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Mechanical gating of a mechanochemical reaction cascade

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/anie.200250842openalex-snapshot
Entropically Driven Ring‐Opening‐Metathesis Polymerization of Macrocyclic Olefins with 21–84 Ring Atoms
inferredcites →https://doi.org/10.1002/anie.201003978openalex-snapshot
Competition between Orbitals and Stress in Mechanochemistry
inferredcites →https://doi.org/10.1002/anie.201300746openalex-snapshot
Model Studies of the Kinetics of Ester Hydrolysis under Stretching Force
inferredcites →https://doi.org/10.1002/anie.201407494openalex-snapshot
Photomechanical Actuation of Ligand Geometry in Enantioselective Catalysis
inferredcites →https://doi.org/10.1002/anie.201508005openalex-snapshot
Force‐Induced Reversal of β‐Eliminations: Stressed Disulfide Bonds in Alkaline Solution
inferredcites →https://doi.org/10.1002/anie.201510171openalex-snapshot
Mechanochromism and Mechanical‐Force‐Triggered Cross‐Linking from a Single Reactive Moiety Incorporated into Polymer Chains
inferredcites →https://doi.org/10.1002/chem.201600866openalex-snapshot
Mechanochemical Cycloreversion of Cyclobutane Observed at the Single Molecule Level
inferredcites →https://doi.org/10.1002/cphc.201200207openalex-snapshot
Quantum‐Chemical Validation of the Local Assumption of Chemomechanics for a Unimolecular Reaction
inferredcites →https://doi.org/10.1002/cphc.201500054openalex-snapshot
Should the Woodward–Hoffmann Rules be Applied to Mechanochemical Reactions?
inferredcites →https://doi.org/10.1007/128_2015_627openalex-snapshot
Molecular Mechanochemistry: Engineering and Implications of Inherently Strained Architectures
inferredcites →https://doi.org/10.1007/128_2015_641openalex-snapshot
Mechanochemical Reactions Reporting and Repairing Bond Scission in Polymers
inferredcites →https://doi.org/10.1016/j.cell.2015.05.013openalex-snapshot
Allosteric Regulation in Gating the Central Channel of the Nuclear Pore Complex
inferredcites →https://doi.org/10.1016/j.polymer.2007.09.014openalex-snapshot
Cyclo-depolymerization of olefin-containing polymers to give macrocyclic oligomers by metathesis and the entropically-driven ROMP of the olefin-containing macrocyclic esters
inferredcites →https://doi.org/10.1016/j.reactfunctpolym.2005.07.010openalex-snapshot
Entropically driven ring-opening metathesis polymerization (ED-ROMP) of macrocyclic olefin-containing oligoamides
inferredcites →https://doi.org/10.1021/acs.accounts.5b00184openalex-snapshot
Polymer Mechanochemistry: From Destructive to Productive
inferredcites →https://doi.org/10.1021/acs.joc.5b01465openalex-snapshot
Accelerating a Mechanically Driven anti-Woodward–Hoffmann Ring Opening with a Polymer Lever Arm Effect
inferredcites →https://doi.org/10.1021/acsami.5b06440openalex-snapshot
Mechanochemically Active Soft Robots
inferredcites →https://doi.org/10.1021/acsmacrolett.5b00440openalex-snapshot
Mechanochemical Strengthening of a Multi-mechanophore Benzocyclobutene Polymer
inferredcites →https://doi.org/10.1021/cr200399qopenalex-snapshot
Covalent Mechanochemistry: Theoretical Concepts and Computational Tools with Applications to Molecular Nanomechanics
inferredcites →https://doi.org/10.1021/cr9001353openalex-snapshot
Mechanically-Induced Chemical Changes in Polymeric Materials
inferredcites →https://doi.org/10.1021/cr9904009openalex-snapshot
Quantum Mechanical Continuum Solvation Models
inferredcites →https://doi.org/10.1021/ja058516bopenalex-snapshot
Single-Molecule Force Spectroscopy of Bimolecular Reactions: System Homology in the Mechanical Activation of Ligand Substitution Reactions
inferredcites →https://doi.org/10.1021/ja1008932openalex-snapshot
Masked Cyanoacrylates Unveiled by Mechanical Force
inferredcites →https://doi.org/10.1021/ja108429hopenalex-snapshot
