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Reactive surface organometallic complexes observed using dynamic nuclear polarization surface enhanced NMR spectroscopy

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/9783527625413openalex-snapshot
Catalysis for Sustainable Energy Production
inferredcites →https://doi.org/10.1002/9783527627097openalex-snapshot
Modern Surface Organometallic Chemistry
inferredcites →https://doi.org/10.1002/anie.200390072openalex-snapshot
Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry
inferredcites →https://doi.org/10.1002/anie.201106030openalex-snapshot
Dynamic Nuclear Polarization Enhanced Solid‐State NMR Spectroscopy of Functionalized Metal–Organic Frameworks
inferredcites →https://doi.org/10.1002/anie.201403905openalex-snapshot
NMR Signatures of the Active Sites in Sn‐β Zeolite
inferredcites →https://doi.org/10.1002/anie.201501172openalex-snapshot
Quantitative Structural Constraints for Organic Powders at Natural Isotopic Abundance Using Dynamic Nuclear Polarization Solid‐State NMR Spectroscopy
inferredcites →https://doi.org/10.1002/anie.201505867openalex-snapshot
Iridium(I)/N‐Heterocyclic Carbene Hybrid Materials: Surface Stabilization of Low‐Valent Iridium Species for High Catalytic Hydrogenation Performance
inferredcites →https://doi.org/10.1002/anie.201510821openalex-snapshot
Atomistic Description of Reaction Intermediates for Supported Metathesis Catalysts Enabled by DNP SENS
inferredcites →https://doi.org/10.1002/cctc.201500607openalex-snapshot
VOx/SiO2 Catalyst Prepared by Grafting VOCl3 on Silica for Oxidative Dehydrogenation of Propane
inferredcites →https://doi.org/10.1002/chem.201405043openalex-snapshot
Natural Abundance 15N NMR by Dynamic Nuclear Polarization: Fast Analysis of Binding Sites of a Novel Amine‐Carboxyl‐Linked Immobilized Dirhodium Catalyst
inferredcites →https://doi.org/10.1002/chem.201406033openalex-snapshot
Effect of Support on Metathesis of n‐Decane: Drastic Improvement in Alkane Metathesis with WMe5 Linked to Silica–Alumina
inferredcites →https://doi.org/10.1007/s12205-014-0229-4openalex-snapshot
Adsorption of CO2 on amine-impregnated mesoporous MCM41 silica
inferredcites →https://doi.org/10.1016/s0022-3697(99)00010-4openalex-snapshot
Thermal stability of mesoporous silica molecular sieve
inferredcites →https://doi.org/10.1016/s0167-2991(02)80223-3openalex-snapshot
About the exclusive mesoporous character of MCM-41
inferredcites →https://doi.org/10.1021/acs.accounts.5b00518openalex-snapshot
Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts
inferredcites →https://doi.org/10.1021/acs.molpharmaceut.5b00610openalex-snapshot
Polymorphs of Theophylline Characterized by DNP Enhanced Solid-State NMR
inferredcites →https://doi.org/10.1021/acscatal.5b01671openalex-snapshot
Mesoporous Silica-Supported Amidozirconium-Catalyzed Carbonyl Hydroboration
inferredcites →https://doi.org/10.1021/acscatal.5b02039openalex-snapshot
Dynamic Nuclear Polarization Solid-State NMR in Heterogeneous Catalysis Research
inferredcites →https://doi.org/10.1021/ja00042a018openalex-snapshot
Silicon-29 NMR study of silica
inferredcites →https://doi.org/10.1021/ja000900fopenalex-snapshot
A Highly Active Well-Defined Rhenium Heterogeneous Catalyst for Olefin Metathesis Prepared via Surface Organometallic Chemistry
inferredcites →https://doi.org/10.1021/ja0264854openalex-snapshot
Coordination Chemistry of Stable Radicals: Homolysis of a Titanium−Oxygen Bond
inferredcites →https://doi.org/10.1021/ja0356784openalex-snapshot
Addition of Stable Nitroxide Radical to Stable Divalent Compounds of Heavier Group 14 Elements
inferredcites →https://doi.org/10.1021/ja046486ropenalex-snapshot
Detailed Structural Investigation of the Grafting of [Ta(CHtBu)(CH2tBu)3] and [Cp*TaMe4] on Silica Partially Dehydroxylated at 700 °C and the Activity of the Grafted Complexes toward Alkane Metathesis
inferredcites →https://doi.org/10.1021/ja104771zopenalex-snapshot
