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Regioselective Hydroamination of Acrylonitrile Catalyzed by Cationic Pincer Complexes of Nickel(II)

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Rhodium-Catalyzed Amination of Vinylpyridines: Hydroamination versus Oxidative Amination
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Metal Insertion into C−C Bonds in Solution
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Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts
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Recent Developments in Transition Metal Catalyzed Intermolecular Hydroamination Reactions—A Breakthrough?
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Chiral Neutral Zirconium Amidate Complexes for the Asymmetric Hydroamination of Alkenes
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Chiral Neutral Zirconium Amidate Complexes for the Asymmetric Hydroamination of Alkenes
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Catalytic Reactivities of Indenyl–nickel, Indenyl–palladium, and PCsp3P–nickel Complexes
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Rhodium-catalysed hydroamination-hydroarylation of norbornene with aniline, toluidines or diphenylamine
inferredcites →https://doi.org/10.1016/j.poly.2006.11.023openalex-snapshot
A highly active two six-membered phosphinite palladium PCP pincer complex [PdCl{C6H3(CH2OPPri)2-2,6}]
inferredcites →https://doi.org/10.1016/s0022-328x(02)02138-1openalex-snapshot
Air- and moisture-stable cationic (diphosphine)palladium(II) complexes as hydroamination catalysts
inferredcites →https://doi.org/10.1016/s0040-4020(02)01511-9openalex-snapshot
The uses of pincer complexes in organic synthesis
inferredcites →https://doi.org/10.1016/s0040-4039(99)01514-2openalex-snapshot
The synthesis of a new palladacycle catalyst. Development of a high performance catalyst for Heck reactions
inferredcites →https://doi.org/10.1021/cr960118ropenalex-snapshot
Cyclometalated Phosphine-Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond Activation
inferredcites →https://doi.org/10.1021/cr960433dopenalex-snapshot
Metal-Initiated Amination of Alkenes and Alkynes
inferredcites →https://doi.org/10.1021/ja002284topenalex-snapshot
Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines
inferredcites →https://doi.org/10.1021/ja00228a022openalex-snapshot
Rational design in homogeneous catalysis. Iridium(I)-catalyzed addition of aniline to norbornylene via nitrogen-hydrogen activation
inferredcites →https://doi.org/10.1021/ja00533a014openalex-snapshot
Large-ring and cyclometalated rhodium complexes from some medium-chain .alpha.,.omega.-diphosphines
inferredcites →https://doi.org/10.1021/ja005881oopenalex-snapshot
Palladium-Catalyzed Hydroamination of 1,3-Dienes: A Colorimetric Assay and Enantioselective Additions
inferredcites →https://doi.org/10.1021/ja017521mopenalex-snapshot
A New Pathway for Hydroamination. Mechanism of Palladium-Catalyzed Addition of Anilines to Vinylarenes
inferredcites →https://doi.org/10.1021/ja017575wopenalex-snapshot
A General Nickel-Catalyzed Hydroamination of 1,3-Dienes by Alkylamines: Catalyst Selection, Scope, and Mechanism
inferredcites →https://doi.org/10.1021/ja052836dopenalex-snapshot
Platinum-Based Catalysts for the Hydroamination of Olefins with Sulfonamides and Weakly Basic Anilines
inferredcites →https://doi.org/10.1021/ja972594kopenalex-snapshot
The [IrCl(Diphosphine)]2/Fluoride System. Developing Catalytic Asymmetric Olefin Hydroamination
inferredcites →https://doi.org/10.1021/ja9729692openalex-snapshot
Highly Active Pd(II) PCP-Type Catalysts for the Heck Reaction
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A Highly Reactive Titanium Precatalyst for Intramolecular Hydroamination Reactions
inferredcites →https://doi.org/10.1021/ol049282oopenalex-snapshot
TiCl4-Catalyzed Intermolecular Hydroamination Reactions of Norbornene
inferredcites →https://doi.org/10.1021/ol0503992openalex-snapshot
Intramolecular Hydroamination of Unactived Olefins with Ti(NMe2)4 as a Precatalyst
inferredcites →https://doi.org/10.1021/om00027a026openalex-snapshot
Protonolysis approach to the catalytic amination of olefins with bis(phosphine)palladium(II) dialkyls
inferredcites →https://doi.org/10.1021/om0103097openalex-snapshot
Kinetics and Mechanisms of Methyl Vinyl Ketone Hydroalkoxylation Catalyzed by Palladium(II) Complexes
inferredcites →https://doi.org/10.1021/om040002iopenalex-snapshot
CO Insertion Reactions into the M−OH Bonds of Monomeric Nickel and Palladium Hydroxides. Reversible Decarbonylation of a Hydroxycarbonyl Palladium Complex
inferredcites →https://doi.org/10.1021/om050844xopenalex-snapshot
Syntheses and Reactivities of New PCsp3P Pincer Complexes of Nickel
inferredcites →https://doi.org/10.1021/om060545nopenalex-snapshot