Molecular Stress Relief through a Force-Induced Irreversible Extension in Polymer Contour Length
inferredcites →https://doi.org/10.1021/ja207421vopenalex-snapshot
The Entropic and Enthalpic Contributions to Force-Dependent Dissociation Kinetics of the Pyrophosphate Bond
inferredcites →https://doi.org/10.1021/ja2074517openalex-snapshot
Mechanically Induced Scission and Subsequent Thermal Remending of Perfluorocyclobutane Polymers
inferredcites →https://doi.org/10.1021/ja2086728openalex-snapshot
Structure–Mechanochemical Activity Relationships for Cyclobutane Mechanophores
inferredcites →https://doi.org/10.1021/ja301928dopenalex-snapshot
Force–Reactivity Property of a Single Monomer Is Sufficient To Predict the Micromechanical Behavior of Its Polymer
inferredcites →https://doi.org/10.1021/ja302996nopenalex-snapshot
Tension Trapping of Carbonyl Ylides Facilitated by a Change in Polymer Backbone
inferredcites →https://doi.org/10.1021/ja305645xopenalex-snapshot
Proton-Coupled Mechanochemical Transduction: A Mechanogenerated Acid
inferredcites →https://doi.org/10.1021/ja403757popenalex-snapshot
“Flex-Activated” Mechanophores: Using Polymer Mechanochemistry To Direct Bond Bending Activation
inferredcites →https://doi.org/10.1021/ja4075997openalex-snapshot
Stress-Responsive Polymers Containing Cyclobutane Core Mechanophores: Reactivity and Mechanistic Insights
inferredcites →https://doi.org/10.1021/ja509585gopenalex-snapshot
A Remote Stereochemical Lever Arm Effect in Polymer Mechanochemistry
inferredcites →https://doi.org/10.1021/ja710642aopenalex-snapshot
Dynamic Strength of the Silicon−Carbon Bond Observed over Three Decades of Force-Loading Rates
inferredcites →https://doi.org/10.1021/ja8095834openalex-snapshot
First Principles Dynamics and Minimum Energy Pathways for Mechanochemical Ring Opening of Cyclobutene
inferredcites →https://doi.org/10.1021/ja9036548openalex-snapshot
gem -Dichlorocyclopropanes as Abundant and Efficient Mechanophores in Polybutadiene Copolymers under Mechanical Stress
inferredcites →https://doi.org/10.1021/jacs.5b02492openalex-snapshot
Force-Rate Characterization of Two Spiropyran-Based Molecular Force Probes
inferredcites →https://doi.org/10.1021/mz500031qopenalex-snapshot
Mechanochemical Activation of Covalent Bonds in Polymers with Full and Repeatable Macroscopic Shape Recovery
inferredcites →https://doi.org/10.1021/ol006059sopenalex-snapshot
Stereoselectivity of Macrocyclic Ring-Closing Olefin Metathesis
inferredcites →https://doi.org/10.1021/om300161zopenalex-snapshot
Mechanical Activation of a Latent Olefin Metathesis Catalyst and Persistence of its Active Species in ROMP
inferredcites →https://doi.org/10.1038/nature05681openalex-snapshot
Biasing reaction pathways with mechanical force
inferredcites →https://doi.org/10.1038/nature07970openalex-snapshot
Force-induced activation of covalent bonds in mechanoresponsive polymeric materials
inferredcites →https://doi.org/10.1038/nchem.1358openalex-snapshot
Mechanically induced chemiluminescence from polymers incorporating a 1,2-dioxetane unit in the main chain
inferredcites →https://doi.org/10.1038/nchem.1540openalex-snapshot
A backbone lever-arm effect enhances polymer mechanochemistry
inferredcites →https://doi.org/10.1038/nchem.167openalex-snapshot
Activating catalysts with mechanical force
inferredcites →https://doi.org/10.1038/nchem.1676openalex-snapshot
The Janus-faced role of external forces in mechanochemical disulfide bond cleavage
inferredcites →https://doi.org/10.1038/nchem.2185openalex-snapshot
Inducing and quantifying forbidden reactivity with single-molecule polymer mechanochemistry
inferredcites →https://doi.org/10.1038/ncomms3538openalex-snapshot
Model studies of force-dependent kinetics of multi-barrier reactions
inferredcites →https://doi.org/10.1038/ncomms5899openalex-snapshot
