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Poly(dimethylsiloxane)-Derived Phosphine and Phosphinite Ligands: Synthesis, Characterization, Solubility in Supercritical Carbon Dioxide, and Sequestration on Silica

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Palladium-Catalyzed Coupling Reactions of Aryl Chlorides
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Fluorous Biphasic Catalysis without Perfluorinated Solvents: Application to Pd-Mediated Suzuki and Sonogashira Couplings
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Perfluoroalkyl‐Substituted Arylphosphanes as Ligands for Homogenous Catalysis in Supercritical Carbon Dioxide
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Synthesis and properties of polydimethylsiloxane‐containing block copolymers via living radical polymerization
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Studies of cyclic and linear poly(dimethylsiloxanes): 30. Adsorption studies on silica in solution
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Adsorption study of alkyl-silicas and methylsiloxy-silicas
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The homo and copolymerisation of 2-(dimethylamino)ethyl methacrylate in supercritical carbon dioxide
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Synthesis of a diverse set of phosphorus ligands on solid support and their screening in the Heck reaction
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Use of fluorinated palladium sources for efficient Pd-catalysed coupling reactions in supercritical carbon dioxide
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Palladium catalysed Heck and enantioselective allylic substitution reactions using reverse phase silica supports
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Homogeneous Catalysis in Supercritical Fluids
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Sugar Acetates as Novel, Renewable CO 2 -philes
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The Polymer Incarcerated Method for the Preparation of Highly Active Heterogeneous Palladium Catalysts
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Fluorous Catalysis under Homogeneous Conditions without Fluorous Solvents: A “Greener” Catalyst Recycling Protocol Based upon Temperature-Dependent Solubilities and Liquid/Solid Phase Separation
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Calculation of Adsorption Energy Distributions of Silica Samples Using Nonlinear Chromatography
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Dispersion Polymerizations in Carbon Dioxide Using Siloxane-Based Stabilizers
inferredcites →https://doi.org/10.1021/ol026007yopenalex-snapshot
Peracetylated Sugar Derivatives Show High Solubility in Liquid and Supercritical Carbon Dioxide
inferredcites →https://doi.org/10.1021/om0100028openalex-snapshot
Carbonylated Phosphines as Ligands for Catalysis in Supercritical CO2
inferredcites →https://doi.org/10.1038/35012040openalex-snapshot
Non-fluorous polymers with very high solubility in supercritical CO2 down to low pressures
inferredcites →https://doi.org/10.1038/35085548openalex-snapshot
Thermolysis of fluoropolymers as a potential source of halogenated organic acids in the environment
inferredcites →https://doi.org/10.1039/a802235fopenalex-snapshot
Palladium-catalysed carbon–carbon bond formation in supercritical carbon dioxide
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Palladium-catalyzed cross-coupling reactions in supercritical carbon dioxide
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Palladium-mediated cross-coupling reactions with supported reagents in supercritical carbon dioxideElectronic supplementary information (ESI) available: experimental procedures for the preparation of compounds 4a-c. See http://www.rsc.org/suppdata/cc/b1/b111430a/
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Polyurea-encapsulated palladium(ii) acetate: a robust and recyclable catalyst for use in conventional and supercritical mediaElectronic supplementary information (ESI) available: representative experimental procedures. See http://www.rsc.org/suppdata/cc/b2/b200677b/
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A green protocol for the silylation of alcohols using bonded fluorous phase catalysisThis work was presented at the Green Solvents for Catalysis Meeting, held in Bruchsal, Germany, 13–16th October 2002.
inferredcites →https://doi.org/10.1039/b212386jopenalex-snapshot
Trimethylsilyl-substituted ligands as solubilizers of metal complexes in supercritical carbon dioxide
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Separation, recovery and recycling of a fluorous-tagged nickel catalyst using fluorous solid-phase extractionElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b308543k/
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Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switchElectronic supplementary information (ESI) available: methods of preparation of fluorous silica and complexes 1 and 2. See http://www.rsc.org/suppdata/cc/b3/b311146f/
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A Comprehensive Handbook

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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The Design of Ligand Systems for Immobilisation in Novel Reaction Media
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Synthetic Organic Chemistry in Supercritical Fluids
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Coordination Chemistry of α‐ω‐Bis(pyridylimine) Ligands Containing Flexible Linkers with Copper(I)
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Suzuki–Miyaura Cross‐Coupling Reactions in a Solkane365/227/Ethanol Blend at Ambient Temperature
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(2,2′‐Bipyridine)palladiumdichloride Derivatives as Recyclable Catalysts in Heck Reactions
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Evaluation of Supercritical Carbon Dioxide as a Tuneable Reaction Medium for Homogeneous Catalysis
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Room temperature aerobic oxidation of alcohols using CuBr2 with TEMPO and a tetradentate polymer based pyridyl-imine ligand
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Utilization of supercritical carbon dioxide as green solvent for the Suzuki-Miyaura reaction
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The use of pyridine-functionalised polydimethylsiloxane polymers as a supercritical carbon dioxide solubilising support for copper compounds
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The Suzuki–Miyaura cross-coupling of bromo- and chloroarenes with arylboronic acids in supercritical carbon dioxide
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Synthesis and theoretical analysis of palladium complexes of polydimethylsiloxane functionalised pyridine and their catalytic activity in alcohol oxidations under low polar conditions
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Homogeneous catalysis using supercritical fluids: Recent trends and systems studied
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Non-conventional methodologies for transition-metal catalysed carbon–carbon coupling: a critical overview. Part 1: The Heck reaction
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Non-conventional methodologies for transition-metal catalysed carbon–carbon coupling: a critical overview. Part 2: The Suzuki reaction
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Homogeneous Metal-Based Catalysis in Supercritical Carbon Dioxide as Reaction Medium
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Carbosilane Dendrons as Solubilizers of Metal Complexes in Supercritical Carbon Dioxide
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Methyltrioxorhenium Complexes of Polydimethylsiloxane-Functionalized Pyridine as Efficient Olefin Epoxidation Catalysts in Solventless and Low-Polar Solvent Conditions
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The Potential of Carbon Dioxide in Synthetic Organic Chemistry
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Phosphines and related tervalent phosphorus systems
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Formation and catalytic activity of Pd nanoparticles on silica in supercritical CO2
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Supercritical carbon dioxide, a new medium for aerobic alcohol oxidations catalysed by copper-TEMPO
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18.2.16 Carbon Dioxide, Carbonyl Sulfide, Carbon Disulfide, Isocyanates, Isothiocyanates, Carbodiimides, and Their Selenium, Tellurium, and Phosphorus Analogues (Update 2014)
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A Study of the Heck Reaction in Non-Polar Hydrocarbon Solvents and in Supercritical Carbon Dioxide
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Selective chemical reactions in supercritical carbon dioxide, water, and ionic liquids
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Difunctional phosphorus dendrimer complexes as catalysts in supercritical CO2
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The green chemistry paradigm in modern organic synthesis
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