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A Flexible Radical-Based Approach to TMS-Substituted Propargyl Alcohols and to 2,3-Allenols

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Outgoing claims: the papers this work cites, builds on, or argues with.

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A New Radical Vinylation Reaction of Iodides and Dithiocarbonates
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Palladium-Catalyzed Regio- and Diastereoselective Tandem Silastannylation/Allyl Addition of Allene Aldehydes and Allene Ketones: Synthesis of cis Cyclopentanols and Cyclohexanols This work was supported by the National Research Laboratory Project administrated by the Ministry of Science and…
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Highly Efficient Stereocontrolled Total Synthesis of the Polyfunctional Carotenoid Peridinin
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Synthesis ofα-Methylene-γ-butyrolactones: Ru-Catalyzed Cyclocarbonylation of Allenyl Aldehydes and Allenyl Ketones
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Modern Allene Chemistry
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Allenic Natural Products and Pharmaceuticals
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On the Trail of Xanthates: Some New Chemistry from an Old Functional Group
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Powerful CarbonCarbon Bond Forming Reactions Based on a Novel Radical Exchange Process
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The Degenerative Radical Transfer of Xanthates and Related Derivatives: An Unusually Powerful Tool for the Creation of Carbon–Carbon Bonds
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Synthese d'heterocycles oxygenes a groupe vinylidene exocyclique par voie organosilicique - partie II
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A conjugate addition-elimination route to alkenoyltrimethylsilanes
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An efficient synthesis of enyne[3]cumulenes
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Synthesis of alkenyl- and alkynylcyclopropenes
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The reaction of 3,3-dichloroallyltrimethylsilane with n-butyllithium
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Mimulaxanthin—a new allenic xanthophyll from the petals of Mimulus guttatus
inferredcites →https://doi.org/10.1016/s0040-4039(00)61767-7openalex-snapshot
The preparation of 3-chloroalkenoyltrimethylsilanes
inferredcites →https://doi.org/10.1016/s0040-4039(00)99962-3openalex-snapshot
Reactivite de silanes propargyliques α-fonctionnels vis a vis des derives carbonyles : preparation d'alcools-ethers, de diols et de dioxannes alleniques.
inferredcites →https://doi.org/10.1016/s0040-4039(01)94157-7openalex-snapshot
A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′)
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Biogenetic type synthesis of grasshopper ketone and loliolide and a possible biogenesis of allenic carotenoids
inferredcites →https://doi.org/10.1016/s0040-4039(02)02241-4openalex-snapshot
Lewis acid-mediated cyclization of allenyl-aldehyde dimethyl acetals: synthesis of cis- and trans-2-haloalkenylcycloalkyl methyl ethers
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Palladium-catalyzed arylation of α-allenic alcohols with hypervalent iodonium salts: Synthesis of epoxides and diol cyclic carbonates
inferredcites →https://doi.org/10.1021/ar020133kopenalex-snapshot
Transition Metal-Catalyzed/Mediated Reaction of Allenes with a Nucleophilic Functionality Connected to the α-Carbon Atom
inferredcites →https://doi.org/10.1021/cr020024jopenalex-snapshot
Some Typical Advances in the Synthetic Applications of Allenes
inferredcites →https://doi.org/10.1021/ja076080popenalex-snapshot
Microwave-Assisted Palladium(0)-Catalyzed Alkylative Cyclization of Allenyl Aldehydes Leading to 3-Substituted 3-Cycloalken-1-ols
inferredcites →https://doi.org/10.1021/ja9904888openalex-snapshot
Pd(0)-Catalyzed Insertion−Cyclization Reaction of 2,3-Allenols with Aryl or Alkenyl Halides. Diastereoselective Synthesis of Highly Optically Active trans-2,3-Disubstituted Vinylic Oxiranes
inferredcites →https://doi.org/10.1021/jm00008a018openalex-snapshot
Synthesis, Absolute Configuration, and Enantioselectivity of Antiretroviral Effect of (R)-(-)- and (S)-(+)-Cytallene. Lipase-Catalyzed Enantioselective Acylations of (.+-.)-N4-Acylcytallenes
inferredcites →https://doi.org/10.1021/jm00100a016openalex-snapshot
(R)-(-)- and (S)-(+)-Adenallene: synthesis, absolute configuration, enantioselectivity of antiretroviral effect, and enzymic deamination.
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Facile Synthesis of [3]Cumulenes via 1,4-Elimination of Hydroxytrimethylsilane from 4-(Trimethylsilyl)-2-butyn-1-ols
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Facile synthesis of .beta.-aryl- or .beta.-alkenyl-.beta.-methyl-.alpha.,.beta.-unsaturated carbonyl compounds by palladium catalyzed reaction of 1,2-dien-4-ols with aryl or alkenyl halides
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New Catalysts for the Oxidation of Sulfides to Sulfones with Hydrogen Peroxide
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Palladium−Indium-Mediated Arylative Cyclization of Allenyl-Aldehydes and -Ketones
inferredcites →https://doi.org/10.1021/jo047887sopenalex-snapshot
Ketyl−Allene Cyclizations Promoted by Samarium(II) Iodide
inferredcites →https://doi.org/10.1021/jo048852vopenalex-snapshot
Stereocontrolled Total Synthesis of a Polyfunctional Carotenoid, Peridinin
inferredcites →https://doi.org/10.1021/jo951445mopenalex-snapshot
o-Quinone Methides from 4-Allenylcyclobutenones: Synthesis and Chemistry
inferredcites →https://doi.org/10.1021/ol005569jopenalex-snapshot
A Short Total Synthesis of (+)-Furanomycin
inferredcites →https://doi.org/10.1021/ol025557topenalex-snapshot
Palladium-Catalyzed Tandem Cyclization of Allenyl-Aldehydes and -Ketones with Aryl Iodides and Bu3SnSnBu3
inferredcites →https://doi.org/10.1021/ol026670mopenalex-snapshot
Preparation of Homoallylic Alcohols by Nickel-Catalyzed Cyclizations of Allenyl Aldehydes
inferredcites →https://doi.org/10.1021/ol034787kopenalex-snapshot
Silylative Carbocyclization of Allenyl-carbonyl Units with Et3SiH Catalyzed by Rhodium: Cis-Stereoselective Synthesis of Homoallylic Cycloalkanols
inferredcites →https://doi.org/10.1021/ol702590fopenalex-snapshot
A Highly Conjunctive β-Keto Phosphonate: Application to the Synthesis of Pyridine Alkaloids Xestamines C, E, and H
inferredcites →https://doi.org/10.1021/ol702966jopenalex-snapshot
Enantioselective Arylative Cyclization of Allenyl Aldehydes with Arylboronic Acids under Pd(II)-diphosphine Catalysis
inferredcites →https://doi.org/10.1021/ol801033eopenalex-snapshot
Facile and Efficient One-Pot Synthesis of Highly Functionalized Thieno[2,3-b]thiopyran-4-ones from β-Keto ε-Xanthyl Phosphonates
inferredcites →https://doi.org/10.1021/ol801162mopenalex-snapshot
Radical Aminomethylation of Unactivated Alkenes
inferredcites →https://doi.org/10.1021/ol801348uopenalex-snapshot
Radical, One-Step Approach to o-Chlorophenyl Thioethers from Xanthates. A Rapid Access to Vinylsilanes
inferredcites →https://doi.org/10.1039/a800736eopenalex-snapshot
A synthesis of enantiomerically enriched propargyl silanes
inferredcites →https://doi.org/10.1039/a804090gopenalex-snapshot
The stereochemistry of the vinylogous Peterson elimination
inferredcites →https://doi.org/10.1039/b207620aopenalex-snapshot
cis-Stereoselective nickel-catalyzed cyclization/alkylation and arylation reactions of allenyl-aldehydes and -ketones with organozinc reagentsElectronic supplementary information (ESI) available: typical procedures, NMR-data, and X-ray data. See http://www.rsc.org/suppdata/cc/b2/b207620a/
inferredcites →https://doi.org/10.1039/b615592hopenalex-snapshot
New routes to organofluorine compounds based on ketenes and the radical transfer of xanthates
inferredcites →https://doi.org/10.1039/c39940002121openalex-snapshot
Facile synthesis of alkyl and aryl substituted 1,2,3-butatrienes
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The synthesis of potential insecticides. Part I. 2,2-Dichlorovinyl carbamates and carbonates
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Synthesis of alkyl and aryl substituted buta-1,2,3-trienes
inferredcites →https://doi.org/10.1055/s-1979-28825openalex-snapshot
Synthesis of 2,5-Dihydrofurans and 5,6-Dihydro-2H-pyrans by Silver(I)-Catalyzed Cyclization of Allenic Alcohols
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Propargylic Silanes: Convenient Syntheses of 1-Trimethylsilyl-2-alkynes, 1,3-Bis[trimethylsilyl]-1-alkynes, and 3-Trimethylsilyl-1-alkynes
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Efficient Synthesis of Branched Propargyl- and Allylsilanes
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Some New Radical Reactions for Organic Synthesis
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Synthesis of 4-Hydroxy-2-cyclopentenone Derivatives by [3 + 2] Annulation of β-Heteroatom-Substituted Acryloylsilanes and Lithium Enolate of Methyl Ketones

