures in Cyclizations of 4‐Penten‐1‐oxyl Radicals
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A Radical Version of the Bromo‐ and the Iodocyclization of Bis(homoallylic) Alcohols — The Synthesis of Halogenated Tetrahydrofurans by Stereoselective Alkoxyl Radical Ring Closures
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Polar and Steric Substituent Effects in 5‐exo‐trig Cyclizations of 1‐Aryl‐4‐penten‐1‐oxyl Radicals
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Mecanismes de l'oxydation des alcools ethyleniques par le tetracetate de plomb, mise en evidence par rpe de l'influence des conditions experimentales sur le cours homolytique ou heterolytique de la reaction
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Synthesis of enantiopure (2R)-configured muscarine alkaloids via selective alkoxyl radical ring-closure reactions
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On the 6- exo - trig ring closure of substituted 5-hexen-1-oxyl radicals
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Radical reactions in organic synthesis
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Cyclisations of allyloxy radicals
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Acyl derivatives of hydroxamic acids as a source of carbon radicals
inferredcites →https://doi.org/10.1016/s0040-4039(01)88653-6openalex-snapshot
Heterocyclisation radicalaire de nitrites ethyleniques
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The effect of α-alkoxy group in radical-mediated β-fragmentation reactions
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Radical reactions in natural product synthesis
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Reagent-Controlled Transition-Metal-Catalyzed Radical Reactions
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Generation of alkoxy radicals from N-alkoxypyridinethiones
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A new and practical method of decarboxylation: photosensitized decarboxylation of N-acyloxyphthalimides via electron-transfer mechanism
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Positive Halogen Compounds. VI. Effects of Structure and Medium on the β-Scission of Alkoxy Radicals
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A New Photochemical Reaction 1
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On the 6-endoSelectivity in 4-Penten-1-oxyl Radical Cyclizations
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Ring Closure Reactions of Substituted 4-Pentenyl-1-oxy Radicals. The Stereoselective Synthesis of Functionalized Disubstituted Tetrahydrofurans
inferredcites →https://doi.org/10.1021/jo00250a051openalex-snapshot
Tris(trimethylsilyl)silane. A new reducing agent
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Synthesis of N-(alkyloxy)pyridine-2(1H)-thiones: alkylations of the ambident nucleophile pyridine-2(1H)-thione N-oxide and attempted isomerizations of 2-(alkylthio)pyridine N-oxide
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β-Fragmentation of Primary Alkoxyl Radicals versus Hydrogen Abstraction: Synthesis of Polyols and α,ω-Differently Substituted Cyclic Ethers from Carbohydrates
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Acetogenins from Annonaceae: recent progress in isolation, synthesis and mechanisms of action
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The Design and Application of Free Radical Chain Reactions in Organic Synthesis. Part 1
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Facile Generation of Alkoxy Radicals from N-Alkoxyphthalimides
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Selectivity in the Chemistry of Oxygen-Centered Radicals - The Formation of Carbon-Oxygen Bonds
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Invention of new reactions useful in the chemistry of natural products

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Generation and Radical-Radical Cross-Coupling of Alkenyloxy Radical: Ester and Ketone Synthesis
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Stereoelectronic Effects with Donor and Acceptor Separated by a Single Bond Bridge
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Unusual Cyclizations
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N‐Alkoxyphtalimides as Versatile Alkoxy Radical Precursors in Modern Organic Synthesis
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Synthesis of ω ‐Functionalized Carbonyls from Hydroperoxides and N‐Hydroxy Compounds: Mn‐Assisted Generation of N ‐Oxyl and C‐Radicals Followed by Their Cross‐Сoupling
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Metal‐Free, Aerobic Dioxygenation of Alkenes Using Hydroxamic Acids
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Catalytic Hydroetherification of Unactivated Alkenes Enabled by Proton‐Coupled Electron Transfer
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Photocatalytic Anti‐Markovnikov Radical Hydro‐ and Aminooxygenation of Unactivated Alkenes Tuned by Ketoxime Carbonates
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Modulating Electron Transfer via Cerium Photocatalysis for Alkoxy Radical‐Mediated Selective Hydroetherification
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Metal‐Free, Aerobic Dioxygenation of Alkenes Using Hydroxamic Acids
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Catalytic Hydroetherification of Unactivated Alkenes Enabled by Proton‐Coupled Electron Transfer
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Photocatalytic Anti ‐Markovnikov Radical Hydro‐ and Aminooxygenation of Unactivated Alkenes Tuned by Ketoxime Carbonates
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Modulating Electron Transfer via Cerium Photocatalysis for Alkoxy Radical‐Mediated Selective Hydroetherification
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Alkyl Enol Ethers: Development in Intermolecular Organic Transformation
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ChemInform Abstract: Chemoselective Oxygen‐Centered Radical Cyclizations onto Silyl Enol Ethers.
