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Transfer Hydrogenation of Acetophenone Catalyzed by Half-Sandwich Ruthenium(II) Complexes Containing Amino Amide Ligands. Detection of the Catalytic Intermediates by Electrospray Ionization Mass Spectrometry

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Trimerisation of the Cationic Fragments [(η-ring)M(Aa)]+ ((η-ring) M=(η5-C5Me5)Rh, (η5-C5Me5)Ir, (η6-p-MeC6H4iPr)Ru; Aa=α-amino acidate) with Chiral Self-Recognition: Synthesis, Characterisation, Solution Studies and Catalytic Reactions of the Trimers [{(η-ring)M(Aa)}3](BF4)3
inferredcites →https://doi.org/10.1002/1521-3765(20000804)6:15<2818::aid-chem2818>3.0.co;2-qopenalex-snapshot
Chiral Induction Effects in Ruthenium(II) Amino Alcohol Catalysed Asymmetric Transfer Hydrogenation of Ketones: An Experimental and Theoretical Approach
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Probing the Reactivity of Oxomanganese−Salen Complexes: An Electrospray Tandem Mass Spectrometric Study of Highly Reactive Intermediates
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New Auxiliaries for Copper-Catalyzed Asymmetric Michael Reactions: Generation of Quaternary Stereocenters at Room Temperature
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Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones
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CH/π Attraction: The Origin of Enantioselectivity in Transfer Hydrogenation of Aromatic Carbonyl Compounds Catalyzed by Chiralη6-Arene-Ruthenium(II) Complexes
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On the Sense of the Enantioselection in Hydrogen Transfer Reactions from 2-Propanol to Ketones
inferredcites →https://doi.org/10.1002/9780470132524.ch16openalex-snapshot
16. (η 6 ‐Hexamethylbenzene)Ruthenium Complexes
inferredcites →https://doi.org/10.1002/anie.199702851openalex-snapshot
The Catalyst Precursor, Catalyst, and Intermediate in the Ru II ‐Promoted Asymmetric Hydrogen Transfer between Alcohols and Ketones
inferredcites →https://doi.org/10.1002/anie.200200560openalex-snapshot
Electrospray Ionization Tandem Mass Spectrometry in High‐Throughput Screening of Homogeneous Catalysts
inferredcites →https://doi.org/10.1002/aoc.216openalex-snapshot
α‐Amino acid: an effective ligand for asymmetric catalysis of transfer hydrogenation of ketones
inferredcites →https://doi.org/10.1002/aoc.590090304openalex-snapshot
Amino‐Acids, peptides and their derivatives: Powerful chiral ligands for metal‐catalyzed asymmetric syntheses
inferredcites →https://doi.org/10.1002/chem.200305553openalex-snapshot
Highly Enantioselective Ruthenium‐Catalyzed Reduction of Ketones Employing Readily Available Peptide Ligands
inferredcites →https://doi.org/10.1016/0022-328x(84)80341-1openalex-snapshot
Asymmetric synthesis of cyclopropane carboxylates: Catalysis of diazoacetate reactions by copper(II) Schiff base complexes derived from α-amino acids
inferredcites →https://doi.org/10.1016/0223-5234(87)90062-6openalex-snapshot
Asymmetric synthesis, construction of chiral molecules using amino acids
inferredcites →https://doi.org/10.1016/j.tet.2004.01.020openalex-snapshot
Recent development of peptide coupling reagents in organic synthesis
inferredcites →https://doi.org/10.1016/j.tetasy.2004.05.025openalex-snapshot
The importance of 1,2-anti-disubstitution in monotosylated diamine ligands for ruthenium(II)-catalysed asymmetric transfer hydrogenation
inferredcites →https://doi.org/10.1016/s0010-8545(03)00024-9openalex-snapshot
[(Cy)Ru(LL*)Cl] and related half-sandwich compounds—two diastereomers in the same single crystal
inferredcites →https://doi.org/10.1016/s0022-328x(00)89228-1openalex-snapshot
Asymmetric hydrogenation of acetophenone with rhodium(I) complexes of new chiral phosphines derived from amino acids. An unusual modification of the catalyst system
