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Rhodium( iii )-catalysed decarbonylative annulation through C–H activation: expedient access to aminoisocoumarins by weak coordination

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Palladium‐Catalyzed Synthesis of Tetrasubstituted Olefins by Triple Domino Process

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Photopromoted Entry to Benzothiophenes, Benzoselenophenes, 3H‐Indoles, Isocoumarins, Benzosultams, and (Thio)flavones by Gold‐Catalyzed Arylative Heterocyclization of Alkynes

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Ru‐ and Rh‐Catalyzed CC Bond Cleavage of Cyclobutenones: Reconstructive and Selective Synthesis of 2‐Pyranones, Cyclopentenes, and Cyclohexenones

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Divergent Syntheses of Fused β‐Naphthol and Indene Scaffolds by Rhodium‐Catalyzed Direct and Decarbonylative Alkyne–Benzocyclobutenone Couplings

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Rhodium(I)‐Catalyzed Decarbonylative Spirocyclization through CC Bond Cleavage of Benzocyclobutenones: An Efficient Approach to Functionalized Spirocycles

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Ruthenium(II)‐Catalyzed Synthesis of Spirobenzofuranones by a Decarbonylative Annulation Reaction

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Distal Weak Coordination of Acetamides in Ruthenium(II)‐Catalyzed C−H Activation Processes

inferredcites →https://doi.org/10.1007/s10593-016-1849-zopenalex-snapshot

Metal-catalyzed synthesis of isocoumarin derivatives (microreview)

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Antioxidant activity of isocoumarins isolated from Paepalanthus bromelioides on mitochondria

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Immunomodulatory activity of thunberginol a and related compounds isolated from hydrangeae dulcis folium on splenocyte proliferation activated by mitogens

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Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

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Iron-Catalyzed C–H Bond Activation

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Rhodium(III)-Catalyzed C–H Activation/Alkyne Annulation by Weak Coordination of Peresters with O–O Bond as an Internal Oxidant

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Selective Oxidative Decarbonylative Cleavage of Unstrained C( sp 3)–C( sp 2) Bond: Synthesis of Substituted Benzoxazinones

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Gold(I)-Catalyzed Cyclization for the Synthesis of 8-Hydroxy-3- substituted Isocoumarins: Total Synthesis of Exserolide F

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Efficient Benzimidazolidinone Synthesis via Rhodium-Catalyzed Double-Decarbonylative C–C Activation/Cycloaddition between Isatins and Isocyanates

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Ru(II)-Catalyzed Regiospecific C–H/O–H Oxidative Annulation to Access Isochromeno[8,1- ab ]phenazines: Far-Red Fluorescence and Live Cancer Cell Imaging

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Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

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Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

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Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

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Ruthenium-Catalyzed Reconstructive Synthesis of Cyclopentenones by Unusual Coupling of Cyclobutenediones with Alkenes Involving Carbon−Carbon Bond Cleavage

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Nickel-Catalyzed Decarbonylative Alkylidenation of Phthalimides with Trimethylsilyl-Substituted Alkynes

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Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes

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Rh-Catalyzed Decarbonylative Coupling with Alkynes via C–C Activation of Isatins

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Nickel-Catalyzed Decarbonylative Addition of Phthalimides to Alkynes

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Nickel-Catalyzed Decarbonylative Addition of Anhydrides to Alkynes

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Nickel-Catalyzed Decarboxylative Carboamination of Alkynes with Isatoic Anhydrides

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Computational Study of Rh-Catalyzed Carboacylation of Olefins: Ligand-Promoted Rhodacycle Isomerization Enables Regioselective C–C Bond Functionalization of Benzocyclobutenones

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Synthesis of Isocoumarin Derivatives via the Copper-Catalyzed Tandem Sequential Cyclization of 2- Halo-N-phenyl Benzamides and Acyclic 1,3-Diketones

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Synthesis of Isocoumarin Derivatives by Copper-Catalyzed Addition of o-Halobenzoic Acids to Active Internal Alkynes

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Antifungal 3-Butylisocoumarins from Asteraceae-Anthemideae

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The Fungal Phytotoxin Alternariol 9-Methyl Ether and Some of Its Synthetic Analogues Inhibit the Photosynthetic Electron Transport Chain

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Cercophorins A−C: Novel Antifungal and Cytotoxic Metabolites from the Coprophilous Fungus Cercophora areolata

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Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages

