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In situ IR study of surface hydroxyl species of dehydrated TiO2: towards understanding pivotal surface processes of TiO2 photocatalytic oxidation of toluene

https://doi.org/10.1039/c2cp40893g
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Probing Defect Sites on TiO2 with [Re3(CO)12H3]: Spectroscopic Characterization of the Surface Species
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Probing Surface Sites of TiO2: Reactions with [HRe(CO)5] and [CH3Re(CO)5]
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Photocatalytic and antibacterial properties of medical‐grade PVC material coated with TiO2 film
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Effects of Activation on the Surface Properties of Silica-Supported Cobalt Catalysts
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Carbon monoxide — A low temperature infrared probe for the characterization of hydroxyl group properties on metal oxide surfaces
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Nature of oxide surface sites and their role in formation of toluene complexes
inferredcites →https://doi.org/10.1016/0920-5861(91)80035-8openalex-snapshot
Support effects on hydrotreating catalysts
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Infrared spectrometric studies of the surface basicity of metal oxides and zeolites using adsorbed probe molecules
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Preparation and characterization of nanosized anatase TiO2 cuboids for photocatalysis
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Effects of morphology on surface hydroxyl concentration: a DFT comparison of anatase–TiO2 and γ-alumina catalytic supports
inferredcites →https://doi.org/10.1016/j.jcat.2005.09.034openalex-snapshot
DFT makes the morphologies of anatase-TiO2 nanoparticles visible to IR spectroscopy
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Characterization of Fe–TiO2 photocatalysts synthesized by hydrothermal method and their photocatalytic reactivity for photodegradation of XRG dye diluted in water
inferredcites →https://doi.org/10.1016/j.solmat.2005.04.032openalex-snapshot
Structural and spectroelectrochemical (UV–vis and IR) studies of nanocrystalline sol–gel derived TiO2 films
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Characterization of vacant coordination sites of cations on the surfaces of oxides and zeolites using infrared spectroscopy of adsorbed probe molecules
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Relationship between the formation of surface species and catalyst deactivation during the gas-phase photocatalytic oxidation of toluene
inferredcites →https://doi.org/10.1016/s0920-5861(99)00156-xopenalex-snapshot
The role of H2O in the photocatalytic oxidation of toluene in vapour phase on anatase TiO2 catalyst
inferredcites →https://doi.org/10.1016/s0926-3373(98)00088-5openalex-snapshot
Photocatalytic oxidation of gaseous toluene on anatase TiO2 catalyst: mechanistic aspects and FT-IR investigation
inferredcites →https://doi.org/10.1016/s0926-860x(00)00641-4openalex-snapshot
Lewis acid and base sites at the surface of microcrystalline TiO2 anatase: relationships between surface morphology and chemical behaviour
inferredcites →https://doi.org/10.1021/cr00033a004openalex-snapshot
Environmental Applications of Semiconductor Photocatalysis
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Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
