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New aspect of the mechanism of photocatalytic oxidation of organic compounds by polyoxometalates in aqueous solutions. The selective photooxidation of propan-2-ol to propanone: The role of OH radicals

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/anie.199100341openalex-snapshot
Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines
inferredcites →https://doi.org/10.1016/0010-8545(91)84012-topenalex-snapshot
Intramolecular energy transfer in polyoxometaloeuropate lattices and their application to a.c. electroluminescence device
inferredcites →https://doi.org/10.1016/0010-8545(92)85001-7openalex-snapshot
Coordination chemistry of soluble metal oxides of molybdenum and vanadium
inferredcites →https://doi.org/10.1016/0020-708x(67)90115-9openalex-snapshot
A compilation of specific bimolecular rate constants for the reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals with inorganic and organic compounds in aqueous solution
inferredcites →https://doi.org/10.1016/0304-5102(94)00083-2openalex-snapshot
Photocatalytic degradation of chlorophenols to CO2 and HCl with polyoxotungstates in aqueous solution
inferredcites →https://doi.org/10.1016/1010-6030(95)04207-5openalex-snapshot
On the mechanism of photocatalytic degradation of chlorinated phenols to CO2 and HCl by polyoxometalates
inferredcites →https://doi.org/10.1016/s0021-9258(18)86325-6openalex-snapshot
CONTRIBUTION TO THE CHEMISTRY OF PHOSPHOMOLYBDIC ACIDS, PHOSPHOTUNGSTIC ACIDS, AND ALLIED SUBSTANCES
inferredcites →https://doi.org/10.1021/ar50124a008openalex-snapshot
Photochromism and electrochromism in amorphous transition metal oxide films
inferredcites →https://doi.org/10.1021/ic00120a019openalex-snapshot
Coexistence of Magnetic and Delocalized Electrons in Hybrid Molecular Materials. The Series of Organic-Inorganic Radical Salts (BEDT-TTF)8[XW12O40](solv)n (X = 2(H+), BIII, SiIV, CuII, CoII, and FeIII; solv = H2O, CH3CN)
inferredcites →https://doi.org/10.1021/ic00185a014openalex-snapshot
Electrochemical and photochemical reduction of decatungstate: a reinvestigation
inferredcites →https://doi.org/10.1021/ic00256a022openalex-snapshot
Characterization of a weak intermolecular photosensitive complex between an organic substrate and a polyoxometalate. Crystal and molecular structure of .alpha.-H3PMo12O40.cntdot.6DMA.cntdot.CH3CN.cntdot.0.5H2O (DMA = N,N-dimethylacetamide)
inferredcites →https://doi.org/10.1021/j100192a083openalex-snapshot
Alkane reactions with photoactivated decatungstate in neutral and acid solution: molecular orbital theory
inferredcites →https://doi.org/10.1021/j150501a012openalex-snapshot
The Extent of the Photochemical Reduction of Phosphotungstic Acid
inferredcites →https://doi.org/10.1021/j150663a004openalex-snapshot
Photocatalytic alcohol dehydrogenation using ammonium heptamolybdate
inferredcites →https://doi.org/10.1021/ja00160a046openalex-snapshot
Photodimerization of cyclohexene and methane by decatungstate anions: molecular orbital theory
inferredcites →https://doi.org/10.1021/ja00224a035openalex-snapshot
Catalytic photochemical oxidation of organic substrates by polyoxometalates. Picosecond spectroscopy, photochemistry, and structural properties of charge-transfer complexes between heteropolytungstic acids and dipolar organic compounds
inferredcites →https://doi.org/10.1021/ja00255a019openalex-snapshot
Photoactivation of metal oxide surfaces: photocatalyzed oxidation of alcohols by heteropolytungstates
inferredcites →https://doi.org/10.1039/f19827802769openalex-snapshot
Relative electron-donating ability of simple alcohol radicals toward 12-heteropolytungstates. A pulse radiolysis study
