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The darkening of copper- or lead-based pigments explained by a structural modification of natural orpiment: a spectroscopic and electrochemical study

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/chem.201002422openalex-snapshot
Modeling the Gas‐Phase Thermochemistry of Organosulfur Compounds
inferredcites →https://doi.org/10.1002/jrs.2350openalex-snapshot
A study on red lead degradation in a medieval manuscript Lorvão Apocalypse (1189)
inferredcites →https://doi.org/10.1002/jrs.4065openalex-snapshot
Micro‐Raman study of Medieval Cistercian 12–13th century manuscripts: Santa Maria de Alcobaça, Portugal
inferredcites →https://doi.org/10.1016/j.dyepig.2014.09.015openalex-snapshot
Understanding the (in)stability of semiconductor pigments by a thermodynamic approach
inferredcites →https://doi.org/10.1016/j.microc.2015.11.030openalex-snapshot
Sulfur K-edge XANES of lazurite: Toward determining the provenance of lapis lazuli
inferredcites →https://doi.org/10.1016/j.proche.2013.03.024openalex-snapshot
Realgar and Light
inferredcites →https://doi.org/10.1016/s0016-7037(99)00205-7openalex-snapshot
Chemical forms of sulfur in geological and archeological asphaltenes from Middle East, France, and Spain determined by sulfur K- and L-edge X-ray absorption near-edge structure spectroscopy
inferredcites →https://doi.org/10.1016/s1386-1425(98)00153-xopenalex-snapshot
Using X-ray absorption to probe sulfur oxidation states in complex molecules
inferredcites →https://doi.org/10.1021/ac0401523openalex-snapshot
Quantitative Raman Reaction Monitoring Using the Solvent as Internal Standard
inferredcites →https://doi.org/10.1021/ac3015627openalex-snapshot
Combined use of Synchrotron Radiation Based Micro-X-ray Fluorescence, Micro-X-ray Diffraction, Micro-X-ray Absorption Near-Edge, and Micro-Fourier Transform Infrared Spectroscopies for Revealing an Alternative Degradation Pathway of the Pigment Cadmium Yellow in a Painting by Van Gogh
inferredcites →https://doi.org/10.1021/ac502303zopenalex-snapshot
Electrochemical Photodegradation Study of Semiconductor Pigments: Influence of Environmental Parameters
inferredcites →https://doi.org/10.1021/ac802518zopenalex-snapshot
Characterization of a Degraded Cadmium Yellow (CdS) Pigment in an Oil Painting by Means of Synchrotron Radiation Based X-ray Techniques
inferredcites →https://doi.org/10.1021/ac951097oopenalex-snapshot
Characterization of Pararealgar and Other Light-Induced Transformation Products from Realgar by Raman Microspectroscopy
inferredcites →https://doi.org/10.1021/acs.analchem.5b02503openalex-snapshot
Unraveling the Reactivity of Minium toward Bicarbonate and the Role of Lead Oxides Therein
inferredcites →https://doi.org/10.1021/jp201097kopenalex-snapshot
Structural and Vibrational Properties of Arsenic Sulfides: Alacranite (As8S9)
inferredcites →https://doi.org/10.1039/c0ja00151aopenalex-snapshot
The darkening of zinc yellow: XANES speciation of chromium in artist's paints after light and chemical exposures
inferredcites →https://doi.org/10.1039/c3an00892dopenalex-snapshot
SR-FTIR imaging of the altered cadmium sulfide yellow paints in Henri Matisse's Le Bonheur de vivre (1905–6) – examination of visually distinct degradation regions
inferredcites →https://doi.org/10.1039/c4ja00424hopenalex-snapshot
Tracking the transformation and transport of arsenic sulfide pigments in paints: synchrotron-based X-ray micro-analyses
inferredcites →https://doi.org/10.1039/c6ja00134copenalex-snapshot
Visualization of As( iii ) and As( v ) distributions in degraded paint micro-samples from Baroque- and Rococo-era paintings
inferredcites →https://doi.org/10.1107/s0909049505012719openalex-snapshot
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
inferredcites →https://doi.org/10.1179/sic.1995.40.2.133openalex-snapshot
An Occurrence of Pararealgar as an Original or Altered Artists' Pigment
inferredcites →https://doi.org/10.1179/sic.2004.49.2.73openalex-snapshot
The Occurrence and Alteration of Realgar on Ancient Egyptian Papyri
inferredcites →https://doi.org/10.1179/sic.2004.49.s2.016openalex-snapshot
THE CONSERVATION OF ARP’S BRONZES: PRESERVING THE SCULPTURE’S HISTORY OR THE ARTIST’S INTENT?