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Amidyl Radical Directed γ‐C(sp3)−H Functionalization with Silyl Enol Ethers via Photoredox Catalysis
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Electrochemical Halocyclization‐Enabled Synthesis of Tetrahydrofuran Derivatives With KBr/ KI
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Electrochemical behavior of N ‐oxyphthalimides: Cascades initiating self‐sustaining catalytic reductive N ― O bond cleavage
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Radical Cascades in the Total Synthesis of Complex Naturally Occurring Heterocycles
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Heteroatom-Centred Radicals for the Synthesis of Heterocyclic Compounds
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2.16 Selected Diastereoselective Reactions: Free Radical Additions and Cyclizations
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4.13 Radical Cyclizations and Sequential Radical Reactions
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8.14 Reduction of NN, N–N, N–O, and O–O Bonds
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Selected Diastereoselective Reactions: Free Radical Additions and Cyclizations
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Reduction of N=N, N-N, N-O, and O-O Bonds
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Access to carbonyl compounds via the electroreduction of N-benzyloxyphthalimides: Mechanism confirmation and preparative applications
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Chemiluminescence-promoted oxidation of alkyl enol ethers by NHPI under mild conditions and in the dark
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Chapter 5.3 Five-membered ring systems: Furans and benzofurans
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Chapter 5.3: Five-Membered Ring Systems: Furans and Benzofurans
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Thirty Years of (TMS) 3 SiH: A Milestone in Radical-Based Synthetic Chemistry
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Ultrasound-Assisted Remote Benzylic C(sp3)–H Alkylation of N-Fluoroamides with Enol Silanes
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Domino Fragmentations in Traceless Directing Groups of Radical Cascades: Evidence for the Formation of Alkoxy Radicals via C–O Scission
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Photoinduced Fragmentation Borylation of Cyclic Alcohols and Hemiacetals
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Intermolecular C–O Bond Formation with Alkoxyl Radicals: Photoredox-Catalyzed α-Alkoxylation of Carbonyl Compounds
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Tuning the Reactivity of Alkoxyl Radicals from Cyclization to 1,2-Silyl Transfer: Stereoselective Synthesis of β-Substituted Cycloalcohols
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Electrochemical Synthesis of β-Functionalized Ketones via Ring-Opening of Cycloalkanols
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Generation and Radical–Radical Cross-Coupling of Alkenyloxy Radical
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Pyridine-Boryl Radical-Enabled Reductive Radical Brook Rearrangement
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Metal-Free C(sp3)–H Allylation via Aryl Carboxyl Radicals Enabled by Donor–Acceptor Complex
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Reductive Radical Cascades Triggered by Alkoxyl Radicals in the β-Cyclodextrin Framework
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Cyclizations of Alkynes: Revisiting Baldwin’s Rules for Ring Closure
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Metal-Free, Aerobic Dioxygenation of Alkenes Using Simple Hydroxamic Acid Derivatives
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Overcoming the Barrier to Intermolecular Alkoxy Radical Reactivity: Proton-Coupled Electron Transfer-Mediated Alkene Hydroetherification
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Alkoxy Radical Cyclizations onto Silyl Enol Ethers Relative to Alkene Cyclization, Hydrogen Atom Transfer, and Fragmentation Reactions
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Unique Diastereoselectivity Trends in Aminyl Radical Cyclizations onto Silyl Enol Ethers
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Alkene Hydrofunctionalization Using Hydroxamic Acids: A Radical-Mediated Approach to Alkene Hydration
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Synthetic methods : Part (i) Free-radical reactions
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Reaction mechanisms : Part (i) Radical and radical ion reactions
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Construction of protected hydroxylated pyrrolidines using nitrogen-centered radical cyclizations
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Catalytic generation of alkoxy radicals from unfunctionalized alcohols
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Cu-catalyzed hydroxycyclopropanol ring-opening cyclization to tetrahydrofurans and tetrahydropyrans: short total syntheses of hyperiones
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Cu-catalyzed enantioconvergent oxygen-centered radical cyclization
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Light-induced radical addition to oximes: a general route to branched primary amines
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Photodecarboxylative Benzylations of N-Methoxyphthalimide under Batch and Continuous-Flow Conditions
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Nouvelles approches pour la préparation de composés hétérocycliques saturés
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