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Meanderings of a Curious Chemist
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Enantioselective Synthesis of 4‐Hydroxy‐2‐cyclohexenones through a Multicomponent Cyclization
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Enantioselective Synthesis of 4‐Hydroxy‐2‐cyclohexenones through a Multicomponent Cyclization
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ChemInform Abstract: A Flexible Radical‐Based Approach to TMS‐Substituted Propargyl Alcohols and to 2,3‐Allenols.
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Radical Alliances: Solutions and Opportunities for Organic Synthesis
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On the Strategic Impact of the Degenerative Transfer of Xanthates on Synthetic Planning
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A flexible, modular route to cyclopentanols
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Discovery of the RAFT/MADIX Process: Mechanistic Insights and Polymer Chemistry Implications
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An Ionic-Radical Approach to Vicinally Functionalized Cyclopentanones and Cyclohexanones
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Extension to the Silyl-Tethered Radical Cyclization: Cyclohex-2-en-1-oxy Vinyl Silanes in Stereoselective Radical Addition/Cyclization Cascades
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How easy are the syntheses of allenes?
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Harmony of CdI 2 with CuBr for the one-pot synthesis of optically active α-allenols
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Stable bromoallene oxides
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Meanderings of a Curious Chemist
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4.4.38.14 Propargylsilanes (Update 2022)
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Some aspects of radical cascade and relay reactions
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The xanthate route to six-membered carbocycles
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Some aspects of radical chemistry in the assembly of complex molecular architectures
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