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Substrate-Specific Photocatalytic Activities of TiO2 and Multiactivity Test for Water Treatment Application
inferredcites →https://doi.org/10.1021/j100108a014openalex-snapshot
Effects of altervalent cation doping of titania on its performance as a photocatalyst for water cleavage
inferredcites →https://doi.org/10.1021/j100679a007openalex-snapshot
Infrared study of the surface of titanium dioxides. I. Hydroxyl groups
inferredcites →https://doi.org/10.1021/j100823a011openalex-snapshot
INFRARED STUDIES OF THE SURFACE HYDROXYL GROUPS ON TITANIUM DIOXIDE, AND OF THE CHEMISORPTION OF CARBON MONOXIDE AND CARBON DIOXIDE
inferredcites →https://doi.org/10.1021/j100885a032openalex-snapshot
Infrared and Gravimetric Study of the Surface Hydration of γ-Alumina
inferredcites →https://doi.org/10.1021/ja044001topenalex-snapshot
Dye Sensitization of the Anatase (101) Crystal Surface by a Series of Dicarboxylated Thiacyanine Dyes
inferredcites →https://doi.org/10.1021/jp0007890openalex-snapshot
Infrared Spectra of Photoinduced Species on Hydroxylated Titania Surfaces
inferredcites →https://doi.org/10.1021/jp071440gopenalex-snapshot
FTIR and NMR Study of the Adsorbed Water on Nanocrystalline Anatase
inferredcites →https://doi.org/10.1021/jp107671kopenalex-snapshot
Surface Structure of TiO 2 P25 Nanoparticles: Infrared Study of Hydroxy Groups on Coordinative Defect Sites
inferredcites →https://doi.org/10.1021/jp993819bopenalex-snapshot
Role of the Crystallite Phase of TiO2 in Heterogeneous Photocatalysis for Phenol Oxidation in Water
inferredcites →https://doi.org/10.1021/la0009240openalex-snapshot
IR Spectroscopy of Surface Water and Hydroxyl Species on Nanocrystalline TiO 2 Films
inferredcites →https://doi.org/10.1021/la960360topenalex-snapshot
Structural Sensitivity in the Dissociation of Water on TiO 2 Single-Crystal Surfaces
inferredcites →https://doi.org/10.1038/41233openalex-snapshot
Light-induced amphiphilic surfaces
inferredcites →https://doi.org/10.1103/physrevlett.81.2954openalex-snapshot
Structure and Energetics of Water Adsorbed at TiO 2 Anatase \(101\) and \(001\) Surfaces

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inferred← citeshttps://doi.org/10.1016/j.surfin.2025.108085openalex-snapshot
Boosting chlorobenzene detection at 150 °C: Ce-Ag co-doped SnO₂ nanostructures with tunable electronic properties - Experimental and Computational insights
inferred← citeshttps://doi.org/10.1016/j.surfin.2025.108094openalex-snapshot
Hydroxyl group-dependent corrosion resistance of fused quartz in HF solution and anhydrous HF gas
inferred← citeshttps://doi.org/10.1016/j.susc.2023.122315openalex-snapshot
In situ DRIFTS and TPD studies on surface properties affecting SO2-resistance of Pt/TiO2 catalyst in low-temperature CO oxidation
inferred← citeshttps://doi.org/10.1016/j.tramat.2026.100194openalex-snapshot
Steering H2O2 activation pathways with synergistic Cu single-atom and cluster sites on carbon nitride nanospindle
inferred← citeshttps://doi.org/10.1016/j.xcrp.2019.100013openalex-snapshot
Surface Water Loading on Titanium Dioxide Modulates Photocatalytic Water Splitting
inferred← citeshttps://doi.org/10.1021/acs.analchem.1c02759openalex-snapshot
Unraveling the Surface Hydroxyl Network on In2O3 Nanoparticles with High-Field Ultrafast Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy
inferred← citeshttps://doi.org/10.1021/acs.est.1c01608openalex-snapshot
Photocatalytic Oxidation of SO2 by TiO2: Aerosol Formation and the Key Role of Gaseous Reactive Oxygen Species
