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Copper- and DMF-mediated switchable oxidative C–H cyanation and formylation of imidazo[1,2- a ]pyridines using ammonium iodide

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/adsc.201200345openalex-snapshot
The Copper‐Catalyzed C‐3‐Formylation of Indole CH Bonds using Tertiary Amines and Molecular Oxygen
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Copper‐Catalyzed Intermolecular Oxidative Cyclization of Halo‐ alkynes: Synthesis of 2‐Halo‐substituted Imidazo[1,2‐a]pyridines, Imidazo[1,2‐a]pyrazines and Imidazo[1,2‐a]pyrimidines
inferredcites →https://doi.org/10.1002/adsc.201500391openalex-snapshot
Regioselective Oxidative Homocoupling Reaction: An Efficient Copper‐Catalyzed Synthesis of Biimidazo[1,2‐a]pyridines
inferredcites →https://doi.org/10.1002/adsc.201900001openalex-snapshot
Palladium‐Catalyzed Primary Amine‐Directed Decarboxylative Annulation of α‐Oxocarboxylic Acids: Access to Indolo[1,2‐a]quinazolines
inferredcites →https://doi.org/10.1002/adsc.201900395openalex-snapshot
DMF as Methine Source: Copper‐Catalyzed Direct Annulation of Hydrazides to 1,3,4‐Oxadiazoles
inferredcites →https://doi.org/10.1002/anie.200900418openalex-snapshot
Catalytic Oxidative Synthesis of Nitriles Directly from Primary Alcohols and Ammonia
inferredcites →https://doi.org/10.1002/anie.200903838openalex-snapshot
Direct Transformation of Methyl Arenes to Aryl Nitriles at Room Temperature
inferredcites →https://doi.org/10.1002/anie.200907291openalex-snapshot
General and Efficient Copper‐Catalyzed Three‐Component Coupling Reaction towards Imidazoheterocycles: One‐Pot Synthesis of Alpidem and Zolpidem
inferredcites →https://doi.org/10.1002/anie.201100362openalex-snapshot
Copper‐Catalyzed Intramolecular Dehydrogenative Aminooxygenation: Direct Access to Formyl‐Substituted Aromatic N‐Heterocycles
inferredcites →https://doi.org/10.1002/anie.201200859openalex-snapshot
N,N‐Dimethylformamide: A Multipurpose Building Block
inferredcites →https://doi.org/10.1002/anie.201206168openalex-snapshot
Synthesis of Aromatic Nitriles Using Nonmetallic Cyano‐Group Sources
inferredcites →https://doi.org/10.1002/anie.201608433openalex-snapshot
A Four‐Component Reaction Strategy for Pyrimidine Carboxamide Synthesis
inferredcites →https://doi.org/10.1002/cber.18840170219openalex-snapshot
Ueber die Ersetzung der Amidgruppe durch Chlor in den aromatischen Substanzen
inferredcites →https://doi.org/10.1002/ejoc.201600401openalex-snapshot
Cross Dehydrogenative Coupling (CDC) Reactions of N,N‐Disubstituted Formamides, Benzaldehydes and Cycloalkanes
inferredcites →https://doi.org/10.1016/j.bmcl.2009.11.008openalex-snapshot
Scaffold hopping from pyridones to imidazo[1,2-a]pyridines. New positive allosteric modulators of metabotropic glutamate 2 receptor
inferredcites →https://doi.org/10.1016/j.bmcl.2011.06.090openalex-snapshot
Novel imidazo[1,2-a]pyridine based inhibitors of the IGF-1 receptor tyrosine kinase: Optimization of the aniline