inferredcites →https://doi.org/10.1016/s0022-328x(99)00433-7openalex-snapshot
Enantioselective hydride transfer hydrogenation of ketones catalyzed by [(η6-p-cymene)Ru(amino acidato)Cl] and [(η6-p-cymene)Ru(amino acidato)]3(BF4)3 complexes
inferredcites →https://doi.org/10.1016/s0040-4039(01)00914-5openalex-snapshot
Use of amino amides derived from proline as chiral ligands in the ruthenium(II)-catalyzed transfer hydrogenation reaction of ketones
inferredcites →https://doi.org/10.1016/s0040-4039(01)02132-3openalex-snapshot
Use of surfactants in water-soluble ruthenium(II) complex-catalyzed asymmetric hydrogen-transfer reduction of aromatic ketones
inferredcites →https://doi.org/10.1016/s0040-4039(03)01705-2openalex-snapshot
Nickel complexes from α-amino amides as efficient catalysts for the enantioselective Et2Zn addition to benzaldehyde
inferredcites →https://doi.org/10.1016/s0957-4166(99)00216-5openalex-snapshot
Asymmetric transfer hydrogenation of CO and CN bonds
inferredcites →https://doi.org/10.1021/ar9502341openalex-snapshot
Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes
inferredcites →https://doi.org/10.1021/cr00013a015openalex-snapshot
Asymmetric hydrogen transfer reactions promoted by homogeneous transition metal catalysts
inferredcites →https://doi.org/10.1021/ja00133a037openalex-snapshot
Asymmetric Transfer Hydrogenation of Aromatic Ketones Catalyzed by Chiral Ruthenium(II) Complexes
inferredcites →https://doi.org/10.1021/ja030272copenalex-snapshot
Mechanism of Asymmetric Hydrogenation of Ketones Catalyzed by BINAP/1,2-Diamine−Ruthenium(II) Complexes
inferredcites →https://doi.org/10.1021/ja046157zopenalex-snapshot
Detection of Transient Radical Cations in Electron Transfer-Initiated Diels−Alder Reactions by Electrospray Ionization Mass Spectrometry
inferredcites →https://doi.org/10.1021/ja954126lopenalex-snapshot
Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using a Formic Acid−Triethylamine Mixture
inferredcites →https://doi.org/10.1021/ja971570aopenalex-snapshot
Asymmetric Transfer Hydrogenation of α, β-Acetylenic Ketones
inferredcites →https://doi.org/10.1021/ja980004sopenalex-snapshot
Ziegler−Natta-like Olefin Oligomerization by Alkylzirconocene Cations in an Electrospray Ionization Tandem Mass Spectrometer
inferredcites →https://doi.org/10.1021/ja991638hopenalex-snapshot
The Metal−Ligand Bifunctional Catalysis: A Theoretical Study on the Ruthenium(II)-Catalyzed Hydrogen Transfer between Alcohols and Carbonyl Compounds
inferredcites →https://doi.org/10.1021/jo00218a004openalex-snapshot
L-Cysteine-, L-methionine- and D-penicillamine-derived ligands for transition metal catalyzed carbon-carbon bond-forming reactions
inferredcites →https://doi.org/10.1021/jo970405aopenalex-snapshot
(1R,2S)-(+)-cis-1-Amino-2-indanol: An Effective Ligand for Asymmetric Catalysis of Transfer Hydrogenations of Ketones
inferredcites →https://doi.org/10.1021/jo972082oopenalex-snapshot
(1S,3R,4R)-2-Azanorbornylmethanol, an Efficient Ligand for Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation of Ketones
inferredcites →https://doi.org/10.1021/jo991615lopenalex-snapshot
Versatile Chiral Bidentate Ligands Derived from α-Amino Acids: Synthetic Applications and Mechanistic Considerations in the Palladium-Mediated Asymmetric Allylic Substitutions
inferredcites →https://doi.org/10.1021/jo991914aopenalex-snapshot
2-Azanorbornyl Alcohols: Very Efficient Ligands for Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation of Aromatic Ketones
inferredcites →https://doi.org/10.1021/ol990098qopenalex-snapshot
A Chiral Rhodium Complex for Rapid Asymmetric Transfer Hydrogenation of Imines with High Enantioselectivity
inferredcites →https://doi.org/10.1021/om010644vopenalex-snapshot
