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Nickel-catalysed Negishi cross-coupling reactions: scope and mechanisms

https://doi.org/10.1039/b805648j
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/(sici)1521-3773(19980918)37:17<2387::aid-anie2387>3.0.co;2-mopenalex-snapshot
An Efficient Nickel-Catalyzed Cross-Coupling Between sp3 Carbon Centers
inferredcites →https://doi.org/10.1002/(sici)1521-3773(19991018)38:20<3018::aid-anie3018>3.0.co;2-fopenalex-snapshot
Towards Efficient and Wide-Scope Metal-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions
inferredcites →https://doi.org/10.1002/anie.200352668openalex-snapshot
Ligands for Palladium‐Catalyzed Cross‐Couplings of Alkyl Halides: Use of an Alkyldiaminophosphane Expands the Scope of the Stille Reaction
inferredcites →https://doi.org/10.1002/anie.200390123openalex-snapshot
Advances in Functional‐Group‐Tolerant Metal‐Catalyzed Alkyl–Alkyl Cross‐Coupling Reactions
inferredcites →https://doi.org/10.1002/anie.200702528openalex-snapshot
Ni‐Catalyzed Cascade Formation of C(sp3)C(sp3) Bonds by Cyclization and Cross‐Coupling Reactions of Iodoalkanes with Alkyl Zinc Halides
inferredcites →https://doi.org/10.1002/asia.200600031openalex-snapshot
Microwave‐Assisted Heterogeneous Cross‐Coupling Reactions Catalyzed by Nickel‐in‐Charcoal (Ni/C)
inferredcites →https://doi.org/10.1016/j.jorganchem.2007.01.021openalex-snapshot
Electron transfer in organonickel complexes of α-diimines: Versatile redox catalysts for C–C or C–P coupling reactions – A review
inferredcites →https://doi.org/10.1016/j.tet.2006.03.123openalex-snapshot
An efficient Negishi cross-coupling reaction catalyzed by nickel(II) and diethyl phosphite
inferredcites →https://doi.org/10.1016/j.tetlet.2005.11.013openalex-snapshot
A convenient one-pot Negishi coupling of amino-heteroaryl chlorides and alkyl bromides
inferredcites →https://doi.org/10.1016/s0040-4020(00)00344-6openalex-snapshot
Improved Nickel-Catalyzed Cross-Coupling Reaction Conditions between ortho -Substituted Aryl Iodides/Nonaflates and Alkylzinc Iodides in Solution and in the Solid-Phase
inferredcites →https://doi.org/10.1021/ja00767a075openalex-snapshot
Selective carbon-carbon bond formation by cross-coupling of Grignard reagents with organic halides. Catalysis by nickel-phosphine complexes
inferredcites →https://doi.org/10.1021/ja00858a011openalex-snapshot
Mechanistic studies of nickel catalysis in the cross coupling of aryl halides with alkylmetals. Role of arylalkylnickel(II) species as intermediates
inferredcites →https://doi.org/10.1021/ja017086wopenalex-snapshot
A Mild and Efficient Catalytic Alkylative Monofunctionalization of Cyclic Anhydrides
inferredcites →https://doi.org/10.1021/ja0363258openalex-snapshot
Palladium-Catalyzed Negishi Cross-Coupling Reactions of Unactivated Alkyl Iodides, Bromides, Chlorides, and Tosylates
inferredcites →https://doi.org/10.1021/ja0389366openalex-snapshot
Cross-Couplings of Unactivated Secondary Alkyl Halides: Room-Temperature Nickel-Catalyzed Negishi Reactions of Alkyl Bromides and Iodides
inferredcites →https://doi.org/10.1021/ja040817iopenalex-snapshot
Evidence for a NiI Active Species in the Catalytic Cross-Coupling of Alkyl Electrophiles [J. Am. Chem. Soc. 2004, 126, 8100−8101].
inferredcites →https://doi.org/10.1021/ja044113kopenalex-snapshot
A Unique Catalyst Effects the Rapid Room-Temperature Cross-Coupling of Organozinc Reagents with Carboxylic Acid Fluorides, Chlorides, Anhydrides, and Thioesters
inferredcites →https://doi.org/10.1021/ja044588bopenalex-snapshot
Highly Efficient Nickel-Catalyzed Cross-Coupling of Succinic and Glutaric Anhydrides with Organozinc Reagents
inferredcites →https://doi.org/10.1021/ja0483903openalex-snapshot
Evidence for a NiI Active Species in the Catalytic Cross-Coupling of Alkyl Electrophiles
inferredcites →https://doi.org/10.1021/ja0506509openalex-snapshot
Asymmetric Nickel-Catalyzed Negishi Cross-Couplings of Secondary α-Bromo Amides with Organozinc Reagents
inferredcites →https://doi.org/10.1021/ja063334iopenalex-snapshot
Ligand Redox Effects in the Synthesis, Electronic Structure, and Reactivity of an Alkyl−Alkyl Cross-Coupling Catalyst
inferredcites →https://doi.org/10.1021/ja067845gopenalex-snapshot
Ligand-Dependent Catalytic Cycle and Role of Styrene in Nickel-Catalyzed Anhydride Cross-Coupling: Evidence for Turnover-Limiting Reductive Elimination
inferredcites →https://doi.org/10.1021/ja800103zopenalex-snapshot
Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Secondary Allylic Chlorides with Alkylzincs
inferredcites →https://doi.org/10.1021/ja982520oopenalex-snapshot
Ni(II)-Catalyzed Cross-Coupling between Polyfunctional Arylzinc Derivatives and Primary Alkyl Iodides
inferredcites →https://doi.org/10.1021/ja990432dopenalex-snapshot
Nickel on Charcoal (“Ni/C”): An Expedient and Inexpensive Heterogeneous Catalyst for Cross-Couplings between Aryl Chlorides and Organometallics. I. Functionalized Organozinc Reagents
inferredcites →https://doi.org/10.1021/jo00364a002openalex-snapshot
Coupling of aryl chlorides by nickel and reducing metals
