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Organosilane high polymers: thermochromic behavior in solution

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Optical and Electronic Properties of the Hexagermane Pr I 3ge(Geph2)4gepr I 3: Absorbance and Emission Studies in Solution and the Solid State and Band Gap Determination
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Photoinitiation of vinyl polymerization by polysilanes
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Intuitive Understanding of σ Delocalization in Loose and σ Localization in Tight Helical Conformations of an Oligosilane Chain
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Soluble Substituted Silane High Poymers
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Conformational Dependence of σ‐Electron Delocalization in Linear Chains: Permethylated Oligosilanes
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Electronic Transitions in Conformationally Controlled Tetrasilanes with a Wide Range of SiSiSiSi Dihedral Angles
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Electronic Transitions in Conformationally Controlled Peralkylated Hexasilanes
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Suppression of Thermochromism in a Poly(di‐n‐hexylsilane)‐Zirconia Hybrid
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Synthesis of Block Copolymers with a Pentasilane Core
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29Si nuclear magnetic resonance of dialkylpolysilanes
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The synthesis of soluble, substituted silane high polymers by Wurtz coupling techniques
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Synthesis of novel polysilylenes bearing phenol groups directly bonded to SiSi main chains for preparing Langmuir–blodgett thin films
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A MNDO study of the structural and electronic properties of polysilane model compounds
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Chromism of soluble polythienylenes
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Comparison of the molecular dimensions of di‐alkyl and aryl‐alkyl‐substituted polysilanes in solution using SEC/LS
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Third-order M�ller-Plesset perturbation theory of electron correlation in infinite systems: A comparison of carbon- and silicon-based polymers
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Modern Synthetic and Application Aspects of Polysilanes: An Underestimated Class of Materials?
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Optical Spectra of Flexible Conjugated Polymers
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Electronic Excitations in Polysilanes: Frenkel Excitons of a Disordered Chain
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The Solid State 29Si and 13C NMR of Poly(Di-n-Alkylsilylenes)
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Electronic Structure and Spectroscopy of Polysilanes
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Optically Active Silicon-Containing Polymers
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Iterative Building Block Approaches to Discrete Polystannane Oligomers
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The solution and solid-state thermochromism of unsymmetrically substituted polysilanes
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Fluorescence quenching of poly(methylphenylsilane) in solution
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Electronic excitation in a syn-tetrasilane: 1,1,2,2,3,3, 4,4-octamethyltetrasilacyclopentane
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Effect of the Chiral Center Position of an Optically Active Terminal Group on the Induction of Optical Activity in Polysilanes
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Electroreductive polymerization of phenylmethyldichlorosilane in a divided cell using a neutral membrane
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The tunability of the electronic structures for poly(carbosilylsilanes): a theoretical study
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A minimal basis-set CNDO/2(S + DES CI) study on the excited states of hydrogenated polysilane model compounds
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Absorption spectrum of flexible conjugated polymers: the weak-disorder limit
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Picosecond reorientations of the transition dipoles in polysilanes using fluorescence anisotropy