Catalysts for the Asymmetric Transfer Hydrogenation of Ketones Derived from l -Prolinamide and (p-CymeneRuCl2)2or (Cp*RhCl2)2
inferredcites →https://doi.org/10.1021/om9903689openalex-snapshot
pH-Dependent Transfer Hydrogenation of Water-Soluble Carbonyl Compounds with [Cp*IrIII(H2O)3]2+(Cp* =η5-C5Me5) as a Catalyst Precursor and HCOONa as a Hydrogen Donor in Water
inferredcites →https://doi.org/10.1039/a908098hopenalex-snapshot
The detection of intermediates in the ruthenium(ii) catalysed asymmetric hydrogenation of ketones using electrospray ionisation mass spectrometry
inferredcites →https://doi.org/10.1039/b106130popenalex-snapshot
The first Ru(II)-catalysed asymmetric hydrogen transfer reduction of aromatic ketones in aqueous media.
inferredcites →https://doi.org/10.1039/b206471eopenalex-snapshot
Novel simple and highly modular ligands for efficient asymmetric transfer-hydrogenation of ketones
inferredcites →https://doi.org/10.1039/b415560bopenalex-snapshot
Aggregation in solution of neutral half-sandwich Ru(ii) precatalysts for transfer hydrogenation
inferredcites →https://doi.org/10.1039/cc9960000233openalex-snapshot
Amino alcohol effects on the ruthenium(II)-catalysed asymmetric transfer hydrogenation of ketones in propan-2-ol
inferredcites →https://doi.org/10.1039/p19870000071openalex-snapshot
Asymmetric oxidation of sulphides to sulphoxides catalysed by titanium complexes of N-salicylidene-L-amino acids
inferredcites →https://doi.org/10.1055/s-1991-20798openalex-snapshot
Asymmetric Cyanosilylation of Aldehydes Promoted by a Novel Chiral Lewis Acid, Organoaluminum Complex of Acyclic Dipeptide Esters or α-Amino Amides Containing a Phenolic Schiff Base
inferredcites →https://doi.org/10.1246/cl.1985.391openalex-snapshot
STERIC EFFECTS OF CHIRAL LIGANDS IN A NEW TYPE OF ALDOL CONDENSATIONS CATALYZED BY ZINC(II) COMPLEXES OF α-AMINO ACID ESTERS
inferredcites →https://doi.org/10.1246/cl.1998.491openalex-snapshot
α-Amino acidate-Ru(II) Catalysts for Asymmetric Transfer Hydrogenation: First Utilization of α-Amino Acids as an Efficient Ligand

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Temperature‐tuned enantioselectivity in transfer hydrogenation: preparation and catalytic property of amino acid‐modified benzimidazole
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Novel cyclohexyl‐based aminophosphine ligands and use of their Ru(II) complexes in transfer hydrogenation of ketones
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Transfer hydrogenation of aryl ketones with homogeneous ruthenium catalysts containing diazafluorene ligands
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Some Novel Dinuclear phenylboronates of biologically potent β‐enaminoesters: Synthesis, Spectroscopic characterization, antimicrobial activity and their antiandrogenic effect
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Expanding the Chemical Diversity in Artificial Imine Reductases Based on the Biotin–Streptavidin Technology
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Double Stereodifferentiation in the Catalytic Asymmetric Aziridination of Imines Prepared from α‐Chiral Amines
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Structural analysis of organometallic compounds with soft ionization mass spectrometry
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Ru(II)‐ η 6 ‐benzene Complexes of Dibenzosuberenyl Appended Aroyl/Acylthiourea Ligands: In vitro Biomolecular Interaction Studies and Catalytic Transfer Hydrogenation
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Pd-Catalyzed asymmetric transformations involving P*-mono- and P*,N-bidentate diamidophosphites derived from (2S,3S)-N 2,3-dimethyl-N 1-phenylpentane-1,2-diamine
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Half-sandwich ruthenium(II) complexes containing 4-substituted aniline derivatives: structural characterizations and catalytic properties in transfer hydrogenation of ketones