A Pentagonal Pyramidal Zirconium Imido Complex for Catalytic Hydroamination of Unactivated Alkenes
inferredcites →https://doi.org/10.1021/om061133hopenalex-snapshot
Addition of N−H and O−H Bonds of Amines and Alcohols to Electron-Deficient Olefins Catalyzed by Monomeric Copper(I) Systems: Reaction Scope, Mechanistic Details, and Comparison of Catalyst Efficiency
inferredcites →https://doi.org/10.1021/om700400xopenalex-snapshot
New Pincer-Type Diphosphinito (POCOP) Complexes of Nickel
inferredcites →https://doi.org/10.1021/om8005454openalex-snapshot
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
inferredcites →https://doi.org/10.1021/om990146aopenalex-snapshot
Constrained Geometry Organolanthanide Catalysts. Synthesis, Structural Characterization, and Enhanced Aminoalkene Hydroamination/Cyclization Activity
inferredcites →https://doi.org/10.1039/b108234popenalex-snapshot
Protonolysis of a toluidinoalkyl platinum(ii) complex derived from the insertion of the CC bond into the Pt–NHR (amido) bond: the role of amine in Pt-catalyzed hydroamination of acrylonitrile
inferredcites →https://doi.org/10.1039/b111487popenalex-snapshot
Synthesis, characterisation and catalytic investigation of a new type of PC(sp3)P pincer Pd(ii) complex
inferredcites →https://doi.org/10.1039/b613812hopenalex-snapshot
New pincer-type diphosphinito (POCOP) complexes of Ni II and Ni III
inferredcites →https://doi.org/10.1039/b802222dopenalex-snapshot
Ni(ii) complexes featuring non-metallated pincer-type ligands
inferredcites →https://doi.org/10.1039/dt9760001020openalex-snapshot
Transition metal–carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis[(di-t-butylphosphino)methyl]phenyl
inferredcites →https://doi.org/10.1039/dt9790001972openalex-snapshot
Formation of large chelate rings and cyclometallated products from diphosphines of type Bu t 2 P(CH 2 ) n PBu t 2 (n= 5–8) and Ph 2 P(CH 2 ) 5 PPh 2 with palladium and platinum chlorides: factors affecting the stability and conformation of large chelate rings
inferredcites →https://doi.org/10.1039/dt9800000059openalex-snapshot
Formation of large chelate rings and cyclometallated complexes from But 2PCH2CH2CHMeCH2CH2PBut 2 and platinum and palladium chlorides. Crystal structure of [Pd2Cl4{But 2PCH2CH2CHMeCH2CH2PBUt 2}2]
inferredcites →https://doi.org/10.1039/dt9820000387openalex-snapshot
Further studies on the interconversion of large ring and cyclometallated complexes of rhodium, with the diphosphines Bu t 2 P(CH 2 ) 5 PBu t 2 and Bu t 2 PCH 2 CHCHCH 2 PBu t 2
inferredcites →https://doi.org/10.1039/dt9820001217openalex-snapshot
Transition metal–carbon bonds. Part 52. Large ring and cyclometallated complexes formed from Bu t 2 PCH 2 CH 2 CHRCH 2 CH 2 PBu t 2 (R H or Me) and IrCl 3 , or [Ir 2 Cl 4 (cyclo-octene) 4 ] : crystal structures of the cyclometallated hydride, [IrHCl(Bu t 2 PCH 2 CH 2 CHCH 2 CH 2 PBu t 2 )], and…
inferredcites →https://doi.org/10.1039/dt9820001225openalex-snapshot
Transition metal–carbon bonds. Part 53. The further chemistry of cyclometallated complexes formed from Bu t 2 P(CH 2 ) 5 PBu t 2 and PtCl 2 : crystal structure of [PtCl{Bu t 2 PCH 2 CH 2 CCHCH 2 PBu t 2 }]
inferredcites →https://doi.org/10.1107/s0108768102003890openalex-snapshot
The Cambridge Structural Database: a quarter of a million crystal structures and rising
inferredcites →https://doi.org/10.1139/v05-079openalex-snapshot
Phosphino-indenyl complexes of nickel(II)

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Cobalt(Ii) Catalyzed Michael-Type Hydroarylamination of Activated Olefins
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Organonickel Chemistry
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Pincer Complexes with Saturated Frameworks: Synthesis and Applications
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A Simple and General Nickel‐Catalyzed Michael‐Type Hydroamination of Activated Olefins Using Arylamines
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On the Stability of a POC sp3 OP‐Type Pincer Ligand in Nickel(II) Complexes
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The Reactivity of Mercapto Groups against Boron Hydrides in Pincer Ligated Nickel Mercapto Complexes
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Small Molecule Activation by POCOP‐Nickel Complexes
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Synthesis and Characterization of a Family of POCOP Pincer Complexes with Nickel: Reactivity Towards CO2 and Phenylacetylene
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Charge Effects in PCP Pincer Complexes of NiII bearing Phosphinite and Imidazol(i)ophosphine Coordinating Jaws: From Synthesis to Catalysis through Bonding Analysis
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Cationic [(Iminophosphine)Nickel(Allyl)]+ Complexes as the First Example of Nickel Catalysts for Direct Hydroamination of Allenes