inferredcites →https://doi.org/10.1021/jo00430a041openalex-snapshot
Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides
inferredcites →https://doi.org/10.1021/jo0105787openalex-snapshot
Nickel-Catalyzed Cross-Coupling between Functionalized Primary or Secondary Alkylzinc Halides and Primary Alkyl Halides
inferredcites →https://doi.org/10.1021/jo702497popenalex-snapshot
Density Functional Theory Studies of Negishi Alkyl–Alkyl Cross-Coupling Reactions Catalyzed by a Methylterpyridyl-Ni(I) Complex
inferredcites →https://doi.org/10.1021/jo982317bopenalex-snapshot
New Efficient Nickel-Catalyzed Cross-Coupling Reaction between Two Csp3Centers
inferredcites →https://doi.org/10.1021/ol051615+openalex-snapshot
Efficient Cross-Coupling of Functionalized Arylzinc Halides Catalyzed by a Nickel Chloride−Diethyl Phosphite System
inferredcites →https://doi.org/10.1021/ol0616337openalex-snapshot
Selective Substituent Transfer from Mixed Zinc Reagents in Ni-Catalyzed Anhydride Alkylation
inferredcites →https://doi.org/10.1021/ol702499hopenalex-snapshot
Direct Aminoalkylation of Arenes and Hetarenes via Ni-Catalyzed Negishi Cross-Coupling Reactions
inferredcites →https://doi.org/10.1021/ol9907872openalex-snapshot
New Efficient Nickel- and Palladium-Catalyzed Cross-Coupling Reactions Mediated by Tetrabutylammonium Iodide
inferredcites →https://doi.org/10.1021/om800300kopenalex-snapshot
Exploring Trifluoromethylation Reactions at Nickel: A Structural and Reactivity Study
inferredcites →https://doi.org/10.1023/a:1013841518270openalex-snapshot
Homogeneous Catalysis for the Production of Fine Chemicals. Palladium- and Nickel-Catalysed Aromatic Carbon–Carbon Bond Formation
inferredcites →https://doi.org/10.1246/bcsj.80.233openalex-snapshot
Transition Metal-Catalyzed Organometallic Reactions that Have Revolutionized Organic Synthesis
inferredcites →https://doi.org/10.1351/pac198052030571openalex-snapshot
The role of electron transfer and charge transfer in organometallic chemistry

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Ni@Fe3o4/L-Alanine-Acrylamide Nanocomposite Catalyzed Suzuki Transformation Reactions and Estrogen Inhibitory Activity: Experimental and Docking Investigation
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Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II)
inferred← citeshttps://doi.org/10.1002/047084289x.rn01428openalex-snapshot
Nickel(II) Chloride Ethylene Glycol Dimethyl Ether Complex
inferred← citeshttps://doi.org/10.1002/0471264180.or100.01openalex-snapshot
The N egishi Cross‐Coupling Reaction
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Catalytic Atroposelective Aryl–Aryl Bond Formation
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Sulfur Dioxide: A Powerful Tool for the Stereoselective Construction of C C Bonds
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Organonickel Chemistry
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Homogeneous Transition‐Metal‐Catalyzed C–O Bond Activation
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Elementary Reactions in Organometallic Chemistry
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Theoretical Study of Pt ‐ C atalysis
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Cross Coupling Reactions
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Mechanistic Aspects of Metal‐Catalyzed C,C‐ and C,X‐Bond Forming Reactions
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Carbon–Carbon Bond Forming Reactions Mediated by Organozinc Reagents
inferred← citeshttps://doi.org/10.1002/9783527655588.ch5openalex-snapshot
Carbon–Carbon‐Bond‐Forming Reactions Mediated by Organomagnesium Reagents
inferred← citeshttps://doi.org/10.1002/9783527655588.ch9openalex-snapshot
Cross‐Coupling Reactions to sp Carbon Atoms
inferred← citeshttps://doi.org/10.1002/9783527658909.ch02openalex-snapshot
Experiences with Negishi Couplings on Technical Scale in Early Development
inferred← citeshttps://doi.org/10.1002/9783527658909.ch08openalex-snapshot
Development of a Practical Negishi Coupling Process for the Manufacturing of BILB 1941, an HCV Polymerase Inhibitor
inferred← citeshttps://doi.org/10.1002/9783527673223.ch10openalex-snapshot
The Next Generation of Silylene Ligands for Better Catalysts
inferred← citeshttps://doi.org/10.1002/9783527675944.ch11openalex-snapshot
Application of Organozinc Reagents in Oxidative Coupling Reactions
inferred← citeshttps://doi.org/10.1002/9783527681303.ch2openalex-snapshot
The Role of Redox Processes in Reactions Catalyzed by Nickel and Palladium Complexes with Anionic Pincer Ligands
inferred← citeshttps://doi.org/10.1002/9783527828166.ch6openalex-snapshot
Pd ‐Catalyzed C C Bond‐Forming Reactions
inferred← citeshttps://doi.org/10.1002/9783527830251.ch8openalex-snapshot
Activation of Amide CN Bonds by Nickel Catalysis
inferred← citeshttps://doi.org/10.1002/adsc.201000144openalex-snapshot
Regioselective Functionalization of the Imidazole Ring via Transition Metal‐Catalyzed CN and CC Bond Forming Reactions
inferred← citeshttps://doi.org/10.1002/adsc.201000390openalex-snapshot
Magnetite (Fe3O4) Nanoparticles‐Catalyzed Sonogashira– Hagihara Reactions in Ethylene Glycol under Ligand‐Free Conditions
