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Reactions of RuHCl(CO)(PiPr3)2 with Alkyn-1-ols: Synthesis of Ruthenium(II) Hydroxyvinyl and Vinylcarbene Complexes

https://doi.org/10.1021/om00023a031
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The Influence of Phosphine Ligands on the Redox Properties of 1,4-Divinylanthrylene-Bridged Diruthenium Complexes and a Derived Macrocyclic Analog
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Late transition-metal multiple bonding: Platinum phosphinidenes and ruthenium alkylidenes
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Hydrido(carbene), Hydrido(diazoalkane), Aqua(carbene), and Vinyl(carbene) Complexes of Osmium(II)
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Rutheniumcarbene in Makrocyclen: Kohlenmonoxid-induzierte Carbenwanderung vom Metall zum Liganden
inferred← citeshttps://doi.org/10.1002/1099-0682(200207)2002:7<1647::aid-ejic1647>3.0.co;2-yopenalex-snapshot
(Alkenylalkylidene)(indenyl)ruthenium(II) Complexes: Synthesis by Protonation of Alkenyl Derivatives
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Eine Reihe definierter Metathesekatalysatoren – Synthese von und Reaktionen mit [RuCl2 ( CHR′)(PR3)2]
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A Series of Well‐Defined Metathesis Catalysts–Synthesis of [RuCl2(CHR′)(PR3)2] and Its Reactions
inferred← citeshttps://doi.org/10.1002/cctc.201600479openalex-snapshot
Ruthenium‐Catalyzed Metathesis of Conjugated Polyenes
inferred← citeshttps://doi.org/10.1002/ejic.200300496openalex-snapshot
A Series of Vinylidene‐, Vinyl‐, Carbene‐ and Carbyneruthenium( II ) Complexes with [Ru(PCy3)2] and [Ru(PiPr3)2] as Molecular Building Blocks
inferred← citeshttps://doi.org/10.1016/0022-328x(95)05522-qopenalex-snapshot
Reactions of [RuH(η3C3H5)(CO)(PiPr3)2] and [Ru(η2C2Ph2)(CO)(PiPr3)2] with terminal alkynes: synthesis and characterization of new five- and six-coordinate bis(alkynyl) and alkynyl(vinyl) derivatives of ruthenium(II)
inferred← citeshttps://doi.org/10.1016/b0-08-045047-4/00092-3openalex-snapshot
Mononuclear Ru/Os Compounds with Hydrocarbon Ligands: Compounds with η1-Ligands
inferred← citeshttps://doi.org/10.1016/j.ccr.2006.07.008openalex-snapshot
Osmium–carbon double bonds: Formation and reactions
inferred← citeshttps://doi.org/10.1016/j.ccr.2006.09.008openalex-snapshot
Ruthenium vinyl carbene intermediates in enyne metathesis
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2010.04.001openalex-snapshot
On the ROMP of 2-norbornene with an in situ ruthenium carbene complex: ESI-MS, NMR and DFT analyses
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2012.04.015openalex-snapshot
Mixed-valent diruthenium half-sandwich complex containing two chelating 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligands: Reactivity toward (cyclo-C6H10)(OH)C CH and PhC(O)C CH
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123185openalex-snapshot
The influence of phosphine ligands on the redox properties of 1,4-divinylanthrylene-bridged diruthenium complexes and a derived macrocyclic analog
inferred← citeshttps://doi.org/10.1016/s0010-8545(99)00166-6openalex-snapshot
Ruthenium and osmium vinylidene complexes and some related compounds
inferred← citeshttps://doi.org/10.1016/s0022-328x(96)06466-2openalex-snapshot
Synthesis and reactivity of new benzophenone imine derivatives containing the Ru(CO)(PiPr3)2 unit
inferred← citeshttps://doi.org/10.1016/s0022-328x(96)06906-9openalex-snapshot
