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Regioselective copper-catalyzed chlorination and bromination of arenes with O2 as the oxidant

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/1521-3773(20020816)41:16<2991::aid-anie2991>3.0.co;2-6openalex-snapshot
Aryl CbH Activation by CuII To Form an Organometallic Aryl–CuIII Species: A Novel Twist on Copper Disproportionation This research was supported by MICYT of Spain through project PBQ2000-0548 and with the grant SGR-3102-UG-01 as well as the Distinction award from from CIRIT Generalitat de…
inferredcites →https://doi.org/10.1002/1521-3773(20021202)41:23<4370::aid-anie11114370>3.0.co;2-dopenalex-snapshot
Aryl CH Activation by CuII To Form an Organometallic Aryl–CuIII Species: A Novel Twist on Copper Disproportionation
inferredcites →https://doi.org/10.1002/1615-4169(200107)343:5<447::aid-adsc447>3.0.co;2-kopenalex-snapshot
The Activation of O2 at Ruthenium Complexes: Catalytic Chlorination of Unsaturated Organic Substrates within the System O2/HCl/H2O
inferredcites →https://doi.org/10.1002/adsc.200505495openalex-snapshot
Sodium Nitrite‐Catalyzed Oxybromination of Aromatic Compounds and Aryl Ketones with a Combination of Hydrobromic Acid and Molecular Oxygen under Mild Conditions
inferredcites →https://doi.org/10.1002/anie.200705420openalex-snapshot
CH Functionalization/CN Bond Formation: Copper‐Catalyzed Synthesis of Benzimidazoles from Amidines
inferredcites →https://doi.org/10.1002/anie.200801240openalex-snapshot
Synthesis of 2‐Arylbenzoxazoles by Copper‐Catalyzed Intramolecular Oxidative CO Coupling of Benzanilides
inferredcites →https://doi.org/10.1016/j.apcata.2006.05.006openalex-snapshot
Aerobic oxychlorination of phenols catalyzed by copper(II) chloride
inferredcites →https://doi.org/10.1016/j.tetlet.2007.06.093openalex-snapshot
A practical highly selective oxybromination of phenols with dioxygen
inferredcites →https://doi.org/10.1016/s0040-4039(03)00834-7openalex-snapshot
Environmentally benign chlorination and bromination of aromatic amines, hydrocarbons and naphthols
inferredcites →https://doi.org/10.1021/ic070057nopenalex-snapshot
Controlled Copper-Mediated Chlorination of Phenol Rings under Mild Conditions
inferredcites →https://doi.org/10.1021/ic50007a004openalex-snapshot
Copper(II) Bromide Complexes. I. A Spectrophotometric Study
inferredcites →https://doi.org/10.1021/ja061715qopenalex-snapshot
Cu(II)-Catalyzed Functionalizations of Aryl C−H Bonds Using O 2 as an Oxidant
inferredcites →https://doi.org/10.1021/ja077406xopenalex-snapshot
Copper-Catalyzed Aerobic Oxidative Amidation of Terminal Alkynes: Efficient Synthesis of Ynamides
inferredcites →https://doi.org/10.1021/ja800795bopenalex-snapshot
Suggestion of an Organometallic Intermediate in an Intramolecular Dechlorination Reaction Involving Copper(I) and a ArCH2Cl Moiety
inferredcites →https://doi.org/10.1021/ja802123popenalex-snapshot
Carbon−Nitrogen Bond Formation Involving Well-Defined Aryl−Copper(III) Complexes
inferredcites →https://doi.org/10.1021/ja804570bopenalex-snapshot
Mechanistic Study of Asymmetric Oxidative Biaryl Coupling: Evidence for Self-Processing of the Copper Catalyst to Achieve Control of Oxidase vs Oxygenase Activity
inferredcites →https://doi.org/10.1021/ja9006657openalex-snapshot
Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction
inferredcites →https://doi.org/10.1021/jo00244a046openalex-snapshot
Selective halogenation of aromatic hydrocarbons with alumina-supported copper(II) halides
inferredcites →https://doi.org/10.1021/jo01013a069openalex-snapshot
Cupric Halide Halogenations
inferredcites →https://doi.org/10.1021/jo0340206openalex-snapshot
Enantioselective Oxidative Biaryl Coupling Reactions Catalyzed by 1,5-Diazadecalin Metal Complexes: Efficient Formation of Chiral Functionalized BINOL Derivatives
inferredcites →https://doi.org/10.1021/ol8013717openalex-snapshot
Copper-Mediated C−H Bond Arylation of Arenes with Arylboronic Acids
inferredcites →https://doi.org/10.1021/ol900298eopenalex-snapshot
Direct Amination of Azoles via Catalytic C−H, N−H Coupling
inferredcites →https://doi.org/10.1021/op030055wopenalex-snapshot
0Oxidative Bromination of Activated Aromatic Compounds Using Aqueous Nitric Acid as an Oxidant
inferredcites →https://doi.org/10.1039/b513329gopenalex-snapshot
Novel highly selective catalytic oxychlorination of phenols
inferredcites →https://doi.org/10.1039/b713829fopenalex-snapshot
An alternative method for the regio- and stereoselective bromination of alkenes, alkynes, toluene derivatives and ketones using a bromide/bromate couple
inferredcites →https://doi.org/10.1039/b814989eopenalex-snapshot
Selective aerobic oxidative dibromination of alkenes with aqueous HBr and sodium nitrite as a catalyst