inferred← citeshttps://doi.org/10.1002/adsc.201100238openalex-snapshot
Synthesis of Diarylalkynes by Iron/Copper Co‐Catalyzed Decarboxylative spsp2 Coupling of Alkynyl Carboxylic Acids and Aryl Halides
inferred← citeshttps://doi.org/10.1002/adsc.201601105openalex-snapshot
Nickel‐Catalyzed Deoxygenative Deuteration of Aryl Sulfamates
inferred← citeshttps://doi.org/10.1002/adsc.201801577openalex-snapshot
Sequential Organozinc Formation and Negishi Cross‐Coupling of Amides Catalysed by Cobalt Salt
inferred← citeshttps://doi.org/10.1002/adsc.202001358openalex-snapshot
Recent Advances in Cross‐Dehydrogenative Couplings (CDC) of C−H Bond in Aqueous Media
inferred← citeshttps://doi.org/10.1002/adsc.202200515openalex-snapshot
Preparation and Evaluation of Sterically Hindered Acridine Photocatalysts
inferred← citeshttps://doi.org/10.1002/adsc.202300450openalex-snapshot
A Simple Preparation of Alkylzinc Reagents Compatible with Carbonyl Functions
inferred← citeshttps://doi.org/10.1002/ajoc.201200089openalex-snapshot
Nickel Complexes Modified by O,N,O’‐Ligands as Synthons for the Straightforward Synthesis of Highly Efficient Precatalysts for CC Bond Formation
inferred← citeshttps://doi.org/10.1002/ajoc.201600045openalex-snapshot
Nickel‐Catalyzed Cross‐Coupling of (Hetero)aryl Chlorides with Aryllithium Compounds
inferred← citeshttps://doi.org/10.1002/ajoc.201600513openalex-snapshot
Visible‐Light Photoredox Decarboxylative Couplings
inferred← citeshttps://doi.org/10.1002/ange.200905196openalex-snapshot
Synthese funktionalisierter Aryl‐Eisen(II)‐Verbindungen und eine Nickel‐katalysierte Kreuzkupplung mit Alkylhalogeniden
inferred← citeshttps://doi.org/10.1002/ange.201100683openalex-snapshot
Nickel‐Catalyzed Cross‐Coupling of Aryltrimethylammonium Iodides with Organozinc Reagents
inferred← citeshttps://doi.org/10.1002/ange.201106762openalex-snapshot
Totalsynthese von Carolacton, einem hochwirksamen Inhibitor von Biofilmen
inferred← citeshttps://doi.org/10.1002/ange.201205969openalex-snapshot
Nickel‐Catalyzed Kumada Reaction of Tosylalkanes with Grignard Reagents to Produce Alkenes and Modified Arylketones
inferred← citeshttps://doi.org/10.1002/ange.201307069openalex-snapshot
Nickel‐Catalyzed Sonogashira Reactions of Non‐activated Secondary Alkyl Bromides and Iodides
inferred← citeshttps://doi.org/10.1002/ange.201505769openalex-snapshot
Iridium‐katalysierte ortho‐Arylierung von Benzoesäuren mit Aryldiazoniumsalzen
inferred← citeshttps://doi.org/10.1002/ange.201510497openalex-snapshot
Lewis‐Säure‐unterstützte metallkatalysierte Kreuzkupplung: Alkylierung von Arylmethylethern unter C‐O‐Bindungsspaltung ohne β‐Hydrideliminierung
inferred← citeshttps://doi.org/10.1002/ange.201604406openalex-snapshot
Nickel‐Catalyzed Methylation of Aryl Halides with Deuterated Methyl Iodide
inferred← citeshttps://doi.org/10.1002/ange.201607270openalex-snapshot
ortho‐C−H Arylation of Benzoic Acids with Aryl Bromides and Chlorides Catalyzed by Ruthenium
inferred← citeshttps://doi.org/10.1002/ange.201611819openalex-snapshot
Catalytic Ester and Amide to Amine Interconversion: Nickel‐Catalyzed Decarbonylative Amination of Esters and Amides by C−O and C−C Bond Activation
inferred← citeshttps://doi.org/10.1002/ange.201612624openalex-snapshot
Selective Reductive Removal of Ester and Amide Groups from Arenes and Heteroarenes through Nickel‐Catalyzed C−O and C−N Bond Activation
inferred← citeshttps://doi.org/10.1002/ange.201712731openalex-snapshot
NiH‐Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp3)−H Alkylation of Alkenes
inferred← citeshttps://doi.org/10.1002/ange.201802656openalex-snapshot
Visible‐Light‐Induced Nickel‐Catalyzed Negishi Cross‐Couplings by Exogenous‐Photosensitizer‐Free Photocatalysis
inferred← citeshttps://doi.org/10.1002/ange.201808654openalex-snapshot
Photoinduced Palladium‐Catalyzed Negishi Cross‐Couplings Enabled by the Visible‐Light Absorption of Palladium–Zinc Complexes
inferred← citeshttps://doi.org/10.1002/ange.201900659openalex-snapshot
Forming Benzylic Iodides via a Nickel Catalyzed Diastereoselective Dearomative Carboiodination Reaction of Indoles
inferred← citeshttps://doi.org/10.1002/ange.201903330openalex-snapshot
From Alkyl Halides to Ketones: Nickel‐Catalyzed Reductive Carbonylation Utilizing Ethyl Chloroformate as the Carbonyl Source
inferred← citeshttps://doi.org/10.1002/ange.201908274openalex-snapshot
A One‐Dimensional π–d Conjugated Coordination Polymer for Sodium Storage with Catalytic Activity in Negishi Coupling
inferred← citeshttps://doi.org/10.1002/ange.201914490openalex-snapshot
Cobalt‐katalysierte Kreuzkupplung funktionalisierter Alkylzinkreagenzien mit (Hetero‐)Arylhalogeniden
inferred← citeshttps://doi.org/10.1002/ange.202011491openalex-snapshot
Nickel‐ and Palladium‐Catalyzed Cross‐Coupling Reactions of Organostibines with Organoboronic Acids
inferred← citeshttps://doi.org/10.1002/ange.202109953openalex-snapshot
Photoinduced Trifluoromethylation of Arenes and Heteroarenes Catalyzed by High‐Valent Nickel Complexes
inferred← citeshttps://doi.org/10.1002/ange.202408834openalex-snapshot
