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Formation and Role of Palladium Chalcogenide and Other Species in Suzuki–Miyaura and Heck C–C Coupling Reactions Catalyzed with Palladium(II) Complexes of Organochalcogen Ligands: Realities and Speculations

https://doi.org/10.1021/om4007196
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Pincer Thioamide and Pincer Thioimide Palladium Complexes Catalyze Highly Efficient Negishi Coupling of Primary and Secondary Alkyl Zinc Reagents at Room Temperature
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Air‐Stable Platinum and Palladium Complexes Featuring Bis[2,4‐bis(trifluoromethyl)phenyl]phosphinous Acid Ligands
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New Palladium Complexes with S‐ or Se‐Containing Schiff‐Base Ligands as Efficient Catalysts for the Suzuki–Miyaura Cross‐Coupling Reaction of Aryl Bromides with Phenylboronic Acid under Aerobic Conditions
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Cyclometallated Pd(II) thiosemicarbazone complexes: new catalyst precursors for Suzuki-coupling reactions
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On the use of phosphine-free PdCl2(SEt2)2 complex as catalyst precursor for the Heck reaction
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Dinuclear pincer-palladium(II) complexes and their use as homogeneous or heterogeneous catalyst for the aldol reaction of methyl isocyanoacetate
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A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions
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Colloidal Chemical Synthesis and Formation Kinetics of Uniformly Sized Nanocrystals of Metals, Oxides, and Chalcogenides
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Cross Coupling
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Anionic Pd(0) and Pd(II) Intermediates in Palladium-Catalyzed Heck and Cross-Coupling Reactions
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Synthesis and Applications of Palladium-Coated Poly(vinylpyridine) Nanospheres
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Additional Investigations of a New Kinetic Method To Follow Transition-Metal Nanocluster Formation, Including the Discovery of Heterolytic Hydrogen Activation in Nanocluster Nucleation Reactions
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The Potential of Palladacycles: More Than Just Precatalysts
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Ditopic Double Pincer Palladacycle Catalyst for C−C Coupling
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Thioamide Pincer Ligands with Charge Versatility
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Mizoroki−Heck Coupling Using Immobilized Molecular Precatalysts: Leaching Active Species from Pd Pincers, Entrapped Pd Salts, and Pd NHC Complexes
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Palladium Nanoparticles as Efficient Green Homogeneous and Heterogeneous Carbon−Carbon Coupling Precatalysts: A Unifying View
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Highly Air-Stable Anionic Mononuclear and Neutral Binuclear Palladium(II) Complexes for C−C and C−N Bond-Forming Reactions
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Palladium-Catalyzed C−C Coupling under Thermomorphic Conditions
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Three-phase test for reactive intermediates. Cyclobutadiene
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Three-phase test for reaction intermediates. Nucleophilic catalysis and elimination reactions
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Nonpolar Polymers for Metal Sequestration and Ligand and Catalyst Recovery in Thermomorphic Systems
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Are Heterogeneous Catalysts Precursors to Homogeneous Catalysts?