Surface Enhanced NMR Spectroscopy by Dynamic Nuclear Polarization
inferredcites →https://doi.org/10.1021/ja110791dopenalex-snapshot
Fast Characterization of Functionalized Silica Materials by Silicon-29 Surface-Enhanced NMR Spectroscopy Using Dynamic Nuclear Polarization
inferredcites →https://doi.org/10.1021/ja307755topenalex-snapshot
Enhanced Solid-State NMR Correlation Spectroscopy of Quadrupolar Nuclei Using Dynamic Nuclear Polarization
inferredcites →https://doi.org/10.1021/ja308135ropenalex-snapshot
Dynamic Nuclear Polarization NMR Spectroscopy of Microcrystalline Solids
inferredcites →https://doi.org/10.1021/ja404476mopenalex-snapshot
Reactivity of TEMPO toward 16- and 17-Electron Organometallic Reaction Intermediates: A Time-Resolved IR Study
inferredcites →https://doi.org/10.1021/ja405813topenalex-snapshot
Large Molecular Weight Nitroxide Biradicals Providing Efficient Dynamic Nuclear Polarization at Temperatures up to 200 K
inferredcites →https://doi.org/10.1021/ja407902gopenalex-snapshot
Bipodal Surface Organometallic Complexes with Surface N-Donor Ligands and Application to the Catalytic Cleavage of C–H and C–C Bonds in n-Butane
inferredcites →https://doi.org/10.1021/ja408074vopenalex-snapshot
Dynamic Nuclear Polarization NMR Spectroscopy Allows High-Throughput Characterization of Microporous Organic Polymers
inferredcites →https://doi.org/10.1021/ja4092038openalex-snapshot
Dynamic Nuclear Polarization Enhanced NMR Spectroscopy for Pharmaceutical Formulations
inferredcites →https://doi.org/10.1021/ja410747gopenalex-snapshot
WMe6 Tamed by Silica: ≡Si–O–WMe5 as an Efficient, Well-Defined Species for Alkane Metathesis, Leading to the Observation of a Supported W–Methyl/Methylidyne Species
inferredcites →https://doi.org/10.1021/ja506344kopenalex-snapshot
Correction to “Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures”
inferredcites →https://doi.org/10.1021/jacs.5b00622openalex-snapshot
Influences of Dilute Organic Adsorbates on the Hydration of Low-Surface-Area Silicates
inferredcites →https://doi.org/10.1021/jacs.5b09964openalex-snapshot
A New Tool for NMR Crystallography: Complete 13C/15N Assignment of Organic Molecules at Natural Isotopic Abundance Using DNP-Enhanced Solid-State NMR
inferredcites →https://doi.org/10.1021/jp310109sopenalex-snapshot
Mesoporous Silica Nanoparticles Loaded with Surfactant: Low Temperature Magic Angle Spinning 13C and 29Si NMR Enhanced by Dynamic Nuclear Polarization
inferredcites →https://doi.org/10.1021/om050086aopenalex-snapshot
Well-Defined Surface Tungstenocarbyne Complexes through the Reaction of [W(⋮CtBu)(CH2tBu)3] with Silica
inferredcites →https://doi.org/10.1021/om050609eopenalex-snapshot
Tantalum Hydrides Supported on MCM-41 Mesoporous Silica: Activation of Methane and Thermal Evolution of the Tantalum-Methyl Species
inferredcites →https://doi.org/10.1039/b612793mopenalex-snapshot
High resolution solid state NMRspectroscopy in surface organometallic chemistry: access to molecular understanding of active sites of well-defined heterogeneous catalysts
inferredcites →https://doi.org/10.1039/c1cc15242dopenalex-snapshot
Non-aqueous solvents for DNP surface enhanced NMR spectroscopy
inferredcites →https://doi.org/10.1039/c1sc00550bopenalex-snapshot
One hundred fold overall sensitivity enhancements for Silicon-29 NMR spectroscopy of surfaces by dynamic nuclear polarization with CPMG acquisition
inferredcites →https://doi.org/10.1039/c2cc15905hopenalex-snapshot
Dynamic nuclear polarization of quadrupolar nuclei using cross polarization from protons: surface-enhanced aluminium-27 NMR
inferredcites →https://doi.org/10.1039/c3cp00039gopenalex-snapshot
Analysis of sensitivity enhancement by dynamic nuclear polarization in solid-state NMR: a case study of functionalized mesoporous materials
inferredcites →https://doi.org/10.1039/c4cs00189copenalex-snapshot
Heterogeneous catalysis for sustainable biodiesel production via esterification and transesterification
