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A Thermodynamically Based and Definitive Demonstration of the Inadequacy of the ECW Model for Phosphorus(III) Ligands

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1016/0010-8545(94)07003-3openalex-snapshot
Associative reactions of metal carbonyl clusters: systematic kinetic studies of some ruthenium and other clusters
inferredcites →https://doi.org/10.1016/0097-8485(82)80010-7openalex-snapshot
Statistical analysis of the isokinetic relationship using a programmable calculator
inferredcites →https://doi.org/10.1021/ic00049a029openalex-snapshot
Steric and electronic factors influencing the reactivity of tertiary phosphines toward platinum(II) complexes
inferredcites →https://doi.org/10.1021/ic00077a021openalex-snapshot
Steric ligand effects of six bidentate bipyridyl ligands
inferredcites →https://doi.org/10.1021/ic00235a033openalex-snapshot
Steric and electronic effects in associative substitution reactions of dodecacarbonyltetrairidium
inferredcites →https://doi.org/10.1021/ic00318a006openalex-snapshot
Systematic substituent effects on dissociative substitution kinetics of ruthenium carbonyl, Ru(CO)4L, complexes (L = phosphorus, arsenic, and antimony donor ligands)
inferredcites →https://doi.org/10.1021/ic970210lopenalex-snapshot
Structure−Reactivity Correlations for the Dissociative Uncatalyzed Isomerization of Monoalkylbis(phosphine)platinum(II) Solvento Complexes
inferredcites →https://doi.org/10.1021/ja00039a028openalex-snapshot
Systematic kinetics of high nuclearity metal carbonyl clusters. Associative substitution reactions of Ru6C(CO)17 with P-donor nucleophiles
inferredcites →https://doi.org/10.1021/ja00093a027openalex-snapshot
Systematic Kinetics of High-Nuclearity Metal Carbonyl Clusters. Exceptional Behavior of Ru5C(CO)15 with P-Donor Nucleophiles
inferredcites →https://doi.org/10.1021/ja00108a045openalex-snapshot
Synthesis of the First Examples of Transition Metal .eta.2-SiH4 Complexes, cis-Mo(.eta.2-SiH4)(CO)(R2PC2H4PR2)2, and Evidence for an Unprecedented Tautomeric Equilibrium between an .eta.2-SiH4 Complex and a Hydridosilyl Species: A Model for Methane Coordination and Activation
inferredcites →https://doi.org/10.1021/ja953581eopenalex-snapshot
Phosphine EB and CB Values
inferredcites →https://doi.org/10.1021/om00002a039openalex-snapshot
Exploring Stereoselectivity through the Quantitative Analysis of Ligand Effects. Addition of Hydride to (.eta.-Cp)(CO)(PR3)Fe[C(OMe)(Me)]+
inferredcites →https://doi.org/10.1021/om00004a025openalex-snapshot
Exploring Stereoselectivity through the Quantitative Analysis of Ligand Effects. Osmylation of Chiral (Acetoxyallyl)silanes
inferredcites →https://doi.org/10.1021/om00007a026openalex-snapshot
Systematic Kinetic Studies of Nucleophile Addition to (.mu.2-H)2Os3(CO)10
inferredcites →https://doi.org/10.1021/om00007a027openalex-snapshot
Activation Parameter Correlations for Nucleophile Addition to (.mu.2-H)2Os3(CO)10
inferredcites →https://doi.org/10.1021/om00007a047openalex-snapshot
.DELTA.E-.DELTA.C Analysis of Phosphine Basicity
inferredcites →https://doi.org/10.1021/om00019a037openalex-snapshot
Entering Ligand Dependent Displacement of Acetone from (.eta.-C5R5)(AC)(CO)Fe(COMe)+ by Organic Nitriles. Quantitative Analysis of Ligand Effects (QALE)
inferredcites →https://doi.org/10.1021/om00029a035openalex-snapshot
The quantitative analysis of ligand effects (QALE). The aryl effect
inferredcites →https://doi.org/10.1021/om00030a013openalex-snapshot
Reinvestigation of the oxidative addition of methyl iodide, hydrogen, and oxygen to Ir(CO)(Cl)L2. Quantitative analysis of ligand effects (QALE)
inferredcites →https://doi.org/10.1021/om00050a051openalex-snapshot
Systematic ligand effects on the rates of CO substitution of (.eta.5-C5H4CO2Me)Co(CO)2
inferredcites →https://doi.org/10.1021/om00119a008openalex-snapshot
Electrochemical investigation of the substitution reactions of the solvent-coordinated acyl complexes .eta.-Cp(acetone)(CO)FeCOMe0,+ involving thio ethers. Applications of the quantitative analysis of ligand effects
inferredcites →https://doi.org/10.1021/om00130a011openalex-snapshot
Quantitative separation of .sigma.- and .pi.-components of transition metal-phosphorus bonding and the application of ligand effects in organometallic chemistry
inferredcites →https://doi.org/10.1021/om00157a033openalex-snapshot
Addition of carbenium ions to allylsilanes: interpretation of kinetic data via the quantitative analysis of ligand effects