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Polymer-supported chiral α-amino amides for the asymmetric addition of diethylzinc to aldehydes: Transforming an inactive homogeneous system into an efficient catalyst
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Catalytic performance of Ru(0) nanoparticles supported on K-OMS-2 in transfer hydrogenation reactions
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NMR investigation of non-covalent aggregation of coordination compounds ranging from dimers and ion pairs up to nano-aggregates
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The application of electrospray ionization mass spectrometry to homogeneous catalysis
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Screening of a library of hemisalen ligands in asymmetric H-transfer: Reduction of aromatic ketones in water
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Tetracoordinate diamidato-bis(phosphanyl) metal systems: Synthesis, characterization, and electrochemical analysis of palladium(II) complexes
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trans- and cis-Ru(II) aminophosphine complexes: Syntheses, X-ray structures and catalytic activity in transfer hydrogenation of acetophenone derivatives
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Diamidato-bis(diphenylphosphino) platinum(II) complexes: Synthesis, characterization, and reactivity in the presence of acid
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Investigation of photocatalytic and catalytic activity of g-C3N4/TiO2 supported Ru(0) nanoparticles in transfer hydrogenation reaction of various ketones
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1,8-Bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene: An electrospray-active analogue for η6-coordinating ligands
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Applications of transition metal complexes containing 3,3′-bis(diphenylphosphinoamine)-2,2′-bipyridine ligand to transfer hydrogenation of ketones
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Synthesis of half-sandwich ruthenium(II) and iridium(III) complexes containing imidazole-based phosphinite ligands and their use in catalytic transfer hydrogenation of acetophenone with isopropanol
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Novel neutral phosphinite bridged dinuclear ruthenium(II) arene complexes and their catalytic use in transfer hydrogenation of aromatic ketones: X-ray structure of a new Schiff base, N3,N3′-di-2-hydroxybenzylidene-[2,2′]bipyridinyl-3,3′-diamine
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Ruthenium-catalyzed transfer hydrogenation of aromatic ketones with aminophosphine or bis(phosphino)amine ligands derived from isopropyl substituted anilines
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Ruthenium complexes of aminophosphine ligands and their use as pre-catalysts in the transfer hydrogenation of aromatic ketones: X-ray crystal structure of thiophene-2-(N-diphenylthiophosphino)methylamine
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Ionic liquid based Ru(II)–phosphinite compounds and their catalytic use in transfer hydrogenation: X-ray structure of an ionic compound 1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-ol
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A new phosphazene derivative, spiro-N3P3[(O2C12H8)2(OC6H6N-3)2], and its Ru(II) complex: Syntheses, crystal structure, catalytic activity and antimicrobial activity studies
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A ruthenium(II) bipyridine complex containing a 4,5-diazafluorene moiety: Synthesis, characterization and its applications in transfer hydrogenation of ketones and dye sensitized solar cells