inferredcites →https://doi.org/10.1039/c5sc03490fopenalex-snapshot
Controlling the hydrogenolysis of silica-supported tungsten pentamethyl leads to a class of highly electron deficient partially alkylated metal hydrides
inferredcites →https://doi.org/10.1039/c6sc01229aopenalex-snapshot
Atomic-level organization of vicinal acid–base pairs through the chemisorption of aniline and derivatives onto mesoporous SBA15
inferredcites →https://doi.org/10.1126/science.276.5309.99openalex-snapshot
Metathesis of Alkanes Catalyzed by Silica-Supported Transition Metal Hydrides

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Theoretical Insight into Selectivity and Catalytic Activity of Γ-Al2o3 Supported Ir(Co)2 Complex for 1,3-Butadiene Partial Hydrogenation
inferred← citeshttps://doi.org/10.1002/9783527839278.ch8openalex-snapshot
Confinement Effects in Catalysis with Molecular Complexes Immobilized into Porous Materials
inferred← citeshttps://doi.org/10.1002/ange.201703758openalex-snapshot
Frozen Acrylamide Gels as Dynamic Nuclear Polarization Matrices
inferred← citeshttps://doi.org/10.1002/anie.201703758openalex-snapshot
Frozen Acrylamide Gels as Dynamic Nuclear Polarization Matrices
inferred← citeshttps://doi.org/10.1002/chem.201805480openalex-snapshot
Structural Insights into Peptides Bound to the Surface of Silica Nanopores
inferred← citeshttps://doi.org/10.1002/chem.202401968openalex-snapshot
Uncovering Factors Controlling Reactivity of Metal‐TEMPO Reaction Systems in the Solid State and Solution
inferred← citeshttps://doi.org/10.1002/chem.71772openalex-snapshot
Structure–Activity Relationships in Methyl‐Driven Overhauser Effect DNP
inferred← citeshttps://doi.org/10.1002/cphc.201700299openalex-snapshot
In Silico Design of DNP Polarizing Agents: Can Current Dinitroxides Be Improved?
inferred← citeshttps://doi.org/10.1002/hlca.201700101openalex-snapshot
Tailored Polarizing Hybrid Solids with Nitroxide Radicals Localized in Mesostructured Silica Walls
inferred← citeshttps://doi.org/10.1002/ppsc.201700183openalex-snapshot
Solvent‐Free Synthesis of Quaternary Metal Sulfide Nanoparticles Derived from Thiourea
inferred← citeshttps://doi.org/10.1016/b978-0-08-102688-5.00002-7openalex-snapshot
Nuclear Magnetic Resonance Spectroscopy
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00037-8openalex-snapshot
Organometallic Chemistry on Oxide Surfaces
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00133-5openalex-snapshot
Surface Organometallic Chemistry and Catalysis
inferred← citeshttps://doi.org/10.1016/bs.arnmr.2018.05.001openalex-snapshot
Solid-State NMR Studies of Molecular Crystals
inferred← citeshttps://doi.org/10.1016/j.ccr.2019.02.017openalex-snapshot
Progress and challenges of graphene oxide/metal-organic composites
inferred← citeshttps://doi.org/10.1016/j.cocis.2018.02.006openalex-snapshot
Dynamic Nuclear Polarization Surface Enhanced NMR spectroscopy (DNP SENS): Principles, protocols, and practice
inferred← citeshttps://doi.org/10.1016/j.jcat.2019.01.013openalex-snapshot
A site-sensitive quasi-in situ strategy to characterize Mo/HZSM-5 during activation
inferred← citeshttps://doi.org/10.1016/j.jmr.2018.05.015openalex-snapshot
Boosting sensitivity and suppressing artifacts via multi-acquisition in direct polarization NMR experiments with small flip-angle pulses
inferred← citeshttps://doi.org/10.1016/j.jmr.2018.10.010openalex-snapshot
Multi-resonant photonic band-gap/saddle coil DNP probehead for static solid state NMR of microliter volume samples
inferred← citeshttps://doi.org/10.1016/j.jmr.2020.106893openalex-snapshot
Characterization of photonic band resonators for DNP NMR of thin film samples at 7 T magnetic field
inferred← citeshttps://doi.org/10.1016/j.jmr.2021.107067openalex-snapshot
Triple-pulse excitation: An efficient way for suppressing background signals and eliminating radio-frequency acoustic ringing in direct polarization NMR experiments
inferred← citeshttps://doi.org/10.1016/j.mcat.2024.114365openalex-snapshot