inferredcites →https://doi.org/10.1080/01614949508007097openalex-snapshot
Heteropoly Acids and Related Compounds as Catalysts for Fine Chemical Synthesis
inferredcites →https://doi.org/10.1126/science.228.4699.533openalex-snapshot
Metal Oxide Chemistry in Solution: The Early Transition Metal Polyoxoanions
inferredcites →https://doi.org/10.1149/1.2069303openalex-snapshot
Deep Ultraviolet Photoresist Based on Tungsten Polyoxometalates and Poly(Vinyl Alcohol) for Bilayer Photolithography
inferredcites →https://doi.org/10.1246/bcsj.69.3435openalex-snapshot
Photocatalysis of H3PW12O40 for 4-Chlorophenol Decomposition in Aqueous Media
inferredcites →https://doi.org/10.1246/bcsj.70.1551openalex-snapshot
Photocatalyzed Decomposition of 4-Chlorophenol by Keggin-Type Heteropolytungstate

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4651633openalex-extracted
Degradation of Methyle Blue Dye Under Sunlight Irradiation Using Dawson Type Heteropolyanion Cesium-Substituted as Photocatalyst
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Polyoxometalates as Homogeneous Oxidation Catalysts
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The Intrinsic Charge Carrier Behaviors and Applications of Polyoxometalate Clusters Based Materials
inferred← citeshttps://doi.org/10.1002/adsc.200303076openalex-snapshot
Heterogeneous Photooxidation of Alcohols in Water by Photocatalytic Membranes Incorporating Decatungstate
inferred← citeshttps://doi.org/10.1002/chem.200501216openalex-snapshot
Tetrabutylammonium Decatungstate‐Photosensitized Alkylation of Electrophilic Alkenes: Convenient Functionalization of Aliphatic CH Bonds
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The Organic Chemistry of TiO2 Photocatalysis of Aromatic Hydrocarbons
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Size‐ and Shape‐Controlled Synthesis and Assembly of a Silver Nanocomplex in UV‐Irradiated TSA Solution
inferred← citeshttps://doi.org/10.1002/ejoc.200500418openalex-snapshot
Aerobic Photooxidation in Water by Polyoxotungstates: The Case of Uracil
inferred← citeshttps://doi.org/10.1007/0-306-47625-8_26openalex-snapshot
Photocatalytic Decontamination by Polyoxometalates
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Photochemistry and Photocatalysis by Polyoxometalates
inferred← citeshttps://doi.org/10.1007/s11224-023-02236-7openalex-snapshot
Insights into substitution effects and reactivity of Lindqvist-type polyoxometalates from DFT calculations
inferred← citeshttps://doi.org/10.1007/s11237-018-9577-3openalex-snapshot
Photocatalytic Monofluorination of Unactivated C(sp3)–H Bonds by N-Fluorobenzenesulfimide Involving the Decatungstate Anion and the Effect of Water Additives on These Reactions
inferred← citeshttps://doi.org/10.1007/s11244-006-0115-5openalex-snapshot
Hybrid photocatalytic membranes embedding decatungstate for heterogeneous photooxygenation
inferred← citeshttps://doi.org/10.1016/b0-08-043748-6/03036-xopenalex-snapshot
Polyoxometalates: Reactivity
inferred← citeshttps://doi.org/10.1016/j.apcata.2009.06.046openalex-snapshot
Preparation and photocatalytic activity of Keggin-ion tungstate and TiO2 hybrid layer-by-layer film composites
inferred← citeshttps://doi.org/10.1016/j.apcata.2010.07.001openalex-snapshot
Preparation and photocatalytic activity of [PW Mo12−O40]3−/TiO2 hybrid film composites
inferred← citeshttps://doi.org/10.1016/j.apcata.2011.03.030openalex-snapshot
Photocatalytic activity and its stacking order dependence of transparent 12 tungsto(VI) phosphoric acid-brookite hybrid films
inferred← citeshttps://doi.org/10.1016/j.apcata.2012.08.030openalex-snapshot