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Elements of group 4
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Excitation dynamics in polysilanes
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Excited state dynamics of poly-di-n-hexyl-silane
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The polysilane high polymers
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Measurement of surface tension for polysilanes
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Higher-order structure and thermal transition behaviour of poly(di-–hexylsilane)
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Theoretical investigation of the origins of abrupt thermochromism in the polysilanes
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Sonochemical Na/K alloy emulsion synthesis of polysilynes
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Fluorescence studies of poly(3-hexylthiophene) solutions
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Theory of order-disorder transitions and optical properties of flexible conjugated polymers
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Electronic properties of σ-conjugated polysilanes
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Polysilanes - prototypical σ-conjugated polymers
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The influence of conformation on the electronic properties of polysilanes
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Theoretical study on the effect of backbone conformation on the electronic structure of poly(di-n-butylsilane)
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Organosilicon and Related Group 14 Polymers
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Dimensional perspectives on metal center associated electrochromism in metal-organic coordinated hybrid polymers: Unveiling electrochromic dynamics
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Novel electrochemical synthesis and characterisation of poly(methyl vinylsilane) and its co-polymers
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Unusual conformational properties of 1,3-dimethyl-1,1,3,3-tetrakis(trimethylsilyl)trisilane: A preparative, X-ray, Raman spectroscopic and ab initio study
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Comparison of solid state studies and electrochemical behavior of poly (dimethylsilane) and poly (dimethylstannum) film electrodes
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Synthesis and investigation of the properties of poly(methyl-β-cyanoethylsilylene)-methylphenylsilylene
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UV, Raman and XRD study of polymorphism of poly(methyl-n-propylsilane)
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Characterization of polydihydrosilane by SEC-MALLS and viscometry
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Chain dimensions and intermolecular interactions of polysilanes bearing alkyl side groups over the UV thermochromic temperature
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Synthesis and structural characterisation of various organosilane–organogermane and organosilane–organostannane statistical copolymers by the Wurtz reductive coupling polymerisation: 119Sn NMR and EXAFS characterisation of the stannane copolymers
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Direct observation of intra-molecular energy migration in σ-conjugated polymer by femto-second laser flash photolysis
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Electrochemical synthesis of polygermanes
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Electrochemical synthesis of germane–germane and germane–silane copolymers
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Conformations of oligosilanes with ethyl and methyl substituents
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Thermochromism and solvatochromism of non-ionic polar polysilanes
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Synthesis and reactivity of novel oligosilanes bearing functional carbosilane side chains
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Synthesis of polysilanes bearing pendant carbosilyl groups and 29Si-NMR probe on the tacticity using side chain silicon atoms
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A new theory for rotational isomeric states: polysilanes lead the way
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Unusual behavior of silicon oligomers and polymers having functional groups