inferredcites →https://doi.org/10.1039/b902946jopenalex-snapshot
Room-temperature aerobic formation of a stable aryl–Cu(iii) complex and its reactions with nucleophiles: highly efficient and diverse arene C–H functionalizations of azacalix[1]arene[3]pyridine
inferredcites →https://doi.org/10.1039/b905275eopenalex-snapshot
Copper-catalyzed aerobic phosphonation of sp3 C–H bonds
inferredcites →https://doi.org/10.1080/00908320701230026openalex-snapshot
Copper(II) Bromide: A Simple and Selective Monobromination Reagent for Electron‐Rich Aromatic Compounds
inferredcites →https://doi.org/10.1081/scc-120006001openalex-snapshot
AN EFFICIENT AND REGIOSELECTIVE OXYBROMINATION OF AROMATIC COMPOUNDS USING POTASSIUM BROMIDE AND OXONE®,*
inferredcites →https://doi.org/10.3184/030823406777946761openalex-snapshot
Grindstone chemistry: (diacetoxyiodo)benzene-mediated oxidative nuclear halogenation of arenes using NaCl, NaBr or I 2

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Copper(I) Complexes of 1,2-Bis(Diphenylphosphino)Benzene as Efficient Catalysts for Alkyne Hydroamination and Azide-Alkyne Cycloaddition
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Organic Synthetic Methods Using Copper Oxygen Chemistry
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Oxidation of Aryl sp2C─H Bond on Substituted Benzene
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Oxidation of Aryl sp 2 C─H Bond on Heteroarene or Perfluoroarene
inferred← citeshttps://doi.org/10.1002/9783527827992.ch57openalex-snapshot
Chloroaromatics: Advances in Synthesis and Applications
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Copper‐Catalyzed sp 2 CH Bond Functionalization
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Functional Enzyme Mimics for Oxidative Halogenation Reactions that Combat Biofilm Formation
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inferred← citeshttps://doi.org/10.1002/adsc.201300062openalex-snapshot
Efficient Oxidative Chlorination of Aromatics on Saturated Sodium Chloride Solution
inferred← citeshttps://doi.org/10.1002/adsc.201401014openalex-snapshot
Copper Chloride‐Catalyzed Aerobic Oxidative Annulation of N‐Furfuryl‐β‐Enaminones:Access to Polysubstituted Pyrroles and Indoles
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Nickel(II)‐Mediated Regioselective CH Monoiodination of Arenes and Heteroarenes by using Molecular Iodine
inferred← citeshttps://doi.org/10.1002/adsc.202101291openalex-snapshot
Generation of Dimethyl Sulfoxide Coordinated Thermally Stable Halogen Cation Pools for C−H Halogenation
inferred← citeshttps://doi.org/10.1002/adsc.202101359openalex-snapshot
Iron(III) Chloride Mediated para‐Selective C‐H Functionalization: Access to C5‐Chloro and C5,C7‐Dichloro/Dianisyl Substituted 2‐Arylbenzoxazoles
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CH Halogenation via Directing Group Strategies With Earth‐Abundant Metals (Cu, Co, Ni, Fe): Scope, Mechanism, and Limitations
inferred← citeshttps://doi.org/10.1002/ajoc.201500245openalex-snapshot
Heterogeneous Cu‐MnO Catalyzed Monoselective ortho ‐Halogenation of Aromatic C−H Bonds under Visible Light
inferred← citeshttps://doi.org/10.1002/ajoc.201800142openalex-snapshot
Transition‐Metal‐Catalyzed Site‐Selective C−H Halogenation Reactions
inferred← citeshttps://doi.org/10.1002/ajoc.201900402openalex-snapshot
Metal‐Free, Facile Synthesis of Sulfenylated Chromones and Indoles Promoted by an Aqueous HBr−DMSO System
inferred← citeshttps://doi.org/10.1002/ajoc.201900606openalex-snapshot
An Efficient Sequential One‐Pot Approach for the Synthesis of C3‐Functionalized Imidazo[1,2‐a]pyridines under Transition‐Metal Free Conditions
inferred← citeshttps://doi.org/10.1002/ajoc.202200060openalex-snapshot
Recent Advances in First‐Row Transition‐Metal‐Mediated C−H Halogenation of (Hetero)arenes and Alkanes
inferred← citeshttps://doi.org/10.1002/ange.201003995openalex-snapshot
Copper‐Catalyzed Direct Carboxylation of CH Bonds with Carbon Dioxide
inferred← citeshttps://doi.org/10.1002/ange.201103945openalex-snapshot
Kupferkatalysierte aerobe oxidative C‐H‐Funktionalisierungen: Trends und Erkenntnisse zum Mechanismus
inferred← citeshttps://doi.org/10.1002/ange.201507100openalex-snapshot
Directed meta‐Selective Bromination of Arenes with Ruthenium Catalysts
inferred← citeshttps://doi.org/10.1002/ange.201612565openalex-snapshot
Isocyanide‐Induced Activation of Copper Sulfate: Direct Access to Functionalized Heteroarene Sulfonic Esters
inferred← citeshttps://doi.org/10.1002/ange.202309104openalex-snapshot
Mild Synthesis of Polychlorinated Arenes for Efficient Organic Light‐emitting Diodes with Dual Thermally Activated Delayed Fluorescence
inferred← citeshttps://doi.org/10.1002/anie.201003995openalex-snapshot