Theoretical insight into selectivity and catalytic activity of γ-(Al2O3) supported Ir(CO)2 complex for 1,3-butadiene partial hydrogenation
inferred← citeshttps://doi.org/10.1016/j.pnmrs.2025.101573openalex-snapshot
Advances in solid-state NMR for the studies of mesoporous solids: fast magic angle spinning and dynamic nuclear polarization
inferred← citeshttps://doi.org/10.1016/j.ssnmr.2019.05.009openalex-snapshot
Recent developments in MAS DNP-NMR of materials
inferred← citeshttps://doi.org/10.1016/j.ssnmr.2022.101785openalex-snapshot
Magic angle spinning dynamic nuclear polarization solid-state NMR spectroscopy of γ-irradiated molecular organic solids
inferred← citeshttps://doi.org/10.1021/acs.chemrev.9b00238openalex-snapshot
The Comparison between Single Atom Catalysis and Surface Organometallic Catalysis
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.1c03200openalex-snapshot
Determining the Three-Dimensional Structures of Silica-Supported Metal Complexes from the Ground Up
inferred← citeshttps://doi.org/10.1021/acs.jpca.4c00228openalex-snapshot
Formation of Stable Radicals by Mechanochemistry and Their Application for Magic Angle Spinning Dynamic Nuclear Polarization Solid-State NMR Spectroscopy
inferred← citeshttps://doi.org/10.1021/acs.jpcb.7b07213openalex-snapshot
In Situ Characterization of Pharmaceutical Formulations by Dynamic Nuclear Polarization Enhanced MAS NMR
inferred← citeshttps://doi.org/10.1021/acs.jpcc.2c01721openalex-snapshot
Design Principles for the Development of Gd(III) Polarizing Agents for Magic Angle Spinning Dynamic Nuclear Polarization
inferred← citeshttps://doi.org/10.1021/acs.jpcc.7b04438openalex-snapshot
Measuring Nano- to Microstructures from Relayed Dynamic Nuclear Polarization NMR
inferred← citeshttps://doi.org/10.1021/acs.jpcc.7b06761openalex-snapshot
Characterization of V–Mo–W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR
inferred← citeshttps://doi.org/10.1021/acs.jpcc.7b06807openalex-snapshot
Revealing Structure Reactivity Relationships in Heterogenized Dirhodium Catalysts by Solid-State NMR Techniques
inferred← citeshttps://doi.org/10.1021/acs.jpcc.7b07965openalex-snapshot
Unusual Local Molecular Motions in the Solid State Detected by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy
inferred← citeshttps://doi.org/10.1021/acs.jpcc.8b07969openalex-snapshot
Selective DNP Signal Amplification To Probe Structures of Core–Shell Polymer Hybrid Nanoparticles
inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b01782openalex-snapshot
Atomic-Scale Structure of Mesoporous Silica-Encapsulated Pt and PtSn Nanoparticles Revealed by Dynamic Nuclear Polarization-Enhanced 29Si MAS NMR Spectroscopy
inferred← citeshttps://doi.org/10.1021/acs.jpclett.0c00716openalex-snapshot
A Formulation Protocol with Pyridine to Enable Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy on Reactive Surface Sites: Case Study with Olefin Polymerization and Metathesis Catalysts
inferred← citeshttps://doi.org/10.1021/acs.jpclett.8b01891openalex-snapshot
Materials Characterization by Dynamic Nuclear Polarization-Enhanced Solid-State NMR Spectroscopy
inferred← citeshttps://doi.org/10.1021/acs.jpclett.9b01655openalex-snapshot
High-Field Magic Angle Spinning Dynamic Nuclear Polarization Using Radicals Created by γ-Irradiation
inferred← citeshttps://doi.org/10.1021/acscatal.7b01249openalex-snapshot
Exploiting Confinement Effects to Tune Selectivity in Cyclooctane Metathesis
inferred← citeshttps://doi.org/10.1021/acscatal.9b02017openalex-snapshot
Spatial Distribution of Silica-Bound Catalytic Organic Functional Groups Can Now Be Revealed by Conventional and DNP-Enhanced Solid-State NMR Methods
inferred← citeshttps://doi.org/10.1021/jacs.2c01013openalex-snapshot
Multiple Surface Site Three-Dimensional Structure Determination of a Supported Molecular Catalyst
inferred← citeshttps://doi.org/10.1021/jacs.6b12981openalex-snapshot
Active Sites in Supported Single-Site Catalysts: An NMR Perspective
