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Selective oxymetalation of terminal alkynes via 6- endo cyclization: mechanistic investigation and application to the efficient synthesis of 4-substituted isocoumarins

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Highly Selective Palladium‐Catalyzed Direct CH α‐Monoarylation of Carbonyl Compounds using Water Containing the Surfactant Polyoxyethylene‐α‐Tocopheryl Sebacate (PTS) as a Solvent

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2‐Alkynylbenzaldehyde: A Versatile Building Block for the Generation of Cyclic Compounds

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Theoretical Investigation on the ClBcat‐Promoted Synthesis of Heterocyclic Boronic Esters

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Regio‐ and Stereoselective Generation of Alkenylindium Compounds from Indium Tribromide, Alkynes, and Ketene Silyl Acetals

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Characterization of the Isochromen‐4‐yl‐gold(I) Intermediate in the Gold(I)‐Catalyzed Glycosidation of Glycosyl ortho‐Alkynylbenzoates and Enhancement of the Catalytic Efficiency Thereof

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Characterization of Vinylgold Intermediates: Gold‐Mediated Cyclization of Acetylenic Amides

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Catalytic Generation of Zinc Carbenes from Alkynes: Zinc‐Catalyzed Cyclopropanation and SiH Bond Insertion Reactions

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Catalyst‐Free Formal Thioboration to Synthesize Borylated Benzothiophenes and Dihydrothiophenes

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BCl3‐Induced Annulative Oxo‐ and Thioboration for the Formation of C3‐Borylated Benzofurans and Benzothiophenes

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Cyclizations of Aryl Enynes Containing Propargyl Alcohol and Diallylamine Groups to Yield Indolecarbaldehydes Induced by Ruthenium Complexes

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Pd‐Catalyzed Reactions of Allenylphosphonates and Related Allenes with Functionalized 2‐Iodophenols, 2‐Iodobenzoic Acid, and 2‐Iodobenzyl Alcohol Leading to Functionalized Benzofurans, Isocoumarins, and Benzopyrans

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How to Lose a Bond in Two Ways ― The Diradical/Zwitterion Dichotomy in Cycloaromatization Reactions

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Synthesis of 4‐Arylisocoumarins (=4‐Aryl‐1H‐2‐benzopyran‐1‐ones) through Acidic Hydrolysis of (Z)‐2‐(1‐Aryl‐2‐methoxyethenyl)benzaldehydes, Followed by Oxidation

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Synthesen von Fluoreszenzfarbstoffen, 11 über die Umlagerung von Alkoxymethylen‐ und Aminomethylenhomophthalsäureanhydriden zu Isocumarinen bzw. Isochinolinonen

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Secondary Fungal Metabolites and Their Biological Activity, VIII. – Partial Synthesis of Oosponol, an Antifungal Isocoumarin

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Total Synthesis of the Toxin Oosponol and of Structural Analogues and Investigation of Their Antibiotic Activities

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The Baldwin rules: revised and extended

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Progress in the Chemistry of Organic Natural Products 109

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Structural insights into hydroxycoumarin-induced apoptosis in U-937 cells

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Anti-HIV activity of stilbene-related heterocyclic compounds

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ZnCl2-catalyzed [4 + 2] benzannulation of 2-ethynylbenzaldehydes with alkynes: Selective synthesis of naphthalene derivatives

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Directing the regioselectivity of rhodium(I) catalysed cyclisation of 2-alkynyl benzoic acids

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Cycloisomerization of γ- and δ-acetylenic acids catalyzed by gold(I) chloride

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PtCl4-catalyzed cyclization of N-acetyl-2-alkynylanilines: A mild and efficient synthesis of N-acetyl-2-substituted indoles

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Polygonolide, an isocoumarin from Polygonum hydropiper possessing anti-inflammatory activity

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The identification of lenzitin as oosponol

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The photochemistry of iminium salts and related heteroaromatic systems