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Synthesis of Pyrrolo-/Indolo[1,2-a]quinolines and Naphtho[2,1-b]thiophenes from gem-Dibromovinyls and Sulphonamides

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Remote site-selective C–H activation directed by a catalytic bifunctional template

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C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

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Unexpected regioselective carbon–hydrogen bond activation/cyclization of indolyl aldehydes or ketones with alkynes to benzo-fused oxindoles

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Direct transition metal-catalyzed functionalization of heteroaromatic compounds

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C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

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Mild metal-catalyzed C–H activation: examples and concepts

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C-H Bond Functionalization in Complex Organic Synthesis

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Spot Tests in Inorganic Analysis

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Isocoumarin and Its Derivatives: An Overview on their Synthesis and Applications

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Dual Functionalization of Alkynes Utilizing the Redox Characteristics of Transition Metal Catalysts

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Effect of Cp‐Ligand Methylation on Rhodium(III)‐Catalyzed Annulations of Aromatic Carboxylic Acids with Alkynes: Synthesis of Isocoumarins and PAHs for Organic Light‐Emitting Devices

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Pd(II)/Ce(III)‐Heterobimetallic Complex‐Catalyzed Decarbonylative Alkyne Annulation Reaction: Synthesis of Spiro‐Benzofuranindenones

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Six-Membered Ring Systems: With O and/or S Atoms

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Synthesis of isocoumarins and PAHs with electron-withdrawing substituents: Impact of the substituent nature on the photophysical behavior

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Mononuclear (C5R5)Ir-complexes with π-linked biaryls: Stability and fluorescence quenching

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Facile synthesis and tunable fluorescent properties of a new D-π-A isocoumarin: Applications in encryption and OLED technology

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Recent advances in synthesis of isocoumarins: An overview

inferred← citeshttps://doi.org/10.1021/acs.chemrev.0c00153openalex-snapshot

Selective Decarbonylation via Transition-Metal-Catalyzed Carbon–Carbon Bond Cleavage

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Tandem C–H Annulation Reaction of Benzaldehydes and Aminobenzoic Acids with Two Equivalents of Alkyne toward Isocoumarin-Conjugated Isoquinolinium Salts: A Family of Organic Luminophores

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Ruthenium(II)-Catalyzed Sequential C–H/N–H Alkene Annulation Cascade of Phenanthroimidazoles: Synthesis and Photophysical Studies

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Concise Synthesis of Isocoumarins through Rh-Catalyzed Direct Vinylene Annulation: Scope and Mechanistic Insight

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Controllable construction of isoquinolinedione and isocoumarin scaffolds via Rh III -catalyzed C–H annulation of N -tosylbenzamides with diazo compounds

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Harnessing hypervalent iodonium ylides as carbene precursors: C–H activation of N -methoxybenzamides with a Rh( iii )-catalyst

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Rh( iii )-Catalysed synthesis of cinnolinium and fluoranthenium salts using C–H activation/annulation reactions: organelle specific mitochondrial staining applications

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Recent advances in decarbonylative annulation reactions

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Rhodium( iii )-catalyzed annulation of 3-arylquinazolinones with alkynes via double C–H activation: an efficient route for quinolino[2,1- b ]quinazolinones

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Palladium-catalysed dual ring-opening [3 + 4] annulation of isatoic anhydrides with cyclic iodoniums to build tribenzo[ b,d,f ]azepines and a mechanistic DFT study

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Isatoic anhydride as a masked directing group and internal oxidant for Rh( iii )-catalyzed decarbonylative annulation through C–H activation: insights from DFT calculations

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Potassium tert-Butoxide Promoted Intramolecular Mizoroki–Heck-Type Radical Cyclization: Photoluminescence Properties and Application in Live Cancer-Cell Imaging

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Directing-Group-Assisted Transition-Metal-Catalyzed Direct C–H Oxidative Annulation of Arenes with Alkynes for Facile Construction of Various Oxygen Heterocycles

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Crystal structures of two new isocoumarin derivatives: 8-amino-6-methyl-3,4-diphenyl-1H-isochromen-1-one and 8-amino-3,4-diethyl-6-methyl-1H-isochromen-1-one

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Novel Metal-Free Synthesis of 3-Substituted Isocoumarins and Evaluation of Their Fluorescence Properties for Potential Applications

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Isocoumarin Synthesis via Metal-Free C-Arylation of Acetoacetates with ortho-Ester-Functionalized Diaryliodonium Salts

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Synthesis and photophysical properties of isocoumarins

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