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On the conversion of CO 2 to value added products over composite PdZn and H-ZSM-5 catalysts: excess Zn over Pd, a compromise or a penalty?

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Handbook of Heterogeneous Catalysis

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Kinetic, Spectroscopic, and Theoretical Assessment of Associative and Dissociative Methanol Dehydration Routes in Zeolites

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Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO 2 Hydrogenation

inferredcites →https://doi.org/10.1002/anie.201906256openalex-snapshot

Supported Intermetallic PdZn Nanoparticles as Bifunctional Catalysts for the Direct Synthesis of Dimethyl Ether from CO‐Rich Synthesis Gas

inferredcites →https://doi.org/10.1007/s11244-007-0240-9openalex-snapshot

The effect of ageing time on co-precipitated Cu/ZnO/ZrO2 catalysts used in methanol synthesis from CO2 and H2

inferredcites →https://doi.org/10.1007/s11244-008-9158-0openalex-snapshot

The Effect of Acid Strength on the Conversion of Methanol to Olefins Over Acidic Microporous Catalysts with the CHA Topology

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Thermodynamics of ordered β1-pdZn alloys

inferredcites →https://doi.org/10.1016/0009-2509(92)80287-mopenalex-snapshot

The reduction of zinc titanate and zinc oxide solids

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Hydrocarbon formation from methanol and dimethyl ether: a review of the experimental observations concerning the mechanism of formation of the primary products

inferredcites →https://doi.org/10.1016/j.apcata.2004.09.014openalex-snapshot

Catalytic activity of the M/(3ZnO·ZrO2) system (M = Cu, Ag, Au) in the hydrogenation of CO2 to methanol

inferredcites →https://doi.org/10.1016/j.apcata.2004.10.040openalex-snapshot

Nanocrystalline zirconia as catalyst support in methanol synthesis

inferredcites →https://doi.org/10.1016/j.apcata.2006.05.035openalex-snapshot

Effect of metal oxide additives on the activity and stability of Cu/ZnO/ZrO2 catalysts in the synthesis of methanol from CO2 and H2

inferredcites →https://doi.org/10.1016/j.apcata.2015.06.017openalex-snapshot

Dimethyl ether synthesis via methanol dehydration: Effect of zeolite structure

inferredcites →https://doi.org/10.1016/j.apcata.2016.01.006openalex-snapshot

Methanol synthesis from CO2 and H2 over Pd/ZnO/Al2O3: Catalyst structure dependence of methanol selectivity

inferredcites →https://doi.org/10.1016/j.apcata.2018.04.036openalex-snapshot

Development of highly selective PdZn/CeO2 and Ca-doped PdZn/CeO2 catalysts for methanol synthesis from CO2 hydrogenation

inferredcites →https://doi.org/10.1016/j.apcatb.2013.03.048openalex-snapshot

Hybrid Cu–ZnO–ZrO2/H-ZSM5 system for the direct synthesis of DME by CO2 hydrogenation

inferredcites →https://doi.org/10.1016/j.apsusc.2019.05.363openalex-snapshot

Tuning adsorption properties of GaxIn2−xO3 catalysts for enhancement of methanol synthesis activity from CO2 hydrogenation at high reaction temperature

inferredcites →https://doi.org/10.1016/j.cej.2017.02.010openalex-snapshot

CO2 hydrogenation to methanol over CuO–ZnO–ZrO2–SiO2 catalysts: Effects of SiO2 contents

inferredcites →https://doi.org/10.1016/j.enconman.2018.01.016openalex-snapshot

Direct synthesis of dimethyl ether from CO 2 hydrogenation over novel hybrid catalysts containing a Cu ZnO ZrO 2 catalyst admixed with WO x /Al 2 O 3 catalysts: Effects of pore size of Al 2 O 3 support and W loading content

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Global warming and carbon dioxide through sciences

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Aerosol synthesis and Rietveld analysis of tetragonal (β1) PdZn

inferredcites →https://doi.org/10.1016/j.jcat.2009.03.004openalex-snapshot

A new approach to the modeling of deactivation in the conversion of methanol on zeolite catalysts

inferredcites →https://doi.org/10.1016/j.jcat.2012.05.005openalex-snapshot

The role of Pd–Ga bimetallic particles in the bifunctional mechanism of selective methanol synthesis via CO2 hydrogenation on a Pd/Ga2O3 catalyst

inferredcites →https://doi.org/10.1016/j.jcat.2012.05.020openalex-snapshot

Comparative study of hydrotalcite-derived supported Pd2Ga and PdZn intermetallic nanoparticles as methanol synthesis and methanol steam reforming catalysts

inferredcites →https://doi.org/10.1016/j.jcat.2016.03.017openalex-snapshot

Pd/ZnO catalysts for direct CO2 hydrogenation to methanol

inferredcites →https://doi.org/10.1016/j.jcat.2018.03.032openalex-snapshot

High Zn/Al ratios enhance dehydrogenation vs hydrogen transfer reactions of Zn-ZSM-5 catalytic systems in methanol conversion to aromatics