inferred← citeshttps://doi.org/10.1021/acs.iecr.5c05100openalex-snapshot
Effect of Support Precalcination on the CO Oxidation Activity and SO 2 Resistance of Pt–Pd/TiO 2 Catalysts
inferred← citeshttps://doi.org/10.1021/acs.jpcc.0c11107openalex-snapshot
Probing Acid–Base Properties of Anatase TiO2 Nanoparticles with Dominant {001} and {101} Facets Using Methanol Chemisorption and Surface Reactions
inferred← citeshttps://doi.org/10.1021/acs.jpcc.7b00472openalex-snapshot
Role of Adsorbed Water on Charge Carrier Dynamics in Photoexcited TiO2
inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b05357openalex-snapshot
Gaseous Photocatalytic Oxidation of Formic Acid over TiO2: A Comparison between the Charge Carrier Transfer and Light-Assisted Mars–van Krevelen Pathways
inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b05699openalex-snapshot
Frequencies and Thermal Stability of Isolated Surface Hydroxyls on Pyrogenic TiO2 Nanoparticles
inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b05805openalex-snapshot
Surface Properties of Reduced and Stoichiometric TiO2 As Probed by SO2 Adsorption
inferred← citeshttps://doi.org/10.1021/acs.langmuir.4c05011openalex-snapshot
Evolution of VOx on TiO2-ZSM-5 Composite Supports upon K Poisoning and Its Effects on Ultralow Temperature NH3–SCR
inferred← citeshttps://doi.org/10.1021/acsami.2c06011openalex-snapshot
Visible-Light Photocatalytic Chlorite Activation Mediated by Oxygen Vacancy Abundant Nd-Doped BiVO 4 for Efficient Chlorine Dioxide Generation and Pollutant Degradation
inferred← citeshttps://doi.org/10.1021/acsami.5c24298openalex-snapshot
B-Site Fe–Mn Bimetallic Synergy in Perovskites Drives Efficient Steam Decoking via Oxygen Vacancy Engineering
inferred← citeshttps://doi.org/10.1021/acsami.7b13043openalex-snapshot
Light-Enhanced Carbon Dioxide Activation and Conversion by Effective Plasmonic Coupling Effect of Pt and Au Nanoparticles
inferred← citeshttps://doi.org/10.1021/acsanm.3c02153openalex-snapshot
Magnetic-Field-Regulated ZnFe2O4 Nanospheres Interfacial Hydroxyl for Photocatalytic Air Purification
inferred← citeshttps://doi.org/10.1021/acscatal.0c01901openalex-snapshot
Identification of a Facile Pathway for Dioxymethylene Conversion to Formate Catalyzed by Surface Hydroxyl on TiO 2 -Based Catalyst
inferred← citeshttps://doi.org/10.1021/acscatal.1c01599openalex-snapshot
Humidity-Independent Photocatalytic Toluene Mineralization Benefits from the Utilization of Edge Hydroxyls in Layered Double Hydroxides (LDHs): A Combined Operando and Theoretical Investigation
inferred← citeshttps://doi.org/10.1021/acscatal.3c01740openalex-snapshot
Autocatalysis through the Generation of Water during Methanol Oxidation over a Titania-Supported Platinum Catalyst
inferred← citeshttps://doi.org/10.1021/acscatal.4c00543openalex-snapshot
Insight into the Role of TiO2 Facets in Photocatalytic Selective Oxidation of p-Xylene
inferred← citeshttps://doi.org/10.1021/acscatal.5b02593openalex-snapshot
Trace Amount of SnO2-Decorated ZnSn(OH)6 as Highly Efficient Photocatalyst for Decomposition of Gaseous Benzene: Synthesis, Photocatalytic Activity, and the Unrevealed Synergistic Effect between ZnSn(OH)6 and SnO2
inferred← citeshttps://doi.org/10.1021/acscatal.8b01357openalex-snapshot
A Perspective on the Selective Catalytic Reduction (SCR) of NO with NH3 by Supported V2O5–WO3/TiO2 Catalysts
inferred← citeshttps://doi.org/10.1021/acsenergylett.0c02306openalex-snapshot
Photoelectrochemistry of Au Nanocluster-Sensitized TiO2: Intricacy Arising from the Light-Induced Transformation of Nanoclusters into Nanoparticles
