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Palladium Iminoacyl Imine Complexes: Strategies toward Imine Insertion

https://doi.org/10.1021/om900574b
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Outgoing claims: the papers this work cites, builds on, or argues with.

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Insertion of Imines into Palladium-Acyl Bonds: Towards Metal-Catalyzed Alternating Copolymerization of Imines with Carbon Monoxide To Form Polypeptides
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The Use of Carbon Monoxide and Imines as Peptide Derivative Synthons: A Facile Palladium-Catalyzed Synthesis ofα-Amino Acid Derived Imidazolines
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A New Pd0���CuIBimetallic Catalyst for the Synthesis of Indoles from Isocyanates and Allyl Carbonates
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Carbon‐Hydrogen‐Transition Metal Bonds
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Industrial R&D on Catalytic CC and CN Coupling Reactions: A Personal Account on Goals, Approaches and Results
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Palladium‐Catalyzed CN and CO Coupling–A Practical Guide from an Industrial Vantage Point †
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Die Fettanalyse im Jahre 1902
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Cyclometalation Reactions
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Modern Synthetic Methods for Copper‐Mediated C(aryl)O, C(aryl)N, and C(aryl)S Bond Formation
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Monoligated Palladium Species as Catalysts in Cross‐Coupling Reactions
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Metal‐Catalyzed Copolymerization of Imines and CO: A Non‐Amino Acid Route to Polypeptides
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Catalytic CC, CN, and CO Ullmann‐Type Coupling Reactions: Copper Makes a Difference
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Iron‐Catalyzed S‐Arylation of Thiols with Aryl Iodides
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Metal‐Catalyzed One‐Step Synthesis: Towards Direct Alternatives to Multistep Heterocycle and Amino Acid Derivative Formation
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Practical Palladium Catalysts for C-N and C-O Bond Formation
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Principles and Applications of Organotransition Metal Chemistry
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Efficient palladium catalysts for the copolymerization of carbon monoxide with olefins to produce perfectly alternating polyketones
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The organometallic chemistry of the transition metals
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Synthesis, characterization, and anti-HIV activity of some 2-p-X-phenyl-1,3-N,N′-diphenyl-amidines
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Palladium-catalysed three component synthesis of α,β-unsaturated amidines and imidates
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Corrigendum to “Palladium-catalysed three component synthesis of α,β-unsaturated amidines and imidates” [Tetrahedron Lett. 45 (2004) 6991]
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The conjunctive response to steric hindrance in dithiocyanato[bis(diphenylphosphino)alkyl or aryl]palladium(II) complexes: a new look at a classic series
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Metal-azo and metal-imine compounds
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The cyclopalladation of benzylidenebenzylamines
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Palladium-catalysed synthesis of imidates, thioimidates and amidines from aryl halides
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5 Amidines and Guanidines in Medicinal Chemistry
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Cyclometallated complexes incorporating a heterocyclic donor atom; the interface of coordination chemistry and organometallic chemistry
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Palladium(II)-catalyzed synthesis of polyamides (aramids) from aromatic dichlorides, diamines, and carbon monoxide
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Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides
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.DELTA.R-ring contributions to phosphorus-31 NMR parameters of transition-metal-phosphorus chelate complexes
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Organometallic intramolecular-coordination compounds containing a nitrogen donor ligand
inferredcites →https://doi.org/10.1021/cr940282jopenalex-snapshot
Palladium-Catalyzed Alternating Copolymerization of Alkenes and Carbon Monoxide
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Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation
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Metal-Catalyzed Carbon−Sulfur Bond Formation
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C−N Bond Formation on Addition of Aryl Carbanions to the Electrophilic Nitrido Ligand in TpOs(N)Cl2
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Steric vs. electronic effects in palladium-thiocyanate complexes. Crystal structures of dithiocyanato[bis(diphenylphosphino)methane](II), isothiocyanatothiocyanato[1,2-bis(diphenylphosphino)ethane]palladium(II), and diisothiocyanato[1,3-bis(diphenylphosphino)propane]palladium(II)
inferredcites →https://doi.org/10.1021/ja0112036openalex-snapshot
Iridium Complex-Catalyzed Allylic Amination of Allylic Esters
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Direct Observation of Aldehyde Insertion into Rhodium−Aryl and −Alkoxide Complexes
