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The mechanism of water–isopropanol exchange in cement pastes evidenced by NMR relaxometry

https://doi.org/10.1039/c4ra00889h
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1007/bf02482126openalex-snapshot
Pore water distribution in mortar during drying as determined by NMR
inferredcites →https://doi.org/10.1016/0008-8846(87)90133-5openalex-snapshot
Diffusion measurements in cement paste by water replacement using Propan-2-OL
inferredcites →https://doi.org/10.1016/0008-8846(88)90016-6openalex-snapshot
The use of solvent exchange to monitor diffusion characteristics of cement pastes containing silica fume
inferredcites →https://doi.org/10.1016/0008-8846(91)90011-6openalex-snapshot
Pretreatment of hardened hydrated cement pastes for mercury intrusion measurements
inferredcites →https://doi.org/10.1016/0008-8846(93)90183-aopenalex-snapshot
The effect of different drying techniques on the pore size distribution of blended cement mortars
inferredcites →https://doi.org/10.1016/0021-9797(86)90416-9openalex-snapshot
Spreading pressures of water and n-propanol on polymer surfaces
inferredcites →https://doi.org/10.1016/0022-2364(77)90230-xopenalex-snapshot
Spin-lattice relaxation in a system governed by diffusion
inferredcites →https://doi.org/10.1016/0730-725x(94)91517-2openalex-snapshot
Surface magnetic relaxation in cement pastes
inferredcites →https://doi.org/10.1016/j.cemconres.2005.11.021openalex-snapshot
The influence of different drying methods on cement paste microstructures as reflected by gas adsorption: Comparison between freeze-drying (F-drying), D-drying, P-drying and oven-drying methods
inferredcites →https://doi.org/10.1016/j.cemconres.2008.02.012openalex-snapshot
The influence of water removal techniques on the composition and microstructure of hardened cement pastes
inferredcites →https://doi.org/10.1016/j.cemconres.2010.08.003openalex-snapshot
Characterisation of intra- and inter-C–S–H gel pore water in white cement based on an analysis of NMR signal amplitudes as a function of water content
inferredcites →https://doi.org/10.1016/j.cemconres.2010.09.011openalex-snapshot
Mechanisms of cement hydration
inferredcites →https://doi.org/10.1016/j.cemconres.2011.06.003openalex-snapshot
Comparison of methods for arresting hydration of cement
inferredcites →https://doi.org/10.1016/j.cocis.2008.10.004openalex-snapshot
NMR and nuclear spin relaxation of cement and concrete materials
inferredcites →https://doi.org/10.1016/j.conbuildmat.2009.06.004openalex-snapshot
Effect of free water removal from early-age hydrated cement pastes on thermal analysis
inferredcites →https://doi.org/10.1016/j.conbuildmat.2011.07.012openalex-snapshot
Drying effect on cement paste porosity at early age observed by NMR methods
inferredcites →https://doi.org/10.1016/j.micromeso.2013.01.032openalex-snapshot
Use of bench-top NMR to measure the density, composition and desorption isotherm of C–S–H in cement paste
inferredcites →https://doi.org/10.1016/j.micromeso.2013.02.032openalex-snapshot
Nanoporous carbons from hydrothermally treated biomass as anode materials for lithium ion batteries
inferredcites →https://doi.org/10.1016/s0008-8846(98)00049-0openalex-snapshot
The surface area of cement paste as measured by neutron scattering: evidence for two C-S-H morphologies
inferredcites →https://doi.org/10.1016/s0008-8846(99)00260-4openalex-snapshot
Solvent exchange in partially saturated and saturated microporous systems
inferredcites →https://doi.org/10.1016/s0730-725x(98)00061-7openalex-snapshot
Water absorption in mortar determined by NMR
inferredcites →https://doi.org/10.1016/s1065-7355(98)00008-xopenalex-snapshot
Solvent Replacement Studies of Hydrated Portland Cement Systems: The Role of Calcium Hydroxide