Reactions of RuHCl(CO)(PPh3)3 with 1-alkynols. Preparation and reactivity of hydroxyvinyl complexes
inferred← citeshttps://doi.org/10.1016/s0022-328x(96)06926-4openalex-snapshot
Five- and six-coordinate ruthenium complexes with the tridentate orthometallated aryl bisphosphine ligand [2,6-(Ph2PCH2)2C6H3]−
inferred← citeshttps://doi.org/10.1016/s0022-328x(97)00080-6openalex-snapshot
Dimeric and polymeric ruthenium complexes with Ru—vinyl linkages
inferred← citeshttps://doi.org/10.1016/s0022-328x(99)00354-xopenalex-snapshot
The metal–carbon multiple bond in iron(I)– and iron(II)–dibenzotetramethyltetra[14]azaannulene: carbene, carbonyl, and isocyanide derivatives
inferred← citeshttps://doi.org/10.1016/s0065-3055(01)47008-0openalex-snapshot
The chemical and catalytic reactions of hydrido-chloro-carbonylbis (triisopropylphosphine)osmium(II) and its major derivatives
inferred← citeshttps://doi.org/10.1016/s1381-1169(02)00242-xopenalex-snapshot
Ligand manipulation and design for ruthenium metathesis and tandem metathesis-hydrogenation catalysis
inferred← citeshttps://doi.org/10.1021/acs.organomet.5c00511openalex-snapshot
Effects of Alkyne Substituents and X-Ligands on Alkyne Insertion Reactions of RuHX(CO)(PPh 3 ) 3
inferred← citeshttps://doi.org/10.1021/cr970473xopenalex-snapshot
Transition Metal Complexes Containing Allenylidene, Cumulenylidene, and Related Ligands
inferred← citeshttps://doi.org/10.1021/ic801302zopenalex-snapshot
Formation of a Coordinated 2-Aminoethylidene Ligand and Its Rearrangement by Deprotonation into a Phosphinoallyl Ligand Containing a Pyrrolidin-2-yl Ring
inferred← citeshttps://doi.org/10.1021/ja053186gopenalex-snapshot
Hydride-Alkenylcarbyne to Alkenylcarbene Transformation in Bisphosphine-Osmium Complexes
inferred← citeshttps://doi.org/10.1021/ja109691vopenalex-snapshot
From Tetrahydroborate− to Aminoborylvinylidene−Osmium Complexes via Alkynyl−Aminoboryl Intermediates
inferred← citeshttps://doi.org/10.1021/om0101386openalex-snapshot
One-Pot Synthesis for Osmium(II) Azavinylidene−Carbyne and Azavinylidene−Alkenylcarbyne Complexes Starting from an Osmium(II) Hydride−Azavinylidene Compound
inferred← citeshttps://doi.org/10.1021/om020442eopenalex-snapshot
Synthesis and Characterization of Linear (CH)8-Bridged Bimetallic Ruthenium Complexes
inferred← citeshttps://doi.org/10.1021/om0208826openalex-snapshot
An Osmium-Carbene Complex with Fischer−Schrock Ambivalent Behavior
inferred← citeshttps://doi.org/10.1021/om021043mopenalex-snapshot
Reactions of Elongated Dihydrogen-Osmium Complexes Containing Orthometalated Ketones with Alkynes: Hydride-Vinylidene-π-Alkyne versus Hydride-Osmacyclopropene
inferred← citeshttps://doi.org/10.1021/om030518mopenalex-snapshot
Preparation and Characterization of 4-Azoniaheptatrienyl, 4-Azaheptatrienyl, Ruthenapyrrolinone, and Pyrrolinyl Complexes of Ruthenium
inferred← citeshttps://doi.org/10.1021/om100707aopenalex-snapshot
Interconversion of Ruthenium-O(CH2CH2PCy2)2 Alkylidene and Alkylidyne Hydride Complexes
inferred← citeshttps://doi.org/10.1021/om101013jopenalex-snapshot
Nucleophilic Addition Reactions to Allenylidene Complexes of Ruthenium Bearing Hemilabile P,N Ligands: Isolation of the Vinylcarbene Complex [Cp*Ru═CHCH═CPh2(iPr2PNHPy)][PF6]
inferred← citeshttps://doi.org/10.1021/om101105sopenalex-snapshot
Preparation of Half-Sandwich Alkoxycarbene Complexes of Osmium(II)
inferred← citeshttps://doi.org/10.1021/om1011962openalex-snapshot