inferred← citeshttps://doi.org/10.1021/jacs.6c09647openalex-snapshot
Surface-Enhanced NMR Spectroscopy via Solid-to-Solid Relayed Dynamic Nuclear Polarization
inferred← citeshttps://doi.org/10.1021/jacs.7b05194openalex-snapshot
Dynamic Nuclear Polarization Efficiency Increased by Very Fast Magic Angle Spinning
inferred← citeshttps://doi.org/10.1021/jacs.8b08081openalex-snapshot
BDPA-Nitroxide Biradicals Tailored for Efficient Dynamic Nuclear Polarization Enhanced Solid-State NMR at Magnetic Fields up to 21.1 T
inferred← citeshttps://doi.org/10.1039/9781837673179-00256openalex-snapshot
Dynamic Nuclear Polarization for Solid-state NMR Spectroscopy
inferred← citeshttps://doi.org/10.1039/c5sc03490fopenalex-snapshot
Controlling the hydrogenolysis of silica-supported tungsten pentamethyl leads to a class of highly electron deficient partially alkylated metal hydrides
inferred← citeshttps://doi.org/10.1039/c7sc01365eopenalex-snapshot
From single-site tantalum complexes to nanoparticles of Ta x N y and TaO x N y supported on silica: elucidation of synthesis chemistry by dynamic nuclear polarization surface enhanced NMR spectroscopy and X-ray absorption spectroscopy
inferred← citeshttps://doi.org/10.1039/c7sc05200fopenalex-snapshot
Exploiting the interactions between the ruthenium Hoveyda–Grubbs catalyst and Al-modified mesoporous silica: the case of SBA15 vs. KCC-1
inferred← citeshttps://doi.org/10.1039/c8cc00293bopenalex-snapshot
Direct 17 O dynamic nuclear polarization of single-site heterogeneous catalysts
inferred← citeshttps://doi.org/10.1039/c8cp04909bopenalex-snapshot
Maximizing NMR signal per unit time by facilitating the e–e–n cross effect DNP rate
inferred← citeshttps://doi.org/10.1039/c8cs00356dopenalex-snapshot
Surface organometallic chemistry in heterogeneous catalysis
inferred← citeshttps://doi.org/10.1039/c8sc00532jopenalex-snapshot
Predicting the DNP-SENS efficiency in reactive heterogeneous catalysts from hydrophilicity
inferred← citeshttps://doi.org/10.1039/c8sc03848aopenalex-snapshot
Fast detection and structural identification of carbocations on zeolites by dynamic nuclear polarization enhanced solid-state NMR
inferred← citeshttps://doi.org/10.1039/c8sc05287eopenalex-snapshot
Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports
inferred← citeshttps://doi.org/10.1039/c9sc02215eopenalex-snapshot
Surface enhanced dynamic nuclear polarization solid-state NMR spectroscopy sheds light on Brønsted–Lewis acid synergy during the zeolite catalyzed methanol-to-hydrocarbon process
inferred← citeshttps://doi.org/10.1039/d0cy01174fopenalex-snapshot
Non-oxidative dehydrogenation of isobutane over supported vanadium oxide: nature of the active sites and coke formation
inferred← citeshttps://doi.org/10.1039/d3sc01079aopenalex-snapshot
Polarizing agents for efficient high field DNP solid-state NMR spectroscopy under magic-angle spinning: from design principles to formulation strategies
inferred← citeshttps://doi.org/10.1146/annurev-matsci-081720-085634openalex-snapshot
Dynamic Nuclear Polarization Solid-State NMR Spectroscopy for Materials Research
inferred← citeshttps://doi.org/10.1515/zpch-2017-1032openalex-snapshot
Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes
inferred← citeshttps://doi.org/10.26434/chemrxiv.11935281openalex-snapshot
A Formulation Protocol with Pyridine to Enable DNP-SENS on Reactive Surface Sites: Case Study with Olefin Polymerization and Metathesis Catalysts
inferred← citeshttps://doi.org/10.31274/td-20240329-415openalex-snapshot
Improving sensitivity and resolution in solid-state nuclear magnetic resonance
inferred← citeshttps://doi.org/10.33540/265openalex-snapshot
Developing novel applications of Dynamic Nuclear Polarization in solid-state NMR spectroscopy
inferred← citeshttps://doi.org/10.70675/65829747z459dz4a3az892dzc7dbbdeae5bdopenalex-snapshot
High sensitivity solid-state NMR spectroscopy of catalytic surfaces
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