Copper‐Catalyzed Direct Carboxylation of CH Bonds with Carbon Dioxide
inferred← citeshttps://doi.org/10.1002/anie.201103945openalex-snapshot
Copper‐Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights
inferred← citeshttps://doi.org/10.1002/anie.201507100openalex-snapshot
Directed meta‐Selective Bromination of Arenes with Ruthenium Catalysts
inferred← citeshttps://doi.org/10.1002/anie.201612565openalex-snapshot
Isocyanide‐Induced Activation of Copper Sulfate: Direct Access to Functionalized Heteroarene Sulfonic Esters
inferred← citeshttps://doi.org/10.1002/anie.202309104openalex-snapshot
Mild Synthesis of Polychlorinated Arenes for Efficient Organic Light‐emitting Diodes with Dual Thermally Activated Delayed Fluorescence
inferred← citeshttps://doi.org/10.1002/asia.201402742openalex-snapshot
Silver‐Catalyzed Oxidative Coupling of Aniline and Ene Carbonyl/Acetylenic Carbonyl Compounds: An Efficient Route for the Synthesis of Quinolines
inferred← citeshttps://doi.org/10.1002/cctc.201200592openalex-snapshot
Biorelevant Metals in Sustainable Metal Catalysis—A Survey
inferred← citeshttps://doi.org/10.1002/cctc.201300734openalex-snapshot
Cu‐Mediated Direct Aryl CH Halogenation: a Strategy to Control Mono‐ and Di‐Selectivity
inferred← citeshttps://doi.org/10.1002/celc.201900406openalex-snapshot
Electrochemical Synthesis of 3‐Bromoimidazo[1,2‐a]pyridines Directly from 2‐Aminopyridines and alpha‐Bromoketones
inferred← citeshttps://doi.org/10.1002/chem.201402815openalex-snapshot
Copper‐Catalyzed Aerobic Oxidative NS Bond Functionalization for CS Bond Formation: Regio‐ and Stereoselective Synthesis of Sulfones and Thioethers
inferred← citeshttps://doi.org/10.1002/chem.201603783openalex-snapshot
Cross‐Dehydrogenative‐Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of Arenes
inferred← citeshttps://doi.org/10.1002/chem.201700280openalex-snapshot
Monoprotected l ‐Amino Acid ( l ‐MPAA), Accelerated Bromination, Chlorination, and Iodination of C(sp2)−H Bonds by Iridium(III) Catalysis
inferred← citeshttps://doi.org/10.1002/chin.201011041openalex-snapshot
ChemInform Abstract: Regioselective Copper‐Catalyzed Chlorination and Bromination of Arenes with O2 as the Oxidant.
inferred← citeshttps://doi.org/10.1002/cjoc.202000055openalex-snapshot
Efficient Pd‐Catalyzed C—H Oxidative Bromination of Arenes with Dimethyl Sulfoxide and Hydrobromic Acid†
inferred← citeshttps://doi.org/10.1002/cssc.201300289openalex-snapshot
A Sustainable Process for Catalytic Oxidative Bromination with Molecular Oxygen
inferred← citeshttps://doi.org/10.1002/ejic.201600540openalex-snapshot
Dual Role of Acetate in Copper(II) Acetate Catalyzed Dehydrogenation of Chelating Aromatic Secondary Amines: A Kinetic Case Study of Copper‐Catalyzed Oxidation Reactions
inferred← citeshttps://doi.org/10.1002/ejic.202500113openalex-snapshot
Mechanism of Phenol Oxidation by CuCl2
inferred← citeshttps://doi.org/10.1002/ejoc.201400158openalex-snapshot
Copper(II)‐Catalyzed Aromatization Followed by Bromination of Cyclohexenones Leading to Phenols and Bromophenols
inferred← citeshttps://doi.org/10.1002/ejoc.201701573openalex-snapshot
Enabling Efficient Late‐Stage Functionalization of Drug‐Like Molecules with LC‐MS and Reaction‐Driven Data Processing
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A Versatile C–H Halogenation Strategy for Indole Derivatives under Electrochemical Catalyst‐ and Oxidant‐Free Conditions
inferred← citeshttps://doi.org/10.1002/ejoc.201800628openalex-snapshot
Direct Access to Halogenated Fused Imidazo[1,5‐a]N‐heteroaromatics through Copper‐Promoted Double Oxidative C–H Amination and Halogenation
inferred← citeshttps://doi.org/10.1002/ejoc.201801097openalex-snapshot
A Visible Light‐Mediated Regioselective Halogenation of Anilides and Quinolines by Using a Heterogeneous Cu‐MnO Catalyst
inferred← citeshttps://doi.org/10.1002/ejoc.201901174openalex-snapshot
One‐Pot Synthesis of 3‐Sulfenyl/Selenylimidazo[1,5‐a]quinolines from 2‐Methylquinolines, Aliphatic Amines/Amino Acids, and Dichalcogenides
inferred← citeshttps://doi.org/10.1002/ejoc.202001066openalex-snapshot
Metal‐Free Electrochemical Oxidative Dihalogenation of Quinolines on the C5 and C7 Positions Using N‐Halosuccinimides
inferred← citeshttps://doi.org/10.1002/ejoc.202101093openalex-snapshot
Step‐Economical Route to 2‐Amido‐3‐bromobenzo[b]thiophenes via Ynamide Formation and Selectfluor‐Mediated Oxidative Bromocyclization
inferred← citeshttps://doi.org/10.1002/ejoc.202200262openalex-snapshot
Catalyst‐ and Oxidant‐Free Electrochemical Halogenation Reactions of 2H‐Indazoles with NaX (X=Cl, Br)
inferred← citeshttps://doi.org/10.1002/ejoc.202200310openalex-snapshot
Bromide Oxidation: A Safe Strategy for Electrophilic Brominations
inferred← citeshttps://doi.org/10.1002/ejoc.202200399openalex-snapshot