Cephalopod-inspired design of electro-mechano-chemically responsive elastomers for on-demand fluorescent patterning
inferredcites →https://doi.org/10.1039/c0cs00148aopenalex-snapshot
Chemomechanics: chemical kinetics for multiscale phenomena
inferredcites →https://doi.org/10.1039/c0jm04079gopenalex-snapshot
The physical chemistry of mechanoresponsive polymers
inferredcites →https://doi.org/10.1039/c2cc37095fopenalex-snapshot
Comparison of the predictive performance of the Bell–Evans, Taylor-expansion and statistical-mechanics models of mechanochemistry
inferredcites →https://doi.org/10.1039/c4sc01945hopenalex-snapshot
Molecular engineering of mechanophore activity for stress-responsive polymeric materials
inferredcites →https://doi.org/10.1039/c6cc04312gopenalex-snapshot
Stress-induced colouration and crosslinking of polymeric materials by mechanochemical formation of triphenylimidazolyl radicals
inferredcites →https://doi.org/10.1063/1.3656367openalex-snapshot
Chemical reactions modulated by mechanical stress: Extended Bell theory
inferredcites →https://doi.org/10.1073/pnas.0511035103openalex-snapshot
Force-dependent chemical kinetics of disulfide bond reduction observed with single-molecule techniques
inferredcites →https://doi.org/10.1073/pnas.1201582109openalex-snapshot
Allosteric gating mechanism underlies the flexible gating of KCNQ1 potassium channels
inferredcites →https://doi.org/10.1103/physrevlett.104.048101openalex-snapshot
Single-Molecule Rupture Dynamics on Multidimensional Landscapes
inferredcites →https://doi.org/10.1126/science.1193412openalex-snapshot
Trapping a Diradical Transition State by Mechanochemical Polymer Extension
inferredcites →https://doi.org/10.1126/science.1248494openalex-snapshot
Toughening Elastomers with Sacrificial Bonds and Watching Them Break
inferredcites →https://doi.org/10.1146/annurev.pharmtox.47.120505.105159openalex-snapshot
Allosteric Modulation of G Protein–Coupled Receptors
inferredcites →https://doi.org/10.1351/pac-con-09-11-36openalex-snapshot
Chemomechanics with molecular force probes

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/anie.202300768openalex-snapshot
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Mechanochemical Approaches to Fundamental Studies in Soft‐Matter Physics
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Force Transduction Through Distant Force‐Bearing Regioisomeric Linkages Affects the Mechanochemical Reactivity of Cyclobutane
inferred← citeshttps://doi.org/10.1002/anie.202408225openalex-snapshot
Mechanochemical Backbone Editing for Controlled Degradation of Vinyl Polymers
inferred← citeshttps://doi.org/10.1002/anie.202512698openalex-snapshot
Logic‐Gated Release of a Dual Payload from a β‐Lactam Mechanophore with a Rotaxane Actuator
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Single-Chain Mechanics at Low Temperatures: A Study of Three Kinds of Polymers from 153 to 300 K
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Force-Accelerated Ring Opening of Episulfide by Pulsed Ultrasonication
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Designing Ruddlesden–Popper Layered Perovskites through Their Organic Cations
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A Mechanochemically Gated Fluorescent Probe
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Mechanical Activation of Platinum–Acetylide Complex for Olefin Hydrosilylation
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A Catenane as a Mechanical Protecting Group
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A Polymer with Mechanochemically Active Hidden Length
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inferred← citeshttps://doi.org/10.1021/jacs.1c02149openalex-snapshot
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Force-Induced Near-Infrared Chromism of Mechanophore-Linked Polymers