Photocatalytic activity and photoinduced hydrophilicity of brookite–heteropolyacid hybrid films
inferred← citeshttps://doi.org/10.1016/j.apcatb.2004.02.016openalex-snapshot
Selective photocatalytic reduction–recovery of palladium using polyoxometallates
inferred← citeshttps://doi.org/10.1016/j.apcatb.2005.06.012openalex-snapshot
Photocatalytic reduction of chromium and oxidation of organics by polyoxometalates
inferred← citeshttps://doi.org/10.1016/j.apcatb.2008.08.001openalex-snapshot
Photocatalytic reductive–oxidative degradation of Acid Orange 7 by polyoxometalates
inferred← citeshttps://doi.org/10.1016/j.apcatb.2013.03.025openalex-snapshot
HydrophobicW10O324−/silica photocatalyst for toluene oxidation in water system
inferred← citeshttps://doi.org/10.1016/j.apcatb.2016.09.031openalex-snapshot
Degradation of emerging concern contaminants in water by heterogeneous photocatalysis with Na4W10O32
inferred← citeshttps://doi.org/10.1016/j.apcatb.2018.10.056openalex-snapshot
Preparation and photocatalytic activity of Mo-modified Ti-doped HAp
inferred← citeshttps://doi.org/10.1016/j.apcatb.2020.119299openalex-snapshot
(NH4)4[NiMo6O24H6].5H2O / g-C3N4 materials for selective photo-oxidation of C O and C C bonds
inferred← citeshttps://doi.org/10.1016/j.apt.2019.05.010openalex-snapshot
Effects of MoO modification on photocatalytic activity of hydroxyapatite and Ti-doped hydroxyapatite
inferred← citeshttps://doi.org/10.1016/j.cattod.2011.11.033openalex-snapshot
Photocatalytic properties of sodium decatungstate supported on sol–gel silica in the oxidation of glycerol
inferred← citeshttps://doi.org/10.1016/j.ccr.2015.06.016openalex-snapshot
Hybrid polyoxometalate materials for photo(electro-) chemical applications
inferred← citeshttps://doi.org/10.1016/j.dyepig.2003.07.004openalex-snapshot
Homogenous photocatalytic degradation of a disperse dye and its dye bath analogue by silicadodecatungstic acid
inferred← citeshttps://doi.org/10.1016/j.ijhydene.2026.155103openalex-snapshot
Polyoxometalates-mediated hydrogen production from photocatalytic methanol reforming
inferred← citeshttps://doi.org/10.1016/j.jcis.2009.07.018openalex-snapshot
Photocatalytic property of a keggin-type polyoxometalates-containing bilayer system for degradation organic dye model
inferred← citeshttps://doi.org/10.1016/j.jcis.2010.07.001openalex-snapshot
Self-assembly of polyoxometalate–azure A multilayer films and their photocatalytic properties for degradation of methyl orange under visible light irradiation
inferred← citeshttps://doi.org/10.1016/j.jcis.2011.09.017openalex-snapshot
Facile synthesis of polyoxometalate–thionine composite via direct precipitation method and its photocatalytic activity for degradation of rhodamine B under visible light
inferred← citeshttps://doi.org/10.1016/j.jphotochem.2006.12.022openalex-snapshot
Photocatalytic reductive destruction of azo dyes by polyoxometallates: Naphthol blue black
inferred← citeshttps://doi.org/10.1016/j.jphotochem.2016.10.036openalex-snapshot
Decatungstate anion as an efficient photocatalytic species for the transformation of the pesticide 2-(1-naphthyl)acetamide in aqueous solution
inferred← citeshttps://doi.org/10.1016/j.jphotochemrev.2012.04.003openalex-snapshot
Overview on oxidation mechanisms of organic compounds by TiO2 in heterogeneous photocatalysis
inferred← citeshttps://doi.org/10.1016/j.jphotochemrev.2012.08.001openalex-snapshot
Polyoxometalate-based molecular/nano composites: Advances in environmental remediation by photocatalysis and biomimetic approaches to solar energy conversion