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Synthesis, spectroscopic and catalytic properties of some new boron hybrid molecule derivatives by BF2 and BPh2 chelation
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C2 symmetrical nickel complexes derived from α-amino amides as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes
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A modular design of ruthenium(II) catalysts with chiral C2-symmetric phosphinite ligands for effective asymmetric transfer hydrogenation of aromatic ketones
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Development of P∗-monodentate diamidophosphites with a C1-symmetric 1,2-diamine backbone: the effects of substituents in the 1,3,2-diazaphospholidine cycle on Pd-catalyzed asymmetric allylations
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Enantioselective nickel-catalyzed conjugate addition of dialkylzinc to chalcones using chiral α-amino amides
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Fine-tuning catalytic activity and selectivity—[Rh(amino acid thioamide)] complexes for efficient ketone reduction
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Visual chiral recognition of mandelic acid and α-amino acid derivatives by enantioselective gel formation and precipitation
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6b01028openalex-snapshot
Troponate/Aminotroponate Ruthenium–Arene Complexes: Synthesis, Structure, and Ligand-Tuned Mechanistic Pathway for Direct C–H Bond Arylation with Aryl Chlorides in Water
inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b04179openalex-snapshot
Indirect Detection of Short-Lived Hydride Intermediates of Iridium N-Heterocyclic Carbene Complexes via Chemical Exchange Saturation Transfer Spectroscopy
inferred← citeshttps://doi.org/10.1021/acscatal.6b00623openalex-snapshot
ESI-MS Insights into Acceptorless Dehydrogenative Coupling of Alcohols
inferred← citeshttps://doi.org/10.1021/ic201343wopenalex-snapshot
Synthesis, Reactivity Studies, Structural Aspects, and Solution Behavior of Half Sandwich Ruthenium(II)N,N′,N″-Triarylguanidinate Complexes
inferred← citeshttps://doi.org/10.1021/jo061154lopenalex-snapshot
The “Reverse-Tethered” Ruthenium (II) Catalyst for Asymmetric Transfer Hydrogenation: Further Applications
inferred← citeshttps://doi.org/10.1021/jo501273topenalex-snapshot
Ruthenium-Catalyzed N-Alkylation of Amines with Alcohols under Mild Conditions Using the Borrowing Hydrogen Methodology
inferred← citeshttps://doi.org/10.1021/jo802611topenalex-snapshot
Synthesis of a Fluorine-Substituted Puromycin Derivative for Brønsted Studies of Ribosomal-Catalyzed Peptide Bond Formation
inferred← citeshttps://doi.org/10.1021/ol062227qopenalex-snapshot
Enantioswitchable Catalysts for the Asymmetric Transfer Hydrogenation of Aryl Alkyl Ketones
inferred← citeshttps://doi.org/10.1021/om3001394openalex-snapshot
Half-Sandwich Complexes of Osmium(II) with l -α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity
inferred← citeshttps://doi.org/10.1021/om4010548openalex-snapshot
Chiral (η6-p-Cymene)ruthenium(II) Complexes Containing Monodentate Acylthiourea Ligands for Efficient Asymmetric Transfer Hydrogenation of Ketones
inferred← citeshttps://doi.org/10.1021/om700775uopenalex-snapshot
From Ion Pairs to Ion Triples through a Hydrogen Bonding-Driven Aggregative Process
inferred← citeshttps://doi.org/10.1021/om8009969openalex-snapshot
Reactivity, Structures, and NMR Spectroscopy of Half-Sandwich Pentamethylcyclopentadienyl Rhodium Amido Complexes Relevant to Transfer Hydrogenation
inferred← citeshttps://doi.org/10.1021/om9001268openalex-snapshot
Base-Free Transfer Hydrogenation of Ketones Using Arene Ruthenium(II) Complexes
inferred← citeshttps://doi.org/10.1039/c0ob00400fopenalex-snapshot