inferredcites →https://doi.org/10.1021/jp3102964openalex-snapshot
Densification of C–S–H Measured by 1 H NMR Relaxometry
inferredcites →https://doi.org/10.1063/1.1716296openalex-snapshot
Modified Spin-Echo Method for Measuring Nuclear Relaxation Times
inferredcites →https://doi.org/10.1063/1.343088openalex-snapshot
Application of nuclear magnetic resonance pore structure analysis to porous silica glass
inferredcites →https://doi.org/10.1088/0370-1328/82/1/303openalex-snapshot
Zero Time Resolution Nuclear Magnetic Resonance Transient in Solids
inferredcites →https://doi.org/10.1088/1367-2630/14/5/055017openalex-snapshot
Focus on the physics of magnetic resonance on porous media
inferredcites →https://doi.org/10.1093/acprof:oso/9780199556984.001.0001openalex-snapshot
Translational Dynamics and Magnetic Resonance: Principles of Pulsed Gradient Spin Echo NMR
inferredcites →https://doi.org/10.1103/physreve.72.011409openalex-snapshot
Surface relaxation and chemical exchange in hydrating cement pastes: A two-dimensional NMR relaxation study
inferredcites →https://doi.org/10.1109/78.995059openalex-snapshot
Solving Fredholm integrals of the first kind with tensor product structure in 2 and 2.5 dimensions
inferredcites →https://doi.org/10.1111/j.1151-2916.1978.tb09224.xopenalex-snapshot
NMR Relaxation Study of Adsorbed Water in Cement and C 3 S Pastes
inferredcites →https://doi.org/10.1111/j.1151-2916.1985.tb15243.xopenalex-snapshot
NMR Line Shape‐Spin‐Lattice Relaxation Correlation Study of Portland Cement Hydration
inferredcites →https://doi.org/10.1111/j.1151-2916.2003.tb03378.xopenalex-snapshot
Detection of Drying‐Induced Microcracking in Cementitious Materials with Space‐Resolved 1 H Nuclear Magnetic Resonance Relaxometry
inferredcites →https://doi.org/10.1111/j.1551-2916.2006.01422.xopenalex-snapshot
Proton Spin–Spin Relaxation Study of the Effect of Temperature on White Cement Hydration
inferredcites →https://doi.org/10.1524/zpch.1999.209.part_2.284openalex-snapshot
NMR Tomography, Diffusometry, Relaxometry

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4661679openalex-extracted
The Deformation of C–S–H Gel and its Link with Length Change of Cement Pastes on Drying and Resaturation
inferred← citeshttps://doi.org/10.1016/j.cemconcomp.2020.103812openalex-snapshot
The effect of chemical aging on water permeability of white cement mortars in the context of sol–gel science
inferred← citeshttps://doi.org/10.1016/j.cemconcomp.2022.104453openalex-snapshot
Pore structure characteristics of concrete composites with surface-modified carbon nanotubes
inferred← citeshttps://doi.org/10.1016/j.cemconcomp.2022.104631openalex-snapshot
Influence of curing conditions on the mechanical and hydric performance of air-lime mortars with nano-Ca(OH)2 and nano-SiO2 additions
inferred← citeshttps://doi.org/10.1016/j.cemconcomp.2022.104639openalex-snapshot
Real-time monitoring the electrical properties of pastes to map the hydration induced microstructure change in cement-based materials
inferred← citeshttps://doi.org/10.1016/j.cemconcomp.2023.105129openalex-snapshot
Micro-nano scale pore structure and fractal dimension of ultra-high performance cementitious composites modified with nanofillers
inferred← citeshttps://doi.org/10.1016/j.cemconres.2015.02.025openalex-snapshot
Evolution of pore structure in blended systems
inferred← citeshttps://doi.org/10.1016/j.cemconres.2016.07.012openalex-snapshot
NMR relaxation of molecules confined inside the cement paste pores under partially saturated conditions
inferred← citeshttps://doi.org/10.1016/j.cemconres.2017.08.002openalex-snapshot
Why permeability to water is anomalously lower than that to many other fluids for cement-based material?