inferredcites →https://doi.org/10.1180/minmag.2011.075.6.2857openalex-snapshot
Anorpiment, As2S3, the triclinic dimorph of orpiment
inferredcites →https://doi.org/10.1186/s40494-015-0040-7openalex-snapshot
Identification of artificial orpiment in the interior decorations of the Japanese tower in Laeken, Brussels, Belgium
inferredcites →https://doi.org/10.1186/s40494-016-0078-1openalex-snapshot
Analytical imaging studies of the migration of degraded orpiment, realgar, and emerald green pigments in historic paintings and related conservation issues
inferredcites →https://doi.org/10.1364/ome.2.000045openalex-snapshot
Photosensitivity and second harmonic generation in chalcogenide arsenic sulfide poled glasses
inferredcites →https://doi.org/10.2113/gscanmin.41.6.1463openalex-snapshot
UZONITE, As4S5, FROM THE TYPE LOCALITY: SINGLE-CRYSTAL X-RAY STUDY AND EFFECTS OF EXPOSURE TO LIGHT
inferredcites →https://doi.org/10.2138/am.2005.1785openalex-snapshot
Light-induced degradation dynamics in realgar: in situ structural investigation using single-crystal X-ray diffraction study and X-ray photoelectron spectroscopy
inferredcites →https://doi.org/10.2138/am.2007.2332openalex-snapshot
Light-induced alteration of arsenic sulfides: A new product with an orthorhombic crystal structure
inferredcites →https://doi.org/10.2298/jmmb0901059sopenalex-snapshot
Kinetics and mechanism of arsenic sulfides oxidation
inferredcites →https://doi.org/10.3389/fnut.2015.00001openalex-snapshot
Chemical and Biochemical Mechanisms Underlying the Cardioprotective Roles of Dietary Organopolysulfides

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4648543openalex-extracted
Multi-Technical Analysis to the Blue–Green Pigment Applied in the Wall Paintings of Kizil Grottoes, Xinjiang, China: A New Degradation Mechanism of Atacamite Under the Influence of Arsenate
inferred← citeshttps://doi.org/10.2139/ssrn.4676610openalex-extracted
Multi-Technical Analysis to the Blue–Green Pigment Applied in the Wall Paintings of Kizil Grottoes, Xinjiang, China: A New Degradation Mechanism of Atacamite Under the Influence of Arsenates
inferred← citeshttps://doi.org/10.1002/adfm.202313043openalex-snapshot
Present Status and Perspectives of Graphene and Graphene‐related Materials in Cultural Heritage
inferred← citeshttps://doi.org/10.1002/chem.201903284openalex-snapshot
X‐ray Diffraction Mapping for Cultural Heritage Science: a Review of Experimental Configurations and Applications
inferred← citeshttps://doi.org/10.1002/jrs.5534openalex-snapshot
Study of dry‐ and wet‐process amorphous arsenic sulfides: Synthesis, Raman reference spectra, and identification in historical art materials
inferred← citeshttps://doi.org/10.1002/jrs.5660openalex-snapshot
Raman and Fourier transform infrared microspectroscopies reveal medieval Hispano–Muslim wood painting techniques and provide new insights into red lead production technology
inferred← citeshttps://doi.org/10.1002/jrs.6408openalex-snapshot
Photoinduced effects of monochromatic visible light with different wavelengths on realgar
inferred← citeshttps://doi.org/10.1002/xrs.3345openalex-snapshot
Scanning X‐ray fluorescence spectroscopy and micro‐X ‐ray absorption near‐edge structure analysis as a guiding tool for the conservation treatment of two eighteenth‐century Philadelphian portraits
inferred← citeshttps://doi.org/10.1007/978-3-030-86865-9_11openalex-snapshot
Non-invasive and Non-destructive Examination of Artists’ Pigments, Paints and Paintings by Means of X-Ray Imaging Methods