Paired Electrolysis Enables Reductive Heck Coupling of Unactivated (Hetero)Aryl Halides and Alkenes
inferred← citeshttps://doi.org/10.1002/ange.202500524openalex-snapshot
Konkurrenz zwischen unimolekularen Ein‐ und Zwei‐Elektron‐Reaktionen später 3d‐Metallkomplexe [(Me3SiCH2)nM]– (M = Fe, Co, Ni, Cu; n = 2 – 4)
inferred← citeshttps://doi.org/10.1002/anie.200905196openalex-snapshot
Preparation of Functionalized Aryl Iron(II) Compounds and a Nickel‐Catalyzed Cross‐Coupling with Alkyl Halides
inferred← citeshttps://doi.org/10.1002/anie.201100683openalex-snapshot
Nickel‐Catalyzed Cross‐Coupling of Aryltrimethylammonium Iodides with Organozinc Reagents
inferred← citeshttps://doi.org/10.1002/anie.201106762openalex-snapshot
Total Synthesis of Carolacton, a Highly Potent Biofilm Inhibitor
inferred← citeshttps://doi.org/10.1002/anie.201205969openalex-snapshot
Nickel‐Catalyzed Kumada Reaction of Tosylalkanes with Grignard Reagents to Produce Alkenes and Modified Arylketones
inferred← citeshttps://doi.org/10.1002/anie.201307069openalex-snapshot
Nickel‐Catalyzed Sonogashira Reactions of Non‐activated Secondary Alkyl Bromides and Iodides
inferred← citeshttps://doi.org/10.1002/anie.201505769openalex-snapshot
Iridium‐Catalyzed ortho‐Arylation of Benzoic Acids with Arenediazonium Salts
inferred← citeshttps://doi.org/10.1002/anie.201510497openalex-snapshot
Lewis Acid Assisted Nickel‐Catalyzed Cross‐Coupling of Aryl Methyl Ethers by C−O Bond‐Cleaving Alkylation: Prevention of Undesired β‐Hydride Elimination
inferred← citeshttps://doi.org/10.1002/anie.201604406openalex-snapshot
Nickel‐Catalyzed Methylation of Aryl Halides with Deuterated Methyl Iodide
inferred← citeshttps://doi.org/10.1002/anie.201607270openalex-snapshot
ortho ‐C−H Arylation of Benzoic Acids with Aryl Bromides and Chlorides Catalyzed by Ruthenium
inferred← citeshttps://doi.org/10.1002/anie.201611819openalex-snapshot
Catalytic Ester and Amide to Amine Interconversion: Nickel‐Catalyzed Decarbonylative Amination of Esters and Amides by C−O and C−C Bond Activation
inferred← citeshttps://doi.org/10.1002/anie.201612624openalex-snapshot
Selective Reductive Removal of Ester and Amide Groups from Arenes and Heteroarenes through Nickel‐Catalyzed C−O and C−N Bond Activation
inferred← citeshttps://doi.org/10.1002/anie.201712731openalex-snapshot
NiH‐Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp 3 )−H Alkylation of Alkenes
inferred← citeshttps://doi.org/10.1002/anie.201802656openalex-snapshot
Visible‐Light‐Induced Nickel‐Catalyzed Negishi Cross‐Couplings by Exogenous‐Photosensitizer‐Free Photocatalysis
inferred← citeshttps://doi.org/10.1002/anie.201808654openalex-snapshot
Photoinduced Palladium‐Catalyzed Negishi Cross‐Couplings Enabled by the Visible‐Light Absorption of Palladium–Zinc Complexes
inferred← citeshttps://doi.org/10.1002/anie.201900659openalex-snapshot
Forming Benzylic Iodides via a Nickel Catalyzed Diastereoselective Dearomative Carboiodination Reaction of Indoles
inferred← citeshttps://doi.org/10.1002/anie.201903330openalex-snapshot
From Alkyl Halides to Ketones: Nickel‐Catalyzed Reductive Carbonylation Utilizing Ethyl Chloroformate as the Carbonyl Source
inferred← citeshttps://doi.org/10.1002/anie.201908274openalex-snapshot
A One‐Dimensional π–d Conjugated Coordination Polymer for Sodium Storage with Catalytic Activity in Negishi Coupling
inferred← citeshttps://doi.org/10.1002/anie.201914490openalex-snapshot
Cobalt‐Catalyzed Cross‐Coupling of Functionalized Alkylzinc Reagents with (Hetero)Aryl Halides
inferred← citeshttps://doi.org/10.1002/anie.202011491openalex-snapshot
Nickel‐ and Palladium‐Catalyzed Cross‐Coupling Reactions of Organostibines with Organoboronic Acids
inferred← citeshttps://doi.org/10.1002/anie.202109953openalex-snapshot
Photoinduced Trifluoromethylation of Arenes and Heteroarenes Catalyzed by High‐Valent Nickel Complexes
inferred← citeshttps://doi.org/10.1002/anie.202408834openalex-snapshot
Paired Electrolysis Enables Reductive Heck Coupling of Unactivated (Hetero)Aryl Halides and Alkenes
inferred← citeshttps://doi.org/10.1002/anie.202500524openalex-snapshot
Competition between One‐ and Two‐Electron Unimolecular Reactions of Late 3d‐Metal Complexes [(Me 3 SiCH 2 ) n M] – (M = Fe, Co, Ni, and Cu; n = 2–4)
inferred← citeshttps://doi.org/10.1002/aoc.3071openalex-snapshot
Nickel‐catalyzed three‐component coupling reaction of terminal alkynes, dihalomethane and amines to propargylamines
inferred← citeshttps://doi.org/10.1002/aoc.5473openalex-snapshot
Efficient Sonogashira and A3 coupling reactions catalyzed by biosynthesized magnetic Fe3O4@Ni nanoparticles from Euphorbia maculata extract
inferred← citeshttps://doi.org/10.1002/asia.201100627openalex-snapshot
Palladium‐Catalyzed Carbonylative Negishi‐type Coupling of Aryl Iodides with Benzyl Chlorides
inferred← citeshttps://doi.org/10.1002/cctc.201801616openalex-snapshot
Heterogeneous Photocatalyzed C−C Cross‐coupling Reactions Under Visible‐light and Near‐infrared Light Irradiation
inferred← citeshttps://doi.org/10.1002/cctc.202100838openalex-snapshot
Dual Functionalization of Alkynes Utilizing the Redox Characteristics of Transition Metal Catalysts