Copper‐Catalyzed Regioselective Halogenation of Anilides with N‐Fluorobenzenesulfonimide
inferred← citeshttps://doi.org/10.1002/ejoc.202300622openalex-snapshot
Electrochemical Direct C−H Halogenation of N‐Heteroarenes and Naphthols
inferred← citeshttps://doi.org/10.1002/jhet.3618openalex-snapshot
CuBr2‐Promoted Multicomponent Aerobic Reaction for the Synthesis of 1,2,3‐Triaroylindolizines
inferred← citeshttps://doi.org/10.1002/poc.3490openalex-snapshot
Production mechanism of active species on the oxidative bromination following perhydrolase activity
inferred← citeshttps://doi.org/10.1002/slct.201601108openalex-snapshot
The Highly Regioselective Halogenation of N‐(8‐quinolinyl)amides on the C‐5 Position with Cuprous Halides Under Mild Conditions
inferred← citeshttps://doi.org/10.1002/slct.201901456openalex-snapshot
Room‐Temperature C‐H Bromination and Iodination with Sodium Bromide and Sodium Iodide Using N ‐Fluorobenzenesulfonimide as an Oxidant
inferred← citeshttps://doi.org/10.1002/slct.201902492openalex-snapshot
BF 3 ⋅Et 2 O‐Promoted Aerobic Bromination of Heteroarenes with LiBr as the Bromination Sources
inferred← citeshttps://doi.org/10.1002/slct.202102956openalex-snapshot
Recent Update on Transition Metal‐Free C(sp 2 )−H Bond Halogenation in (Hetero) Arenes
inferred← citeshttps://doi.org/10.1007/978-94-007-0913-3_6openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/978-981-15-1490-6_8openalex-snapshot
Functional Enzyme Mimics for Oxidative Halogenation Reactions that Combat Biofilm Formation
inferred← citeshttps://doi.org/10.1007/s00706-014-1383-6openalex-snapshot
Effects of tertiary amine catalysis on the regioselectivity of anisole chlorination with trichloroisocyanuric acid
inferred← citeshttps://doi.org/10.1007/s11426-012-4795-3openalex-snapshot
Mechanistic study of copper-catalyzed intramolecular ortho-C-H activation/carbon-nitrogen and carbon-oxygen cyclizations
inferred← citeshttps://doi.org/10.1016/b978-0-08-097742-3.00715-1openalex-snapshot
7.13 Directed Aryl CH Oxidations with Transition Metals
inferred← citeshttps://doi.org/10.1016/j.apcata.2013.08.045openalex-snapshot
Light-triggered oxy-chlorination of cyclohexane by metal chlorides
inferred← citeshttps://doi.org/10.1016/j.cattod.2012.05.012openalex-snapshot
In situ acidic carbon dioxide/water system for selective oxybromination of electron-rich aromatics catalyzed by copper bromide
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2015.01.015openalex-snapshot
Vanadium-catalyzed chlorination under molecular oxygen
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2018.01.053openalex-snapshot
Copper(II) complexes of a heterotopic N-heterocyclic carbene ligand: Preparation and catalytic application
inferred← citeshttps://doi.org/10.1016/j.mcat.2023.113575openalex-snapshot
Copper(I) complexes of 1,2-bis(diphenylphosphino)benzene as efficient catalysts for alkyne hydroamination and azide-alkyne cycloaddition
inferred← citeshttps://doi.org/10.1016/j.molstruc.2012.07.054openalex-snapshot
“Abnormal” bromination reaction selectivity of 5-diarylamino-2-methylbenzo[b]thiophene caused by a “non-planar” conjugated model: Synthesis and theoretical calculation
inferred← citeshttps://doi.org/10.1016/j.nanoen.2020.105532openalex-snapshot
Ultrathin Fe–N –C single-atom catalysts with bifunctional active site for simultaneous production of ethylene and aromatic chlorides
inferred← citeshttps://doi.org/10.1016/j.tet.2010.06.042openalex-snapshot
Vanadium-catalyzed oxidative bromination promoted by Brønsted acid or Lewis acid
inferred← citeshttps://doi.org/10.1016/j.tet.2014.08.052openalex-snapshot
Oxidative chlorination of 4-pentenols and other functionalized hydrocarbons
inferred← citeshttps://doi.org/10.1016/j.tet.2014.11.037openalex-snapshot
Copper and palladium mediated C–H chlorination on 8-acylaminoquinoline scaffolds
inferred← citeshttps://doi.org/10.1016/j.tet.2025.134723openalex-snapshot
N-Bromo-N-fuorobenzenesulfonylamide (BFBSA) – A newly developed reagent for the bromination of (Het)arenes, drugs and natural products under mild conditions
inferred← citeshttps://doi.org/10.1016/j.tetlet.2013.04.071openalex-snapshot
Liquid crystalline bis(N-salicylideneaniline)s: synthesis and thermal behavior of constitutional isomers
inferred← citeshttps://doi.org/10.1016/j.tetlet.2014.02.071openalex-snapshot
The direct C–H halogenations of indoles
inferred← citeshttps://doi.org/10.1016/j.tetlet.2019.05.019openalex-snapshot
Iodine(III)/AlX3-mediated electrophilic chlorination and bromination of arenes. Dual role of AlX3 (X = Cl, Br) for (PhIO)n depolymerization and as the halogen source
inferred← citeshttps://doi.org/10.1016/j.tetlet.2023.154517openalex-snapshot
A mild oxidative bromination of ketones with the combination of KBr/Fe(NO3)3∙9H2O