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Covalent Mechanochemistry and Contemporary Polymer Network Chemistry: A Marriage in the Making
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Mechanochemistry of Cubane
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Force-Triggered Atropisomerization of a Parallel Diarylethene to Its Antiparallel Diastereomers
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Coumarin Dimer Is an Effective Photomechanochemical AND Gate for Small-Molecule Release
inferred← citeshttps://doi.org/10.1021/jacs.3c08595openalex-snapshot
Sacrificial Mechanical Bond is as Effective as a Sacrificial Covalent Bond in Increasing Cross-Linked Polymer Toughness
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Bicyclo[2.2.0]hexene: A Multicyclic Mechanophore with Reactivity Diversified by External Forces
inferred← citeshttps://doi.org/10.1021/jacs.4c07445openalex-snapshot
Polyethylene Materials with Tunable Degradability by Incorporating In-Chain Mechanophores
inferred← citeshttps://doi.org/10.1021/jacs.4c13319openalex-snapshot
Accelerated Mechanochemical Bond Scission and Stabilization against Heat and Light in Carbamoyloxime Mechanophores
inferred← citeshttps://doi.org/10.1021/jacs.4c13480openalex-snapshot
Advancing the Mechanosensitivity of Atropisomeric Diarylethene Mechanophores through a Lever-Arm Effect
inferred← citeshttps://doi.org/10.1021/jacs.4c15655openalex-snapshot
A Dual-Pathway Responsive Mechanophore for Intelligent Luminescent Polymer Materials
inferred← citeshttps://doi.org/10.1021/jacs.5c03945openalex-snapshot
Polymer Mechanochemistry: Where Is It Going?
inferred← citeshttps://doi.org/10.1021/jacs.5c06150openalex-snapshot
Computational Exploration of Polymer Mechanochemistry: Quantitation of Activation Force and Systematic Discovery of Reaction Sites by the Extended Artificial Force-Induced Reaction Method
inferred← citeshttps://doi.org/10.1021/jacs.5c14243openalex-snapshot
Catalytic Alternating Copolymerization to Access Mechanoresponsive Cyclic Olefin Copolymers with On-Demand Recyclability
inferred← citeshttps://doi.org/10.1021/jacs.6c10807openalex-snapshot
Molecular Motion and Connectivity Govern Mechanophore Activation in High- T g Glassy Polymers
inferred← citeshttps://doi.org/10.1021/jacs.8b05110openalex-snapshot
Mechanochemical Degradation of Denpols: Synthesis and Ultrasound-Induced Chain Scission of Polyphenylene-Based Dendronized Polymers
inferred← citeshttps://doi.org/10.1021/jacs.8b09628openalex-snapshot
Mechanochemical Regulation of a Photochemical Reaction
inferred← citeshttps://doi.org/10.1021/jacs.9b01736openalex-snapshot
Benzoladderene Mechanophores: Synthesis, Polymerization, and Mechanochemical Transformation
inferred← citeshttps://doi.org/10.1021/jacs.9b08663openalex-snapshot
Mechanically Triggered Small Molecule Release from a Masked Furfuryl Carbonate
inferred← citeshttps://doi.org/10.1021/jacs.9b12482openalex-snapshot
A Polymer with “Locked” Degradability: Superior Backbone Stability and Accessible Degradability Enabled by Mechanophore Installation
inferred← citeshttps://doi.org/10.1021/jacs.9b13359openalex-snapshot
Mechanically Gated Degradable Polymers
inferred← citeshttps://doi.org/10.1021/jacsau.6c00989openalex-snapshot
Designing Heterolytic and Homolytic Bond Scission in Diarylmethane Mechanophores
inferred← citeshttps://doi.org/10.1038/s41467-017-01412-8openalex-snapshot
Multi-modal mechanophores based on cinnamate dimers
inferred← citeshttps://doi.org/10.1038/s41467-018-05996-7openalex-snapshot
The photoregulation of a mechanochemical polymer scission
inferred← citeshttps://doi.org/10.1038/s41467-022-30972-7openalex-snapshot
Force–reversible chemical reaction at ambient temperature for designing toughened dynamic covalent polymer networks