inferred← citeshttps://doi.org/10.1016/j.cemconres.2017.12.002openalex-snapshot
Pore-size resolved water vapor adsorption kinetics of white cement mortars as viewed from proton NMR relaxation
inferred← citeshttps://doi.org/10.1016/j.cemconres.2018.12.004openalex-snapshot
Early age creep of cement paste - Governing mechanisms and role of water-A microindentation study
inferred← citeshttps://doi.org/10.1016/j.cemconres.2019.04.006openalex-snapshot
Creep of cement paste containing fly ash - An investigation using microindentation technique
inferred← citeshttps://doi.org/10.1016/j.cemconres.2021.106461openalex-snapshot
Physical and chemical effects of isopropanol exchange in cement-based materials
inferred← citeshttps://doi.org/10.1016/j.cemconres.2022.106710openalex-snapshot
The role of cavitation in drying cementitious materials
inferred← citeshttps://doi.org/10.1016/j.cemconres.2024.107478openalex-snapshot
How the materials knowledge of Roman mortars could be helpful for the production of future materials: The case of the Aqua Traiana aqueduct (Rome, Italy)
inferred← citeshttps://doi.org/10.1016/j.cemconres.2024.107693openalex-snapshot
The deformation of C S H gels and its link with dynamic length change of cement pastes upon drying and resaturation
inferred← citeshttps://doi.org/10.1016/j.cemconres.2024.107698openalex-snapshot
Full-scale observation of drying-induced microstructure change in hardened cement paste by water and 2-propanol 1H NMR relaxometry
inferred← citeshttps://doi.org/10.1016/j.cemconres.2025.108117openalex-snapshot
Quantitative dependence of dynamic drying shrinkage of white cement pastes on pore-scale water removal kinetics
inferred← citeshttps://doi.org/10.1016/j.cemconres.2026.108249openalex-snapshot
Pore structure and sorption of MgO-hydromagnesite cement pastes – on the mechanisms of moisture-induced weakening
inferred← citeshttps://doi.org/10.1016/j.conbuildmat.2022.130148openalex-snapshot
The deterioration mechanisms of hardened cement paste exposed to combined action of cyclic wetting–drying, salt attack and carbonation
inferred← citeshttps://doi.org/10.1016/j.conbuildmat.2023.131482openalex-snapshot
Utilization of coal gangue powder to improve the sustainability of ultra-high performance concrete
inferred← citeshttps://doi.org/10.1016/j.conbuildmat.2023.133981openalex-snapshot
New insight of solvent-replacement-induced damage to pores of cement stone by comparison with 1H NMR relaxometry, mercury intrusion porosimetry, and nitrogen adsorption
inferred← citeshttps://doi.org/10.1016/j.conbuildmat.2025.140597openalex-snapshot
Bound water evolution and machine-learning-assisted early hydration degree estimation of cement paste based on hyperspectral imaging
inferred← citeshttps://doi.org/10.1016/j.conbuildmat.2026.147978openalex-snapshot
Phase evolution and mechanical stability of deep-earth cementitious systems under 300 °C hydrothermal and dry-heating conditions
inferred← citeshttps://doi.org/10.1016/j.engfailanal.2024.108788openalex-snapshot
Novel approach to detect encasement failures in the anchorage system of guyed transmission towers by distribution of relaxation times
inferred← citeshttps://doi.org/10.1016/j.jobe.2024.108635openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.jobe.2024.110388openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.jobe.2025.112621openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.jobe.2025.114871openalex-snapshot
New insight into water transport in cement paste by a coupled NEMD-LBM approach
inferred← citeshttps://doi.org/10.1016/j.jobe.2026.116112openalex-snapshot
Water migration and pore fractal dimension characterizations of alkali-activated fly ash-slag cementitious materials based on 1H LF-NMR technology
inferred← citeshttps://doi.org/10.1021/acs.iecr.1c01819openalex-snapshot
Pore Structure Evolution of Cemented Paste Backfill Observed with Two-Dimensional NMR Relaxation Correlation Measurements
inferred← citeshttps://doi.org/10.1038/s41598-026-48224-9openalex-snapshot
Effect of particle recombination on mechanical property and microstructure of solidified waste sludge
inferred← citeshttps://doi.org/10.1039/d6ra04661dopenalex-snapshot
Probe into the pore structure of carbonated calcium silicate cement compacts by proton nuclear magnetic resonance relaxometry
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Revealing the influence of water-cement ratio on the pore size distribution in hydrated cement paste by using cyclohexane
inferred← citeshttps://doi.org/10.1080/21650373.2026.2641230openalex-snapshot
Improving multi-exponential inversion of low-field NMR relaxation data for porous cement-based materials through Bayesian principles and prior information
inferred← citeshttps://doi.org/10.1520/gtj20200039openalex-snapshot
Effects of Oven Temperature and Addition of Ethanol on Measurement of Water Content and Specific Gravity of Cement-Stabilized Soft Clay
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Oven dying kinetics and status of cement-based porous materials for in-lab microstructure investigation
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inferred← citeshttps://doi.org/10.2139/ssrn.5736684openalex-snapshot
Pore structure and sorption of MgO-hydromagnesite cement pastes – the effect of moisture on strength and stiffness
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Multi-exponential Inversion of the Relaxometry Data of Low-field Nuclear Magnetic Resonance for Cement-based Materials
inferred← citeshttps://doi.org/10.3151/jact.23.507openalex-snapshot
Full-scale Microstructure and Volume Composition Changes in Hardened Cement Paste during Drying and Accelerated Carbonation by Water-2-propanol 1H-NMR Relaxometry
inferred← citeshttps://doi.org/10.3390/constrmater5030047openalex-snapshot
A Comprehensive Study of the Macro-Scale Performance of Graphene Oxide Enhanced Low Carbon Concrete
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inferred← citeshttps://doi.org/10.3390/ma14123288openalex-snapshot
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inferred← citeshttps://doi.org/10.3390/ma15010036openalex-snapshot
Deformations in Cement Pastes during Capillary Imbibition and Their Relation to Water and Isopropanol as Imbibing Liquids
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