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A theoretical investigation of α-substituents on the structure, proton affinities and inversion barriers of silyl anions

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Reactions of 2-acylbenzoates with dimethyloxosulphonium methylide: A novel route to isocoumarins

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Une synthese originale et inattendue d'isocoumarines fonctionnelles

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Organic Photoredox Catalysis

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The Recent Impact of Solid-Phase Synthesis on Medicinally Relevant Benzoannelated Oxygen Heterocycles

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Five-membered heteroaromatic rings as intermediates in organic synthesis

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Cycloaddition reactions of heteroaromatic six-membered rings

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Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity

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Isocoumarins. Developments Since 1950

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Gold Catalysis 2.0

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Crystal and Molecular Structure of Indium(III) Iodide (In 2 I 6 )

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Mercury in organic chemistry. 26. Synthesis of heterocycles via intramolecular solvomercuration of aryl acetylenes

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Pd(II) Acts Simultaneously as a Lewis Acid and as a Transition-Metal Catalyst: Synthesis of Cyclic Alkenyl Ethers from Acetylenic Aldehydes

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Generation and Reaction of Tungsten-Containing Carbonyl Ylides: [3 + 2]-Cycloaddition Reaction with Electron-Rich Alkenes

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Rules for Anionic and Radical Ring Closure of Alkynes

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Aminoboration: Addition of B–N σ Bonds across C–C π Bonds

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Catalyst-Free Synthesis of Borylated Lactones from Esters via Electrophilic Oxyboration

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Catalytic B–H Bond Insertion Reactions Using Alkynes as Carbene Precursors

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Systematic Enumeration of Heteroaromatic Ring Systems as Reagents for Use in Medicinal Chemistry

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Synthesis of Isocoumarins and α-Pyrones via Electrophilic Cyclization

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Catalytic Cyclopropanation of Alkenes via (2-Furyl)carbene Complexes from 1-Benzoyl-cis-1-buten-3-yne with Transition Metal Compounds

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Synthesis of Cyclic Alkenyl Ethers via Intramolecular Cyclization of O-Alkynylbenzaldehydes. Importance of Combination between CuI Catalyst and DMF

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Indium(III)-Catalyzed Tandem Reaction with Alkynylbenzaldehydes and Alkynylanilines to Heteroaromatic Compounds

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Phthalide and Isocoumarin Derivatives Produced by an Acremonium sp. Isolated from a Mangrove Rhizophora apiculata

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Doyle−Kirmse Reaction of Allylic Sulfides with Diazoalkane-Free (2-Furyl)carbenoid Transfer

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Platinum(II)-Catalyzed Reaction of 2-Alkynylbenzoates or Benzothioates with Vinyl Ethers: A Concise Method for Synthesis of 1-Acyl-4-alkoxy- or 1-Acyl-4-alkylsulfanylnaphthalene Derivatives

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Palladium-Catalyzed Oxidative Activation of Arylcyclopropanes

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Pd- and Cu-Catalyzed One-Pot Multicomponent Synthesis of Hetero α,α′-Dimers of Heterocycles

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Equilibrium between η2-(o-Ethynylbenzoyl)rhenium Complexes and Rhenium Isobenzofuryl Carbene Complexes and Subsequent Reactions of Isobenzofuryl Carbene Complexes

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Deconvolution of the Mechanism of Homogeneous Gold-Catalyzed Reactions

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Docking and scoring in virtual screening for drug discovery: methods and applications

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The synthesis of oosponol and oospoglycol

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Finding the right path: Baldwin “Rules for Ring Closure” and stereoelectronic control of cyclizations

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Silver-catalyzed cascade cyclization–stannylation of o-alkynylaniline derivatives with 2-tributylstannylfuran: an efficient synthesis of (3-indolyl)stannanes

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Intramolecular cyclization assisted oxidative addition: synthesis of octahedral cycloplatinated methyl complexes

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Experimental electron densities of neutral and zwitterionic forms of the drug piroxicam

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Transition metal-catalyzed cross-coupling reactions using organoindium reagents

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Rhodium-Catalyzed Reaction of 2H-Azirines with Carbonyl-ene-yne Compounds Giving 1-Furyl-2-aza-1,3-dienes

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Total Synthesis of RS-42358 and Analogs Using Lateral Lithiation

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Antifungal activity of oosponol, oospolactone, phyllodulcin, hydrangenol, and some other related compounds.