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Nanoscale ZnS/TiO2 composites: Preparation, characterization, and visible-light photocatalytic activity
inferred← citeshttps://doi.org/10.1016/j.matchemphys.2013.12.047openalex-snapshot
Comparative study of photoinduced wettability conversion between [PW12O40]3−/brookite and [SiW12O40]4−/brookite hybrid films
inferred← citeshttps://doi.org/10.1016/j.materresbull.2007.04.012openalex-snapshot
Synthesis of Se nanoparticles by using TSA ion and its photocatalytic application for decolorization of cango red under UV irradiation
inferred← citeshttps://doi.org/10.1016/j.materresbull.2007.06.004openalex-snapshot
Synthesis of novel urchin-like architecture Au by self-assembly coupled without template
inferred← citeshttps://doi.org/10.1016/j.molcata.2013.01.037openalex-snapshot
Photocatalysis with Na4W10O32 in water system: Formation and reactivity of OH radicals
inferred← citeshttps://doi.org/10.1016/j.molcata.2016.01.031openalex-snapshot
Keggin type of cesium phosphomolybdate synthesized via solid-state reaction as an efficient catalyst for the photodegradation of a dye pollutant in aqueous phase
inferred← citeshttps://doi.org/10.1016/s0021-9517(03)00037-xopenalex-snapshot
Preparation and heterogeneous photocatalytic behaviors of the surface-modified porous silica materials impregnated with monosubstituted keggin units
inferred← citeshttps://doi.org/10.1016/s0143-7208(02)00031-1openalex-snapshot
Application of polyoxotungstates as environmental catalysts: wet air oxidation of acid dye Orange II
inferred← citeshttps://doi.org/10.1016/s0926-3373(02)00264-3openalex-snapshot
Photocatalytic reduction—recovery of silver using polyoxometalates
inferred← citeshttps://doi.org/10.1016/s1010-6030(02)00042-4openalex-snapshot
Photolytic degradation of all chlorophenols with polyoxometallates and H2O2
inferred← citeshttps://doi.org/10.1016/s1010-6030(02)00185-5openalex-snapshot
Near-UV–VIS light induced acid orange 7 bleaching in the presence of SiW12O404− catalyst
inferred← citeshttps://doi.org/10.1021/acs.jpcc.0c10734openalex-snapshot
Photoconversion of 2-Propanol on Rutile Titania: A Combined Liquid-Phase and Surface Science Study
inferred← citeshttps://doi.org/10.1021/acscatal.7b03354openalex-snapshot
Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope
inferred← citeshttps://doi.org/10.1021/cm800167xopenalex-snapshot
Processing and Photocatalytic Properties of Transparent 12 Tungsto(VI) Phosphoric Acid−TiO2 Hybrid Films
inferred← citeshttps://doi.org/10.1021/cr050193eopenalex-snapshot
Hydrogen Production by Molecular Photocatalysis
inferred← citeshttps://doi.org/10.1021/es000212wopenalex-snapshot
Sonolytic, Photolytic, and Photocatalytic Decomposition of Atrazine in the Presence of Polyoxometalates
inferred← citeshttps://doi.org/10.1021/es020933qopenalex-snapshot
Photocatalytic Reduction and Recovery of Copper by Polyoxometalates
inferred← citeshttps://doi.org/10.1021/es0493143openalex-snapshot
Photocatalytic Reduction and Recovery of Mercury by Polyoxometalates
inferred← citeshttps://doi.org/10.1021/es990802yopenalex-snapshot
Light Induced Elimination of Mono- and Polychlorinated Phenols from Aqueous Solutions by PW12O403-. The Case of 2,4,6-Trichlorophenol
inferred← citeshttps://doi.org/10.1021/ic051134mopenalex-snapshot
Inorganic−Metalorganic Hybrids Based on Copper(II)-Monosubstituted Keggin Polyanions and Dinuclear Copper(II)−Oxalate Complexes. Synthesis, X-ray Structural Characterization, and Magnetic Properties
inferred← citeshttps://doi.org/10.1021/ic060762gopenalex-snapshot
Hybrid Inorganic−Metalorganic Compounds Containing Copper(II)-Monosubstituted Keggin Polyanions and Polymeric Copper(I) Complexes.