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A General and Efficient Copper Catalyst for the Amidation of Aryl Halides
inferredcites →https://doi.org/10.1021/ja027474dopenalex-snapshot
The Development of a Catalytic Synthesis of Münchnones: A Simple Four-Component Coupling Approach to α-Amino Acid Derivatives
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Palladium-Catalyzed Amination of Aryl and Heteroaryl Tosylates at Room Temperature
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Palladium Alkoxides: Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III)
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Direct Observation of C−O Reductive Elimination from Palladium Aryl Alkoxide Complexes To Form Aryl Ethers
inferredcites →https://doi.org/10.1021/ja9806581openalex-snapshot
Electronic Dependence of C−O Reductive Elimination from Palladium (Aryl)neopentoxide Complexes
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Carbon−Sulfur Bond-Forming Reductive Elimination Involving sp-, sp 2 -, and sp 3 -Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation
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Ti-Catalyzed Enantioselective Addition of Cyanide to Imines. A Practical Synthesis of Optically Pure α-Amino Acids
inferredcites →https://doi.org/10.1021/ja9840706openalex-snapshot
Insertion of Imine into Palladium−Methyl and Palladium−Acyl Bonds. A Density Functional Study
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Highly Active, Air-Stable Palladium Catalysts for the C−C and C−S Bond-Forming Reactions of Vinyl and Aryl Chlorides: Use of Commercially Available [(t-Bu)2P(OH)]2PdCl2, [(t-Bu)2P(OH)PdCl2]2, and [[(t-Bu)2PO···H···OP(t-Bu)2]PdCl]2 as Catalysts
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Nickel(0)/Dihydroimidazol-2-ylidene Complex Catalyzed Coupling of Aryl Chlorides and Amines
inferredcites →https://doi.org/10.1021/jo802594dopenalex-snapshot
A General, Efficient, and Functional-Group-Tolerant Catalyst System for the Palladium-Catalyzed Thioetherification of Aryl Bromides and Iodides
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Zinc-Mediated Palladium-Catalyzed Formation of Carbon−Sulfur Bonds
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The First N-Heterocyclic Carbene-Based Nickel Catalyst for C−S Coupling
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[(CyPF-tBu)PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides
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Effect of ring size on NMR parameters: cyclic bisphosphine complexes of molybdenum, tungsten, and platinum. Bond angle dependence of metal shieldings, metal-phosphorus coupling constants, and the phosphorus-31 chemical shift anisotropy in the solid state
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Umpolung with rhodium iminoacyls. The use of metal oxidation state to control the nucleophilicity or electrophilicity of acyl carbons
inferredcites →https://doi.org/10.1021/om000685bopenalex-snapshot
Sequential Insertion of Carbon Monoxide and Imines into Nickel−Methyl Bonds: A New Route to Imine Hydroacylation
inferredcites →https://doi.org/10.1021/om000745dopenalex-snapshot
Insertion of Imines and Carbon Monoxide into Manganese−Alkyl Bonds: Synthesis and Structure of a Manganese−α-Amino Acid Derivative
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DFT Study of Olefin versus Nitrogen Bonding in the Coordination of Nitrogen-Containing Polar Monomers to Diimine and Salicylaldiminato Nickel(II) and Palladium(II) Complexes. Implications for Copolymerization of Olefins with Nitrogen-Containing Polar Monomers
inferredcites →https://doi.org/10.1021/om010852nopenalex-snapshot
Palladium Complexes with Tridentate Pincer Bis-Carbene Ligands as Efficient Catalysts for C−C Coupling
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Influence of Chelating Phosphines on the Insertion of Isocyanides into Palladium−Methyl Bonds in (P−P)Pd(Me)Cl Complexes and Their Further Reaction with Olefins and Isothiocyanates
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Synthesis and Structural Characterization of a Novel Dipalladium Complex with an Unprecedented PdCN Bonding Motif
inferredcites →https://doi.org/10.1021/om030493ropenalex-snapshot
Studies on the Reactivity of Isocyanates and Isothiocyanates with Palladium−Imidoyl Complexes
inferredcites →https://doi.org/10.1021/om050126aopenalex-snapshot
Neutral N−O Chelated Palladium(II) Complexes: Syntheses, Characterization, and Reactivity
inferredcites →https://doi.org/10.1021/om9709244openalex-snapshot
The Novel Insertion of Imines into a Late-Metal−Carbon σ-Bond: Developing a Palladium-Mediated Route to Polypeptides
inferredcites →https://doi.org/10.1039/a708128fopenalex-snapshot
Calamitic smectic liquid crystalline supramolecular architecture from octaalkoxy-substituted PdII–η1-benzylideneaniline complexes
inferredcites →https://doi.org/10.1039/b103899kopenalex-snapshot
Copolymerization of carbon monoxide and aziridine
inferredcites →https://doi.org/10.1039/c39910000421openalex-snapshot
Cationic palladium( II )–diphosphine complexes as catalysts for the carbonylation of alkenes to ketones
inferredcites →https://doi.org/10.1039/dt9760000439openalex-snapshot
Effect of chelate-ring size on spectroscopic and chemical properties of methylplatinum(II) complexes of the ditertiary phosphines Ph2P[CH2] n PPh2(n= 1,2, or 3)
inferredcites →https://doi.org/10.1126/science.188.4194.1224openalex-snapshot
Organotransition-Metal Chemistry
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Selected applications to organic synthesis of intramolecular C-H activation reactions by transition metals

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