inferred← citeshttps://doi.org/10.1007/s12520-025-02292-6openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/s40766-025-00070-7openalex-snapshot
Advanced X-ray techniques to study the alteration of pigments in paintings
inferred← citeshttps://doi.org/10.1016/j.apsusc.2025.163581openalex-snapshot
Susceptibility of different pigments to irradiation by two lasers with different pulse duration and wavelength
inferred← citeshttps://doi.org/10.1016/j.culher.2026.07.007openalex-snapshot
Lab-based XANES spectroscopy for chemical and structural characterization of pigments in cultural heritage science
inferred← citeshttps://doi.org/10.1016/j.dyepig.2017.10.009openalex-snapshot
Identification by Raman spectroscopy of pararealgar as a starting material in the synthesis of amorphous arsenic sulfide pigments
inferred← citeshttps://doi.org/10.1016/j.jasrep.2019.102065openalex-snapshot
Colourants on the wall paintings of a mediӕval fortress at the mount Sofeh in Isfahan, central Iran
inferred← citeshttps://doi.org/10.1016/j.jasrep.2023.104294openalex-snapshot
Analysis of a pigment grinding muller from Lacapelle Livron (Tarn and Garonne, France): A tool to prepare cinnabar in a medieval painter workshop or a scriptorium?
inferred← citeshttps://doi.org/10.1016/j.jhazmat.2023.131453openalex-snapshot
Identification, transformations and mobility of hazardous arsenic-based pigments on 19th century bookbindings in accessible library collections
inferred← citeshttps://doi.org/10.1016/j.microc.2018.01.001openalex-snapshot
Non-invasive analysis of a 15th century illuminated manuscript fragment: point-based vs imaging spectroscopy
inferred← citeshttps://doi.org/10.1016/j.microc.2020.104811openalex-snapshot
Identification of green pigments and binders in late medieval painted wings from Norwegian churches
inferred← citeshttps://doi.org/10.1016/j.microc.2024.110891openalex-snapshot
Non-invasive spectroscopic analyses of M. E. Chevreul’s colour plates: shedding new light on 19th century colour theory representation
inferred← citeshttps://doi.org/10.1016/j.saa.2020.118574openalex-snapshot
Spectroscopic investigation and comprehensive analysis of the polychrome clay sculpture of Hua Yan Temple of the Liao Dynasty
inferred← citeshttps://doi.org/10.1016/j.saa.2026.127959openalex-snapshot
New insights into the effects of Yb-doped fiber laser on tempera paintings: Influence of the pigment and binder
inferred← citeshttps://doi.org/10.1021/acs.analchem.6c01993openalex-snapshot
Deadly Red: Photochemical Alterations in Bonazziite, Realgar, Pararealgar, and Other Arsenic Sulfide Pigments
inferred← citeshttps://doi.org/10.1021/acssuschemeng.8b02070openalex-snapshot
Treating Water by Degrading Oxyanions Using Metallic Nanostructures
inferred← citeshttps://doi.org/10.1021/jacs.2c12271openalex-snapshot
Two Pathways for the Degradation of Orpiment Pigment (As 2 S 3 ) Found in Paintings
inferred← citeshttps://doi.org/10.1039/d1ja00271fopenalex-snapshot
Development of a multi-method analytical approach based on the combination of synchrotron radiation X-ray micro-analytical techniques and vibrational micro-spectroscopy methods to unveil the causes and mechanism of darkening of “fake-gilded” decorations in a Cimabue painting
inferred← citeshttps://doi.org/10.1080/00393630.2023.2201094openalex-snapshot
Degradation of Fourteenth-century Mordant Gilding Layers: Synchrotron-based Microfocus XRF, XRD, and XANES Analyses of Two Paintings by Pietro Lorenzetti
inferred← citeshttps://doi.org/10.1088/2053-1591/ad3f7bopenalex-snapshot