inferredcites →https://doi.org/10.1016/j.jcou.2015.09.002openalex-snapshot

Hydrogenation of CO2 to methanol over In2O3 catalyst

inferredcites →https://doi.org/10.1016/j.jcou.2018.01.028openalex-snapshot

Acidity control of zeolite functionality on activity and stability of hybrid catalysts during DME production via CO2 hydrogenation

inferredcites →https://doi.org/10.1016/j.jpowsour.2005.05.082openalex-snapshot

Dimethyl ether (DME) as an alternative fuel

inferredcites →https://doi.org/10.1016/j.mcat.2019.04.011openalex-snapshot

A smarter approach to catalysts by design: Combining surface organometallic chemistry on oxide and metal gives selective catalysts for dehydrogenation of 2,3-dimethylbutane

inferredcites →https://doi.org/10.1016/s0144-2449(82)80002-xopenalex-snapshot

Hydrophobic natures of zeolite ZSM-5

inferredcites →https://doi.org/10.1016/s0926-860x(01)00625-1openalex-snapshot

Surface active structure of ultra-fine Cu/ZrO2 catalysts used for the CO2+H2 to methanol reaction

inferredcites →https://doi.org/10.1016/s1054-3589(08)60423-8openalex-snapshot

Studies in Surface Science and Catalysis

inferredcites →https://doi.org/10.1016/s1387-1811(99)00063-3openalex-snapshot

Comparison between the surface acidity of solid catalysts determined by TPD and FTIR analysis of pre-adsorbed pyridine

inferredcites →https://doi.org/10.1017/s0885715613000924openalex-snapshot

PyFAI: a Python library for high performance azimuthal integration on GPU

inferredcites →https://doi.org/10.1021/acs.iecr.8b00230openalex-snapshot

Hydrogenation of CO2 to Dimethyl Ether over Brønsted Acidic PdZn Catalysts

inferredcites →https://doi.org/10.1021/acs.jpcc.5b09289openalex-snapshot

Selective Grafting of Ga(i-Bu)3 on the Silanols of Mesoporous H-ZSM-5 by Surface Organometallic Chemistry

inferredcites →https://doi.org/10.1021/acscatal.5b00654openalex-snapshot

Reaction Behaviors and Kinetics during Induction Period of Methanol Conversion on HZSM-5 Zeolite

inferredcites →https://doi.org/10.1021/acscatal.5b01271openalex-snapshot

Intermetallic GaPd 2 Nanoparticles on SiO 2 for Low-Pressure CO 2 Hydrogenation to Methanol: Catalytic Performance and In Situ Characterization

inferredcites →https://doi.org/10.1021/acscatal.5b02367openalex-snapshot

Computational Assessment of the Dominant Factors Governing the Mechanism of Methanol Dehydration over H-ZSM-5 with Heterogeneous Aluminum Distribution

inferredcites →https://doi.org/10.1021/acscatal.6b02928openalex-snapshot

Pd2Ga-Based Colloids as Highly Active Catalysts for the Hydrogenation of CO2 to Methanol

inferredcites →https://doi.org/10.1021/acscatal.8b04848openalex-snapshot

Revealing the Synergy between Oxide and Alloy Phases on the Performance of Bimetallic In–Pd Catalysts for CO 2 Hydrogenation to Methanol

inferredcites →https://doi.org/10.1021/cr068357uopenalex-snapshot

Transformation of Carbon Dioxide

inferredcites →https://doi.org/10.1021/ie50582a048openalex-snapshot

Thermodynamics in Methanol Synthesis

inferredcites →https://doi.org/10.1021/jacs.7b03101openalex-snapshot

Highly Active and Selective Hydrogenation of CO 2 to Ethanol by Ordered Pd–Cu Nanoparticles

inferredcites →https://doi.org/10.1021/jp075934popenalex-snapshot

Preparation and Morphology of Pyramidal MFI Single-Crystal Segments

inferredcites →https://doi.org/10.1021/jp1103164openalex-snapshot

Formation and Characterization of PdZn Alloy: A Very Selective Catalyst for Alkyne Semihydrogenation

inferredcites →https://doi.org/10.1023/a:1023596524663openalex-snapshot

The Preparation and Characterisation of Pd–ZnO Catalysts for Methanol Synthesis

inferredcites →https://doi.org/10.1038/nchem.2794openalex-snapshot

Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst

inferredcites →https://doi.org/10.1039/c4cy01568aopenalex-snapshot

Direct synthesis of dimethyl ether from CO 2 hydrogenation over Cu–ZnO–ZrO 2 /SO 4 2− –ZrO 2 hybrid catalysts: effects of sulfur-to-zirconia ratios

inferredcites →https://doi.org/10.1039/c5cp00222bopenalex-snapshot

Structural evolution of an intermetallic Pd–Zn catalyst selective for propane dehydrogenation