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Dehydrocoupling polymerization of arylsilanes with chloro(aryloxy)bis(cyclopentadienyl)zirconium complex catalysts
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Catalytic Dehydrocoupling: A General Strategy for the Formation of Element–Element Bonds
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Synthesis, functionalization, and cross-linking reactions of organosilicon polymers using silyl triflate intermediates
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Polysilanes for semiconductor fabrication
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The five favored backbone conformations of n-Si4Et10: cisoid, gauche, ortho, deviant, and transoid
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Catalytic dehydrocoupling: a general method for the formation of element-element bonds
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Singlet excitation in polysilanes: Ab initio calculations on oligosilane models
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Electron propagator theory of bonding in saturated silicon chains
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Electroluminescent characteristics of one-dimensional silicon chains in dialkyl polysilanes
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Photoinitiation of cationic polymerization by using poly(methyl phenyl silane) in combination with addition–fragmentation agents
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Far-Ultraviolet Spectroscopy and Quantum Chemical Calculation Studies of the Conformational Dependence on the Electronic Structure and Transitions of Cyclohexane, Methyl and Dimethyl Cyclohexane, and Decalin; Effects of Axial Substitutions on the Electronic Transitions
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Organometallic-like C−H Bond Activation and C−S Bond Formation on the Disulfide Bridge in the RuSSRu Core Complexes
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Paramagnetic Cp/Dithiolene Complexes as Molecular Hinges: Interplay of Metal/Ligand Electronic Delocalization and Solid-State Magnetic Behavior
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Application of Polysilanes to LSI Manufacturing ProcessesTheir Antireflective Properties and Etching Selectivity toward Resists
inferred← citeshttps://doi.org/10.1021/cm960373sopenalex-snapshot
Ionochromic and Thermochromic Phenomena in a Regioregular Polythiophene Derivative Bearing Oligo(oxyethylene) Side Chains
inferred← citeshttps://doi.org/10.1021/ic0483646openalex-snapshot
Synthesis and Structural Characterization of Some Selenoruthenates and Telluroruthenates
inferred← citeshttps://doi.org/10.1021/ic8024364openalex-snapshot
Hexacoordinated Oligosilanes from a Hexacoordinated Silicon(IV) Complex Containing an O,N,N,O Salen-type and Thiocyanato-N Ligands
inferred← citeshttps://doi.org/10.1021/ja0167250openalex-snapshot
Helical-Sense Programming through Polysilane-Poly(triphenylmethyl methacrylate) Block Copolymers
inferred← citeshttps://doi.org/10.1021/ja953835wopenalex-snapshot
A Correlation between Global Conformation of Polysilane and UV Absorption Characteristics
inferred← citeshttps://doi.org/10.1021/ja972543nopenalex-snapshot
Induction of Helical Chirality in Linear Oligosilanes by Terminal Chiral Substituents
inferred← citeshttps://doi.org/10.1021/jacs.2c01820openalex-snapshot
Poly(cyclosilane) Connectivity Tunes Optical Absorbance
inferred← citeshttps://doi.org/10.1021/jacs.8b02541openalex-snapshot
Directional Building Blocks Determine Linear and Cyclic Silicon Architectures
inferred← citeshttps://doi.org/10.1021/jacs.9b04780openalex-snapshot
Effect of Conformation on Electron Localization and Delocalization in Infinite Helical Chains [X(CH3)2]∞(X = Si, Ge, Sn, and Pb)
inferred← citeshttps://doi.org/10.1021/jp010840fopenalex-snapshot
Dynamics of the Excited State of Polysilane Dendrimers: Origin of the Broad Visible Emission of Branched Silicon Chains
inferred← citeshttps://doi.org/10.1021/jp064643yopenalex-snapshot
Calculation of Relative Energies of Permethylated Oligosilane Conformers in Vapor and in Alkane Solution
inferred← citeshttps://doi.org/10.1021/jp9847080openalex-snapshot
Ion Beam Induced Crosslinking Reactions in Poly(di-n-hexylsilane)
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Molecular Design and Characterization of Chromic Polyfluorene Derivatives
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Thermochromic and Solvatochromic Conjugated Polymers by Design