Raman evidence for the oxidation of amorphous As 2 (Se x S 1–x ) 3 film surfaces under visible light
inferred← citeshttps://doi.org/10.1149/1945-7111/ab67acopenalex-snapshot
Review—Electrochemical and SERS Sensors for Cultural Heritage Diagnostics and Conservation: Recent Advances and Prospects
inferred← citeshttps://doi.org/10.1177/0003702819856606openalex-snapshot
Multi-Analytical Study of Copper-Based Historic Pigments and their Alteration Products
inferred← citeshttps://doi.org/10.1186/s40494-019-0296-4openalex-snapshot
Painting the Palace of Apries II: ancient pigments of the reliefs from the Palace of Apries, Lower Egypt
inferred← citeshttps://doi.org/10.1186/s40494-020-00406-yopenalex-snapshot
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inferred← citeshttps://doi.org/10.1186/s40494-022-00785-4openalex-snapshot
Virtual reconstruction of the painting process and original colors of a color-changed Northern Wei Dynasty mural in Cave 254 of the Mogao Grottoes
inferred← citeshttps://doi.org/10.1186/s40494-024-01406-yopenalex-snapshot
Atacamite discolouration under the influence of arsenates in wall paintings in the Kizil Grottoes, Xinjiang, China
inferred← citeshttps://doi.org/10.12654/jcs.2024.40.3.07openalex-snapshot
Study on the Methods for Reducing Discoloration of Orpiment Pigment used in Traditional Material Dancheong
inferred← citeshttps://doi.org/10.12775/aunc_zik.2021.006openalex-snapshot
Influence of Arsenic Compounds on the Colour Palette of 15th- and 16th-Century Icons from the National Museum in Cracow
inferred← citeshttps://doi.org/10.15407/ujpe70.3.206openalex-snapshot
Раманівське дослідження фотоокислення скла As2S3 : Ag під дією видимого світла
inferred← citeshttps://doi.org/10.3390/app11031197openalex-snapshot
The Importance of Being Versatile: INFN-CHNet MA-XRF Scanner on Furniture at the CCR “La Venaria Reale”
inferred← citeshttps://doi.org/10.3390/ijerph191811247openalex-snapshot
Harmless Treatment of High Arsenic Tin Tailings and Environmental Durability Assessment
inferred← citeshttps://doi.org/10.3390/molecules30163318openalex-snapshot
Mechanistic Study on Orpiment Pigment Discoloration Induced by Reactive Oxygen Species
inferred← citeshttps://doi.org/10.56112/zpp.2025.1.01openalex-snapshot
Research on the stucco decoration in the Chapel of All Saints at Telč Castle - between art history, technology, and restoration
inferred← citeshttps://doi.org/10.6084/m9.figshare.12569708openalex-snapshot
Additional file 1 of Beyond the connoisseurship approach: creating a chronology in Hokusai prints using non-invasive techniques and multivariate data analysis
inferred← citeshttps://doi.org/10.6084/m9.figshare.21358094openalex-snapshot
Additional file 1 of Virtual reconstruction of the painting process and original colors of a color-changed Northern Wei Dynasty mural in Cave 254 of the Mogao Grottoes
inferred← citeshttps://doi.org/10.6084/m9.figshare.26629032openalex-snapshot
Additional file 1 of Atacamite discolouration under the influence of arsenates in wall paintings in the Kizil Grottoes, Xinjiang, China
inferred← citeshttps://doi.org/10.70675/4393240az84fdz4d9cz8716z937271bcdebaopenalex-snapshot
Biochemical and electrochemical studies of metalloproteins involved in oxygen reduction pathway in Acidithiobacillus ferrooxidans
inferred← citeshttps://doi.org/10.7584/jktappi.2024.10.56.5.94openalex-snapshot
Stability Evaluation of the Coloring Layer of Orpiment Used in Traditional Dancheong
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