inferred← citeshttps://doi.org/10.1002/chem.200901913openalex-snapshot
Nickel‐Catalyzed Cross‐Coupling of Alkyl Zinc Halides for the Formation of C(sp2)C(sp3) Bonds: Scope and Mechanism
inferred← citeshttps://doi.org/10.1002/chem.200903273openalex-snapshot
The Nickel‐Catalyzed Carbonylative Cycloaddition of Allyl Halides and Acetylenes: An Efficient Tool for Cyclopentane Annelation
inferred← citeshttps://doi.org/10.1002/chem.201000733openalex-snapshot
Exclusive Synthesis of β‐Alkylpyrroles under Indium Catalysis: Carbonyl Compounds as Sources of Alkyl Groups
inferred← citeshttps://doi.org/10.1002/chem.201101029openalex-snapshot
Identification of a Higher‐Order Organozincate Intermediate Involved in Negishi Cross‐Coupling Reactions by Mass Spectrometry and NMR Spectroscopy
inferred← citeshttps://doi.org/10.1002/chem.201101037openalex-snapshot
Negishi Cross‐Coupling Reactions Catalyzed by an Aminophosphine‐Based Nickel System: A Reliable and General Applicable Reaction Protocol for the High‐Yielding Synthesis of Biaryls
inferred← citeshttps://doi.org/10.1002/chem.201103784openalex-snapshot
Aryl Ether as a Negishi Coupling Partner: An Approach for Constructing CC Bonds under Mild Conditions
inferred← citeshttps://doi.org/10.1002/chem.201103882openalex-snapshot
Theoretical Study on the Mechanism of Ni‐Catalyzed Alkyl–Alkyl Suzuki Cross‐Coupling
inferred← citeshttps://doi.org/10.1002/chem.201200190openalex-snapshot
Nickel‐Mediated Inter‐ and Intramolecular Reductive Cross‐Coupling of Unactivated Alkyl Bromides and Aryl Iodides at Room Temperature
inferred← citeshttps://doi.org/10.1002/chem.201200431openalex-snapshot
Palladium‐Catalysed Cross‐Coupling of Vinyldisiloxanes with Benzylic and Allylic Halides and Sulfonates
inferred← citeshttps://doi.org/10.1002/chem.201202138openalex-snapshot
Palladium‐Catalyzed Carbonylative Coupling of Aryl Iodides and Benzyl Acetylenes to 3‐Alkylidenefuran‐2‐ones under Mild Conditions and Its Density Functional Theory Modeling
inferred← citeshttps://doi.org/10.1002/chem.201202950openalex-snapshot
Three‐Coordinate Nickel(I) Complexes Stabilised by Six‐, Seven‐ and Eight‐Membered Ring N‐Heterocyclic Carbenes: Synthesis, EPR/DFT Studies and Catalytic Activity
inferred← citeshttps://doi.org/10.1002/chem.201300882openalex-snapshot
Ni‐Catalyzed Cascade Cyclization–Kumada Alkyl–Alkyl Cross‐Coupling
inferred← citeshttps://doi.org/10.1002/chem.201404398openalex-snapshot
Palladium‐Catalysed Direct Cross‐Coupling of Organolithium Reagents with Aryl and Vinyl Triflates
inferred← citeshttps://doi.org/10.1002/chem.201500110openalex-snapshot
Computational Insight into Nickel‐Catalyzed Carbon–Carbon versus Carbon–Boron Coupling Reactions of Primary, Secondary, and Tertiary Alkyl Bromides
inferred← citeshttps://doi.org/10.1002/chem.201500192openalex-snapshot
“(Diphosphine)Nickel”‐Catalyzed Negishi Cross‐Coupling: An Experimental and Theoretical Study
inferred← citeshttps://doi.org/10.1002/chem.201502709openalex-snapshot
tBuLi‐Mediated One‐Pot Direct Highly Selective Cross‐Coupling of Two Distinct Aryl Bromides
inferred← citeshttps://doi.org/10.1002/chem.201504049openalex-snapshot
Stereoselective Synthesis of Trisubstituted Alkenes through Sequential Iron‐Catalyzed Reductive anti‐Carbozincation of Terminal Alkynes and Base‐Metal‐Catalyzed Negishi Cross‐Coupling
inferred← citeshttps://doi.org/10.1002/chem.201505106openalex-snapshot
Nickel‐Catalyzed Cross‐Coupling of Organolithium Reagents with (Hetero)Aryl Electrophiles
inferred← citeshttps://doi.org/10.1002/chem.201602202openalex-snapshot
Efficient Synthesis of Diaryl Ketones by Nickel‐Catalyzed Negishi Cross‐Coupling of Amides by Carbon–Nitrogen Bond Cleavage at Room Temperature Accelerated by a Solvent Effect
inferred← citeshttps://doi.org/10.1002/chem.201602486openalex-snapshot
Formation of C(sp3)–C(sp3) Bonds through Nickel‐Catalyzed Decarboxylative Olefin Hydroalkylation Reactions
inferred← citeshttps://doi.org/10.1002/chem.201603758openalex-snapshot
NiI Catalyzes the Regioselective Cross‐Coupling of Alkylzinc Halides and Propargyl Bromides to Allenes
inferred← citeshttps://doi.org/10.1002/chem.201604452openalex-snapshot
Decarboxylative Aminomethylation of Aryl‐ and Vinylsulfonates through Combined Nickel‐ and Photoredox‐Catalyzed Cross‐Coupling
inferred← citeshttps://doi.org/10.1002/chem.201704049openalex-snapshot
Circumventing Intrinsic Metal Reactivity: Radical Generation with Redox‐Active Ligands
inferred← citeshttps://doi.org/10.1002/chem.201705463openalex-snapshot
Cobalt‐Catalyzed Enantioselective Negishi Cross‐Coupling of Racemic α‐Bromo Esters with Arylzincs
inferred← citeshttps://doi.org/10.1002/chem.201901163openalex-snapshot
Cross‐Coupling Reaction of Alkenyl Sulfoximines and Alkenyl Aminosulfoxonium Salts with Organozincs by Dual Nickel Catalysis and Lewis Acid Promotion
inferred← citeshttps://doi.org/10.1002/chem.202005261openalex-snapshot
A Nickel(II)‐Mediated Thiocarbonylation Strategy for Carbon Isotope Labeling of Aliphatic Carboxamides
inferred← citeshttps://doi.org/10.1002/chem.202103272openalex-snapshot