inferredcites →https://doi.org/10.1016/j.bmcl.2011.06.093openalex-snapshot
Discovery of novel imidazo[1,2-a]pyridines as inhibitors of the insulin-like growth factor-1 receptor tyrosine kinase
inferredcites →https://doi.org/10.1016/j.catcom.2019.01.025openalex-snapshot
Heterogeneous copper-catalyzed three-component reaction of 2-aminopyridines, acetophenones and benzyl cyanide towards 3-cyanoimidazo[1,2-a]pyridines
inferredcites →https://doi.org/10.1016/j.tet.2006.11.043openalex-snapshot
Facile synthesis of azocino[4,3-b]indoles by ring-closing metathesis
inferredcites →https://doi.org/10.1016/j.tet.2009.06.091openalex-snapshot
N,N-Dimethylformamide: much more than a solvent
inferredcites →https://doi.org/10.1016/j.tet.2017.05.018openalex-snapshot
Synthesis of benzimidazoles from o -phenylenediamines and DMF derivatives in the presence of PhSiH 3
inferredcites →https://doi.org/10.1016/s0040-4020(01)91791-0openalex-snapshot
Tetrahedron report number 163
inferredcites →https://doi.org/10.1021/acs.joc.5b02417openalex-snapshot
Regioselective Copper-Catalyzed Dicarbonylation of Imidazo[1,2‑ a ]pyridines with N,N-Disubstituted Acetamide or Acetone: An Approach to 1,2-Diketones Using Molecular Oxygen
inferredcites →https://doi.org/10.1021/acs.joc.6b01355openalex-snapshot
H 2 O 2 /DMSO-Promoted Regioselective Synthesis of 3,3′-Bisimidazopyridinylmethanes via Intermolecular Oxidative C(sp 2 )–H Bond Activation of Imidazoheterocycles
inferredcites →https://doi.org/10.1021/acs.joc.7b02433openalex-snapshot
Carbonylation Access to Phthalimides Using Self-Sufficient Directing Group and Nucleophile
inferredcites →https://doi.org/10.1021/acs.orglett.5b00170openalex-snapshot
NH4I-Mediated Three-Component Coupling Reaction: Metal-Free Synthesis of β-Alkoxy Methyl Sulfides from DMSO, Alcohols, and Styrenes
inferredcites →https://doi.org/10.1021/acs.orglett.6b01588openalex-snapshot
A Carbonylation Approach Toward Activation of Csp2-H and Csp3-H Bonds: Cu-Catalyzed Regioselective Cross Coupling of Imidazo[1,2-a]pyridines with Methyl Hetarenes
inferredcites →https://doi.org/10.1021/acs.orglett.6b02265openalex-snapshot
Cyanation of Phenol Derivatives with Aminoacetonitriles by Nickel Catalysis
inferredcites →https://doi.org/10.1021/acs.orglett.9b00969openalex-snapshot
Metal-Free C–B Bond Cleavage: An Acid Catalyzed Three-Component Reaction Construction of Imidazole-Containing Triarylmethanes
inferredcites →https://doi.org/10.1021/acs.orglett.9b03861openalex-snapshot
Copper-Mediated Direct Cyanation of Heteroarene and Arene C–H Bonds by the Combination of Ammonium and DMF
inferredcites →https://doi.org/10.1021/cr00080a006openalex-snapshot
Cyanation of aromatic halides
inferredcites →https://doi.org/10.1021/cr00087a004openalex-snapshot
Radical reactions of arenediazonium ions: An easy entry into the chemistry of the aryl radical
inferredcites →https://doi.org/10.1021/cr60204a003openalex-snapshot
The Reimer-Tiemann Reaction.