inferred← citeshttps://doi.org/10.1021/acs.accounts.5b00060openalex-snapshot
Copper-Catalyzed Aerobic Oxidations of Organic Molecules: Pathways for Two-Electron Oxidation with a Four-Electron Oxidant and a One-Electron Redox-Active Catalyst
inferred← citeshttps://doi.org/10.1021/acs.chemrev.6b00089openalex-snapshot
Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00507openalex-snapshot
3d Transition Metals for C–H Activation
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c02816openalex-snapshot
Copper-Substituted Polyoxotungstates as Catalysts for the Electrocatalytic Oxygenation of Light Alkanes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.9b01891openalex-snapshot
Directed Structural Transformations of Coordination Polymers Supported Single-Site Cu(II) Catalysts To Control the Site Selectivity of C–H Halogenation
inferred← citeshttps://doi.org/10.1021/acs.joc.3c01200openalex-snapshot
POCl3/Sulfoxide and AcCl/Sulfoxide Mediated Chlorination of Pyrrolo[2,1-a]isoquinolines
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02008openalex-snapshot
A Method for the Synthesis of Thioindoles through Copper-Catalyzed C–S Bond Coupling Reaction
inferred← citeshttps://doi.org/10.1021/acs.joc.4c00151openalex-snapshot
HCl/DMSO/HFIP-Mediated Chlorination of Pyrrolo[2,1-a]isoquinolines and Other Electron-Rich Heteroarenes
inferred← citeshttps://doi.org/10.1021/acs.joc.5b01351openalex-snapshot
Cu(II)-Mediated C(sp2)–H Hydroxylation
inferred← citeshttps://doi.org/10.1021/acs.joc.5b02384openalex-snapshot
Copper-Mediated Aerobic Oxidative Synthesis of 3-Bromo-imidazo[1,2-a]pyridines with Pyridines and Enamides
inferred← citeshttps://doi.org/10.1021/acs.joc.5c01775openalex-snapshot
Visible-Light-Induced Organic-Dye-Catalyzed Bromination of Activated Alkenes with Sodium Bromide
inferred← citeshttps://doi.org/10.1021/acs.joc.5c02508openalex-snapshot
Methyloxime-Directed Regioselective C2–H Bromination of Indoles and Their Subsequent Synthetic Elaboration to Carbazoles
inferred← citeshttps://doi.org/10.1021/acs.joc.6b02117openalex-snapshot
Aerobic Copper-Catalyzed Halocyclization of Methyl N-Heteroaromatics with Aliphatic Amines: Access to Functionalized Imidazo-Fused N-Heterocycles
inferred← citeshttps://doi.org/10.1021/acs.joc.6b02731openalex-snapshot
Palladium-Catalyzed, ortho-Selective C–H Halogenation of Benzyl Nitriles, Aryl Weinreb Amides, and Anilides
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02637openalex-snapshot
Sodium Salts (NaI/NaBr/NaCl) for the Halogenation of Imidazo-Fused Heterocycles
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c00704openalex-snapshot
Chlorination Reaction of Aromatic Compounds and Unsaturated Carbon–Carbon Bonds with Chlorine on Demand
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00193openalex-snapshot
Cu(II)-Catalyzed Coupling of Aromatic C–H Bonds with Malonates
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00932openalex-snapshot
Efficient and Practical Oxidative Bromination and Iodination of Arenes and Heteroarenes with DMSO and Hydrogen Halide: A Mild Protocol for Late-Stage Functionalization
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b02383openalex-snapshot
Highly Regioselective α-Chlorination of the BODIPY Chromophore with Copper(II) Chloride
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b03198openalex-snapshot
Para -Selective Halogenation of Nitrosoarenes with Copper(II) Halides
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b00079openalex-snapshot
One-Pot Strategy for Thiazoline Synthesis from Alkenes and Thioamides
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b00275openalex-snapshot
Selective C(sp2)–H Halogenation of “Click” 4-Aryl-1,2,3-triazoles
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b02208openalex-snapshot
Catalytic Bromination of Alkyl sp3C–H Bonds with KBr/Air under Visible Light
inferred← citeshttps://doi.org/10.1021/acsami.1c07496openalex-snapshot
Metalloenzyme-Inspired Ce-MOF Catalyst for Oxidative Halogenation Reactions
inferred← citeshttps://doi.org/10.1021/acscatal.1c01722openalex-snapshot
Sequential Catalytic Functionalization of Aryltriazenyl Aldehydes for the Synthesis of Complex Benzenes
inferred← citeshttps://doi.org/10.1021/acscatal.5b01182openalex-snapshot
Indole-Catalyzed Bromolactonization in Lipophilic Solvent: A Solid–Liquid Phase Transfer Approach
inferred← citeshttps://doi.org/10.1021/acscatal.5b02490openalex-snapshot
Photocatalytic Selective Bromination of Electron-Rich Aromatic Compounds Using Microporous Organic Polymers with Visible Light
inferred← citeshttps://doi.org/10.1021/acsomega.3c05954openalex-snapshot
Sustainable Aerobic Bromination with Controllable Chemoselectivity
inferred← citeshttps://doi.org/10.1021/cr300527gopenalex-snapshot