Hydride Alkenylcarbyne Osmium Complexes versus Cyclopentadienyl Type Half-Sandwich Ruthenium Derivatives
inferred← citeshttps://doi.org/10.1021/om200485kopenalex-snapshot
Reactions of Osmium–Pinacolboryl Complexes: Preparation of the First Vinylideneboronate Esters
inferred← citeshttps://doi.org/10.1021/om300811gopenalex-snapshot
Complicated Electronic Process of C–C σ-Bond Activation of Cyclopropene by Ruthenium and Iridium Complexes: Theoretical Study
inferred← citeshttps://doi.org/10.1021/om900442mopenalex-snapshot
Aromatization of a Dihydro-3-ruthenaindolizine Complex
inferred← citeshttps://doi.org/10.1021/om960124dopenalex-snapshot
Five-Coordinate Complex [RuHCl(CO)(PPri3)2] as a Precursor for the Preparation of New Cyclopentadienylruthenium Compounds Containing Unsaturated η1-Carbon Ligands
inferred← citeshttps://doi.org/10.1021/om9602926openalex-snapshot
Synthesis of Rh(acac)H(GeEt3)(PCy3) and Rh(acac)H(SnPh3)(PCy3) and Their Reactions with Alkynes
inferred← citeshttps://doi.org/10.1021/om960525topenalex-snapshot
Synthesis, Spectroscopic Characterization, and Reactivity of the Unusual Five-Coordinate Hydrido−Vinylidene Complex OsHCl(CCHPh)(PiPr3)2: Precursor for Dioxygen Activation
inferred← citeshttps://doi.org/10.1021/om9606707openalex-snapshot
C5H5-Bridged Dimeric Ruthenium Complexes
inferred← citeshttps://doi.org/10.1021/om970081gopenalex-snapshot
Carbon−Carbon Coupling of Two Alkenyl Fragments on a Saturated Compound
inferred← citeshttps://doi.org/10.1021/om9700829openalex-snapshot
Coupling Reactions of Terminal Acetylenes with Ruthenium Complexes Containing the Ortho-Metalated Ligand 2,6-(PPh2CH2)2C6H3
inferred← citeshttps://doi.org/10.1021/om970140qopenalex-snapshot
Synthesis of Symmetrical C5H5-Bridged Dimeric Ruthenium Complexes
inferred← citeshttps://doi.org/10.1021/om970237copenalex-snapshot
Meyer's Complex OsH2Cl2(PiPr3)2 as a Precursor for the Preparation of New Cyclopentadienylosmium Compounds
inferred← citeshttps://doi.org/10.1021/om970270zopenalex-snapshot
Synthesis and Reactivity of the Unusual Five-Coordinate Hydrido−Hydroxo Complex OsH(OH)(CO)(PiPr3)2
inferred← citeshttps://doi.org/10.1021/om970301qopenalex-snapshot
The Os(CO)(PiPr3)2 Unit as a Support for the Transformation of Two Alkyne Molecules into New Organometallic Ligands
inferred← citeshttps://doi.org/10.1021/om970431zopenalex-snapshot
Acid-Catalyzed Carbonylation of Lactone to Cyclic Anhydride on Tungsten Metal
inferred← citeshttps://doi.org/10.1021/om970633vopenalex-snapshot
Five-Coordinate Complexes MHCl(CO)(PiPr3)2 (M = Os, Ru) as Precursors for the Preparation of New Hydrido− and Alkenyl−Metallothiol and Monothio−β-Diketonato Derivatives
inferred← citeshttps://doi.org/10.1021/om9708539openalex-snapshot
Addition of Carbon Nucleophiles to the Allenylidene Ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PiPr3)]BF4: Synthesis of New Organic Ligands by Formal C−C Coupling between Mutually Inert Fragments
inferred← citeshttps://doi.org/10.1021/om980132popenalex-snapshot
Cycloaddition between a Transition-Metal Phenylallenylidene Complex and Allyl Alcohol
inferred← citeshttps://doi.org/10.1021/om980300dopenalex-snapshot
Regioselective Synthesis of Indenylruthenium(II) Vinylalkylidene Complexes via Proton Additions to Vinylalkenyl Derivatives
inferred← citeshttps://doi.org/10.1021/om9803366openalex-snapshot
Seven-Coordinate Dihydrido Complex OsH2(κ2-O2CCH3){κ1-OC(O)CH3}(PiPr3)2 as Precursor of New Organometallic Compounds Containing Unsaturated η1-Carbon Ligands