inferredcites →https://doi.org/10.1021/ja104917topenalex-snapshot
A New Combined Source of “CN” from N,N-Dimethylformamide and Ammonia in the Palladium-Catalyzed Cyanation of Aryl C−H Bonds
inferredcites →https://doi.org/10.1021/ja1067993openalex-snapshot
A Direct Intramolecular C−H Amination Reaction Cocatalyzed by Copper(II) and Iron(III) as Part of an Efficient Route for the Synthesis of Pyrido[1,2-a]benzimidazoles fromN-Aryl-2-aminopyridines
inferredcites →https://doi.org/10.1021/ja204063zopenalex-snapshot
Direct Transformation of N , N -Dimethylformamide to −CN: Pd-Catalyzed Cyanation of Heteroarenes via C–H Functionalization
inferredcites →https://doi.org/10.1021/ja2048495openalex-snapshot
Mild and Selective Ru-Catalyzed Formylation and Fe-Catalyzed Acylation of Free (N–H) Indoles Using Anilines as the Carbonyl Source
inferredcites →https://doi.org/10.1021/ja211389gopenalex-snapshot
Copper-Mediated Sequential Cyanation of Aryl C–B and Arene C–H Bonds Using Ammonium Iodide and DMF
inferredcites →https://doi.org/10.1021/jacs.5b01671openalex-snapshot
Direct Aerobic Carbonylation of C(sp 2 )–H and C(sp 3 )–H Bonds through Ni/Cu Synergistic Catalysis with DMF as the Carbonyl Source
inferredcites →https://doi.org/10.1021/jm201561ropenalex-snapshot
Imidazo[1,2-a]pyridines: Orally Active Positive Allosteric Modulators of the Metabotropic Glutamate 2 Receptor
inferredcites →https://doi.org/10.1021/jo034187zopenalex-snapshot
Regiospecific C -Acylation of Pyrroles and Indoles Using N -Acylbenzotriazoles
inferredcites →https://doi.org/10.1021/jo2004956openalex-snapshot
Aerobic Oxidative Transformation of Primary Azides to Nitriles by Ruthenium Hydroxide Catalyst
inferredcites →https://doi.org/10.1021/jo3003024openalex-snapshot
CuSO4–Glucose for in Situ Generation of Controlled Cu(I)–Cu(II) Bicatalysts: Multicomponent Reaction of Heterocyclic Azine and Aldehyde with Alkyne, and Cycloisomerization toward Synthesis of N-Fused Imidazoles
inferredcites →https://doi.org/10.1021/jo501385wopenalex-snapshot
Dimethyl Sulfoxide Participant Iron-Mediated Cascade Oxidation/α-Formylation Reaction of Substituted 2,3-Dihydropyrroles under Air and Protonic Acid Free Condition
inferredcites →https://doi.org/10.1021/jo502013sopenalex-snapshot
Palladium-Catalyzed Oxidative Carbonylation for the Synthesis of Polycyclic Aromatic Hydrocarbons (PAHs)
inferredcites →https://doi.org/10.1021/jo502328jopenalex-snapshot
Base-Mediated Decomposition of Amide-Substituted Furfuryl Tosylhydrazones: Synthesis and Cytotoxic Activities of Enynyl-Ketoamides
inferredcites →https://doi.org/10.1021/ol0620747openalex-snapshot
A Synthesis of the Welwistatin Core
inferredcites →https://doi.org/10.1021/ol101094uopenalex-snapshot
An Efficient Transformation from Benzyl or Allyl Halides to Aryl and Alkenyl Nitriles
inferredcites →https://doi.org/10.1021/ol201713bopenalex-snapshot
Copper-Mediated Cyanation of Aryl Halide with the Combined Cyanide Source
inferredcites →https://doi.org/10.1021/ol300232aopenalex-snapshot
Direct Arylation of Imidazo[1,2-a]pyridine at C-3 with Aryl Iodides, Bromides, and Triflates via Copper(I)-Catalyzed C–H Bond Functionalization
inferredcites →https://doi.org/10.1021/ol301674mopenalex-snapshot
Copper-Mediated Selective Cyanation of Indoles and 2-Phenylpyridines with Ammonium Iodide and DMF
inferredcites →https://doi.org/10.1021/ol403040gopenalex-snapshot
DMF as Carbon Source: Rh-Catalyzed α-Methylation of Ketones
inferredcites →https://doi.org/10.1021/ol4031414openalex-snapshot
One-Pot Regiospecific Synthesis of Imidazo[1,2-a]pyridines: A Novel, Metal-Free, Three-Component Reaction for the Formation of C–N, C–O, and C–S Bonds
inferredcites →https://doi.org/10.1039/c1cs15004aopenalex-snapshot
Recent developments and perspectives in palladium-catalyzed cyanation of aryl halides: synthesis of benzonitriles
