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Iridium-catalysed hydrosilylation of cyclopropanes via regioselective carbon–carbon bond cleavage

https://doi.org/10.1039/c7cc04296e
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/anie.201207723openalex-snapshot
Rhodium‐Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives
inferredcites →https://doi.org/10.1002/anie.201210328openalex-snapshot
Palladium‐Catalyzed ortho‐Selective CH Borylation of 2‐Phenylpyridine and Its Derivatives at Room Temperature
inferredcites →https://doi.org/10.1002/anie.201603153openalex-snapshot
Rhodium‐Catalyzed Enantioselective Silylation of Cyclopropyl C−H Bonds
inferredcites →https://doi.org/10.1002/anie.201700864openalex-snapshot
B(C6F5)3‐Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes
inferredcites →https://doi.org/10.1002/chem.200902656openalex-snapshot
Metal‐Catalyzed Ring‐Opening of Alkylidenecyclopropanes: New Access to Building Blocks with an Acyclic Quaternary Stereogenic Center
inferredcites →https://doi.org/10.1002/chem.201406508openalex-snapshot
Iridium‐Catalyzed Intermolecular Dehydrogenative Silylation of Polycyclic Aromatic Compounds without Directing Groups
inferredcites →https://doi.org/10.1002/chem.201504718openalex-snapshot
Rhodium‐Catalyzed Synthesis of Chiral Spiro‐9‐silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters
inferredcites →https://doi.org/10.1002/chem.201701579openalex-snapshot
Rhodium‐Catalyzed Silylative and Germylative Cyclization with Dehydrogenation Leading to 9‐Sila‐ and 9‐Germafluorenes: A Combined Experimental and Computational Mechanistic Study
inferredcites →https://doi.org/10.1002/chin.200322074openalex-snapshot
Selective, Catalytic Carbon—Carbon Bond Activation and Functionalization Promoted by Late Transition Metal Catalysts.
inferredcites →https://doi.org/10.1002/ejoc.201101616openalex-snapshot
Transition‐Metal‐Mediated Cleavage and Activation of C–C Single Bonds
inferredcites →https://doi.org/10.1007/978-1-4020-8172-9openalex-snapshot
Hydrosilylation : a comprehensive review on recent advances
inferredcites →https://doi.org/10.1016/0040-4039(95)01628-uopenalex-snapshot
CC bond activation of cyclopropane ring in hydrosilylation catalyzed by wilkinson complex
inferredcites →https://doi.org/10.1016/j.tet.2014.04.057openalex-snapshot
Recent developments in the synthesis and reactivity of methylene- and alkylidenecyclopropane derivatives
inferredcites →https://doi.org/10.1016/j.tet.2016.06.014openalex-snapshot
Ring-opening, cycloaddition and rearrangement reactions of nitrogen-substituted cyclopropane derivatives
inferredcites →https://doi.org/10.1016/j.tetlet.2006.06.052openalex-snapshot
Syntheses of dipeptides containing (1R,5S)-6,6-dimethyl-3-azabicyclo[3.1.0]hexane-2(S)-carboxylic acid (4), (1R,5S)-spiro[3-azabicyclo[3.1.0]hexane-6,1′-cyclopropane]- 2(S)-carboxylic acid (5) and (1S,5R)-6,6-dimethyl-3-azabicyclo[3.1.0]hexane-2(S)-carboxylic acid (6)
inferredcites →https://doi.org/10.1016/j.tetlet.2016.09.045openalex-snapshot
Catalytic carbon–carbon sigma-bond hydrogenolysis
inferredcites →https://doi.org/10.1016/s0022-328x(99)00041-8openalex-snapshot
Comparative chemistry of η3-oxaallyl and η3-allyl rhodium(I) complexes in the hydrosilylation of cyclopropyl ketones: observation of an unprecedented rearrangement
inferredcites →https://doi.org/10.1016/s0040-4020(01)00899-7openalex-snapshot
The first total synthesis of (±)-1-desoxyhypnophilin
inferredcites →https://doi.org/10.1016/s0040-4039(01)00925-xopenalex-snapshot
Aluminum chloride catalyzed hydrosilylation of cyclopropanes with chlorodimethylsilane
inferredcites →https://doi.org/10.1016/s0040-4039(02)00165-xopenalex-snapshot
Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane
inferredcites →https://doi.org/10.1016/s0040-4039(02)01978-0openalex-snapshot
Total synthesis of the putative structure of the novel triquinane natural product isocapnellenone
inferredcites →https://doi.org/10.1021/acs.chemrev.5b00138openalex-snapshot
Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals
inferredcites →https://doi.org/10.1021/acs.chemrev.6b00599openalex-snapshot
Recent Methodologies That Exploit C–C Single-Bond Cleavage of Strained Ring Systems by Transition Metal Complexes
inferredcites →https://doi.org/10.1021/acs.joc.5b00920openalex-snapshot
Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation and Germylation of Unactivated C(sp3)–H Bonds
inferredcites →https://doi.org/10.1021/acs.orglett.5b00575openalex-snapshot
Iridium-Catalyzed Dehydrogenative Silylation of Azulenes Based on Regioselective C–H Bond Activation
inferredcites →https://doi.org/10.1021/acs.orglett.5b01373openalex-snapshot
Rhodium-Catalyzed Synthesis of Benzosilolometallocenes via the Dehydrogenative Silylation of C(sp 2 )–H Bonds
inferredcites →https://doi.org/10.1021/acs.orglett.6b02134openalex-snapshot
Synthesis and Properties of Sila[n]helicenes via Dehydrogenative Silylation of C–H Bonds under Rhodium Catalysis
inferredcites →https://doi.org/10.1021/acscatal.5b02308openalex-snapshot
Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes
inferredcites →https://doi.org/10.1021/ar300200hopenalex-snapshot
Efficient Routes to Carbon–Silicon Bond Formation for the Synthesis of Silicon-Containing Peptides and Azasilaheterocycles
inferredcites →https://doi.org/10.1021/cr010005uopenalex-snapshot
Heterocycles from Alkylidenecyclopropanes
inferredcites →https://doi.org/10.1021/cr050988lopenalex-snapshot
Transition Metal Chemistry of Cyclopropenes and Cyclopropanes
inferredcites →https://doi.org/10.1021/cr400686jopenalex-snapshot
Progress in the Synthesis and Transformations of Alkylidenecyclopropanes and Alkylidenecyclobutanes
inferredcites →https://doi.org/10.1021/ic401931yopenalex-snapshot
POP-Pincer Silyl Complexes of Group 9: Rhodium versus Iridium
inferredcites →https://doi.org/10.1021/ja028912jopenalex-snapshot
Selective, Catalytic Carbon−Carbon Bond Activation and Functionalization Promoted by Late Transition Metal Catalysts
inferredcites →https://doi.org/10.1021/ja107698popenalex-snapshot
Rhodium-Catalyzed Synthesis of Silafluorene Derivatives via Cleavage of Silicon−Hydrogen and Carbon−Hydrogen Bonds
inferredcites →https://doi.org/10.1021/jacs.6b08608openalex-snapshot
New Initiation Modes for Directed Carbonylative C–C Bond Activation: Rhodium-Catalyzed (3 + 1 + 2) Cycloadditions of Aminomethylcyclopropanes
inferredcites →https://doi.org/10.1021/jm1013693openalex-snapshot
Synopsis of Some Recent Tactical Application of Bioisosteres in Drug Design
inferredcites →https://doi.org/10.1021/jm3010114openalex-snapshot
Organosilicon Molecules with Medicinal Applications
inferredcites →https://doi.org/10.1021/jm3013757openalex-snapshot
Increased Hydrophobicity and Estrogenic Activity of Simple Phenols with Silicon and Germanium-Containing Substituents
inferredcites →https://doi.org/10.1021/jo020293+openalex-snapshot
Platinum Complex-Catalyzed Hydrosilylation and Isomerization of Methylenecyclopropane Derivatives. Effect of Structures of the Substrate and Catalyst
inferredcites →https://doi.org/10.1021/jo0508752openalex-snapshot
Synthesis of (+)-Sulcatine G
inferredcites →https://doi.org/10.1021/jo8010683openalex-snapshot
Synthesis of (−)-Hamigeran B
inferredcites →https://doi.org/10.1021/jo901513vopenalex-snapshot
Palladium-Catalyzed Preparation of Silyl Enolates from α,β-Unsaturated Ketones or Cyclopropyl Ketones with Hydrosilanes
inferredcites →https://doi.org/10.1021/jo961536zopenalex-snapshot
Synthesis of Mono-, Di-, and Trisilyl-Substituted Alkenes via the Hydrosilylation of Methylenecyclopropanes Catalyzed by Rh(I) Complexes
inferredcites →https://doi.org/10.1021/np0205607openalex-snapshot
An Efficient Formal Synthesis of the Sesquiterpenoid Longifolene
inferredcites →https://doi.org/10.1021/ol006390bopenalex-snapshot
Intramolecular 4 + 3 Cycloadditions. Aspects of Stereocontrol in the Synthesis of Cyclooctanoids. A Synthesis of (+)-Dactylol