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Effect of Catalysis on the Stability of Metallic Nanoparticles: Suzuki Reaction Catalyzed by PVP-Palladium Nanoparticles
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The Role of Pd Nanoparticles in Ionic Liquid in the Heck Reaction
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Mercaptopropyl-Modified Mesoporous Silica: A Remarkable Support for the Preparation of a Reusable, Heterogeneous Palladium Catalyst for Coupling Reactions
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Transition Metal Nanocluster Formation Kinetic and Mechanistic Studies. A New Mechanism When Hydrogen Is the Reductant: Slow, Continuous Nucleation and Fast Autocatalytic Surface Growth
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Tridentate SCS Palladium(II) Complexes: New, Highly Stable, Recyclable Catalysts for the Heck Reaction
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On the Nature of the ‘Heterogeneous' Catalyst: Nickel-on-Charcoal
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Oxime Carbapalladacycle Covalently Anchored to High Surface Area Inorganic Supports or Polymers as Heterogeneous Green Catalysts for the Suzuki Reaction in Water
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Palladium Nanoparticles as Efficient Catalysts for Suzuki Cross-Coupling Reactions
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A Catalytic Probe of the Surface of Colloidal Palladium Particles Using Heck Coupling Reactions
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Sulfur-Containing Palladacycles as Catalyst Precursors for the Heck Reaction
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Sulfur-Containing Palladacycles: Efficient Phosphine-Free Catalyst Precursors for the Suzuki Cross-Coupling Reaction at Room Temperature
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Tandem Catalysis and Self-Assembly: A One-Pot Approach to Functionalized Polymers
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Homeopathic Ligand-Free Palladium as a Catalyst in the Heck Reaction. A Comparison with a Palladacycle
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Selenium-Ligated Palladium(II) Complexes as Highly Active Catalysts for Carbon−Carbon Coupling Reactions: The Heck Reaction
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Synthesis of Novel Palladacycles and Their Application in Heck and Suzuki Reactions under Aerobic Conditions
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Highly Efficient and Reusable Supported Pd Catalysts for Suzuki−Miyaura Reactions of Aryl Chlorides
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pH-Dependent Cross-Coupling Reactions of Water-Soluble Organic Halides with Organoboron Compounds Catalyzed by the Organometallic Aqua Complex [(SCS)PdII(H2O)]+ (SCS = C6H3-2,6-(CH2SBut)2)
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Investigations into the Stability of Tethered Palladium(II) Pincer Complexes during Heck Catalysis
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pH-Dependent C−C Coupling Reactions Catalyzed by Water-Soluble Palladacyclic Aqua Catalysts in Water
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1,1‘-P/O-Ferrocenyl Ligands in Palladium-Catalyzed Suzuki Coupling of Aryl Chlorides
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1-Indenyldialkylphosphines and Cyclopentadienyldialkylphosphines as Ligands for High-Activity Palladium-Catalyzed Cross-Coupling Reactions with Aryl Chlorides
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Thioether-Functionalized N-Heterocyclic Carbenes: Mono- and Bis-( S , C NHC ) Palladium Complexes, Catalytic C−C Coupling, and Characterization of a Unique Ag 4 I 4 ( S , C NHC ) 2 Planar Cluster
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Dinuclear and Tetranuclear Palladium(II) Complexes of a Thiolato-Functionalized, Benzannulated N-Heterocyclic Carbene Ligand and Their Activities toward Suzuki−Miyaura Coupling