Asymmetric transfer hydrogenation of ketones catalyzed by rhodium complexes containing amino acid triazole ligands
inferred← citeshttps://doi.org/10.1039/c3dt51275dopenalex-snapshot
Synthesis, characterisation and biological activities of [(p-cym)RuX(pz4lut)]n+ and [{(p-cym)RuX}2(μ-pz4lut)]n+ (X = Cl, H2O and pz4lut = α,α,α′,α′-tetra(pyrazol-1-yl)-2,6-lutidine)
inferred← citeshttps://doi.org/10.1039/c4ra15341copenalex-snapshot
Dual stereocontrolled alkylation of aldehydes with polystyrene-supported nickel complexes derived from α-amino amides
inferred← citeshttps://doi.org/10.1039/c6ob01878eopenalex-snapshot
Mechanistic implications of the enantioselective addition of alkylzinc reagents to aldehydes catalyzed by nickel complexes with α-amino amide ligands
inferred← citeshttps://doi.org/10.1039/c6ra12428copenalex-snapshot
Ru( ii )-p-cymene complexes containing esters of chiral d / l -phenylalanine derived aroylthiourea ligands for enantioselective reduction of pro-chiral ketones
inferred← citeshttps://doi.org/10.1039/c7ra04152gopenalex-snapshot
Syntheses, characterisation, and catalytic role of (η 5 -C 5 Me 5 )Rh( iii ) guanidinato complexes in transfer hydrogenation (TH) and TH–etherification
inferred← citeshttps://doi.org/10.1039/c9ra08736bopenalex-snapshot
Anticancer and antimicrobial properties of novel η 6 - p -cymene ruthenium( ii ) complexes containing a N,S-type ligand, their structural and theoretical characterization
inferred← citeshttps://doi.org/10.1080/00958972.2017.1300659openalex-snapshot
Developments in transfer hydrogenations of aromatic ketones catalyzed by boron compounds
inferred← citeshttps://doi.org/10.1080/00958972.2022.2054339openalex-snapshot
Ketone transfer hydrogenation reactions catalyzed by catalysts based on a phosphinite ligand
inferred← citeshttps://doi.org/10.1080/10426507.2014.966190openalex-snapshot
Synthesis of Tetranuclear Ruthenium (Ii) Complex of Pyridyloxy-Substituted 2,2′-Dioxybiphenyl-Cyclotriphosphazene Platform and its Catalytic Application in the Transfer Hydrogenation of Ketones
inferred← citeshttps://doi.org/10.1080/10426507.2021.1948852openalex-snapshot
Hg(II) and Ru(II) complexes of mono- and dichalcogenides of bis(diphenylphosphino)amine chelating ligands: Synthesis, characterization and catalytic activity in transfer hydrogenation of acetophenone derivatives
inferred← citeshttps://doi.org/10.1080/15533174.2012.751421openalex-snapshot
Synthesis and Catalytic Activity of Semiconducting p-Cymene Ruthenium 1,3,4-Thiadiazole and 1,2,4-Triazole Complexes
inferred← citeshttps://doi.org/10.1515/mgmc-2015-0023openalex-snapshot
Some heteroleptic boron derivatives and their isomers derived from Schiff bases and glycol: synthesis, characterization and antimicrobial activities
inferred← citeshttps://doi.org/10.2174/1876214x01003010030openalex-snapshot
Transfer Hydrogenation of Ketones Using Recyclable (η6-Arene) Ruthenium(II) Naphthylazo-p-Methyl Phenolate Complex~!2009-08-25~!2009-10-14~!2010-03-30~!
inferred← citeshttps://doi.org/10.3390/molecules25112501openalex-snapshot
An Efficient Greener Approach for N-acylation of Amines in Water Using Benzotriazole Chemistry
inferred← citeshttps://doi.org/10.3906/kim-1506-15openalex-snapshot
The role of N-heterocyclic carbene substituents on ruthenium(II) complexes in the catalytic transfer hydrogenation of acetophenone
inferred← citeshttps://doi.org/10.3987/com-09-11863openalex-snapshot
Synthesis of Optically Active γ-Valerolactone and γ-Nonanolactone via Optical Resolution Using Chiral Amine Derived from Amino Acid
inferred← citeshttps://doi.org/10.4236/mrc.2014.33010openalex-snapshot
The Nature of the True Catalyst in Transfer Hydrogenation with Alcohol Donors Using (arene)2Ru2Cl4(II)/TsDPEN Precursor
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