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The Effect of ZnII Coordination on the Addition of 2‐(Aminomethyl)benzimidazole to Acrylonitrile
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Syntheses and Structures of Group 10 Metal POCOP Pincer Complexes Bearing A Mercapto‐ o– carborane Auxiliary Ligand
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A Facile Highly Selective Anti‐Markovnikov Hydroamination of Vinyl Pyridines by Free Radical Oxidation
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Recent Advances on the Chemistry of POCOP–Nickel Pincer Compounds
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Catalytic Conversion of Nitriles by Metal Pincer Complexes
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PC(sp 3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications
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Tuning of PCP Pincer Ligand Electronic and Steric Properties
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ECE-Type Pincer Complexes of Nickel
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Does cation break the cyano bond? A critical evaluation of nitrile-cation interaction
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Classification and synthesis of nickel pincer complexes
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Synthesis and characterization of six-membered pincer nickelacycles and application in alkylation of benzothiazole
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Phosphorus-Based Pincer Ligands
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Nickel-Carbon σ-Bonded Complexes
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Aliphatic pincer-type POCOP ligands and their complexation behaviour with iridium: Crystal structure of an iridium(III) phosphinite complex
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Amidate ligand design effects in zirconium-catalyzed enantioselective hydroamination of aminoalkenes
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Aminotroponiminate zinc complexes as catalysts for the intramolecular hydroamination
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New POCOP-type pincer complexes of Nickel(II)
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Synthesis and characterisation of new PCsp3P-supported nickel complexes
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Metathesis reactivity of bis(phosphinite) pincer ligated nickel chloride, isothiocyanate and azide complexes
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d8 Nickel and palladium difluorocarbenes derived from trifluoromethyl POCOP-type pincer complexes
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α-Cyanocarbanion complexes and their application in synthesis
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C-Ni bond functionalization in the reaction of binuclear cyclometallated Ni(II) complexes with chlorophosphines
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Addition of amines and phenols to acrylonitrile derivatives catalyzed by the POCOP-type pincer complex [{κP,κC,κP-2,6-(i-Pr2PO)2C6H3}Ni(NCMe)][OSO2CF3]
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Bis-pyrazolyl-s-triazine Ni(II) pincer complexes as selective gram positive antibacterial agents; synthesis, structural and antimicrobial studies
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Micrometer long bimetallic Nickel-cobalt schiff base MOF as supercapacitor electrodes
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Synthesis, characterization and application of pincer-type nickel iminophosphinite complexes
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Nickel catalyzed hydroamination reactions: An overview
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Which Type of Pincer Complex Is Thermodynamically More Stable? Understanding the Structures and Relative Bond Strengths of Group 10 Metal Complexes Supported by Benzene-Based PYCYP Pincer Ligands
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Oxygen Atom Transfer to Cationic PCPNi(II) Complexes Using Amine-N-Oxides
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POCOP-Type Pincer Complexes of Nickel: Synthesis, Characterization, and Ligand Exchange Reactivities of New Cationic Acetonitrile Adducts
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Configurational Stability and Stereochemistry of P-Stereogenic Nickel POCOP-Pincer Complexes
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Synthesis of Quinoline-Based NNN-Pincer Nickel(II) Complexes: A Robust and Improved Catalyst System for C–H Bond Alkylation of Azoles with Alkyl Halides
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Nickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings