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Hybrid Thiophosphoryl–Benzothiazole Palladium SCN-Pincer Complexes: Synthesis and Effect of Structure Modifications on Catalytic Performance in the Suzuki Cross-Coupling
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Preparation of New Buchwald-Type Secondary Phosphine Oxide Ligands and Applications in Suzuki−Miyaura Reactions
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Toward the Ideal Catalyst: From Atomic Centers to a “Cocktail” of Catalysts
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Chalcogen-Dependent Palladation at the Benzyl Carbon of 2,3-Bis[(phenylchalcogeno)methyl]quinoxaline: Palladium Complexes Catalyzing Suzuki–Miyaura Coupling via Palladium–Chalcogen Nanoparticles
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Half-Sandwich Ruthenium(II) Complexes of Click Generated 1,2,3-Triazole Based Organosulfur/-selenium Ligands: Structural and Donor Site Dependent Catalytic Oxidation and Transfer Hydrogenation Aspects
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Selenium-Containing N-Heterocyclic Carbenes and Their First Palladium(II) Complexes: Synthesis, Structure, and Pendent Alkyl Chain Length Dependent Catalytic Activity for Suzuki–Miyaura Coupling
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Palladacycles of Thioethers Catalyzing Suzuki–Miyaura C–C Coupling: Generation and Catalytic Activity of Nanoparticles
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Hetero-multimetallic Tetrakis(SCS-pincer palladium)−(Metallo)porphyrin Hybrids. Tunable Precatalysts in a Heck Reaction
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inferredcites →https://doi.org/10.1021/om900570gopenalex-snapshot
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inferredcites →https://doi.org/10.1021/om900984topenalex-snapshot
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inferredcites →https://doi.org/10.1039/a908133jopenalex-snapshot
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inferredcites →https://doi.org/10.1039/b200617kopenalex-snapshot
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inferredcites →https://doi.org/10.1039/c2dt12113aopenalex-snapshot
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inferredcites →https://doi.org/10.1039/dt9800002312openalex-snapshot
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inferredcites →https://doi.org/10.1351/pac200476030565openalex-snapshot
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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1021/acsomega.0c02403openalex-snapshot
Synthesis of Nanosheets Containing Uniformly Dispersed PdII Ions at an Aqueous/Aqueous Interface: Development of a Highly Active Nanosheet Catalyst for Mizoroki–Heck Reaction
inferred← citeshttps://doi.org/10.1021/acsomega.3c02769openalex-snapshot
Synthesis of Selenocyanates and Selenoethers of Amino Pyrazoles and Amino Uracils by In Situ Triselenium Dicyanide from Malononitrile and Selenium Dioxide
inferred← citeshttps://doi.org/10.1021/jo402661bopenalex-snapshot
Synthesis of Selenazoles by in Situ Cycloisomerization of Propargyl Selenoamides Using Oxygen–Selenium Exchange Reaction
inferred← citeshttps://doi.org/10.1021/om500714copenalex-snapshot
Synthesis of Rhodium–Primary Thioamide Complexes and Their Desulfurization Leading to Rhodium Sulfido Cubane-Type Clusters and Nitriles
inferred← citeshttps://doi.org/10.1021/om5008924openalex-snapshot
Palladacycle from Cyclometalation of the Unsubstituted Cyclopentadienyl Ring in Ferrocene: Synthesis, Characterization, Theoretical Studies, and Application to Suzuki–Miyaura Reaction
inferred← citeshttps://doi.org/10.1021/om5012038openalex-snapshot
(N-Heterocyclic Carbene)-Palladate Complexes in Anionic Mizoroki–Heck Coupling Cycles: A Combined Experimental and Computational Study
inferred← citeshttps://doi.org/10.1039/c4dt01396dopenalex-snapshot
Shape dependent catalytic activity of nanoflowers and nanospheres of Pd 4 S generated via one pot synthesis and grafted on graphene oxide for Suzuki coupling