inferred← citeshttps://doi.org/10.1038/s41467-023-35925-2openalex-snapshot
Mechanochemically accessing a challenging-to-synthesize depolymerizable polymer
inferred← citeshttps://doi.org/10.1038/s41557-019-0396-5openalex-snapshot
The cascade unzipping of ladderane reveals dynamic effects in mechanochemistry
inferred← citeshttps://doi.org/10.1038/s41557-023-01266-2openalex-snapshot
Experimental quantitation of molecular conditions responsible for flow-induced polymer mechanochemistry
inferred← citeshttps://doi.org/10.1038/s41557-024-01510-3openalex-snapshot
Mechanical scission of a knotted polymer
inferred← citeshttps://doi.org/10.1038/s41570-020-00249-yopenalex-snapshot
The many flavours of mechanochemistry and its plausible conceptual underpinnings
inferred← citeshttps://doi.org/10.1038/s41570-023-00514-wopenalex-snapshot
Editing of polymer backbones
inferred← citeshttps://doi.org/10.1038/s41578-020-00249-wopenalex-snapshot
The role of polymer mechanochemistry in responsive materials and additive manufacturing
inferred← citeshttps://doi.org/10.1039/c7sm00882aopenalex-snapshot
Spin variable approach for the statistical mechanics of folding and unfolding chains
inferred← citeshttps://doi.org/10.1039/c8py00720aopenalex-snapshot
Empowering mechanochemistry with multi-mechanophore polymer architectures
inferred← citeshttps://doi.org/10.1039/c8sc04830dopenalex-snapshot
Force–conductance spectroscopy of a single-molecule reaction
inferred← citeshttps://doi.org/10.1039/c9cc07439bopenalex-snapshot
Effect of disulphide loop length on mechanochemical structural stability of macromolecules
inferred← citeshttps://doi.org/10.1039/c9py01937eopenalex-snapshot
Polymer mechanochemistry-enabled pericyclic reactions
inferred← citeshttps://doi.org/10.1039/d0cs00940gopenalex-snapshot
Mechanochemical tools for polymer materials
inferred← citeshttps://doi.org/10.1039/d0qm00435aopenalex-snapshot
Reaction Cascades in Polymer Mechanochemistry
inferred← citeshttps://doi.org/10.1039/d0ra09834eopenalex-snapshot
The activation efficiency of mechanophores can be modulated by adjacent polymer composition
inferred← citeshttps://doi.org/10.1039/d0sc06140aopenalex-snapshot
Empowering self-reporting polymer blends with orthogonal optical properties responsive in a broader force range
inferred← citeshttps://doi.org/10.1039/d1cc05305aopenalex-snapshot
Force-induced strengthening of a mechanochromic polymer based on a naphthalene-fused cyclobutane mechanophore
inferred← citeshttps://doi.org/10.1039/d1sc02890aopenalex-snapshot
A modular approach to mechanically gated photoswitching with color-tunable molecular force probes
inferred← citeshttps://doi.org/10.1039/d1sc03182aopenalex-snapshot
Force-modulated reductive elimination from platinum( ii ) diaryl complexes
inferred← citeshttps://doi.org/10.1039/d2cc01223eopenalex-snapshot
Aromatic foldamers as molecular springs in network polymers
inferred← citeshttps://doi.org/10.1039/d2fd00141aopenalex-snapshot
Concluding remarks: Fundamentals, applications and future of mechanochemistry
inferred← citeshttps://doi.org/10.1039/d2py00728bopenalex-snapshot
A double-spiro ring-structured mechanophore with dual-signal mechanochromism and multistate mechanochemical behavior: non-sequential ring-opening and multimodal analysis
inferred← citeshttps://doi.org/10.1039/d2py00892kopenalex-snapshot
Light- and mechanic field controlled dynamic soft matter materials
inferred← citeshttps://doi.org/10.1039/d2sc05051jopenalex-snapshot
Bond breaking of furan–maleimide adducts via a diradical sequential mechanism under an external mechanical force
inferred← citeshttps://doi.org/10.1039/d3cp04160copenalex-snapshot
Polymer mechanochemistry: from single molecule to bulk material
inferred← citeshttps://doi.org/10.1039/d3mr00018dopenalex-snapshot
Kinetics of primary mechanochemical covalent-bond-forming reactions