inferred← citeshttps://doi.org/10.1021/om980374popenalex-snapshot
Polyazolyl Chelate Chemistry. 8.1Organometallic Dihydridobis(pyrazol-1-yl)borato Complexes of Ruthenium(II)
inferred← citeshttps://doi.org/10.1021/om980476fopenalex-snapshot
Addition of Ethyl Diazoacetate to the Allenylidene Ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PPri3)]BF4: Synthesis of Ruthenium Organometallic Compounds Containing New Cyclic Unsaturated η1-Carbon Ligands
inferred← citeshttps://doi.org/10.1021/om980683fopenalex-snapshot
Synthesis and Reactivity of Neutral and Cationic Ruthenium(II) Tris(pyrazolyl)borate Alkylidenes
inferred← citeshttps://doi.org/10.1021/om980898popenalex-snapshot
Ruthenium−Carbene Functionality Bonded to Dibenzotetramethyltetraaza[14]annulene: Metal-to-Macrocycle Ligand-Induced Carbene Migration
inferred← citeshttps://doi.org/10.1021/om981042nopenalex-snapshot
The π-(Hydroxyalkenyl)germane Complexes Rh(acac){η2-(E)-Et3GeCHCHC(OH)R2}(PCy3) (R = Me, Ph) as Intermediates in the Hydrogermylation of Alkynols Catalyzed by Rh(acac)(cyclooctene)(PCy3)
inferred← citeshttps://doi.org/10.1021/om990129lopenalex-snapshot
Hydrovinylation and [2+2] Cycloaddition Reactions of Alkynes and Alkenes Catalyzed by a Well-Defined Cationic Ruthenium−Alkylidene Complex
inferred← citeshttps://doi.org/10.1021/om990234vopenalex-snapshot
Synthesis of Hydrido−Vinylidene and Hydrido−Carbyne Osmium Complexes Containing Pyrazole: New Examples of N−H···Y (Y = N, F, Cl) Hydrogen Bonds
inferred← citeshttps://doi.org/10.1021/om990456topenalex-snapshot
Synthesis of Novel Organometallic Compounds Containing η1-Carbon Polycyclic Ligands: Condensation of Propargyl Alcohol with the Allenylidene Ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PPri3)]BF4
inferred← citeshttps://doi.org/10.1021/om9904706openalex-snapshot
Addition of Secondary and Primary Amines to the Allenylidene Ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PiPr3)]BF4: Synthesis of Azoniabutadienyl, Aminoallenyl, and Azabutadienyl Derivatives of Ruthenium(II)
inferred← citeshttps://doi.org/10.1021/om9909542openalex-snapshot
Hydride−Hydroxyosmacyclopropene versus Hydride−Hydroxycarbyne and Cyclic Hydroxycarbene: Influence of the Substituents at the C(OH) Carbon Atom of the Carbon Donor Ligand
inferred← citeshttps://doi.org/10.1021/om9910017openalex-snapshot
A 14-Electron Ruthenium(II) Hydride, [RuH(CO)(PtBu2Me)2]BAr‘4 (Ar‘ = 3,5-(C6H3)(CF3)2): Synthesis, Structure, and Reactivity toward Alkenes and Oxygen Ligands
inferred← citeshttps://doi.org/10.1039/a902021gopenalex-snapshot
Control of intramolecular acetate–allenylidene coupling by spectator co-ligand π-acidity
inferred← citeshttps://doi.org/10.1039/b314425aopenalex-snapshot
Vinyl and carbene ruthenium( ii ) complexes from hydridoruthenium( ii ) precursors
inferred← citeshttps://doi.org/10.1039/c1cc12499dopenalex-snapshot
Enantioselective hydrovinylation via asymmetric counteranion-directed ruthenium catalysis
inferred← citeshttps://doi.org/10.1039/c4qo00152dopenalex-snapshot
1,2-Migration in the reactions of ruthenium vinyl carbene with propargyl alcohols
inferred← citeshttps://doi.org/10.1134/s1070328416120034openalex-snapshot
Reactivity of dinuclear ruthenium complex containing two 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligands toward HC≡CCH(OH)(CH3)2
inferred← citeshttps://doi.org/10.1246/bcsj.71.1525openalex-snapshot
The Chemistry of η3-Vinylcarbene Complexes
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