inferred← citeshttps://doi.org/10.1039/c4dt03471fopenalex-snapshot
Palladium( ii )-1-phenylthio-2-arylchalcogenoethane complexes: palladium phosphide nano-peanut and ribbon formation controlled by chalcogen and Suzuki coupling activation
inferred← citeshttps://doi.org/10.1039/c4ra09574jopenalex-snapshot
Palladium( ii ) complexes bearing the 1,2,3-triazole based organosulfur/ selenium ligand: synthesis, structure and applications in Heck and Suzuki–Miyaura coupling as a catalyst via palladium nanoparticles
inferred← citeshttps://doi.org/10.1039/c4ra16584eopenalex-snapshot
Insight into luminescent bisazoaromatic CNN pincer palladacycle: synthesis, structure, electrochemistry and some catalytic applications in C–C coupling
inferred← citeshttps://doi.org/10.1039/c5dt00197hopenalex-snapshot
Polydentate chalcogen reagents for the facile preparation of Pd 2 and Pd 4 complexes
inferred← citeshttps://doi.org/10.1039/c5dt00438aopenalex-snapshot
Exhibition of the Brønsted acid–base character of a Schiff base in palladium( ii ) complex formation: lithium complexation, fluxional properties and catalysis of Suzuki reactions in water
inferred← citeshttps://doi.org/10.1039/c5dt01565kopenalex-snapshot
Bis(chalcogenones) as pincer ligands: isolation and Heck activity of the selone-ligated unsymmetrical C,C,Se–Pd pincer complex
inferred← citeshttps://doi.org/10.1039/c6dt00060fopenalex-snapshot
Palladacycles of unsymmetrical (N,C − ,E) (E = S/Se) pincers based on indole: their synthesis, structure and application in the catalysis of Heck coupling and allylation of aldehydes
inferred← citeshttps://doi.org/10.1039/c7dt01279aopenalex-snapshot
Palladium( ii ) complexes of N,N-diphenylacetamide based thio/selenoethers and flower shaped Pd 16 S 7 and prismatic Pd 17 Se 15 nano-particles tailored as catalysts for C–C and C–O coupling
inferred← citeshttps://doi.org/10.1039/c7nj00452dopenalex-snapshot
Development of (quinolinyl)amido-based pincer palladium complexes: a robust and phosphine-free catalyst system for C–H arylation of benzothiazoles
inferred← citeshttps://doi.org/10.1039/d0dt01201gopenalex-snapshot
Organochalcogen ligands in catalysis of oxidation of alcohols and transfer hydrogenation
inferred← citeshttps://doi.org/10.1039/d1dt04371dopenalex-snapshot
Organosulphur and organoselenium compounds as emerging building blocks for catalytic systems for O -arylation of phenols, a C–O coupling reaction
inferred← citeshttps://doi.org/10.1039/d1nj02971aopenalex-snapshot
Organosulfur, organoselenium, and organotellurium ligands in the development of palladium, nickel, and copper-based catalytic systems for Heck coupling
inferred← citeshttps://doi.org/10.1039/d2dt02558bopenalex-snapshot
Organosulphur, organoselenium and organotellurium compounds for the development of heterogeneous and nanocatalytic systems for Suzuki coupling
inferred← citeshttps://doi.org/10.1039/d2nj00924bopenalex-snapshot
Experimental and theoretical insights into the trans influence of organo-sulfur and -selenium ligands in 5,6-membered palladium( ii ) cationic pincer complexes based on iminophosphoranes
inferred← citeshttps://doi.org/10.1039/d2nj02364dopenalex-snapshot
Click chemistry in the synthesis of catalytically relevant organoselenium compounds: development and applications of catalysts for organic synthesis
inferred← citeshttps://doi.org/10.1039/d2nj04408kopenalex-snapshot
Metal-metalloid bond containing complexes of the bulky organotellurium ligand: applications in catalysis of C–O coupling and aldehyde to amide transformation reactions
inferred← citeshttps://doi.org/10.1039/d2nj04812dopenalex-snapshot
On the coordination behaviour of diorganoselenium ligands based on amino and azole functionalities: silver( i ) complexes with relevance for biological applications
inferred← citeshttps://doi.org/10.1039/d2nj05357hopenalex-snapshot
Palladium( ii )-complexes of bi- and tri-dentate phosphine ligands: precursor for palladium–phosphorous nanoparticles and activity towards Suzuki–Miyaura coupling