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Cobalt POCOP Pincer Complexes via Ligand C–H Bond Activation with Co2(CO)8: Catalytic Activity for Hydrosilylation of Aldehydes in an Open vs a Closed System
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Synthesis, Characterization, and Reactivity of PCN Pincer Nickel Complexes
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Janus POCOP Pincer Complexes of Nickel
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C–H Nickelation of Naphthyl Phosphinites: Electronic and Steric Limitations, Regioselectivity, and Tandem C–P Functionalization
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Catalysis Involving Phosphinite-Based Metallacycles
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Late Transition Metal-Catalyzed Hydroamination and Hydroamidation
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Monomeric and Dimeric Nickel Complexes Derived from a Pincer Ligand Featuring a Secondary Amine Donor Moiety
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Characterization of Divalent and Trivalent Species Generated in the Chemical and Electrochemical Oxidation of a Dimeric Pincer Complex of Nickel
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Synthesis and Reactivity of New Ni, Pd, and Pt 2,6-Bis(di-tert-butylphosphinito)pyridine Pincer Complexes
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Pincer-Ligated Nickel Hydridoborate Complexes: the Dormant Species in Catalytic Reduction of Carbon Dioxide with Boranes
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Nickel(II) Complexes Containing a Pyrrole–Diphosphine Pincer Ligand
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Hemilabile and Bimetallic Coordination in Rh and Ir Complexes of NCN Pincer Ligands
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Calculation of Ionization Energy, Electron Affinity, and Hydride Affinity Trends in Pincer-Ligated d8-Ir(tBu4PXCXP) Complexes: Implications for the Thermodynamics of Oxidative H2 Addition
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Synthesis of Tertiary Alkyl Amines from Terminal Alkenes: Copper-Catalyzed Amination of Alkyl Boranes
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Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System
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Regulating Access to Active Sites via Hydrogen Bonding and Cation–Dipole Interactions: A Dual Cofactor Approach to Switchable Catalysis
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Reactions of Phenylhydrosilanes with Pincer–Nickel Complexes: Evidence for New Si–O and Si–C Bond Formation Pathways
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Mechanistic Models for LAH Reductions of Acetonitrile and Malononitrile. Aggregation Effects of Li+ and AlH3 on Imide–Enamide Equilibria
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Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes of (Imidazolinyl)aryl Phosphinite Ligands: Synthesis via Ligand C−H Activation, Crystal Structures, and Catalytic Studies
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Mechanistic Insights into C−S Cross-Coupling Reactions Catalyzed by Nickel Bis(phosphinite) Pincer Complexes
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Hydroamination and Alcoholysis of Acrylonitrile Promoted by the Pincer Complex {κ P ,κ C ,κ P -2,6-(Ph 2 PO) 2 C 6 H 3 }Ni(OSO 2 CF 3 )
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Iron Hydride Complexes Bearing Phosphinite-Based Pincer Ligands: Synthesis, Reactivity, and Catalytic Application in Hydrosilylation Reactions
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Nickelation of PCP- and POCOP-Type Pincer Ligands: Kinetics and Mechanism
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Impact of Backbone Substituents on POCOP-Ni Pincer Complexes: A Structural, Spectroscopic, and Electrochemical Study
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Synthesis, Characterization, and Catalytic Activity of Nickel(II) Alkyl Complexes Supported by Pyrrole–Diphosphine Ligands
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Fluoro and Trifluoromethyl Derivatives of POCOP-Type Pincer Complexes of Nickel: Preparation and Reactivities in SN2 Fluorination and Direct Benzylation of Unactivated Arenes
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Synthesis, Characterization, and Oxidation of New POCNimine-Type Pincer Complexes of Nickel
inferred← citeshttps://doi.org/10.1021/om500916dopenalex-snapshot
POCOP-Ligated Nickel Siloxide Complexes: Syntheses, Characterization, and Reactivities
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Synthesis and Reactivities of New NCN-Type Pincer Complexes of Nickel