Aerobic Copper-Catalyzed Organic Reactions
inferred← citeshttps://doi.org/10.1021/cs300644sopenalex-snapshot
Oxyhalogenation of Activated Arenes with Nanocrystalline Ceria
inferred← citeshttps://doi.org/10.1021/ie2004863openalex-snapshot
Environment-Friendly Bromination of Aromatic Heterocycles Using a Bromide–Bromate Couple in an Aqueous Medium
inferred← citeshttps://doi.org/10.1021/ja103838dopenalex-snapshot
Cu(I)-Catalyzed Regioselective Diamination of Conjugated Dienes via Dual Mechanistic Pathways
inferred← citeshttps://doi.org/10.1021/ja1045378openalex-snapshot
Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate
inferred← citeshttps://doi.org/10.1021/ja204040kopenalex-snapshot
Enantioselective Total Synthesis of (−)-Kibdelone C
inferred← citeshttps://doi.org/10.1021/ja207691aopenalex-snapshot
Cu(I)-Catalyzed Diamination of Conjugated Dienes. Complementary Regioselectivity from Two Distinct Mechanistic Pathways Involving Cu(II) and Cu(III) Species
inferred← citeshttps://doi.org/10.1021/ja4026424openalex-snapshot
Divergence between Organometallic and Single-Electron-Transfer Mechanisms in Copper(II)-Mediated Aerobic C–H Oxidation
inferred← citeshttps://doi.org/10.1021/ja4096472openalex-snapshot
Simple Catalytic Mechanism for the Direct Coupling of α-Carbonyls with Functionalized Amines: A One-Step Synthesis of Plavix
inferred← citeshttps://doi.org/10.1021/ja412880ropenalex-snapshot
Cu(II)-Mediated C–H Amidation and Amination of Arenes: Exceptional Compatibility with Heterocycles
inferred← citeshttps://doi.org/10.1021/jacs.6b05484openalex-snapshot
Synthesis and Biological Evaluation of Kibdelone C and Its Simplified Derivatives
inferred← citeshttps://doi.org/10.1021/jo300152uopenalex-snapshot
Cu(ClO4)2-Mediated Arene C–H Bond Halogenations of Azacalixaromatics Using Alkali Metal Halides as Halogen Sources
inferred← citeshttps://doi.org/10.1021/jo300731zopenalex-snapshot
Cu–Mn Spinel Oxide Catalyzed Regioselective Halogenation of Phenols and N-Heteroarenes
inferred← citeshttps://doi.org/10.1021/jo301039yopenalex-snapshot
Cu(II)-Promoted Transformations of α-Thienylcarbinols into Spirothienooxindoles: Regioselective Halogenation of Dienyl Sulfethers Containing Electron-Rich Aryl Rings
inferred← citeshttps://doi.org/10.1021/jo501626bopenalex-snapshot
Copper(II)-Catalyzed Indolizines Formation Followed by Dehydrogenative Functionalization Cascade to Synthesize 1-Bromoindolizines
inferred← citeshttps://doi.org/10.1021/ol101490nopenalex-snapshot
Copper-Catalyzed Synthesis of Phenanthridine Derivatives under an Oxygen Atmosphere Starting from Biaryl-2-carbonitriles and Grignard Reagents
inferred← citeshttps://doi.org/10.1021/ol102767jopenalex-snapshot
Complementary Regioselectivity in the Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamides
inferred← citeshttps://doi.org/10.1021/ol300205ropenalex-snapshot
Construction of Caryl–Calkynyl Bond from Copper-Mediated Arene–Alkyne and Aryl Iodide–Alkyne Cross-Coupling Reactions: A Common Aryl-CuIII Intermediate in Arene C–H Activation and Castro–Stephens Reaction
inferred← citeshttps://doi.org/10.1021/ol301583yopenalex-snapshot
Copper-Catalyzed Aerobic Spirocyclization of Biaryl-N-H-imines via 1,4-Aminooxygenation of Benzene Rings
inferred← citeshttps://doi.org/10.1021/ol302562aopenalex-snapshot
CuI-Mediated Sequential Iodination/Cycloetherification ofo-Arylphenols: Synthesis of 2- or 4-Iododibenzofurans and Mechanistic Studies
inferred← citeshttps://doi.org/10.1021/ol403258copenalex-snapshot
Dichlorination of (Hexadehydro-Diels–Alder Generated) Benzynes and a Protocol for Interrogating the Kinetic Order of Bimolecular Aryne Trapping Reactions
inferred← citeshttps://doi.org/10.1021/ol5027377openalex-snapshot
Cu(OAc)2-Catalyzed Coupling of Aromatic C–H Bonds with Arylboron Reagents
inferred← citeshttps://doi.org/10.1021/om300553bopenalex-snapshot
Copper-Mediated Multiple C–H Functionalization of Aromatic N-Heterocycles: Bromoamination of Indoles and Pyrroles
inferred← citeshttps://doi.org/10.1038/s41467-021-26997-zopenalex-snapshot
Photoelectrocatalytic C–H halogenation over an oxygen vacancy-rich TiO2 photoanode
inferred← citeshttps://doi.org/10.1038/s41557-024-01462-8openalex-snapshot
Tandem catalysis enables chlorine-containing waste as chlorination reagents
inferred← citeshttps://doi.org/10.1038/s41929-019-0398-0openalex-snapshot
DMSO-catalysed late-stage chlorination of (hetero)arenes
inferred← citeshttps://doi.org/10.1039/c003074kopenalex-snapshot
Solvent free catalytic C–H functionalisation
inferred← citeshttps://doi.org/10.1039/c0dt00385aopenalex-snapshot
Solvent-free aromatic C–H functionalisation/halogenation reactions
inferred← citeshttps://doi.org/10.1039/c0gc00328jopenalex-snapshot
An efficient copper-catalysed aerobic oxybromination of arenes in water