inferred← citeshttps://doi.org/10.1039/d3ra04690gopenalex-snapshot
Diastereospecific arylation and cascade deconstructive amidation/thioesterification of readily available lactam-fused bromolactones
inferred← citeshttps://doi.org/10.1039/d4dd00099dopenalex-snapshot
OM-Diff: inverse-design of organometallic catalysts with guided equivariant denoising diffusion
inferred← citeshttps://doi.org/10.1039/d4ob00552jopenalex-snapshot
Organosulphur and organoselenium compounds as ligands for catalytic systems in the Sonogashira coupling
inferred← citeshttps://doi.org/10.1039/d4ra03401eopenalex-snapshot
Catalytic system having an organotellurium ligand on graphene oxide: immobilization of Pd(0) nanoparticles and application in heterogeneous catalysis of cross-coupling reactions
inferred← citeshttps://doi.org/10.1039/d5na00364dopenalex-snapshot
A nanomagnetic triazole-based Schiff-base complex of palladium(0) as an efficient heterogeneous catalyst for the Mizoroki–Heck C–C cross-coupling reaction under green conditions
inferred← citeshttps://doi.org/10.1039/d5na01048aopenalex-snapshot
A novel palladium-2-picolylamine complex grafted on magnetic UiO-66-NH 2 nanocomposites: as an efficient heterogeneous catalyst for fast Suzuki–Miyaura cross coupling
inferred← citeshttps://doi.org/10.1039/d5nj00754bopenalex-snapshot
Anthracene and pyrene appended Schiff bases having a ( N , N ) donor for the synthesis of highly stable colloidal silver nano-particles: application in selective sensing and nitroarene reduction
inferred← citeshttps://doi.org/10.1055/s-0040-1707515openalex-snapshot
Aqueous Suzuki–Miyaura Coupling with Ultralow Palladium Loading and Simple Product Separation
inferred← citeshttps://doi.org/10.1055/s-0040-1720131openalex-snapshot
Tellurenated Compounds: Synthesis and Application in Ion Detection and as a Catalyst
inferred← citeshttps://doi.org/10.1080/10406638.2021.1874429openalex-snapshot
Microwave-Assisted Synthesis of 2-Aryl and 2,5-Diarylthiophene DerivativesviaSuzuki-Miyaura Cross-Coupling Using Novel Palladium Complex as a Catalyst
inferred← citeshttps://doi.org/10.1080/10426507.2022.2119237openalex-snapshot
Organoselenium compounds. Synthesis, application, and biological activity
inferred← citeshttps://doi.org/10.1155/2014/578762openalex-snapshot
Facile Synthesis of Pyrazole- and Benzotriazole-Containing Selenoethers
inferred← citeshttps://doi.org/10.21203/rs.3.rs-7546711/v1openalex-snapshot
Formamidinyl Thiazole-Based Palladium Complexes as Efficient Nano-sized Catalysts for Aqueous Suzuki –Miyaura Cross-Couplings
inferred← citeshttps://doi.org/10.2174/1570193x18666211215145005openalex-snapshot
Suzuki-Miyaura Coupling: A Field of Uninterrupted Research Since 1979
inferred← citeshttps://doi.org/10.2174/2210298101666210922144232openalex-snapshot
Metal Nanoparticles: Ligand-Free Approach Towards Coupling Reactions
inferred← citeshttps://doi.org/10.3390/books978-3-0365-2576-1openalex-snapshot
Transition Metal Catalyzed Cross-Coupling Reactions
inferred← citeshttps://doi.org/10.3390/catal10101107openalex-snapshot
Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions
inferred← citeshttps://doi.org/10.3390/catal7010035openalex-snapshot
The Use of Palladium on Magnetic Support as Catalyst for Suzuki–Miyaura Cross-Coupling Reactions
inferred← citeshttps://doi.org/10.3390/catal7090267openalex-snapshot
Heck Reaction—State of the Art
inferred← citeshttps://doi.org/10.3762/bjoc.10.299openalex-snapshot
A novel 4-aminoantipyrine-Pd(II) complex catalyzes Suzuki–Miyaura cross-coupling reactions of aryl halides
inferred← citeshttps://doi.org/10.3762/bjoc.13.166openalex-snapshot
An effective Pd nanocatalyst in aqueous media: stilbene synthesis by Mizoroki–Heck coupling reaction under microwave irradiation
inferred← citeshttps://doi.org/10.3762/bjoc.14.160openalex-snapshot
Water-soluble SNS cationic palladium(II) complexes and their Suzuki–Miyaura cross-coupling reactions in aqueous medium
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