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Inhibition of Compound 48/80-Mediated Histamine Release from Isolated Rat Mast Cells by Oosponol-Related Compounds (4-Acyl-Isocoumarins).

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Inhibition of Angiogenesis by a New Isocoumarin, NM-3.

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Anti-angiogenic Activities of Novel Isocoumarins, AGI-7 and Sescandelin.

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1021/acs.orglett.0c02112openalex-snapshot

Concise Synthesis of Isocoumarins through Rh-Catalyzed Direct Vinylene Annulation: Scope and Mechanistic Insight

inferred← citeshttps://doi.org/10.1021/acs.orglett.0c02851openalex-snapshot

Synthesis of 4-Alkylated Isocoumarins via Pd-Catalyzed α-Arylation Reaction

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c01008openalex-snapshot

Palladium-Catalyzed 1,1-Alkynyloxygenation of 2-Vinylbenzoates with Alkynyl Bromides

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c03028openalex-snapshot

A Synthesis of 4-(Hydroxymethyl)-1H-isochromen-1-one Analogs by Hydroxyl Oxetane Rearrangement in Protonic Acids

inferred← citeshttps://doi.org/10.1021/acscatal.0c00220openalex-snapshot

Gold(I) or Gold(III) as Real Intermediate Species in Gold-Catalyzed Cycloaddition Reactions of Enynal/Enynone?

inferred← citeshttps://doi.org/10.1021/acsomega.5c07356openalex-snapshot

Synthesis and Fluorescent Properties of Alkynylated 3-Methylidenephthalides with Extended π-Systems

inferred← citeshttps://doi.org/10.1021/jacs.4c08291openalex-snapshot

Total Synthesis of Ganoapplanin Enabled by a Radical Addition/Aldol Reaction Cascade

inferred← citeshttps://doi.org/10.1039/d1ob01065dopenalex-snapshot

Modular synthesis of 3-substituted isocoumarins via silver-catalyzed aerobic oxidation/ 6-endo heterocyclization of ortho -alkynylbenzaldehydes

inferred← citeshttps://doi.org/10.1039/d3nj02073hopenalex-snapshot

Rh( iii )-catalyzed cascade annulation reaction of N , N -dimethyl enaminones with iodonium ylides to give substituted isocoumarins

inferred← citeshttps://doi.org/10.1039/d3nj04361dopenalex-snapshot

Access to derivatives of 4-(arylthio)isocoumarins via hydrogen bonding network assisted electrophilic cyclization

inferred← citeshttps://doi.org/10.1055/a-2109-0183openalex-snapshot

Ruthenium(II)-Catalyzed C–H Annulation of Mandelic Acids with Internal Alkynes to Construct Isocoumarins

inferred← citeshttps://doi.org/10.1055/a-2114-7582openalex-snapshot

Halogenative Annulation Reactions of Alkyne-Tethered N- and O-Containing Arenes: Methods for Accessing Aryl-Fused Halogenated N- and O-Heterocycles

inferred← citeshttps://doi.org/10.1055/a-2818-3037openalex-snapshot

Brønsted Acid-Mediated Synthesis of Isocoumarins and Isoquinolines

inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.80.1000openalex-snapshot

Lewis Acid-mediated Carbon-Fluorine Bond Transformation: Substitution of Fluorine and Insertion into a Carbon-Fluorine Bond

inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.80.14openalex-snapshot

Development of Carbometalation and Oxymetalation by Using Moderate Lewis Acidity and π-Electrophilic Affinity of Heavy Main-group Metals

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