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Complete Characterization of a Chiral Lewis Acid−Product Complex for the Enantioselective Diels−Alder Reaction between Methacrolein and Cyclopentadiene: Mechanistic Considerations

https://doi.org/10.1021/om700717e
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Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/(sici)1521-3773(19990503)38:9<1219::aid-anie1219>3.0.co;2-dopenalex-snapshot
A Stable and Recoverable Chiral Ru Lewis Acid: Synthesis, Asymmetric Diels–Alder Catalysis and Structure of the Lewis Acid Methacrolein Complex
inferredcites →https://doi.org/10.1016/s0040-4039(00)60902-4openalex-snapshot
The structure of the 2-methylacrolein boron trifluoride complex in the crystalline phase and in solution
inferredcites →https://doi.org/10.1016/s0040-4039(00)96814-xopenalex-snapshot
Stereochemical aspects of asymmetric diels-alder reaction catalyzed by chiral alkoxyaluminum dichlorides
inferredcites →https://doi.org/10.1021/ja00042a015openalex-snapshot
Homogeneous catalysis: a ruthenium-based Lewis-acid catalyst for the Diels-Alder reaction
inferredcites →https://doi.org/10.1021/ja00047a051openalex-snapshot
Synthesis and DNA binding properties of a cisplatin analog containing a tethered dansyl group
inferredcites →https://doi.org/10.1021/ja00061a012openalex-snapshot
Spectroscopic studies on the structure and conformation of Lewis acid-aldehyde complexes
inferredcites →https://doi.org/10.1021/ja00855a063openalex-snapshot
Demonstration of controlled asymmetric induction in organoiron chemistry. Suggestions concerning the specification of chirality in pseudotetrahedral metal complexes containing polyhapto ligands
inferredcites →https://doi.org/10.1021/ja031995zopenalex-snapshot
The Complete Characterization of a Rhodium Lewis Acid−Dipolarophile Complex as an Intermediate for the Enantioselective Catalytic 1,3-Dipolar Cycloaddition of C,N-Diphenylnitrone to Methacrolein
inferredcites →https://doi.org/10.1021/ja0539443openalex-snapshot
Enantioselective 1,3-Dipolar Cycloaddition of Nitrones to Methacrolein Catalyzed by (η5-C5Me5)M{(R)-Prophos} Containing Complexes (M = Rh, Ir; (R)-Prophos = 1,2-bis(Diphenylphosphino)propane): On the Origin of the Enantioselectivity
inferredcites →https://doi.org/10.1021/ja991190kopenalex-snapshot
Chiral Bis(oxazoline)copper(II) Complexes as Lewis Acid Catalysts for the Enantioselective Diels−Alder Reaction
inferredcites →https://doi.org/10.1021/jo00268a001openalex-snapshot
Chiral (acyloxy)borane (CAB): a powerful and practical catalyst for asymmetric Diels-Alder reactions
inferredcites →https://doi.org/10.1021/jo062200kopenalex-snapshot
Conformational Preferences of Methacrolein in Diels−Alder and 1,3-Dipolar Cycloaddition Reactions
inferredcites →https://doi.org/10.1039/a705605bopenalex-snapshot
Chiral ruthenium complexes as catalysts in enantioselective Diels–Alder reactions. Crystal structure of the Lewis acid–dienophile adduct
inferredcites →https://doi.org/10.1039/b006530gopenalex-snapshot
Arene ruthenium complexes with pyridyloxazolines: synthesis and applications as asymmetric catalysts for Diels–Alder reactions †
inferredcites →https://doi.org/10.1039/c39790000437openalex-snapshot
Asymmetric Diels–Alder reaction catalysed by chiral alkoxyaluminium dichloride
inferredcites →https://doi.org/10.1055/s-2002-25752openalex-snapshot
The Diels-Alder Reaction Selected Practical Methods