inferredcites →https://doi.org/10.1021/om950564popenalex-snapshot
Comments on Coupling Graphical and Regression Analyses of Ligand Effect Data
inferredcites →https://doi.org/10.1021/om9508290openalex-snapshot
Displacement of Acetone from η-(C5R5)(CO)Fe(AC)(COMe)+ by Thioethers. Application of the Quantitative Analysis of Ligand Effects (QALE)
inferredcites →https://doi.org/10.1021/om960646topenalex-snapshot
Examination of Drago's EB and CB Parameters for Phosphines through the Quantitative Analysis of Ligand Effects (QALE)
inferredcites →https://doi.org/10.1021/om9702183openalex-snapshot
The Aryl Effect in Disubstituted Dimanganese and Dicobalt Carbonyls
inferredcites →https://doi.org/10.1021/om970789vopenalex-snapshot
Reactivity of Phosphorus Donors
inferredcites →https://doi.org/10.1021/om971041fopenalex-snapshot
Exploring Ligand Effects through Isoequilibrium Phenomena: The Quantitative Analysis of Ligand Effects
inferredcites →https://doi.org/10.1039/cs9891800477openalex-snapshot
The isokinetic relationship
inferredcites →https://doi.org/10.1080/00958979408024240openalex-snapshot
KINETIC STUDIES OF LEWIS BASE ADDITION TO CpFe(CO)(η3-CH2C6H4-p-X); X = OMe, Me, H,F, Cl, Br
inferredcites →https://doi.org/10.1139/v95-146openalex-snapshot
Systematic substitution kinetics of the clusters Ru3(CO)11L and Ru3(CO)10L2 (L = P-donor ligands): The unimolecular path
inferredcites →https://doi.org/10.1351/pac198860081209openalex-snapshot
Systematic kinetics of associative reactions of metal carbonyls

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4772835openalex-extracted
The Influence of Phosphine Ligands on the Redox Properties of 1,4-Divinylanthrylene-Bridged Diruthenium Complexes and a Derived Macrocyclic Analog
inferred← citeshttps://doi.org/10.1002/jcc.20551openalex-snapshot
Electronic reorganization: Origin of sigma trans promotion effect
inferred← citeshttps://doi.org/10.1016/j.ccr.2004.04.005openalex-snapshot
Recent advances in high-pressure infrared and NMR techniques for the determination of catalytically active species in rhodium- and cobalt-catalysed hydroformylation reactions
inferred← citeshttps://doi.org/10.1016/j.ccr.2004.08.021openalex-snapshot
Predicting the net donating ability of phosphines?do we need sophisticated theoretical methods?
inferred← citeshttps://doi.org/10.1016/j.ccr.2008.04.017openalex-snapshot
Building ligand knowledge bases for organometallic chemistry: Computational description of phosphorus(III)-donor ligands and the metal–phosphorus bond
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2005.06.020openalex-snapshot
Tertiary phosphine induced migratory carbonyl insertion in cyclopentadienyl complexes of iron(II)
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123185openalex-snapshot
The influence of phosphine ligands on the redox properties of 1,4-divinylanthrylene-bridged diruthenium complexes and a derived macrocyclic analog
inferred← citeshttps://doi.org/10.1016/s0010-8545(02)00099-1openalex-snapshot
Cone angles: Tolman's and Plato's
inferred← citeshttps://doi.org/10.1016/s0166-1280(00)00415-2openalex-snapshot
Phosphane lone-pair energies as a measure of ligand donor strengths and relation to activation energies
inferred← citeshttps://doi.org/10.1021/acs.jpca.5b11543openalex-snapshot
Correlation and Prediction of Redox Potentials of Hydrogen Evolution Mononuclear Cobalt Catalysts via Molecular Electrostatic Potential: A DFT Study
inferred← citeshttps://doi.org/10.1021/ic0109400openalex-snapshot
Quantifying the Electronic Effect of Substituted Phosphine Ligands via Molecular Electrostatic Potential
inferred← citeshttps://doi.org/10.1021/om4011593openalex-snapshot
Iron-57 NMR and Structural Study of [Fe(η 5 -Cp)(SnPh 3 )(CO)(PR 3 )] (PR 3 = Phosphine, Phosphite). Separation of Steric and Electronic σ and π Effects
inferred← citeshttps://doi.org/10.1039/a804900iopenalex-snapshot
Chapter 27. Mechanisms of reactions in solution
inferred← citeshttps://doi.org/10.1039/a902298hopenalex-snapshot
A thermodynamic method based on isoequilibrium behavior to determine the values of stereoelectronic parameters of phosphines
inferred← citeshttps://doi.org/10.1039/a909250aopenalex-snapshot
The stereoelectronic parameters of phosphites. The quantitative analysis of ligand effects (QALE)
inferred← citeshttps://doi.org/10.1039/b003494kopenalex-snapshot
Assessing the stereoelectronic properties of pyrrolyl phosphines and related ligands. The quantitative analysis of ligand effects (QALE)
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