inferred← citeshttps://doi.org/10.1039/d3qm00282aopenalex-snapshot
Real time optical monitoring of cascade mechanochemical reactions and capture of ultra-unstable intermediates under hydrostatic pressure
inferred← citeshttps://doi.org/10.1039/d5py00232jopenalex-snapshot
Cation–π interactions in polymer science: from fundamental insights to material applications
inferred← citeshttps://doi.org/10.1055/a-1480-3215openalex-snapshot
Highly Efficient Visible-Light-Driven [2+2] Cycloaddition of Maleimides to Alkenes and Alkynes for the Synthesis of 3-Azabicyclo[3.2.0]heptane-Fused Scaffolds
inferred← citeshttps://doi.org/10.1055/a-1703-2608openalex-snapshot
Heterocyclic Mechanophores in Polymer Mechanochemistry
inferred← citeshttps://doi.org/10.1055/a-1710-5656openalex-snapshot
The Contributions of Model Studies for Fundamental Understanding of Polymer Mechanochemistry
inferred← citeshttps://doi.org/10.1055/s-0042-1751536openalex-snapshot
Harnessing the Conformer/Atropisomer-Dependent Photochromism of Diarylethene Photoswitches and Forcing a Diarylethene Atropisomer to Its Configurational Diastereomers with Polymer Mechanochemistry
inferred← citeshttps://doi.org/10.1063/1.5026386openalex-snapshot
Thermodynamics of small systems with conformational transitions: The case of two-state freely jointed chains with extensible units
inferred← citeshttps://doi.org/10.1080/15583724.2020.1801727openalex-snapshot
Synthetic strategies, properties, and applications of unsaturated main-chain metallopolymers prepared by olefin metathesis polymerization
inferred← citeshttps://doi.org/10.1101/2023.02.17.528971openalex-snapshot
Rapid Molecular Mechanotyping with Microfluidic Force Spectroscopy
inferred← citeshttps://doi.org/10.1103/physreve.98.052146openalex-snapshot
Isotensional and isometric force-extension response of chains with bistable units and Ising interactions
inferred← citeshttps://doi.org/10.1126/science.aan1026openalex-snapshot
Experimentally realized mechanochemistry distinct from force-accelerated scission of loaded bonds
inferred← citeshttps://doi.org/10.1126/science.adg3229openalex-snapshot
Facile mechanochemical cycloreversion of polymer cross-linkers enhances tear resistance
inferred← citeshttps://doi.org/10.1134/s0036029519040116openalex-snapshot
Selective Deformation of Single Macromolecules and Biomolecular Structures as a Method for Remote Control of Their Properties and Functions for Next-Generation Medicine
inferred← citeshttps://doi.org/10.1177/02670836241309813openalex-snapshot
Preparation of high-performance red fluorescent epoxy resin films guided by rare earth europium
inferred← citeshttps://doi.org/10.21203/rs.3.rs-4310783/v1openalex-snapshot
Mechanochemical Backbone Editing for Controlled Degradation of Vinyl Polymers
inferred← citeshttps://doi.org/10.26434/chemrxiv-2023-lx3q4openalex-snapshot
Bicyclo[2.2.0]hexene (BCH): A Multimodal Mechanophore with Force-Governed Chemoselectivity
inferred← citeshttps://doi.org/10.26434/chemrxiv.13514377openalex-snapshot
Toughening Hydrogels Through Force-triggered Chemical Reactions that Lengthen Polymer Strands
inferred← citeshttps://doi.org/10.26434/chemrxiv.13514377.v1openalex-snapshot
Toughening Hydrogels Through Force-triggered Chemical Reactions that Lengthen Polymer Strands
inferred← citeshttps://doi.org/10.3390/catal15070690openalex-snapshot
Mechanochemical and Transition-Metal-Catalyzed Reactions of Alkynes
inferred← citeshttps://doi.org/10.3390/inventions4010019openalex-snapshot
Full Statistics of Conjugated Thermodynamic Ensembles in Chains of Bistable Units
inferred← citeshttps://doi.org/10.70675/c6954e6ezb405z411czb59fz0792e9e7b0dcopenalex-snapshot
Statistical mechanics and thermodynamics of systems with conformational transitions : applications to biological macromolecules
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