inferredcites →https://doi.org/10.1039/c1cs15119copenalex-snapshot
New and unusual scaffolds in medicinal chemistry
inferredcites →https://doi.org/10.1039/c3cc46427jopenalex-snapshot
Amine formylation via carbon dioxide recycling catalyzed by a simple and efficient heterogeneous palladium catalyst
inferredcites →https://doi.org/10.1039/c3cc47926aopenalex-snapshot
Catalytic cyanation of aryl iodides using DMF and ammonium bicarbonate as the combined source of cyanide: a dual role of copper catalysts
inferredcites →https://doi.org/10.1039/c3ra40695dopenalex-snapshot
Copper(ii)-catalyzed C–H (sp3) oxidation and C–N cleavage: synthesis of methylene-bridged compounds using TMEDA as a carbon source in water
inferredcites →https://doi.org/10.1039/c4cc02275kopenalex-snapshot
Copper-catalysed oxidative Csp 3 –H methylenation to terminal olefins using DMF
inferredcites →https://doi.org/10.1039/c4cc07606kopenalex-snapshot
Ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones
inferredcites →https://doi.org/10.1039/c4cc09134eopenalex-snapshot
Cu-Catalyzed selective C3-formylation of imidazo[1,2-a]pyridine C–H bonds with DMSO using molecular oxygen
inferredcites →https://doi.org/10.1039/c5cc05821jopenalex-snapshot
Copper-mediated three-component synthesis of 3-cyanoimidazo[1,2-a]pyridines
inferredcites →https://doi.org/10.1039/c5ra07584jopenalex-snapshot
Ammonium iodide-promoted cyclization of ketones with DMSO and ammonium acetate for synthesis of substituted pyridines
inferredcites →https://doi.org/10.1039/c7md00043jopenalex-snapshot
Design, synthesis and biological evaluation of imidazopyridine–propenone conjugates as potent tubulin inhibitors
inferredcites →https://doi.org/10.1039/c8ra04985hopenalex-snapshot
Beyond a solvent: triple roles of dimethylformamide in organic chemistry
inferredcites →https://doi.org/10.1039/c9gc01766fopenalex-snapshot
A visible-light-induced intermolecular [3 + 2] alkenylation–cyclization strategy: metal-free construction of pyrrolo[2,1,5- cd ]indolizine rings
inferredcites →https://doi.org/10.1080/00397911.2019.1606920openalex-snapshot
Gluconic acid promoted cascade reactions of 2-phenylimidazo[1,2-a] pyridine-3-carbaldehyde with cyclohexane-1,3-dione to create novel fused bisheterocycles
inferredcites →https://doi.org/10.3390/molecules23081939openalex-snapshot
Recent Uses of N,N-Dimethylformamide and N,N-Dimethylacetamide as Reagents
inferredcites →https://doi.org/10.6023/cjoc1107281openalex-snapshot
Recent Progress in the Research of the Transition-Metal-Catalyzed C—CN Bonds Coupling Reactions

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/9781119716846.ch12openalex-snapshot
Ligand‐Promoted Catalyzed Reactions
inferred← citeshttps://doi.org/10.1002/9781119716846.ch3openalex-snapshot
Oxidation and Reduction
inferred← citeshttps://doi.org/10.1002/adsc.202400473openalex-snapshot
Iodine Mediated Annulation of Triethylamine, Aldehydes and 2‐Aminopyridines for the Synthesis of 3‐Formyl‐Imidazo [1,2‐a]pyridine Derivatives
inferred← citeshttps://doi.org/10.1002/adsc.202400482openalex-snapshot
Nucleophilic Cyanation of Enones and Imines with Formamide as the Cyano Source
inferred← citeshttps://doi.org/10.1002/ajoc.202300603openalex-snapshot
Hexamethyldisilazane‐Mediated Synthesis of N‐Formamides, Benzimidazoles and Quinazolinones Using N,N‐Dimethylformamide as a C1 Source
inferred← citeshttps://doi.org/10.1002/asia.202300001openalex-snapshot
Electrochemically Enabled Direct C3‐Formylation of Imidazopyridines with Me3N as a Carbonyl Source
inferred← citeshttps://doi.org/10.1002/cjoc.202100489openalex-snapshot
Micellar Catalysis: Visible‐Light Mediated Imidazo[1,2‐a]pyridine C—H Amination with N‐Aminopyridinium Salt Accelerated by Surfactant in Water
inferred← citeshttps://doi.org/10.1002/ejoc.202400178openalex-snapshot