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Synthesis and Spectroscopic Characterization of Heteroatom Polysilylenes: Poly(dialkoxysilylene)s and Evidence for Silicon σ−Oxygen n Mixing Interaction
inferred← citeshttps://doi.org/10.1021/ma0101714openalex-snapshot
Thermochromism of Poly(di-n-hexylsilane) in Solution Revisited
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Conformational Transition of End-Grafted Poly(di-n-hexylsilane) in Solventless Conditions
inferred← citeshttps://doi.org/10.1021/ma034854qopenalex-snapshot
Spectroscopic Evidence of Si−H End Groups in Dialkylpolysilanes Synthesized via Wurtz Coupling
inferred← citeshttps://doi.org/10.1021/ma047847qopenalex-snapshot
Synthesis, Characterization, and Photoluminescence Properties of Asymmetrically Substituted Functional Polysilanes Bearing Carbosilyl Side Chains, −[R(Me)Si]n− and −[R(Ph)Si]n− [R = (CH2)xSiR‘3; x = 2 or 3]
inferred← citeshttps://doi.org/10.1021/ma960407hopenalex-snapshot
Structural, Photophysical, and Conductive Properties of n-Hexyl Substituted Hybrid Polysilylene−Polysilyne Networks
inferred← citeshttps://doi.org/10.1021/ma961322jopenalex-snapshot
Order−Disorder Transition in the Electroactive Polymer Poly(3-dodecylthiophene)
inferred← citeshttps://doi.org/10.1021/ma970872uopenalex-snapshot
Amorphous Poly[(alkoxy-n-alkyl)methylsilane]s and Crystalline Poly[bis(alkoxy-n-alkyl)silane]s: The Effect of Side-Chain Flexibility on the Thermochromic Transition
inferred← citeshttps://doi.org/10.1021/ma980427eopenalex-snapshot
Temperature Dependent CD Spectra of Poly(dihexylsilylene)s with Terminal Chiral Groups. Coupled Cotton Effects of Silicon σ Chains
inferred← citeshttps://doi.org/10.1021/ma981466topenalex-snapshot
A Statistical Model for the Cooperative Thermochromic Transition of Polysilanes
inferred← citeshttps://doi.org/10.1021/ma990001fopenalex-snapshot
Electronic Structures of Polymers Containing Carbon Multiple Bond and Disilane Units in Their Backbone
inferred← citeshttps://doi.org/10.1021/ma990556aopenalex-snapshot
Self-Assembled Micelles of Amphiphilic Polysilane Block Copolymers
inferred← citeshttps://doi.org/10.1021/ma9917803openalex-snapshot
Optical Properties and Dual Electrical and Ionic Conductivity in Poly(3-methylhexa(oxyethylene)oxy-4-methylthiophene)
inferred← citeshttps://doi.org/10.1021/om901104hopenalex-snapshot
Cyclic and Bicyclic Methylpolysilanes and Some Oligosilanylene-Bridged Derivatives
inferred← citeshttps://doi.org/10.1021/om970696dopenalex-snapshot
Correlation of Structure and Molecular Weight Distributions during the Formation of Poly(methylphenylsilylene) by the Wurtz Reductive-Coupling Reaction
inferred← citeshttps://doi.org/10.1021/om990002wopenalex-snapshot
Synthesis, Structure, and Spectroscopic Properties of Perhexyloligosilanes
inferred← citeshttps://doi.org/10.1023/a:1020635323423openalex-snapshot
Heteroatom Polysilylenes
inferred← citeshttps://doi.org/10.1023/a:1021710224530openalex-snapshot
Excitation and Detection Energy Dependence of the Fluorescence of Polysilanes in Dilute Solutions
inferred← citeshttps://doi.org/10.1023/b:silc.0000047943.63883.1eopenalex-snapshot
Synthesis of poly (ethylene oxide)-b-polysilane by anionic polymerization of masked disilenes using a macroinitiator method
inferred← citeshttps://doi.org/10.1039/b302087hopenalex-snapshot
Time-dependent density functional theory treatment of the first UV absorption band in all-transoid permethyloligosilanes SinMe2n+2 (n = 2-8, 10)
inferred← citeshttps://doi.org/10.1039/b613642gopenalex-snapshot
Structurally and conformationally defined small methyl polysilanes
inferred← citeshttps://doi.org/10.1039/c0cc03949gopenalex-snapshot
Nanocrystallization of oligosilanes by a reprecipitation method: easy fabrication of H-aggregates of linear-chain oligosilane molecules
inferred← citeshttps://doi.org/10.1039/c4tc00689eopenalex-snapshot
Stimuli-responsive metallo-supramolecular polymer films: design, synthesis and device fabrication
inferred← citeshttps://doi.org/10.1039/c7dt00384fopenalex-snapshot
Asymmetric charge separation and recombination in symmetrically functionalized σ–π hybrid oligosilanes
inferred← citeshttps://doi.org/10.1063/1.1808908openalex-snapshot
Photobleaching Comparison of Poly(methylphenylsilylene) and Poly(phenylsilyne)
inferred← citeshttps://doi.org/10.1063/1.451312openalex-snapshot
Order–disorder transitions of π-conjugated polymers in condensed phases. I. General theory