inferred← citeshttps://doi.org/10.1021/acsestengg.6c00166openalex-snapshot
Operando DRIFTS and NMR Spectroscopy Study of Hydrolytic and Photoinduced Transformations of Dimethyl Succinate on TiO 2 and CeO 2
inferred← citeshttps://doi.org/10.1021/acsmaterialsau.5c00140openalex-snapshot
Mild Synthesis of Ag-Decorated TiO 2 Aerogels for Light-Driven CO 2 Reduction
inferred← citeshttps://doi.org/10.1021/acsmaterialslett.4c01024openalex-snapshot
Photocatalytic Surface Initiation for Area-Selective Chemical Vapor Deposition of Polymer Thin Film
inferred← citeshttps://doi.org/10.1021/acsomega.4c08137openalex-snapshot
Inside- and Outside-Coated PANI and/or PIN-TiO 2 Nanotubes for Enhanced Photocatalytic Degradation of 4-Nitrophenol in Wastewater
inferred← citeshttps://doi.org/10.1021/acsomega.4c10501openalex-snapshot
Scheelite Catalysts for Thermal Mineralization of Toluene: A Mechanistic Overview
inferred← citeshttps://doi.org/10.1021/acssuschemeng.3c02236openalex-snapshot
Regulation of Free •OH Radicals via d–p Orbital Hybridization in Ternary Perovskite Catalysts for the Efficient Reaction of Coke and Steam
inferred← citeshttps://doi.org/10.1021/es304188kopenalex-snapshot
Combination of Photocatalysis and HC/SCR for Improved Activity and Durability of DeNOx Catalysts
inferred← citeshttps://doi.org/10.1021/jacs.0c09683openalex-snapshot
Photoinduced Adsorption and Oxidation of SO2 on Anatase TiO2(101)
inferred← citeshttps://doi.org/10.1021/jacs.4c07539openalex-snapshot
Upside-Down Adsorption: The Counterintuitive Influences of Surface Entropy and Surface Hydroxyl Density on Hydrogen Spillover
inferred← citeshttps://doi.org/10.1021/jacsau.0c00028openalex-snapshot
Elucidation of Active Sites in Aldol Condensation of Acetone over Single-Facet Dominant Anatase TiO2 (101) and (001) Catalysts
inferred← citeshttps://doi.org/10.1021/jp5013076openalex-snapshot
Novel V2O5/BiVO4/TiO2 Nanocomposites with High Visible-Light-Induced Photocatalytic Activity for the Degradation of Toluene
inferred← citeshttps://doi.org/10.1021/jp504402zopenalex-snapshot
Titanium Dioxide Nanoparticle Surface Reactivity with Atmospheric Gases, CO2, SO2, and NO2: Roles of Surface Hydroxyl Groups and Adsorbed Water in the Formation and Stability of Adsorbed Products
inferred← citeshttps://doi.org/10.1021/la5047595openalex-snapshot
DRIFTS Evidence for Facet-Dependent Adsorption of Gaseous Toluene on TiO2 with Relative Photocatalytic Properties
inferred← citeshttps://doi.org/10.1029/2023jd040017openalex-snapshot
Unveiling the Role of Carbonate Radical Anions in Dust‐Driven SO2 Oxidation
inferred← citeshttps://doi.org/10.1038/s41598-018-35335-1openalex-snapshot
Robustness of elastic properties in polymer nanocomposite films examined over the full volume fraction range
inferred← citeshttps://doi.org/10.1039/c2ta00382aopenalex-snapshot
Formation of WO 3 nanotube-based bundles directed by NaHSO 4 and its application in water treatment
inferred← citeshttps://doi.org/10.1039/c3cs60227copenalex-snapshot
Conversion of glycerol to hydrogen rich gas
inferred← citeshttps://doi.org/10.1039/c3cy00358bopenalex-snapshot
How metallic is gold in the direct epoxidation of propene: an FTIR study
inferred← citeshttps://doi.org/10.1039/c3gc42369gopenalex-snapshot
Preparation of the CuCr 2 O 4 spinel nanoparticles catalyst for selective oxidation of toluene to benzaldehyde
inferred← citeshttps://doi.org/10.1039/c4cp05423gopenalex-snapshot
On the role of gold nanoparticles in the selective photooxidation of 2-propanol over Au/TiO 2