Formation of Stable NiIII N‐Confused Porphyrins Aided by a 3‐Ethoxy Group
inferred← citeshttps://doi.org/10.1002/chem.202203988openalex-snapshot
Stereoselective Synthesis of Tetraarylethylenes Enabled by Reductive anti‐ 1,2‐Dimetallation of Alkynes
inferred← citeshttps://doi.org/10.1002/chem.202302841openalex-snapshot
Atroposelective NiII‐Catalyzed Cross‐Coupling Reactions Enable a Deeper Understanding of Negishi Couplings: Isolation and Application of Solid Aryl Higher‐Order Zincates
inferred← citeshttps://doi.org/10.1002/chem.202303337openalex-snapshot
Merging Photocatalytic Doubly‐Decarboxylative Csp2−Csp2 Cross‐Coupling for Stereo‐Selective (E)‐α,β‐Unsaturated Ketones Synthesis
inferred← citeshttps://doi.org/10.1002/chin.200939238openalex-snapshot
ChemInform Abstract: Nickel‐Catalyzed Negishi Cross‐Coupling Reactions: Scope and Mechanisms
inferred← citeshttps://doi.org/10.1002/cjoc.201900322openalex-snapshot
Negishi Coupling for Highly Selective Syntheses of Allenes via Ligand Effect and Mechanistic Study via SAESI‐MS/MS
inferred← citeshttps://doi.org/10.1002/cssc.202200906openalex-snapshot
α‐Amino Radical Halogen Atom Transfer Agents for Metallaphotoredox‐Catalyzed Cross‐Electrophile Couplings of Distinct Organic Halides
inferred← citeshttps://doi.org/10.1002/ejic.201101036openalex-snapshot
Nickel‐Catalyzed Cross‐Coupling with Pincer Ligands
inferred← citeshttps://doi.org/10.1002/ejic.201101253openalex-snapshot
Application of Nickel Complexes Modified by Tridentate O,N,O′‐Ligands as Precatalysts in Nickel‐Catalyzed C(sp2)–C(sp3) Bond Formations
inferred← citeshttps://doi.org/10.1002/ejic.201500447openalex-snapshot
A Kumada Coupling Catalyst, [Ni{(Ph2P)2N(CH2)3Si(OCH3)3‐P,P′}Cl2], Bearing a Ligand for Direct Immobilization Onto Siliceous Mesoporous Molecular Sieves
inferred← citeshttps://doi.org/10.1002/ejoc.200901084openalex-snapshot
Nickel‐Catalyzed Solvent‐Free Three‐Component Coupling of Aldehyde, Alkyne and Amine
inferred← citeshttps://doi.org/10.1002/ejoc.201000359openalex-snapshot
Pd‐PEPPSI Complexes and the Negishi Reaction
inferred← citeshttps://doi.org/10.1002/ejoc.201201519openalex-snapshot
Palladium‐Catalyzed Diorganozinc Conjugate Additions to Enones: Preparative and Computational Studies
inferred← citeshttps://doi.org/10.1002/ejoc.201301404openalex-snapshot
Direct C–C Bond Construction from Arylzinc Reagents and Aryl Halides without External Catalysts
inferred← citeshttps://doi.org/10.1002/ejoc.201403007openalex-snapshot
Nickel‐Catalyzed Kumada Coupling of Benzyl Chlorides and Vinylogous Derivatives
inferred← citeshttps://doi.org/10.1002/ejoc.201500987openalex-snapshot
Pincer‐Nickel‐Catalyzed Cross‐Coupling of Aryl Sulfamates with Arylzinc Chlorides
inferred← citeshttps://doi.org/10.1002/ejoc.201600275openalex-snapshot
Efficient Iron‐Catalyzed Kumada Cross‐Coupling Reactions Utilizing Flow Technology under Low Catalyst Loadings
inferred← citeshttps://doi.org/10.1002/ejoc.201800849openalex-snapshot
Iron‐Catalyzed Coupling of Propargyl Bromides and Alkyl Grignard Reagents
inferred← citeshttps://doi.org/10.1002/ejoc.201901146openalex-snapshot
Synergistic Photoredox/Transition‐Metal Catalysis for Carbon–Carbon Bond Formation Reactions
inferred← citeshttps://doi.org/10.1002/ejoc.202200906openalex-snapshot
Structure–Reactivity Relationship of Organozinc and Organozincate Reagents: Key Elements towards Molecular Understanding
inferred← citeshttps://doi.org/10.1002/ejoc.202201036openalex-snapshot
Post‐Modification of Amino Acids and Peptides for the Rapid Synthesis of C‐Glycoamino Acids and C‐Glycopeptides
inferred← citeshttps://doi.org/10.1002/ejoc.202300874openalex-snapshot
Cross‐Electrophile Coupling between Two Different Tosylates Enabled by Nickel/Palladium Cooperative Catalysis
inferred← citeshttps://doi.org/10.1002/ejoc.202301143openalex-snapshot
Synthesis, Reactivity and Application of Vinyl Sulfoximines and Vinyl Aminosulfoxonium Salts
inferred← citeshttps://doi.org/10.1002/ejoc.202301185openalex-snapshot
Rose‐Bengal‐Photocatalyzed Cross‐Dehydrogenative Coupling Reactions under Visible Light
inferred← citeshttps://doi.org/10.1002/hc.21267openalex-snapshot
Ni‐Catalyzed Cross‐Coupling Reaction: The Direct Synthesis of Symmetrical Disulfanes from Aryl and Primary Alkyl Halides
inferred← citeshttps://doi.org/10.1002/jcc.27374openalex-snapshot
TS‐tools: Rapid and automated localization of transition states based on a textual reaction SMILES input
inferred← citeshttps://doi.org/10.1002/jcc.70462openalex-snapshot
Reaction Enumeration Based on NBO‐Informed Molecular Graphs
inferred← citeshttps://doi.org/10.1002/nadc.201178359openalex-snapshot
Des Palladiums kleiner Bruder: Neues aus der Nickel‐Katalyse
inferred← citeshttps://doi.org/10.1002/open.70217openalex-snapshot
Recent Advances in Nickel Catalysts for Sonogashira Coupling
inferred← citeshttps://doi.org/10.1002/slct.201600643openalex-snapshot
Alkyl Iodides and [ 11 C]CO in Nickel‐Mediated Cross‐Coupling Reactions: Successful Use of Alkyl Electrophiles containing a β Hydrogen Atom in Metal‐Mediated [ 11 C]Carbonylation
inferred← citeshttps://doi.org/10.1002/slct.201901131openalex-snapshot
