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A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/(sici)1099-0682(200005)2000:5<1061::aid-ejic1061>3.0.co;2-7openalex-snapshot
Syntheses and Structures of Bis(aryloxo)fluoroytterbium(III) Complexes, [Yb(OAr)2F(THF)]2 (OAr = OC6H2-2,6-tBu2-4-R; R = H, Me, tBu), and Bis(cyclopentadienyl)fluoroytterbium(III) Complexes, [YbCp2F]3, [Yb(MeCp)2F]4, [YbCp2F(OPPh3)]2, and [Yb(MeCp)2F(THF)]2
inferredcites →https://doi.org/10.1002/(sici)1521-3773(19990802)38:15<2233::aid-anie2233>3.0.co;2-xopenalex-snapshot
Stabilization of a Discrete Lanthanide(II) Hydrido Complex by a Bulky Hydrotris(pyrazolyl)borate Ligand
inferredcites →https://doi.org/10.1002/ange.200801530openalex-snapshot
Intense Near‐IR Emission from Nanoscale Lanthanoid Fluoride Clusters
inferredcites →https://doi.org/10.1002/anie.200704887openalex-snapshot
Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State
inferredcites →https://doi.org/10.1002/anie.200705001openalex-snapshot
Remarkable Stability of Metallocenes with Superbulky Ligands: Spontaneous Reduction of SmIII to SmII
inferredcites →https://doi.org/10.1002/anie.200804934openalex-snapshot
Dinitrogen Reduction and CH Activation by the Divalent Organoneodymium Complex [(C5H2tBu3)2Nd(μ‐I)K([18]crown‐6)]
inferredcites →https://doi.org/10.1002/anie.201108662openalex-snapshot
A Double Addition of LnH to a Carbon–Carbon Triple Bond and Competitive Oxidation of Ytterbium(II) and Hydrido Centers
inferredcites →https://doi.org/10.1002/chem.200700963openalex-snapshot
Steric Modulation of Coordination Number and Reactivity in the Synthesis of Lanthanoid(III) Formamidinates
inferredcites →https://doi.org/10.1002/chem.200802294openalex-snapshot
Intramolecular Metal–Fluorocarbon Coordination, CF Bond Activation and Lanthanoid–Fluoride Clusters with Tethered Polyfluorophenylamide Ligands
inferredcites →https://doi.org/10.1002/chem.201302021openalex-snapshot
Physical Properties of Superbulky Lanthanide Metallocenes: Synthesis and Extraordinary Luminescence of [EuII(CpBIG)2] (CpBIG=(4‐nBu‐C6H4)5‐Cyclopentadienyl)
inferredcites →https://doi.org/10.1016/0022-2860(88)87037-6openalex-snapshot
Structural Methods in Inorganic Chemistry
inferredcites →https://doi.org/10.1016/s0022-328x(01)01428-0openalex-snapshot
β-SiH agostic bonding in sterically crowded lanthanidocene silylamide complexes
inferredcites →https://doi.org/10.1016/s0277-5387(00)88154-1openalex-snapshot
Encapsulated alkaline-earth metallocenes—4. Thermal instability in tetraphenylcyclopentadienyl barium complexes
inferredcites →https://doi.org/10.1021/ic062011kopenalex-snapshot
The Importance of Questioning Scientific Assumptions: Some Lessons from f Element Chemistry
inferredcites →https://doi.org/10.1021/ic402769uopenalex-snapshot
Synthesis, Bonding, and Reactivity of a Cerium(IV) Fluoride Complex
inferredcites →https://doi.org/10.1021/ic700403dopenalex-snapshot
Syntheses and Structures of Ytterbium(II) Hydride and Hydroxide Complexes: Similarities and Differences with Their Calcium Analogues
inferredcites →https://doi.org/10.1021/ja0451012openalex-snapshot
Hydrogen for fluorine exchange in C6F6 and C6F5H by monomeric [1,3,4-(Me3C)3C5H2]2CeH: experimental and computational studies.