inferredcites →https://doi.org/10.1021/ol303353mopenalex-snapshot
Rhodium-Catalyzed Intramolecular Silylation of Unactivated C(sp3)–H Bonds
inferredcites →https://doi.org/10.1021/ol503355qopenalex-snapshot
Rhodium-Catalyzed Dehydrogenative Germylation of C–H Bonds: New Entry to Unsymmetrically Functionalized 9-Germafluorenes
inferredcites →https://doi.org/10.1038/nchem.1841openalex-snapshot
Conversion of 1-alkenes into 1,4-diols through an auxiliary-mediated formal homoallylic C–H oxidation
inferredcites →https://doi.org/10.1039/c4cc09508aopenalex-snapshot
Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp 3 )–H bonds adjacent to a nitrogen atom
inferredcites →https://doi.org/10.1039/c4ra17281gopenalex-snapshot
Hydrosilylation reaction of olefins: recent advances and perspectives
inferredcites →https://doi.org/10.1039/c5ob00868aopenalex-snapshot
Heterocycles from methylenecyclopropanes
inferredcites →https://doi.org/10.1246/cl.170369openalex-snapshot
Iridium-catalyzed Dehydrogenative Dimerization of Benzylmethylsilanes via Silylation of C(sp3)–H Bonds Adjacent to a Silicon Atom
inferredcites →https://doi.org/10.1246/cl.1999.705openalex-snapshot
Rhodium Catalyzed Transformation of 4-Pentynyl Cyclopropanes to Bicyclo[4.3.0]nonenones via Cleavage of Cyclopropane Ring

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/9781119426295.ch10openalex-snapshot
Addition Reactions
inferred← citeshttps://doi.org/10.1002/ange.202401579openalex-snapshot
Cooperative Photoredox and Cobalt‐Catalyzed Acceptorless Dehydrogenative Functionalization of Cyclopropylamides towards Allylic N,O‐Acyl‐acetal Derivatives
inferred← citeshttps://doi.org/10.1002/anie.202401579openalex-snapshot
Cooperative Photoredox and Cobalt‐Catalyzed Acceptorless Dehydrogenative Functionalization of Cyclopropylamides towards Allylic N,O ‐Acyl‐acetal Derivatives
inferred← citeshttps://doi.org/10.1002/chem.201900564openalex-snapshot
Total Synthesis of α‐Tocopherol through Enantioselective Iridium‐Catalyzed Fragmentation of a Spiro‐Cyclobutanol Intermediate
inferred← citeshttps://doi.org/10.1002/ijch.202000082openalex-snapshot
Regioselective C(sp2)−C(sp3) Oxidative Bond Cleavage of 1‐(1‐Hydroxyalkyl) naphthalen‐2‐ols: First Synthesis of 1‐Azido‐halo‐naphthalene‐2(1H)‐ones
inferred← citeshttps://doi.org/10.1007/3418_2020_55openalex-snapshot
Iridium-Catalyzed Silylation
inferred← citeshttps://doi.org/10.1016/j.tetlet.2023.154887openalex-snapshot
Direct amidation of 1-aryl-2,2,2-trifluoroethanones with isothiocyanates via C–C bond cleavage strategy
inferred← citeshttps://doi.org/10.1021/acs.joc.2c02024openalex-snapshot
Substitution-Dependent Ring-Opening Hydrosilylation or Dehydrogenative Hydrosilylation of Cyclopropyl Aldehydes and Ketones Catalyzed by Au Nanoparticles
inferred← citeshttps://doi.org/10.1021/acs.joc.8b00027openalex-snapshot
Synthesis of 1,1′-Diarylethanes and Related Systems by Displacement of Trichloroacetimidates with Trimethylaluminum
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c00173openalex-snapshot
Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c04052openalex-snapshot
Ru(II)-Catalyzed Difunctional Pyridyloxy-Directed Regio- and Stereospecific Addition of Carboxylic Acids to Internal Alkynes
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b00658openalex-snapshot
Chromium-Mediated Stannylcyclopropanation of Alkenes with (Diiodomethyl)stannanes
inferred← citeshttps://doi.org/10.1021/jacs.8b09297openalex-snapshot
Use of Cyclopropane as C1 Synthetic Unit by Directed Retro-Cyclopropanation with Ethylene Release
inferred← citeshttps://doi.org/10.1039/d5cc03258jopenalex-snapshot
Hydro- and chloroelementation reactions across an iron–carbon bond using heavy group 15 reagents
inferred← citeshttps://doi.org/10.1055/a-2342-8284openalex-snapshot
Photoredox- and Cobalt-Cocatalyzed Dehydrogenative Ring-Opening/Functionalization of Monodonor Cyclopropanes
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