inferred← citeshttps://doi.org/10.1063/1.454829openalex-snapshot
Spectral hole burning in polysilanes
inferred← citeshttps://doi.org/10.1063/1.460445openalex-snapshot
A simplified model of oligosilane ionization energies
inferred← citeshttps://doi.org/10.1063/1.462464openalex-snapshot
Poly(di-n-hexyl-silane) in solid solutions: Experimental and theoretical studies of electronic excitations of a disordered linear chain
inferred← citeshttps://doi.org/10.1063/1.467011openalex-snapshot
Theoretical study of the effect of substituent and backbone conformation on the electronic properties of symmetrically substituted poly(di-n-alkylsilanes)
inferred← citeshttps://doi.org/10.1073/pnas.0403209101openalex-snapshot
Magnetic circular dichroism of peralkylated tetrasilane conformers
inferred← citeshttps://doi.org/10.1080/00268949008047850openalex-snapshot
One-Dimensional σ-Conjugated Polysilylenes—Science and Technology
inferred← citeshttps://doi.org/10.1080/02603598608079841openalex-snapshot
Cyclotrisilanes and Related Compounds
inferred← citeshttps://doi.org/10.1080/10408439008242184openalex-snapshot
Chromogenic materials for transmittance control of large-area windows
inferred← citeshttps://doi.org/10.1103/physrevb.39.13350openalex-snapshot
Conformational effects in organopolysilanes: A first-principles approach
inferred← citeshttps://doi.org/10.1103/physrevb.40.7839openalex-snapshot
Electronic properties of polymeric silicon hydrides
inferred← citeshttps://doi.org/10.1103/physrevb.63.073403openalex-snapshot
Temperature dependence of exciton dynamics in poly(di-n-hexylsilane)
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Near-ultraviolet light-emitting diodes based on σ-conjugated linear silicon-backbone polymers
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Positive-Negative Inversion of Silicon Based Resist Materials: Poly(di-n-hexylsilane) for Ion Beam Irradiation
inferred← citeshttps://doi.org/10.1246/bcsj.68.1052openalex-snapshot
Thermochromic Behavior of Polysilanes Concerning the Dependence on the Sequence Length
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The Induction of a Helical Conformation in Polysilanes with an Optically Active Terminal Group
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Remarkable Temperature Dependence of Two-Photon Absorption Spectrum of Poly(dihexylsilylene) in Solution
inferred← citeshttps://doi.org/10.1246/cl.2001.600openalex-snapshot
Synthesis and Unusual Spectral Properties of (Alkoxycarbonyl)methyl-Substituted Polysilanes
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Regulation of Main-Chain Conformation of Permethyldecasilane by Complexation with γ-Cyclodextrin
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Molecular Conformation and Intermolecular Interactions of Linear, Cyclic, and Branched Polymers in Solution by Means of Synchrotron-Radiation Small-Angle X-ray Scattering
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Electrochromic Organic–Metallic Hybrid Polymers: Fundamentals and Device Applications
inferred← citeshttps://doi.org/10.13160/ricns.2011.4.3.177openalex-snapshot
Dehydrocoupling of Bis(1-sila-3-butyl)benzene and 2-Phenyl-1,3-disilapropane to Polymers Using Zirconocene Combination Catalysts
inferred← citeshttps://doi.org/10.13160/ricns.2012.5.2.079openalex-snapshot
Redistribution/Dehydrocoupling of Endocrine n- $Bu_3SnH$ to Polystannanes Catalyzed by Group 4 Metallocene Complexes
inferred← citeshttps://doi.org/10.13160/ricns.2013.6.1.034openalex-snapshot
Disproportionation/Dehydrocoupling of Endocrine Disruptor, Tributyltin Hydride to Polystannanes Using Cp′2TiCl2/N-Selectride (Cp' = Cp' = C5H5, Cp; Me-C5H4, Me-Cp; Me5C5, Cp*) Catalyst
inferred← citeshttps://doi.org/10.2494/photopolymer.18.203openalex-snapshot
Development of Photo-functional Materials from Organic/Inorganic Nano-Hybrids
inferred← citeshttps://doi.org/10.3233/mgc-220100openalex-snapshot
Absorbance and emission studies in solution and the solid state and band gap determination of Pri3Ge(GePh2)4GePri3
inferred← citeshttps://doi.org/10.32920/19911169openalex-snapshot
Preparation of Light and Moisture Stable Flexible and Rigid Asymmetrical Polystannanes
inferred← citeshttps://doi.org/10.32920/19911169.v1openalex-snapshot
Preparation of Light and Moisture Stable Flexible and Rigid Asymmetrical Polystannanes
inferred← citeshttps://doi.org/10.5796/electrochemistry.74.668openalex-snapshot
Electrochemical Synthesis of Poly (cyclotetramethylenesilylene)
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