inferred← citeshttps://doi.org/10.1039/c1dt11158bopenalex-snapshot
Influence of the anions on the structure and magnetic properties of a series of bis(μ-diphenoxo)-bridged linear trinuclear copper(II) complexes: an experimental and theoretical study
inferred← citeshttps://doi.org/10.1039/c2cc33426gopenalex-snapshot
A CuBr-mediated aerobic reaction of 2-alkynylbenzaldehydes and primary amines: synthesis of 4-bromoisoquinolones
inferred← citeshttps://doi.org/10.1039/c2cs15323hopenalex-snapshot
Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process
inferred← citeshttps://doi.org/10.1039/c2ob25310kopenalex-snapshot
Copper(ii)-mediated oxidative cyclization of enamides to oxazoles
inferred← citeshttps://doi.org/10.1039/c2ra22213bopenalex-snapshot
Palladium catalysed regioselective arylation of indoles, benzofuran and benzothiophene with aryldiazonium salts
inferred← citeshttps://doi.org/10.1039/c3cc47174hopenalex-snapshot
Copper-catalyzed ortho-halogenation of protected anilines
inferred← citeshttps://doi.org/10.1039/c3cc47431copenalex-snapshot
Room-temperature Pd-catalyzed C–H chlorination by weak coordination: one-pot synthesis of 2-chlorophenols with excellent regioselectivity
inferred← citeshttps://doi.org/10.1039/c3ob40185eopenalex-snapshot
Copper-catalyzed aromatic C–H bond halogenation with lithium halides under aerobic conditions
inferred← citeshttps://doi.org/10.1039/c3ra43071eopenalex-snapshot
Copper-catalyzed oxidative aromatization of 2-cyclohexen-1-ones to phenols in the presence of catalytic hydrogen bromide under molecular oxygen
inferred← citeshttps://doi.org/10.1039/c3sc50582kopenalex-snapshot
Copper(i)-catalyzed diastereoselective hydroxytrifluoromethylation of dienes accelerated by phosphine ligands
inferred← citeshttps://doi.org/10.1039/c3sc51489gopenalex-snapshot
Benzofuran synthesis via copper-mediated oxidative annulation of phenols and unactivated internal alkynes
inferred← citeshttps://doi.org/10.1039/c4ra01641fopenalex-snapshot
The vicinal functionalization of olefins: a facile route to the direct synthesis of β-chlorohydrins and β-chloroethers
inferred← citeshttps://doi.org/10.1039/c5cc00531kopenalex-snapshot
Copper-catalyzed ortho-halogenation of arenes and heteroarenes directed by a removable auxiliary
inferred← citeshttps://doi.org/10.1039/c5cc02533hopenalex-snapshot
Pd( ii ) catalyzed ortho C–H iodination of phenylcarbamates at room temperature using cyclic hypervalent iodine reagents
inferred← citeshttps://doi.org/10.1039/c5cc02676hopenalex-snapshot
Iron-mediated C–H coupling of arenes and unactivated terminal alkenes directed by sulfur
inferred← citeshttps://doi.org/10.1039/c5cc05821jopenalex-snapshot
Copper-mediated three-component synthesis of 3-cyanoimidazo[1,2-a]pyridines
inferred← citeshttps://doi.org/10.1039/c5gc00184fopenalex-snapshot
From simple organobromides or olefins to highly value-added bromohydrins: a versatile performance of dimethyl sulfoxide
inferred← citeshttps://doi.org/10.1039/c5gc00528kopenalex-snapshot
Efficient bromination of olefins, alkynes, and ketones with dimethyl sulfoxide and hydrobromic acid
inferred← citeshttps://doi.org/10.1039/c5nj00118hopenalex-snapshot
Facile, efficient, and environmentally friendly α- and aromatic regioselective chlorination of toluene using KHSO 5 and KCl under catalyst-free conditions
inferred← citeshttps://doi.org/10.1039/c5ob01228gopenalex-snapshot
Cu-mediated direct regioselective C-2 chlorination of indoles
inferred← citeshttps://doi.org/10.1039/c6dt01780kopenalex-snapshot
Effective bromo and chloro peroxidation catalysed by tungsten( vi ) amino triphenolate complexes
inferred← citeshttps://doi.org/10.1039/c6ob00883fopenalex-snapshot
Iron-mediated oxidative C–H coupling of arenes and alkenes directed by sulfur: an expedient route to dihydrobenzofurans
inferred← citeshttps://doi.org/10.1039/c6ra14863hopenalex-snapshot
PhI(OAc) 2 oxidative C5 halogenation of quinolines using copper halides under mild conditions
inferred← citeshttps://doi.org/10.1039/c7ra00319fopenalex-snapshot
Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate
inferred← citeshttps://doi.org/10.1039/c7sc03010jopenalex-snapshot
Room temperature C(sp 2 )–H oxidative chlorination via photoredox catalysis
inferred← citeshttps://doi.org/10.1039/c8nj06412aopenalex-snapshot
Metal-free, green and efficient oxidative α halogenation of enaminones by halo acid and DMSO
inferred← citeshttps://doi.org/10.1039/c8ob01095aopenalex-snapshot
Inexpensive NaX (X = I, Br, Cl) as a halogen donor in the practical Ag/Cu-mediated decarboxylative halogenation of aryl carboxylic acids under aerobic conditions
inferred← citeshttps://doi.org/10.1039/c8ob01448eopenalex-snapshot
Cobalt( ii )-catalyzed regioselective C–H halogenation of anilides