inferredcites →https://doi.org/10.1021/ja0504800openalex-snapshot
Hydrogen for Fluorine Exchange in CH4-xFx by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Studies
inferredcites →https://doi.org/10.1021/ja403753jopenalex-snapshot
Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr 2+ , Gd 2+ , Tb 2+ , and Lu 2+
inferredcites →https://doi.org/10.1021/ja800639fopenalex-snapshot
Fluorine for Hydrogen Exchange in the Hydrofluorobenzene Derivatives C6HxF(6-x), where x = 2, 3, 4 and 5 by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: The Solid State Isomerization of [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,5-C6HF4) to [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,6-C6HF4)
inferredcites →https://doi.org/10.1021/om00157a006openalex-snapshot
Defluorination of perfluoroolefins by divalent lanthanoid reagents: activating carbon-fluorine bonds
inferredcites →https://doi.org/10.1021/om021039aopenalex-snapshot
A Half-Sandwich Perfluoroorganoytterbium(II) Complex from a Simple Redox Transmetalation/Ligand Exchange Synthesis
inferredcites →https://doi.org/10.1021/om800501zopenalex-snapshot
Accessing Decaphenylmetallocenes of Ytterbium, Calcium, and Barium by Desolvation of Solvent-Separated Ion Pairs: Overcoming Adverse Solubility Properties
inferredcites →https://doi.org/10.1039/b419047eopenalex-snapshot
Steric engineering of C–F activation with lanthanoid formamidinates
inferredcites →https://doi.org/10.1039/b514358fopenalex-snapshot
Dinuclear alkynyllanthanoid(ii) dications with pentaphenylcyclopentadienyl or tri-tert-butyldiphosphacyclopentadienyl counter ions
inferredcites →https://doi.org/10.1039/b809872gopenalex-snapshot
Superbulky metallocene complexes of the heavier alkaline-earth metals strontium and barium
inferredcites →https://doi.org/10.1039/c2dt30604bopenalex-snapshot
The effects of light lanthanoid elements (La, Ce, Nd) on (Ar)CF–Ln coordination and C–F activation in N,N-dialkyl-N′-2,3,5,6-tetrafluorophenylethane-1,2-diaminate complexes
inferredcites →https://doi.org/10.1039/c39890000136openalex-snapshot
Reaction of (C 5 Me 5 ) 2 Yb with fluorocarbons: formation of (C 5 Me 5 ) 4 Yb 2 (µ-F) by intermolecular C–F activation
inferredcites →https://doi.org/10.1039/c39940002723openalex-snapshot
Phosphorus–heteroatom bond cleavage by ytterbium metal. Synthesis of mono(η 5 -tetramethylphospholyl)ytterbium( II ) chloride and thiolate complexes and structural characterisation of [Yb(µ-Cl)(η 5 -C 4 Me 4 P)(thf) 2 ] 2 and [Yb(µ-SPh)(η 5 -C 4 Me 4 P)(thf) 2 ] 2
inferredcites →https://doi.org/10.1107/s0567739476001551openalex-snapshot
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
inferred← citeshttps://doi.org/10.2139/ssrn.4863374openalex-extracted
Imidobis(Tetraphenylphosphinato)Lanthanoid(Iii) Complexes: Synthesis Byoxidative Protolysis, and Redox Transmetallation/ Protolysis, Structural Studies and Hirshfeld Surface Analysis
inferred← citeshttps://doi.org/10.1002/chem.201502953openalex-snapshot
Enhancing the Value of Free Metals in the Synthesis of Lanthanoid Formamidinates: Is a Co‐oxidant Needed?
inferred← citeshttps://doi.org/10.1002/chem.201704322openalex-snapshot
Generation of ϵ,ϵ‐Difluorinated Metal‐Pentadienyl Species through Lanthanide‐Mediated C−F Activation
inferred← citeshttps://doi.org/10.1002/chem.201804703openalex-snapshot
Can Bismuth Replace Mercury in Redox Transmetallation/Protolysis Syntheses from Free Lanthanoid Metals?