inferred← citeshttps://doi.org/10.1039/c5ta02295aopenalex-snapshot
Insight into the mechanism of photocatalytic degradation of gaseous o-dichlorobenzene over flower-type V 2 O 5 hollow spheres
inferred← citeshttps://doi.org/10.1039/c5ta05659dopenalex-snapshot
Quantum-sized BiVO 4 modified TiO 2 microflower composite heterostructures: efficient production of hydroxyl radicals towards visible light-driven degradation of gaseous toluene
inferred← citeshttps://doi.org/10.1039/c6ra06684dopenalex-snapshot
Synergistic interactions of Cu and N on surface altered amorphous TiO 2 nanoparticles for enhanced photocatalytic oxidative desulfurization of dibenzothiophene
inferred← citeshttps://doi.org/10.1039/c6ta10114copenalex-snapshot
Incorporation of graphene nanodots and oxygen defects triggers robust coupling between solar energy and reactive oxygen
inferred← citeshttps://doi.org/10.1039/c7cp06646eopenalex-snapshot
Structural changes of water molecules during photoelectrochemical water oxidation on TiO 2 thin film electrodes
inferred← citeshttps://doi.org/10.1039/c7en00920hopenalex-snapshot
Structure–activity relationship of surface hydroxyl groups during NO 2 adsorption and transformation on TiO 2 nanoparticles
inferred← citeshttps://doi.org/10.1039/c7ra02276jopenalex-snapshot
One-step fabrication of recyclable and robust fluorine/polymer-free superhydrophobic fabrics
inferred← citeshttps://doi.org/10.1039/c9cc00814dopenalex-snapshot
Ozone modification as an efficient strategy for promoting the photocatalytic effect of TiO 2 for air purification
inferred← citeshttps://doi.org/10.1039/c9dt01455aopenalex-snapshot
Photo-induced charge separation in hydroxycoumarins on TiO 2 and F–TiO 2
inferred← citeshttps://doi.org/10.1039/d0ee01124jopenalex-snapshot
How to make an efficient gas-phase heterogeneous CO 2 hydrogenation photocatalyst
inferred← citeshttps://doi.org/10.1039/d0nj01432jopenalex-snapshot
Effect of a mixed precursor over monolith MnO x /La–Al 2 O 3 catalyst for toluene oxidation
inferred← citeshttps://doi.org/10.1039/d0ra05010eopenalex-snapshot
Alkali modified P25 with enhanced CO 2 adsorption for CO 2 photoreduction
inferred← citeshttps://doi.org/10.1039/d1cy00362copenalex-snapshot
CO 2 -assisted ethane oxidative dehydrogenation over MoO x catalysts supported on reducible CeO 2 –TiO 2
inferred← citeshttps://doi.org/10.1039/d1cy01450aopenalex-snapshot
Nanocrystalline rhenium-doped TiO 2 : an efficient catalyst in the one-pot conversion of carbohydrates into levulinic acid. The synergistic effect between Brønsted and Lewis acid sites
inferred← citeshttps://doi.org/10.1039/d1nj02368copenalex-snapshot
Pesticide degradation on solid surfaces: a moisture dependent process governed by the interaction between TiO 2 and H 2 O
inferred← citeshttps://doi.org/10.1039/d2nr03877copenalex-snapshot
A spatial homojunction of titanium vacancies decorated with oxygen vacancies in TiO 2 and its directed charge transfer
inferred← citeshttps://doi.org/10.1039/d2ta07555eopenalex-snapshot
Understanding the suppressive role of catalytically active Pt–TiO 2 interfacial sites of supported metal catalysts towards complete oxidation of toluene
inferred← citeshttps://doi.org/10.1039/d3cy01436copenalex-snapshot
Cerium modification enhances the performance of Pd/USY for formaldehyde catalytic oxidation at room temperature
inferred← citeshttps://doi.org/10.1039/d3ee02800copenalex-snapshot
Photochromic single atom Ag/TiO 2 catalysts for selective CO 2 reduction to CH 4
inferred← citeshttps://doi.org/10.1039/d5ra08363jopenalex-snapshot