inferred← citeshttps://doi.org/10.1021/ic061671mopenalex-snapshot
Tetrahydroxy-p-benzoquinone as a Source of Polydentate O-Donor Ligands. Synthesis, Crystal Structure, and Magnetic Properties of the [Cu(bpy)(dhmal)]2Dimer and the Two-Dimensional [{SiW12O40}{Cu2(bpy)2(H2O)(ox)}2]·16H2O Inorganic−Metalorganic Hybrid
inferred← citeshttps://doi.org/10.1021/jp067010sopenalex-snapshot
Facile Size-Controlled Synthesis of Silver Nanoparticles in UV-Irradiated Tungstosilicate Acid Solution
inferred← citeshttps://doi.org/10.1039/a908588bopenalex-snapshot
Reactivity of the charge transfer excited state of sodium decatungstate at the nanosecond time scale
inferred← citeshttps://doi.org/10.1039/b610551copenalex-snapshot
Solvent-free, heterogeneous photooxygenation of hydrocarbons by Hyflon? membranes embedding a fluorous-tagged decatungstate
inferred← citeshttps://doi.org/10.1039/b700395copenalex-snapshot
Photocatalysis: a promising route for 21st century organic chemistry
inferred← citeshttps://doi.org/10.1039/b717151jopenalex-snapshot
One-step synthesis of silver nanoparticles in self-assembled multilayered films based on a Keggin structure compound
inferred← citeshttps://doi.org/10.1039/b817071aopenalex-snapshot
Layer-by-layer assembly of chitosan/tungstosilicate acid-Ag nanocomplex with electrocatalytic properties
inferred← citeshttps://doi.org/10.1039/c1dt11220aopenalex-snapshot
New trends in polyoxometalate photoredox chemistry: From photosensitisation to water oxidation catalysis
inferred← citeshttps://doi.org/10.1039/c2jm33246aopenalex-snapshot
Polyoxometalate-based materials for efficient solar and visible light harvesting: application to the photocatalytic degradation of azo dyes
inferred← citeshttps://doi.org/10.1039/c3ra43378aopenalex-snapshot
Organic–inorganic hybrid: a novel template for synthesis of nanostructured Ag
inferred← citeshttps://doi.org/10.1039/c4ee00389fopenalex-snapshot
Molecular catalysts for hydrogen production from alcohols
inferred← citeshttps://doi.org/10.1039/c7ra01342fopenalex-snapshot
Electrostatic polypyridine–ruthenium( ii )⋯decatungstate dyads: structures, characterizations and photodegradation of dye
inferred← citeshttps://doi.org/10.1039/c8cp07101bopenalex-snapshot
Multi-electron reduction of Wells–Dawson polyoxometalate films onto metallic, semiconducting and dielectric substrates
inferred← citeshttps://doi.org/10.1039/d0gc01326aopenalex-snapshot
Facile synthesis of B/g-C 3 N 4 composite materials for the continuous-flow selective photo-production of acetone
inferred← citeshttps://doi.org/10.1039/d6sc04575hopenalex-snapshot
Pre-association enables visible-light induced proton-coupled electron-transfer in a titanium-functionalized polyoxotungstate
inferred← citeshttps://doi.org/10.1080/21622515.2025.2458795openalex-snapshot
Degradation of methyl blue dye under direct sunlight irradiation using cesium-substituted Dawson heteropolyanion photocatalyst
inferred← citeshttps://doi.org/10.1081/ese-120021484openalex-snapshot
Novel Catalytic Photochemical and Hydrothermal Treatment Processes for Acid Dye Wastewater
inferred← citeshttps://doi.org/10.1134/1.1366012openalex-snapshot
Investigation of photochromic cluster systems based on molybdenum oxides by ESR spectroscopy
inferred← citeshttps://doi.org/10.1201/9781420027679.ch13openalex-snapshot
The Organic Chemistry of TiO2 Photocatalysis of Aromatic Hydrocarbons
inferred← citeshttps://doi.org/10.2741/1156openalex-snapshot
Photocatalytic processes with tungsten oxygen anion clusters
inferred← citeshttps://doi.org/10.70675/7c245027z368bz41ccz80a2z8bc2949a44abopenalex-snapshot
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