inferredcites →https://doi.org/10.1039/c5cs00304kopenalex-snapshot

The formation and degradation of active species during methanol conversion over protonated zeotype catalysts

inferredcites →https://doi.org/10.1039/c6cy01832gopenalex-snapshot

Pd@Zn core–shell nanoparticles of controllable shell thickness for catalytic methanol production

inferredcites →https://doi.org/10.1039/c6fd00189kopenalex-snapshot

PdZn catalysts for CO 2 hydrogenation to methanol using chemical vapour impregnation (CVI)

inferredcites →https://doi.org/10.1039/c6gc02366eopenalex-snapshot

A promising low pressure methanol synthesis route from CO 2 hydrogenation over Pd@Zn core–shell catalysts

inferredcites →https://doi.org/10.1039/c6ra08393eopenalex-snapshot

Influence of acid site density on the three-staged MTH induction reaction over HZSM-5 zeolite

inferredcites →https://doi.org/10.1039/c7cy00129kopenalex-snapshot

New insights into catalyst deactivation and product distribution of zeolites in the methanol-to-hydrocarbons (MTH) reaction with methanol and dimethyl ether feeds

inferredcites →https://doi.org/10.1039/c7cy01403aopenalex-snapshot

A review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons

inferredcites →https://doi.org/10.1039/c7cy01549fopenalex-snapshot

Direct and selective hydrogenation of CO 2 to ethylene and propene by bifunctional catalysts

inferredcites →https://doi.org/10.1080/01411594.2010.549944openalex-snapshot

SNBL, a dedicated beamline for combined in situ X-ray diffraction, X-ray absorption and Raman scattering experiments

inferredcites →https://doi.org/10.1107/s0909049505012719openalex-snapshot

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT

inferredcites →https://doi.org/10.1107/s1600576716000455openalex-snapshot

FIT2D : a multi-purpose data reduction, analysis and visualization program

inferredcites →https://doi.org/10.1126/sciadv.1701290openalex-snapshot

A highly selective and stable ZnO-ZrO 2 solid solution catalyst for CO 2 hydrogenation to methanol

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Dehydration of Methanol to Dimethyl Ether over ZSM-5 Zeolite

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← backgroundhttps://doi.org/10.5281/zenodo.10037232zenodo-depositor-declared

inferred← citeshttps://doi.org/10.1007/s11244-020-01405-wopenalex-snapshot

A Short Review of Recent Advances in Direct CO2 Hydrogenation to Alcohols

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Development of mono and bimetallic Ni, Fe and NiM catalysts for CO2 methanation on sustainable biochar supports

inferred← citeshttps://doi.org/10.1016/j.apcata.2022.118568openalex-snapshot

Supported PdZn nanoparticles for selective CO2 conversion, through the grafting of a heterobimetallic complex on CeZrOx

inferred← citeshttps://doi.org/10.1016/j.apcata.2023.119100openalex-snapshot

PdZn/ZrO2+SAPO-34 bifunctional catalyst for CO2 conversion: Further insights by spectroscopic characterization

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Evolution of surface and bulk structure of supported palladium nanoparticles by in situ X-ray absorption and infrared spectroscopies: Effect of temperature, CO and CH4 gas

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Finding the active species: The conversion of methanol to aromatics over Zn-ZSM-5/alumina shaped catalysts

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CO2 utilization in syngas conversion to dimethyl ether and aromatics: Roles and challenges of zeolites-based catalysts

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Harnessing Zn-volatility for compositional tuning in PtZn nanoalloy catalysts

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Zn Redistribution and Volatility in ZnZrO x Catalysts for CO 2 Hydrogenation

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From Lab to Technical CO2 Hydrogenation Catalysts: Understanding PdZn Decomposition

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The Critical Role of βPdZn Alloy in Pd/ZnO Catalysts for the Hydrogenation of Carbon Dioxide to Methanol

inferred← citeshttps://doi.org/10.1021/acscatal.2c04600openalex-snapshot

Evaluating the Role of Descriptor- and Spectator-Type Reaction Intermediates During the Early Phases of Zeolite Catalysis

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Multifunctional Catalyst Combination for the Direct Conversion of CO 2 to Propane

inferred← citeshttps://doi.org/10.1039/d0cy01550dopenalex-snapshot

CO 2 hydrogenation to methanol and hydrocarbons over bifunctional Zn-doped ZrO 2 /zeolite catalysts

inferred← citeshttps://doi.org/10.1039/d0fd00135jopenalex-snapshot

Identification of C 2 –C 5 products from CO 2 hydrogenation over PdZn/TiO 2 –ZSM-5 hybrid catalysts

inferred← citeshttps://doi.org/10.1039/d5ta05950jopenalex-snapshot

Structural and catalytic insights into Pd-UiO-67 frameworks for CO 2 hydrogenation to methanol

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Direct Synthesis of Dimethyl Ether from CO2: Recent Advances in Bifunctional/Hybrid Catalytic Systems

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Development of new supported bifunctional catalysts for selective conversion of CO2 to light hydrocarbons

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