inferred← citeshttps://doi.org/10.1039/c8ob02351dopenalex-snapshot
Catalytic dehydrogenative aromatization of cyclohexanones and cyclohexenones
inferred← citeshttps://doi.org/10.1039/c8ra01974fopenalex-snapshot
Copper-catalyzed C–H acyloxylation of 2-phenylpyridine using oxygen as the oxidant
inferred← citeshttps://doi.org/10.1039/c9gc00913bopenalex-snapshot
Direct electrosynthesis for N -alkyl-C3-halo-indoles using alkyl halide as both alkylating and halogenating building blocks
inferred← citeshttps://doi.org/10.1039/c9nj05732copenalex-snapshot
Bioinspired catalysis and bromoperoxidase like activity of a multistimuli-responsive supramolecular metallogel: supramolecular assembly triggered by pi–pi stacking and hydrogen bonding interactions
inferred← citeshttps://doi.org/10.1039/c9qo00429gopenalex-snapshot
Transition metal catalysed C7 and ortho -selective halogenation of 2-arylbenzo[ d ]oxazoles
inferred← citeshttps://doi.org/10.1039/d1qo00916hopenalex-snapshot
Amine hydrochloride salts as bifunctional reagents for the radical aminochlorination of maleimides
inferred← citeshttps://doi.org/10.1039/d3ob01732jopenalex-snapshot
One-pot tandem reduction and site-selective halogenation of nitroarenes
inferred← citeshttps://doi.org/10.1039/d3re00591gopenalex-snapshot
A metal-free, eco-friendly protocol for the oxidative halogenation of aromatic compounds by using highly efficient and reusable graphene oxide
inferred← citeshttps://doi.org/10.1039/d6ob01085gopenalex-snapshot
Recent advances in the thioglycosylation of indoles and tryptophan: strategies and applications in natural product synthesis
inferred← citeshttps://doi.org/10.1055/sos-sd-131-00075openalex-snapshot
31.2.3 Chloroarenes (Update 2015)
inferred← citeshttps://doi.org/10.1055/sos-sd-131-00094openalex-snapshot
31.3.3 Bromoarenes (Update 2015)
inferred← citeshttps://doi.org/10.1073/pnas.2122425119openalex-snapshot
Chlorination of arenes via the degradation of toxic chlorophenols
inferred← citeshttps://doi.org/10.1080/00397911.2021.1943751openalex-snapshot
Bromination of 1,1-diarylethylenes with bromoethane
inferred← citeshttps://doi.org/10.1080/00397911.2022.2125325openalex-snapshot
Introduction of efficient catalytic system for the regioselective aerobic bromination of aromatic compounds
inferred← citeshttps://doi.org/10.1107/s1600536812047848openalex-snapshot
1,5-Dibromo-2,4-dimethoxybenzene
inferred← citeshttps://doi.org/10.11113/mjfas.v0n0.549openalex-snapshot
Alternative pathway to brominate 2,13-benzothiadiazole: Preparation of 4,7-dibromobenzo[c]-1,2,5-thiadiazole via N-bromosuccinimide
inferred← citeshttps://doi.org/10.1246/cl.170734openalex-snapshot
Oxidative Bromination Reactions in Aqueous Media by Using Bu4NBr/TFA/H2O2 System
inferred← citeshttps://doi.org/10.1515/revce-2024-0021openalex-snapshot
Comprehensive and in-depth insights into photo-assisted halogenation reactions: a pharmaceutical industry perspective
inferred← citeshttps://doi.org/10.2174/2213346110666230213113910openalex-snapshot
Oxidative Chlorination: A Sustainable Alternative for the Preparation of Chloroarenes
inferred← citeshttps://doi.org/10.3390/catal11030378openalex-snapshot
The Influence of Copper on Halogenation/Dehalogenation Reactions of Aromatic Compounds and Its Role in the Destruction of Polyhalogenated Aromatic Contaminants
inferred← citeshttps://doi.org/10.3390/molecules24203772openalex-snapshot
Synthesis of 1,1′-Bis(1-Methyl/Chloro-2,3,4,5-Tetraphenyl-1-Silacyclopentadienyl) [Ph4C4Si(Me/Cl)-(Me/Cl)SiC4Ph4] from Silole Anion [MeSiC4Ph4]−•[Li+ or Na+] and Silole Dianion [SiC4Ph4]2−•2[Li+]; Oxidative Coupling of Silole Anion [MeSiC4Ph4]−•[Li+ or Na+] by Ferrous Chloride (FeCl2) and…
inferred← citeshttps://doi.org/10.3390/pr12061102openalex-snapshot
Sodium Hypochlorite Pentahydrate as a Chlorinating Reagent: Application to the Tandem Conversion of β,γ-Unsaturated Carboxylic Acids to α,β-Unsaturated Lactones
inferred← citeshttps://doi.org/10.3762/bjoc.11.230openalex-snapshot
C–H bond halogenation catalyzed or mediated by copper: an overview
inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.77.227openalex-snapshot
Oxidative Halogenation Reactions by Using Halide Salt as a Halide Source
inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.80.357openalex-snapshot
Development of Novel and Efficient Catalytic Systems for C-H Activation and Application to Practical Synthesis of Pharmaceuticals
inferred← citeshttps://doi.org/10.70675/162d895fz1089z49e5zb883za75987080b97openalex-snapshot
Approches synthétiques à de nouvelles séries de phosphahélicènes
inferred← citeshttps://doi.org/10.71086/iajse/v11i1/iajse1109openalex-snapshot
Cu-Catalyzed Halogenation of Diaryliodonium Salts Containing Ortho-sidearm
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