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A comparative DFT study of TBD-catalyzed reactions of amines with CO 2 and hydrosilane: the effect of solvent polarity on the mechanistic preference and the origins of chemoselectivities

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Outgoing claims: the papers this work cites, builds on, or argues with.

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An Isolated CO2 Adduct of a Nitrogen Base: Crystal and Electronic Structures
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A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2
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Betaine Catalysis for Hierarchical Reduction of CO2 with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines
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Understanding the mechanism of CuI-catalyzed N–H carboxylation of heterocyclic rings with CO2 from a theoretical point of view
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Bridging Amines with CO2: Organocatalyzed Reduction of CO2 to Aminals
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Utilization of CO2 as a C1 Building Block for Catalytic Methylation Reactions
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Natural Product Glycine Betaine as an Efficient Catalyst for Transformation of CO2 with Amines to Synthesize N-Substituted Compounds
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Waste Recycling: Ionic Liquid-Catalyzed 4-Electron Reduction of CO2 with Amines and Polymethylhydrosiloxane Combining Experimental and Theoretical Study
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An Unexpected Role of a Trace Amount of Water in Catalyzing Proton Transfer in Phosphine-Catalyzed (3 + 2) Cycloaddition of Allenoates and Alkenes
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The Real Role of N-Heterocyclic Carbene in Reductive Functionalization of CO2: An Alternative Understanding from Density Functional Theory Study
inferredcites →https://doi.org/10.1021/jacs.5b06077openalex-snapshot
Iron-Catalyzed Reduction of CO 2 into Methylene: Formation of C–N, C–O, and C–C Bonds
inferredcites →https://doi.org/10.1021/ol061095yopenalex-snapshot
Theoretical Rationale for Regioselection in Phosphine-Catalyzed Allenoate Additions to Acrylates, Imines, and Aldehydes
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Using carbon dioxide as a building block in organic synthesis
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Reversible homogeneous catalysis of carbon dioxide hydrogenation/reduction at room temperature and low pressures
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Sequential covalent bonding activation and general base catalysis: insight into N-heterocyclic carbene catalyzed formylation of N–H bonds using carbon dioxide and silane
inferredcites →https://doi.org/10.1039/c4gc01614aopenalex-snapshot
Reductive functionalization of CO 2 with amines: an entry to formamide, formamidine and methylamine derivatives
inferredcites →https://doi.org/10.1039/c7cc06795jopenalex-snapshot
A DFT study unveils the secret of how H 2 is activated in the N-formylation of amines with CO 2 and H 2 catalyzed by Ru( ii ) pincer complexes in the absence of exogenous additives
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Efficient, selective and sustainable catalysis of carbon dioxide
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Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO 2 , and hydrosilane catalyzed by 1,3,2-diazaphospholene?

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Carboxylate‐Functionalized Zeolitic Imidazolate Framework Enables Catalytic N‐Formylation Using Ambient CO2
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Pivotal Role of the Basic Character of Organic and Salt Catalysts in C−N Bond Forming Reactions of Amines with CO2
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Organic base-mediated fixation of CO2 into value-added chemicals
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Hydrogen bond promotion for CO2 activation in homogeneous catalytic systems
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Design of Lewis base functionalized ionic liquids for the N-formylation of amines with CO2 and hydrosilane: The cation effects
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A polymeric ionic liquid catalyst for the N-formylation and N-methylation of amines using CO2/PhSiH3
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Highly effective capture and subsequent catalytic transformation of low-concentration CO 2 by superbasic guanidines
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Recent advances in liquid hydrosilane-mediated catalytic N -formylation of amines with CO 2
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Theoretical study of reductive CO 2 functionalization with amines and phenylsilanes: what kind of solvents can be used as catalysts?
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