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Enantioselective Friedel-Crafts Alkylation of 1,3,5-Trimethoxybenzene with Trans-Β-Nitrostyrenes Catalysed by [Cp*Rh{(R)-Prophos}(H2o)][Sbf6]2 (Prophos = Propane-1,2-Diyl-Bis(Diphenylphosphane)
inferred← citeshttps://doi.org/10.1002/9783527623075.ch11openalex-snapshot
Iridium‐Catalyzed Cycloadditions
inferred← citeshttps://doi.org/10.1002/adsc.201000408openalex-snapshot
Iridium(I)‐Catalyzed Coupling of (Z)‐2‐En‐4‐yn‐1‐ols with Activated Alkynes: A New Synthetic Route to 7‐Oxanorbornadienes
inferred← citeshttps://doi.org/10.1002/chem.201601301openalex-snapshot
Temperature Dual Enantioselective Control in a Rhodium‐Catalyzed Michael‐Type Friedel–Crafts Reaction: A Mechanistic Explanation
inferred← citeshttps://doi.org/10.1016/j.ica.2017.12.031openalex-snapshot
Alkyl Al, Ga and Zn complexes chelated by mono-O-thiocarbamate-phenol ligands: Synthesis, characterization and activity as Diels-Alder catalysts
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2010.10.029openalex-snapshot
Palladacycle mediated synthesis of cyano-functionalized chiral 1,2-diphosphine and subsequent functional group transformations
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123377openalex-snapshot
Enantioselective Friedel-Crafts alkylation of 1,3,5-trimethoxybenzene with trans-β-nitrostyrenes catalysed by [Cp*Rh{(R)-Prophos}(H2O)][SbF6]2 (Prophos = propane-1,2-diyl-bis(diphenylphosphane)
inferred← citeshttps://doi.org/10.1016/j.molcata.2014.01.021openalex-snapshot
Enantioselective catalysts based on the chiral fragment (η5-C5Me5)Ir(Prophos) for Diels–Alder reactions
inferred← citeshttps://doi.org/10.1016/j.tetasy.2011.05.003openalex-snapshot
Enantioselective Friedel–Crafts alkylations catalysed by well-defined iridium and rhodium half-sandwich complexes
inferred← citeshttps://doi.org/10.1021/om200859zopenalex-snapshot
Enantioselective Catalysts for the Diels–Alder Reaction between Methacrolein and Cyclopentadiene Based on the Chiral Fragment (η5-C5Me5)M(chiral diphosphane) (M = Rh, Ir)
inferred← citeshttps://doi.org/10.1021/om200944yopenalex-snapshot
Enantioselective Diels–Alder Reactions Catalyzed by Well-Defined Arene–Ruthenium Complexes. Relationship between Catalyst Structure and Enantioselectivity
inferred← citeshttps://doi.org/10.1021/om300346sopenalex-snapshot
Enantioselective Catalytic Diels–Alder Reactions with Enones As Dienophiles
inferred← citeshttps://doi.org/10.1021/om301089copenalex-snapshot
Chiral Octahedral Phosphano–Oxazoline Iridium(III) Complexes as Catalysts in Asymmetric Cycloaddition Reactions
inferred← citeshttps://doi.org/10.1039/b802381fopenalex-snapshot
Chiral pyridylamino-ruthenium(ii) complexes: synthesis, structure and catalytic properties in Diels–Alder reactions
inferred← citeshttps://doi.org/10.1039/c3dt51222copenalex-snapshot
Half-sandwich rhodium and iridium complexes containing homochiral imidazolyl-imine ligands: synthesis, characterization and catalytic applications
inferred← citeshttps://doi.org/10.1039/c4cy01533aopenalex-snapshot
Asymmetric 1,3-dipolar cycloaddition reactions between enals and nitrones catalysed by half-sandwich rhodium or iridium diphosphane complexes
inferred← citeshttps://doi.org/10.1039/d2ra06982bopenalex-snapshot
Synthesis of chiral-at-metal rhodium complexes from achiral tripodal tetradentate ligands: resolution and application to enantioselective Diels–Alder and 1,3-dipolar cycloadditions
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