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Reductive Addition of the Benzenethiyl Radical to Alkynes by Amine-Mediated Single Electron Transfer Reaction to Diphenyl Disulfide

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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A Study of Vinyl Radical Cyclization onto the Azido Group by Addition of Sulfanyl, Stannyl, and Silyl Radicals to Alkynyl Azides⋆

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Flight from the Tyranny of Tin: The Quest for Practical Radical Sources Free from Metal Encumbrances

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Radicals in Organic Synthesis

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Radical‐Mediated Alkenylation, Alkynylation, Methanimination, and Cyanation of B‐Alkylcatecholboranes

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Highly Efficient Reduction of Unactivated Aryl and Alkyl Iodides by a Ground‐State Neutral Organic Electron Donor

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Radical‐Mediated Alkenylation, Alkynylation, Methanimination, and Cyanation of B‐Alkylcatecholboranes

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Formation of Carbanions Using Neutral Organic Molecules as Electron‐Transfer Reagents: A Radical Concept

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trans Lipids: The Free Radical Path

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The redox cleavage of the sulfur-sulfur bond and carbon-sulfur bond in organic disulfides by a model coenzyme

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Polar substituent and solvent effects on the kinetics of radical reactions with thiols

inferredcites →https://doi.org/10.1016/j.tet.2008.06.005openalex-snapshot

Synthesis of (−)-trachelanthamidine using a single electron transfer reaction in 1,4-dimethylpiperazine

inferredcites →https://doi.org/10.1016/j.tet.2008.07.107openalex-snapshot

Thiol-mediated radical cyclizations

inferredcites →https://doi.org/10.1016/j.tet.2008.09.022openalex-snapshot

Hydrothiolation of terminal alkynes with diaryl disulfides and diphenyl diselenide: selective synthesis of (Z)-1-alkenyl sulfides and selenides

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Radical cyclizations in 1,4-dimethylpiperazine

inferredcites →https://doi.org/10.1016/s0040-4020(98)00458-xopenalex-snapshot

Attempts at vinyl radical carbonylation through cyclization onto carbonyl and cyano groups

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Kinetics and mechanism of some vinyl radical cyclisations

inferredcites →https://doi.org/10.1016/s0040-4039(01)81027-3openalex-snapshot

Thiophenol promoted cyclization of enynes

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Trans Lipids: The Free Radical Path

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Dimethylzinc-Initiated Radical Reactions

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Nucleophilic Substitution Reactions by Electron Transfer

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Tin-Free and Catalytic Radical Cyclizations

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Sustainable Radical Reduction through Catalytic Hydrogen Atom Transfer

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Complexes of Borane and N-Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor

inferredcites →https://doi.org/10.1021/ja808764qopenalex-snapshot

Organoactinide-Mediated Hydrothiolation of Terminal Alkynes with Aliphatic, Aromatic, and Benzylic Thiols

inferredcites →https://doi.org/10.1021/jo00803a008openalex-snapshot

Redox cleavage of the sulfur-sulfur bond and carbon-sulfur bond in tetramethylthiuram disulfide by N-benzyl-1,4-dihydronicotinamide

inferredcites →https://doi.org/10.1021/jo050931zopenalex-snapshot

Stereoselective Hydrothiolation of Alkynes Catalyzed by Cesium Base: Facile Access to ( Z )-1-Alkenyl Sulfides

inferredcites →https://doi.org/10.1021/jo060883yopenalex-snapshot

Formation of Five- and Six-Membered Carbocycles with Nitrogenated Tetrasubstituted Carbons by Radical Addition-Carbocyclization of Alkynyl Ketoxime Ethers

inferredcites →https://doi.org/10.1021/jo801644sopenalex-snapshot

Synthesis of 1,1-Disubstituted Alkyl Vinyl Sulfides via Rhodium-Catalyzed Alkyne Hydrothiolation: Scope and Limitations

inferredcites →https://doi.org/10.1021/jo971652hopenalex-snapshot

Highly Regioselective Thioselenation of Acetylenes by Using a (PhS)2−(PhSe)2 Binary System

inferredcites →https://doi.org/10.1021/ol036391eopenalex-snapshot

Disulfidation of Alkynes and Alkenes with Gallium Trichloride

inferredcites →https://doi.org/10.1021/ol7016609openalex-snapshot

Expanding the Scope of Trialkylborane/Water-Mediated Radical Reactions

inferredcites →https://doi.org/10.1021/ol801162mopenalex-snapshot

Radical Aminomethylation of Unactivated Alkenes

inferredcites →https://doi.org/10.1021/om049082gopenalex-snapshot

New Catalytic System for S−S and Se−Se Bond Addition to Alkynes Based on Phosphite Ligands