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Synthesis and Structural Characterization of Nickel Complexes Possessing P-Stereogenic Pincer Scaffolds and Their Application in Asymmetric Aza-Michael Reactions
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New POCN-Type Pincer Complexes of Nickel(II) and Nickel(III)
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Functionalized Aminotroponiminate Zinc Complexes as Catalysts for the Intramolecular Hydroamination of Alkenes
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A comparison between nickel and palladium precatalysts of 1,2,4-triazole based N-heterocyclic carbenes in hydroamination of activated olefins
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Fascinating frontiers of N/O-functionalized N-heterocyclic carbene chemistry: from chemical catalysis to biomedical applications
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The impact of P-substituents on the structures, spectroscopic properties, and reactivities of POCOP-type pincer complexes of nickel(ii)
inferred← citeshttps://doi.org/10.1039/c2cc35377fopenalex-snapshot
Nickel(ii) complexes of the new pincer-type unsymmetrical ligands PIMCOP, PIMIOCOP, and NHCCOP: versatile binding motifs
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Novel access to carbodiphosphoranes in the coordination sphere of group 10 metals: template synthesis and protonation of PCP pincer carbodiphosphorane complexes of C(dppm)2
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Easily available nickel complexes as catalysts for the intermolecular hydroamination of alkenes and alkynes
inferred← citeshttps://doi.org/10.1039/c3gc40968fopenalex-snapshot
Direct, one-pot synthesis of POCOP-type pincer complexes from metallic nickel
inferred← citeshttps://doi.org/10.1039/c4dt02718copenalex-snapshot
Nickel complexes of a binucleating ligand derived from an SCS pincer
inferred← citeshttps://doi.org/10.1039/c5dt00161gopenalex-snapshot
Reactions of phenylacetylene with nickel POCOP-pincer hydride complexes resulting in different outcomes from their palladium analogues
inferred← citeshttps://doi.org/10.1039/c5dt01516bopenalex-snapshot
Bond and small-molecule activation with low-valent nickel complexes
inferred← citeshttps://doi.org/10.1039/c5dt03778fopenalex-snapshot
Non-precious metal complexes with an anionic PCP pincer architecture
inferred← citeshttps://doi.org/10.1039/c5nj00807gopenalex-snapshot
Synthesis of unsymmetrical 5,6-POCOP′-type pincer complexes of nickel( ii ): impact of nickelacycle size on structures and spectroscopic properties
inferred← citeshttps://doi.org/10.1039/c6cc00763eopenalex-snapshot
The synthesis and efficient one-pot catalytic “self-breeding” of asymmetrical NC(sp 3 )E-hybridised pincer complexes
inferred← citeshttps://doi.org/10.1039/c6dt02105kopenalex-snapshot
On the mechanism of Ni( ii )-promoted Michael-type hydroamination of acrylonitrile and its substituted derivatives
inferred← citeshttps://doi.org/10.1039/d1nj01698aopenalex-snapshot
Achiral and chiral NNN-pincer nickel complexes with oxazolinyl backbones: application in transfer hydrogenation of ketones
inferred← citeshttps://doi.org/10.1039/d2dt02979kopenalex-snapshot
Reactivities of cyclonickellated complexes with hydroxylamines: formation of κ O -hydroxylamine and κ N -imine adducts and a κ O , κ N -aminoxide derivative
inferred← citeshttps://doi.org/10.1039/d3cc04687gopenalex-snapshot
Accessing Ni(0) to Ni(IV) via nickel–carbon–phosphorus bond reorganization
inferred← citeshttps://doi.org/10.1055/a-2282-7702openalex-snapshot
Lanthanoids in Hydroarylaminations: Yb(III)- and Tb(III)-Catalyzed Addition of Arylamines to Activated Olefins
inferred← citeshttps://doi.org/10.1139/cjc-2020-0137openalex-snapshot
POCOP-type cobalt and nickel pincer complexes bearing an appended phosphinite group
inferred← citeshttps://doi.org/10.1140/epjd/e2013-40216-1openalex-snapshot
Effect of primary and secondary ligands on electronic structures and spectra of a series of nickel (II) complexes: a density functional theory study
inferred← citeshttps://doi.org/10.3390/catal10070773openalex-snapshot
Recent Progress with Pincer Transition Metal Catalysts for Sustainability
inferred← citeshttps://doi.org/10.3390/catal14010069openalex-snapshot
Advances in Cross-Coupling Reactions Catalyzed by Aromatic Pincer Complexes Based on Earth-Abundant 3d Metals (Mn, Fe, Co, Ni, Cu)
inferred← citeshttps://doi.org/10.3390/catal8110508openalex-snapshot
Application of POCOP Pincer Nickel Complexes to the Catalytic Hydroboration of Carbon Dioxide
inferred← citeshttps://doi.org/10.3390/pr12071466openalex-snapshot
Para-Hydroxy Ni(II)-POCOP Pincer Complexes as Modifiers on Carbon Paste Electrodes and Their Application in Methanol Electro-Oxidation in Alkaline Media
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