inferred← citeshttps://doi.org/10.1002/chem.202103865openalex-snapshot
Europium is Different: Solvent and Ligand Effects on Oxidation State Outcomes and C‐F Activation in Reactions Between Europium Metal and Pentafluorophenylsilver
inferred← citeshttps://doi.org/10.1002/ejic.201801481openalex-snapshot
Replacing Mercury: Syntheses of Lanthanoid Pyrazolates from Free Lanthanoid Metals, Pentafluorophenylsilver, and Pyrazoles, Aided by a Facile Synthesis of Polyfluoroarylsilver Compounds
inferred← citeshttps://doi.org/10.1002/ejoc.202200202openalex-snapshot
Organic Synthesis with Elemental Lanthanides – Going Beyond Samarium and Ytterbium
inferred← citeshttps://doi.org/10.1002/zaac.202200189openalex-snapshot
Unexpected C−F activation during redox transmetallation with silverN,N′‐bis(2,6‐difluorophenyl)formamidinate
inferred← citeshttps://doi.org/10.1002/zaac.202200251openalex-snapshot
Synthesis and characterisation of divalent di(1,3‐bis(diphenylphosphano)cyclopentadienyl)lanthanoid and alkaline earth complexes as potential platforms for heterometallic complexes
inferred← citeshttps://doi.org/10.1007/s10870-020-00862-1openalex-snapshot
Crystal Structure of Decakis(μ-chloro)-tetrakis(1,2,4-triphenylcyclopentadienyl)-hexakis(tetrahydrofuran)-di-potassium-tetra-neodymium(III) Tetrahydrofuran Trisolvate
inferred← citeshttps://doi.org/10.1007/s11172-020-2871-yopenalex-snapshot
Synthesis and structure of half-sandwich SmII and YIII cyclopentadienyl halide complexes with the penta(benzyl)cyclopentadienyl ligand
inferred← citeshttps://doi.org/10.1016/j.ccr.2015.07.017openalex-snapshot
Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2014
inferred← citeshttps://doi.org/10.1016/j.ccr.2020.213232openalex-snapshot
Syntheses of reactive rare earth complexes by redox transmetallation/protolysis reactions–A simple and convenient method
inferred← citeshttps://doi.org/10.1016/j.ica.2024.122385openalex-snapshot
Imidobis(tetraphenylphosphinato)lanthanoid(III) complexes: Synthesis by oxidative protolysis, and redox transmetallation/protolysis, structural studies and Hirshfeld surface analysis
inferred← citeshttps://doi.org/10.1016/j.ica.2025.122962openalex-snapshot
Tris(triphenylcyclopentadienyl) lanthanide complexes – at the edge of steric overcrowding
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2016.06.003openalex-snapshot
Catalytic activity of phenyl substituted cyclopentadienyl neodymium complexes in the ethylene oligomerization process
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123094openalex-snapshot
Lanthanoid pseudo-Grignard reagents: A review
inferred← citeshttps://doi.org/10.1021/acs.chemrev.1c00842openalex-snapshot
Rare Earth Starting Materials and Methodologies for Synthetic Chemistry
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c02304openalex-snapshot
Assessing the 4f Orbital Participation in the Ln–C Bonds of [Li(THF)4][Ln(C6Cl5)4] (Ln = La, Ce)
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c01062openalex-snapshot
Divalent ansa-Octaphenyllanthanocenes: Synthesis, Structures, and EuII Luminescence
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00842openalex-snapshot
Divalent Tetra- and Penta-phenylcyclopentadienyl Europium and Samarium Sandwich and Half-Sandwich Complexes: Synthesis, Characterization, and Remarkable Luminescence Properties
inferred← citeshttps://doi.org/10.1021/om501150bopenalex-snapshot
Bulky Group 2 Octaphenylmetallocenes and Direct Access to Calcium and Ytterbium Pseudo-Grignard Complexes
inferred← citeshttps://doi.org/10.1039/c5dt04239aopenalex-snapshot
Exploring the effect of the Ln III /Ln II redox potential on C–F activation and on oxidation of some lanthanoid organoamides
inferred← citeshttps://doi.org/10.1039/d0nj03852kopenalex-snapshot
Half-sandwich scandium dibenzyl complexes bearing penta- or tetra-arylcyclopentadienyl ligands: synthesis, structure and syndiospecific styrene polymerization activity
inferred← citeshttps://doi.org/10.1039/d2cc00698gopenalex-snapshot
Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes
inferred← citeshttps://doi.org/10.1071/ch21324openalex-snapshot
A new divalent organoeuropium(II) fluoride and serendipitous discovery of an alkoxide complex from pentaphenylcyclopentadiene precursors†
inferred← citeshttps://doi.org/10.3390/molecules27227704openalex-snapshot
Synthesis and Characterisation of Novel Bis(diphenylphosphane oxide)methanidoytterbium(III) Complexes
inferred← citeshttps://doi.org/10.3791/57948openalex-snapshot
Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
inferred← citeshttps://doi.org/10.6023/a23010004openalex-snapshot
Progress in Rare-earth Metal Complexes with Different Ligands in Olefin Polymerization
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