C(sp2)‐H Imination of Imidazo[1,2‐a]pyridines: A Catalyst‐Free, Multicomponent Approach
inferred← citeshttps://doi.org/10.1002/ejoc.202501115openalex-snapshot
Recent Advances in Ammonium Iodide (NH 4 I)‐Mediated Transformations: Toward Greener and Metal‐Free Organic Synthesis
inferred← citeshttps://doi.org/10.1002/tcr.202300063openalex-snapshot
Recent Advances On Direct Formylation Reactions
inferred← citeshttps://doi.org/10.1007/s41061-026-00543-1openalex-snapshot
Recent Progress of N,N-Dimethylformamide (DMF) as Versatile Synthons in Organic Synthesis
inferred← citeshttps://doi.org/10.1016/b978-0-323-98410-2.00008-4openalex-snapshot
Five-membered ring systems: with more than one N atom
inferred← citeshttps://doi.org/10.1016/j.gresc.2022.03.007openalex-snapshot
Recent advances in transition-metal-free C–H functionalization of imidazo[1,2-a]pyridines
inferred← citeshttps://doi.org/10.1016/j.molstruc.2023.135612openalex-snapshot
Copper iodide mediated telescoped synthesis of 3-cyanoimidazo[1,2-a]pyridines, photophysical and DFT studies
inferred← citeshttps://doi.org/10.1016/j.tet.2024.133943openalex-snapshot
HFIP-promoted synthesis of imidazo [1,2-a]pyridines containing CF3-substituted tertiary alcohols at room temperature
inferred← citeshttps://doi.org/10.1016/j.tet.2026.135312openalex-snapshot
Indirect electro-oxidative cyanation of imidazo-fused heterocycles with malononitrile under mild conditions
inferred← citeshttps://doi.org/10.1021/acs.joc.1c01371openalex-snapshot
Copper-Catalyzed C-3 Functionalization of Imidazo[1,2-a]pyridines with 3-Indoleacetic Acids
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02067openalex-snapshot
N , N -Dimethylformamide as Carbon Synthons for the Synthesis of N -Heterocycles: Pyrrolo/Indolo[1,2- a ]quinoxalines and Quinazolin-4-ones
inferred← citeshttps://doi.org/10.1021/acs.joc.3c00176openalex-snapshot
A Palladium-Catalyzed Carbonylative Acetylation of N-Phenylpyridin-2-amine Using DMF and CO as the Acetyl Source
inferred← citeshttps://doi.org/10.1021/acs.joc.4c00321openalex-snapshot
TBHP/Et 3 N-Promoted Chemoselective Formylation and Peroxidation of Pyrrolo[2,1- a ]isoquinolines
inferred← citeshttps://doi.org/10.1039/d1ob01520fopenalex-snapshot
Application of combined cyanide sources in cyanation reactions
inferred← citeshttps://doi.org/10.1039/d1ob02043aopenalex-snapshot
Synthesis of methylene-bridged α,β-unsaturated ketones: α-C sp 3 –H methylenation of aromatic ketones using Selectfluor as a mild oxidant
inferred← citeshttps://doi.org/10.1039/d4ob00868eopenalex-snapshot
A benzimidazole-based Cu( ii ) complex catalyzed site-selective C–H sulfenylation of imidazo-[1,2- a ]pyridines using CS 2 as a sulfur source
inferred← citeshttps://doi.org/10.1039/d4ob02095bopenalex-snapshot
Iodine-mediated regioselective C-3 sulfenylation using elemental sulfur and arylhydrazine hydrochloride to access 3-sulfenylated imidazo[1,2- a ]pyridines
inferred← citeshttps://doi.org/10.3390/molecules26216374openalex-snapshot
A Journey from June 2018 to October 2021 with N,N-Dimethylformamide and N,N-Dimethylacetamide as Reactants
inferred← citeshttps://doi.org/10.3390/molecules30030607openalex-snapshot
Recent Advances in Visible Light-Induced C-H Functionalization of Imidazo[1,2-a]pyridines
inferred← citeshttps://doi.org/10.3987/com-21-14576openalex-snapshot
Metal-Free C3-H Hydrazination of Imidazo[1,2-a]pyridine with Azodiformates in Water at Room Temperature
inferred← citeshttps://doi.org/10.6023/cjoc202110015openalex-snapshot
An Efficient Three-Component Tandem Approach for the Synthesis of Imidazoheterocycle-Hydrazine Derivatives under Mild Conditions
inferred← citeshttps://doi.org/10.6023/cjoc202503008openalex-snapshot
Alumina-Promoted Michael Addition of Imidazo[1,2-a]pyridines with α,β-Unsaturated Ketones
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