Nickel‐Catalyzed Heck Reaction of Aryl Halides and Terminal Olefins Using Zinc/Triflate Ligand/DMA/TBAB
inferred← citeshttps://doi.org/10.1002/slct.202202860openalex-snapshot
Alkaline Transition Metal‐Free Oxidative Coupling of Benzylic and Quasi Benzylic sp 3 Bonds with O 2
inferred← citeshttps://doi.org/10.1002/slct.202500354openalex-snapshot
Selective Sulfonation/Diiodination of Nonactivated 1,8‐Enyne for the Synthesis of ((( E )‐2,3‐Diiodoallyl)oxy)‐2‐(( E )‐3‐(arylsulfonyl)allyl)benzene Derivatives
inferred← citeshttps://doi.org/10.1002/tcr.201800093openalex-snapshot
Nickel, Cobalt and Palladium Catalysed C−H Functionalization of Un‐Activated C(sp3)−H Bond
inferred← citeshttps://doi.org/10.1002/tcr.70222openalex-snapshot
Visible‐Light‐Induced Decarboxylative Cross‐Coupling Reactions: Transition‐Metal and Metal‐Free Approaches
inferred← citeshttps://doi.org/10.1002/zaac.201400609openalex-snapshot
Introduction of (2‐CF3)Phenyl Group via Nickel‐catalyzed C–Cl Bond Activation and Arylation
inferred← citeshttps://doi.org/10.1007/128_2011_261openalex-snapshot
Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? A Fruitful Interplay Anyway
inferred← citeshttps://doi.org/10.1007/128_2011_288openalex-snapshot
Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?: A Fruitful Interplay Anyway
inferred← citeshttps://doi.org/10.1007/3418_2012_32openalex-snapshot
Palladium-Catalysed Coupling Reactions
inferred← citeshttps://doi.org/10.1007/3418_2023_87openalex-snapshot
Zinc-Catalyzed C-C Coupling Reactions
inferred← citeshttps://doi.org/10.1007/7081_2015_141openalex-snapshot
Metal-Catalyzed Cross-Coupling Reactions in the Decoration of Pyridines
inferred← citeshttps://doi.org/10.1007/7081_2018_22openalex-snapshot
Functionalization of Heteroarenes Under Continuous Flow
inferred← citeshttps://doi.org/10.1007/978-3-031-51912-3_6openalex-snapshot
Funktionalisierung von Heteroarenen unter kontinuierlichem Durchfluss
inferred← citeshttps://doi.org/10.1007/978-3-319-01490-6_1openalex-snapshot
General Introduction
inferred← citeshttps://doi.org/10.1007/978-3-319-01490-6_4openalex-snapshot
The Negishi Reaction Mechanism
inferred← citeshttps://doi.org/10.1007/978-3-642-32368-3_4openalex-snapshot
Pharmaceuticals
inferred← citeshttps://doi.org/10.1007/978-3-662-65244-2_6openalex-snapshot
Übergangsmetallkatalysierte Kupplungsreaktionen
inferred← citeshttps://doi.org/10.1007/978-3-662-70963-4_6openalex-snapshot
Transition Metal-Catalyzed Coupling Reactions
inferred← citeshttps://doi.org/10.1007/978-90-481-3817-3_3openalex-snapshot
Theoretical Evaluation of Phosphine Effects in Cross-Coupling Reactions
inferred← citeshttps://doi.org/10.1007/978-981-19-2734-8_6openalex-snapshot
Catalysis: Application and Scope in Organic Synthesis
inferred← citeshttps://doi.org/10.1007/s00706-016-1878-4openalex-snapshot
A triazine-based Ni(II) PNP pincer complex as catalyst for Kumada–Corriu and Negishi cross-coupling reactions
inferred← citeshttps://doi.org/10.1007/s10562-013-0979-5openalex-snapshot
Nickel-catalyzed C(sp2)–C(sp2) Cross Coupling Reactions of Sulfur-Functionalities and Grignard Reagents
inferred← citeshttps://doi.org/10.1007/s10562-021-03577-wopenalex-snapshot
Enhanced Performance of Palladium Catalyst Confined Within Carbon Nanotubes for Heck Reaction
inferred← citeshttps://doi.org/10.1007/s10563-023-09421-yopenalex-snapshot
Disulfide Bridged Two-Dimensional Erythrosine-B Polymer as a Tool for Photo-Catalytic C–H Activation
inferred← citeshttps://doi.org/10.1007/s40242-016-6071-0openalex-snapshot
Zirconium-mediated selective synthesis of 1,4-dialkyl(aryl)-hexa-substituted benzenes from two silyl-substituted alkynes and one internal alkyne
inferred← citeshttps://doi.org/10.1007/s40828-020-00124-9openalex-snapshot
Transmetalation: a fundamental organometallic reaction critical to synthesis and catalysis
inferred← citeshttps://doi.org/10.1007/s41061-016-0067-6openalex-snapshot
Ni-Catalyzed C–C Couplings Using Alkyl Electrophiles
inferred← citeshttps://doi.org/10.1007/s41061-026-00540-4openalex-snapshot
Earth-Abundant Transition Metals Catalyzed Alkylation, Alkenylation, and Alkynylation of Arenes via Cross Dehydrogenative Coupling (CDC): Synthetic Strategies and Mechanistic Pathways
inferred← citeshttps://doi.org/10.1016/b978-0-08-097742-3.00307-4openalex-snapshot
3.04 Alkylations of Nonstabilized Carbanions
inferred← citeshttps://doi.org/10.1016/b978-0-08-097742-3.00311-6openalex-snapshot
3.07 Coupling Reactions Between sp3-Carbon Centers
inferred← citeshttps://doi.org/10.1016/b978-0-08-097774-4.00603-3openalex-snapshot
Cross-Coupling Reactions
inferred← citeshttps://doi.org/10.1016/b978-0-08-097774-4.00816-0openalex-snapshot
Bond Activation and Catalysis
inferred← citeshttps://doi.org/10.1016/b978-0-08-097774-4.00932-3openalex-snapshot
CC Bond Formation
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00063-9openalex-snapshot
Introduction to the Organometallic Chemistry of Carbon Dioxide
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00090-1openalex-snapshot
Zinc Reagents in Organic Synthesis
inferred← citeshttps://doi.org/10.1016/b978-0-32-390644-9.00143-8openalex-snapshot