inferredcites →https://doi.org/10.1038/203075a0openalex-snapshot

Redox Cleavage of S—S Linkage in Diaryl and Cyclic Alkyl Disulphides

inferredcites →https://doi.org/10.1039/p19910002103openalex-snapshot

Free-radical reactions of benzenethiol and diphenyl disulphide with alkynes. Chemical reactivity of intermediate 2-(phenylthio)vinyl radicals

inferredcites →https://doi.org/10.1055/s-2002-28507openalex-snapshot

Tin Hydride Substitutes in Reductive Radical Chain Reactions

inferredcites →https://doi.org/10.1246/cl.1987.1647openalex-snapshot

Et3B Induced Radical Addition of Thiols to Acetylenes

inferredcites →https://doi.org/10.3998/ark.5550190.0009.e02openalex-snapshot

Role of 1,4-dimethylpiperazine in radical cyclizations

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Main‐Group Elements in Radical Chemistry

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Organic Electron Donors as Powerful Single‐Electron Reducing Agents in Organic Synthesis

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ChemInform Abstract: Reductive Addition of the Benzenethiyl Radical to Alkynes by Amine‐Mediated Single Electron Transfer Reaction to Diphenyl Disulfide.

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Transition‐Metal‐Free Dehalogenative 1,2‐Dichalcogenation of Internal Fluoroalkyl Alkenes

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Visible‐Light‐Promoted Intramolecular Annulation of 2‐Alkynylbiphenyl Compounds to Synthesize 9‐Sulfenylphenanthrenes Under Metal‐Free and Additive‐Free Conditions

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Five-Membered Ring Systems: Furans and Benzofurans

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Five-Membered Ring Systems

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4.05 Addition of HX Reagents to Alkenes, Alkynes, and Allenes without Transition Metal

inferred← citeshttps://doi.org/10.1016/b978-0-08-097742-3.00418-3openalex-snapshot

4.12 Radical Addition Reactions

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Synthesis of organochalcogens: use of nonconventional solvents/reaction media

inferred← citeshttps://doi.org/10.1016/j.molstruc.2024.140226openalex-snapshot

Hydromethylthiolation of alkynes via nucleophilic addition of dimethyl disulfide in DMSO

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Applications of allylamines for the syntheses of aza-heterocycles

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Novel radical tandem 1,6-enynes thioacylation/cyclization: Au–Pd nanoparticles catalysis versus thermal activation as a function of the substrate specificity

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Recent advances in sulfur- and phosphorous-centered radical reactions for the formation of S–C and P–C bonds

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Visible light induced acridinium catalyzed C(sp2)–H thiolation of imidazopyridines with thioalcohols

inferred← citeshttps://doi.org/10.1016/s0959-6380(11)22007-5openalex-snapshot

Five-Membered Ring Systems

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Thiolation of Terminal Alkynes with Thiuram Disulfide Reagents Using Water as the Hydrogen Source: Stereoselective Synthesis of ( Z )-Vinyl Sulfides

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Selective Synthesis of Vinyl Sulfides or 2-Methyl Benzothiazoles from Disulfides and CaC2 Mediated by a Trisulfur Radical Anion

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Electrochemical Giese Reaction of α-Trifluoromethylstyrenes with Disulfides: Efficient Access to β-Trifluoromethylated Thioethers

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Silver-Catalyzed Direct Thiolation of Quinones by Activation of Aryl Disulfides to Synthesize Quinonyl Aryl Thioethers

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Nickel-Catalyzed Regioselective Cleavage of C sp 2 –S Bonds: Method for the Synthesis of Tri- and Tetrasubstituted Alkenes

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Visible-Light-Driven α-Allenylic C–O Bond Cleavage and Alkenyl C–S Formation: Metal-Free and Oxidant-Free Thiolation of Allenyl Phosphine Oxides

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Cascade Radical Cyclization on Alkynyl Vinylogous Carbonates for the Divergent Synthesis of Tetrasubstituted Furans and Dihydrofurans

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Diethylaminosulfur Trifluoride: A Novel, Low-Cost, Stable Double Thiolation Reagent for Imidazo[1,2-α]pyridines

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Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems

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Thiyl Radicals in Organic Synthesis

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Single Electron Transfer in Radical Ion and Radical-Mediated Organic, Materials and Polymer Synthesis

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An Insight into the Radical Thiol/Yne Coupling: The Emergence of Arylalkyne-Tagged Sugars for the Direct Photoinduced Glycosylation of Cysteine-Containing Peptides

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A Radical Cascade Cyclization To Prepare Dihydrothiophenes Induced by Thiyl Radicals as Sulfur Biradical Equivalents

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Iron-Catalyzed Regio- and Stereoselective Chlorosulfonylation of Terminal Alkynes with Aromatic Sulfonyl Chlorides

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Carbon Dioxide Mediated Stereoselective Copper-Catalyzed Reductive Coupling of Alkynes and Thiols

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Rearrangements of N-Acyl Isothioureas. Alternate Access to Acylguanidines from Cyanamides

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