Polyvinyl alcohol and hydroquinone-based electrolyte coupled with mesoporous carbon nitride for high energy density supercapacitors
inferred← citeshttps://doi.org/10.1039/d5ta03026aopenalex-snapshot
Design of bifunctional bimetallic Fischer–Tropsch synthesis (FTS) catalysts: acid functionalization of TiO 2 support for enhanced product selectivity
inferred← citeshttps://doi.org/10.1063/5.0139103openalex-snapshot
Ultrafast 2D-IR spectroscopy of intensely optically scattering pelleted solid catalysts
inferred← citeshttps://doi.org/10.1080/23744731.2018.1556051openalex-snapshot
Performance of various commercial TiO 2 in photocatalytic degradation of a mixture of indoor air pollutants: Effect of photocatalyst and operating parameters
inferred← citeshttps://doi.org/10.1111/php.12374openalex-snapshot
In Situ FTIR Spectroscopy Study of the Photodegradation of Acetaldehyde and azo Dye Photobleaching on Bismuth‐Modified TiO2
inferred← citeshttps://doi.org/10.15541/jim20250157openalex-snapshot
Ligand-hydroxylated UiO-66 for Enhanced Photothermally Catalytic VOCs Oxidation
inferred← citeshttps://doi.org/10.2139/ssrn.5357398openalex-snapshot
Alkanol Dehydration and Dehydrogenation Pathways on Anatase Tio₂ Under Oxidative and Nonoxidative Conditions
inferred← citeshttps://doi.org/10.2139/ssrn.5985168openalex-snapshot
Zinc as an Electronic Switch: Steering the Methanol Steam Reforming Pathway via Modulating Cu0-Cu+ Pairs at the Molecular Level
inferred← citeshttps://doi.org/10.32604/jrm.2024.031050openalex-snapshot
A Comprehensive Analysis of the Thermo-Chemical Properties of Sudanese Biomass for Sustainable Applications
inferred← citeshttps://doi.org/10.3390/inorganics13110355openalex-snapshot
The Electrochemical Performance of Co3O4 Electrodes with Platinum Nanoparticles for Chlorine Evolution
inferred← citeshttps://doi.org/10.3390/ma10050566openalex-snapshot
Markedly Enhanced Surface Hydroxyl Groups of TiO2 Nanoparticles with Superior Water-Dispersibility for Photocatalysis
inferred← citeshttps://doi.org/10.3390/ma15103657openalex-snapshot
Graphene Oxide@Heavy Metal Ions (GO@M) Complex Simulated Waste as an Efficient Adsorbent for Removal of Cationic Methylene Blue Dye from Contaminated Water
inferred← citeshttps://doi.org/10.3390/ma15155132openalex-snapshot
Photoreduction of Copper Ions Using Silica–Surfactant Hybrid and Titanium (IV) Oxide under Sulfuric Acid Conditions
inferred← citeshttps://doi.org/10.3390/ma9121018openalex-snapshot
First Principles Study on the Interaction Mechanisms of Water Molecules on TiO2 Nanotubes
inferred← citeshttps://doi.org/10.3390/molecules25204605openalex-snapshot
Morphology, Surface Structure and Water Adsorption Properties of TiO2 Nanoparticles: A Comparison of Different Commercial Samples
inferred← citeshttps://doi.org/10.5772/60887openalex-snapshot
The Relevance of ATR-FTIR Spectroscopy in Semiconductor Photocatalysis
inferred← citeshttps://doi.org/10.70675/3a0d865fz854cz4d8azb6afz37492e547f4aopenalex-snapshot
Photocatalytic production of chemicals and hydrogen from biomass
inferred← citeshttps://doi.org/10.70675/95b8f55fze566z498bz8881z68db2db44cc1openalex-snapshot
Valorization of Sudanese biomass for the production of biocomposite and bioenergy.
inferred← citeshttps://doi.org/10.70675/9b0b89f9z957dz4c2ez9127z374d6876ef40openalex-snapshot
Metal oxide and metal oxide-silica thin films deposited by low pressure plasma process : Comparative study of films obtained from Zirconium (IV) tert-Butoxide and Titanium (IV) Isopropoxide
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