Asymmetric Dual Catalytic Processes: Transition Metal Catalysis and Photoredox Catalysis
inferred← citeshttps://doi.org/10.1016/b978-0-443-16166-7.00021-9openalex-snapshot
Green metal catalyzed reactions under sustainable conditions toward medicinally potent biomolecules
inferred← citeshttps://doi.org/10.1016/b978-0-443-29011-4.00017-1openalex-snapshot
Synthesis approaches of conjugated polymers: innovations and challenges
inferred← citeshttps://doi.org/10.1016/b978-0-443-31482-7.00076-xopenalex-snapshot
Vinyl and Aryl Halides
inferred← citeshttps://doi.org/10.1016/b978-0-443-36542-3.00002-5openalex-snapshot
Two-group disconnections: bifunctional compounds containing two carbon–carbon multiple bonds (dienes, diynes, and enynes)
inferred← citeshttps://doi.org/10.1016/b978-044453347-0.50425-0openalex-snapshot
Palladium catalysed coupling reactions
inferred← citeshttps://doi.org/10.1016/bs.adomc.2021.04.003openalex-snapshot
Recent progress on group 10 metal complexes of pincer ligands: From synthesis to activities and catalysis
inferred← citeshttps://doi.org/10.1016/j.catcom.2019.105785openalex-snapshot
One-pot Negishi cross-coupling reaction of aryldiazonium salts via Ni catalysis induced by visible-light
inferred← citeshttps://doi.org/10.1016/j.ccr.2021.213863openalex-snapshot
On the mechanism of homogeneous Pt-catalysis: A theoretical view
inferred← citeshttps://doi.org/10.1016/j.giant.2023.100154openalex-snapshot
Precise control of conjugated polymer synthesis from step-growth polymerization to iterative synthesis
inferred← citeshttps://doi.org/10.1016/j.ica.2010.04.006openalex-snapshot
Suzuki–Miyaura cross-coupling of aryl chlorides catalyzed by palladium precatalysts of N/O-functionalized pyrazolyl ligands
inferred← citeshttps://doi.org/10.1016/j.ica.2012.02.033openalex-snapshot
Structural and spectroscopic characteristics of [Ni{(Ph2P)2N-S-CHMePh-P,P′}X2], X = Cl, Br: Catalytic activity and selectivity in Kumada and Suzuki–Miyaura coupling reactions
inferred← citeshttps://doi.org/10.1016/j.ica.2014.11.005openalex-snapshot
Nickel N-heterocyclic carbene complexes and their utility in homogeneous catalysis
inferred← citeshttps://doi.org/10.1016/j.ica.2026.123396openalex-snapshot
Cyclometalated Ni(II) complexes [Ni(dpb)(carboxylate)] (Hdpb = 1,3-di(2-pyridyl)benzene) for Negishi-type CC cross coupling
inferred← citeshttps://doi.org/10.1016/j.inoche.2025.115547openalex-snapshot
Silver nanoparticles supported over chitosan-tannic acid composite-modified magnetic nanoparticles as recyclable catalyst for creation of propargylamines
inferred← citeshttps://doi.org/10.1016/j.jcat.2026.117054openalex-snapshot
A convenient approach to the mechanosynthesis of benzophenones from amines and amides using oxo acids and acid esters
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2013.07.009openalex-snapshot
Iminophosphorane–phosphines: Versatile ligands for homogeneous catalysis
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2021.122095openalex-snapshot
Synthesis of novel ferrocenated enynes via the Sonogashira coupling of ferrocenated vinyllic chlorides and alkyne in the catalytic presence of selenated NHC-Pd(II) full pincer complex under Cu and amine free aerobic conditions
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2022.122368openalex-snapshot
DFT studies on the mechanisms of nickel-catalyzed reductive-coupling cyanation of aryl bromide
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123131openalex-snapshot
Applications of N S ligands for palladium-catalysed cross-coupling reactions
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2025.123766openalex-snapshot
Synthesis and application of tannic acid–gelatin hydrogel polymers capped silver nanoparticles as efficient and reusable nanocatalyst for A3 coupling reactions
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2025.123798openalex-snapshot
Bio-decorated gold nanoparticles over the surface of graphene oxide mediated by Orange leaves extract as efficient catalyst for synthesis of propargylamines and evaluation of its antioxidant activity
inferred← citeshttps://doi.org/10.1016/j.jscs.2022.101589openalex-snapshot
Stereospecific/stereoselective nickel catalyzed reductive cross-coupling: An efficient tool for the synthesis of biological active targeted molecules
inferred← citeshttps://doi.org/10.1016/j.molstruc.2023.135226openalex-snapshot
Pd-PEPPSI complexes in water: Synthesis of (E)-2-(styryl)pyridines via Heck coupling reaction and screening of the optoelectronicproperties
inferred← citeshttps://doi.org/10.1016/j.poly.2025.117495openalex-snapshot
Ni@Fe3O4/l-alanine-acrylamide nanocomposite catalyzed Suzuki transformation reactions and estrogen inhibitory activity: Experimental and docking investigation
inferred← citeshttps://doi.org/10.1016/j.rechem.2023.101135openalex-snapshot
Isolation, synthesis and medicinal chemistry of biphenyl analogs – A review
inferred← citeshttps://doi.org/10.1016/j.tet.2013.02.001openalex-snapshot
Aryl–aryl coupling via palladium-catalyzed C–P/C–H bond cleavage
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