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The post-modification of polyolefins with emerging synthetic methods

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Synthesis of maleic anhydride grafted polyethylene and polypropylene, with controlled molecular structures

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Kinetics of the Solid-State Chlorination of High-Density Polyethylene

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Regiospecific Side‐Chain Functionalization of Linear Low‐Density Polyethylene with Polar Groups

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Regioselective C−H Xanthylation as a Platform for Polyolefin Functionalization

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C−H Functionalization of Commodity Polymers

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Emerging Palladium and Nickel Catalysts for Copolymerization of Olefins with Polar Monomers

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A novel process for the chlorination of polymers in solution

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Oxidation behavior and stabilization of metallocene and other polyolefins

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Sulfonyl azides—an alternative route to polyolefin modification

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Studies on chlorinated polyethylenes. I. Infrared spectra of chlorinated polyethylenes

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Difluorocarbene modification of polymer and fiber surfaces

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Suspension bromination of high‐density polyethylene

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Ink adhesion on corona‐treated polyethylene studied by chemical derivatization of surface functional groups

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Preparation of sulfonated polypropylene and its dyeability: Thiol as a functionalization template of polypropylene

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Functionalization of polypropylene at high temperature under oxidative/inert environment

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Bond Dissociation Energies of Organic Molecules

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Direct azidation of isotactic polypropylene and synthesis of ‘grafted to’ derivatives thereof using azide–alkyne cycloaddition chemistry

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Dehydrogenation and chain cleavage of polymers with peroxides and copper salts

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Sulfur modification of polyethylene surfaces. II. Modification of polyethylene surfaces with fuming sulfuric acid

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Hydrophilic graft modification of a commercial crystalline polyolefin

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Synthesis of quaternary ammonium ion‐grafted polyolefins via activation of inert CH bonds and nitroxide mediated radical polymerization

inferredcites →https://doi.org/10.1002/pola.24493openalex-snapshot

Grafting of functional nitroxyl free radicals to polyolefins as a tool to postreactor modification of polyethylene‐based materials with control of macromolecular architecture

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Synthesis and characterization of polypropylene‐graft‐poly( l ‐lactide) copolymers by CuAAC click chemistry

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New Plasma Techniques for Polymer Surface Modification with Monotype Functional Groups

inferredcites →https://doi.org/10.1002/sia.740020306openalex-snapshot

X‐ray photoelectron spectroscopy studies of polymer surfaces, 4—further studies of the chromic acid etching of low density polyethylene

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Ethylene-Propene Copolymerization with C1-symmetric ansa-Fluorenyl-zirconocene Catalysts: Effects of Catalyst Structure and Comonomer on Molar Mass

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Stereoblock Polypropylenes Prepared by Efficient Chain Shuttling Polymerization of Propylene with Binary Zirconium Catalysts and iBu3Al

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Mathematical description of the softening temperature of poly(vinyl chloride) blends with solid-state chlorinated polyethylene

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E.s.c.a. studies of corona-discharge-treated polyethylene surfaces by use of gas-phase derivatization

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Polyolefin functionalization by carbene insertion for polymer blends

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Surface-initiated reversible addition–fragmentation chain transfer polymerization from “clickable” polypropylene surface modified by iodine plasma activation

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Direct fluorination—Useful tool to enhance commercial properties of polymer articles

inferredcites →https://doi.org/10.1016/j.memsci.2012.06.033openalex-snapshot

Surface modification of polypropylene macroporous membrane by marrying RAFT polymerization with click chemistry

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Catalytic post-modification of alkene polymers

inferredcites →https://doi.org/10.1016/j.polymdegradstab.2009.11.016openalex-snapshot

Mediated melt functionalization of polypropylene

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Xenon difluoride plasma fluorination of polymer surfaces

inferredcites →https://doi.org/10.1016/j.progpolymsci.2009.04.008openalex-snapshot

Control of macromolecular architecture during the reactive functionalization in the melt of olefin polymers

inferredcites →https://doi.org/10.1016/j.surfcoat.2009.05.050openalex-snapshot

Haloform plasma modification of polyolefin surfaces

inferredcites →https://doi.org/10.1016/s0032-3861(01)00069-6openalex-snapshot

Functionalization of isotactic polypropylene with maleic anhydride by reactive extrusion: mechanism of melt grafting

inferredcites →https://doi.org/10.1016/s0079-6700(98)00017-3openalex-snapshot

The synthesis of polyolefin graft copolymers by reactive extrusion

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A comparative study of the thermal behavior of PVC, a series of synthesized chlorinated polyethylenes and HDPE

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Diazo transfer for azido-functional surfaces

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Direct Amination of Polyethylene by Metal-Free Reaction

inferredcites →https://doi.org/10.1021/acs.orglett.6b02391openalex-snapshot

Alkylation of Nonacidic C(sp3)–H Bonds by Photoinduced Catalytic Michael-Type Radical Addition

inferredcites →https://doi.org/10.1021/acs.orglett.6b03731openalex-snapshot

Remote C(sp3)–H Oxygenation of Protonated Aliphatic Amines with Potassium Persulfate

inferredcites →https://doi.org/10.1021/acscentsci.7b00255openalex-snapshot

Catalytic Hydroxylation of Polyethylenes

inferredcites →https://doi.org/10.1021/cr990251uopenalex-snapshot

Copolymerization of Polar Monomers with Olefins Using Transition-Metal Complexes

inferredcites →https://doi.org/10.1021/ja016763jopenalex-snapshot

Rhodium-Catalyzed, Regiospecific Functionalization of Polyolefins in the Melt

inferredcites →https://doi.org/10.1021/ja044440sopenalex-snapshot

Catalytic Hydroxylation of Polypropylenes

inferredcites →https://doi.org/10.1021/ja508469uopenalex-snapshot

Site-Selective Aliphatic C–H Bromination Using N-Bromoamides and Visible Light

inferredcites →https://doi.org/10.1021/jacs.5b09099openalex-snapshot

Platinum-Catalyzed, Terminal-Selective C(sp3)–H Oxidation of Aliphatic Amines

inferredcites →https://doi.org/10.1021/jacs.5b12308openalex-snapshot

Site-Selective Aliphatic C–H Chlorination Using N-Chloroamides Enables a Synthesis of Chlorolissoclimide

inferredcites →https://doi.org/10.1021/jacs.9b05799openalex-snapshot

Chemo- and Regioselective Functionalization of Isotactic Polypropylene: A Mechanistic and Structure–Property Study

inferredcites →https://doi.org/10.1021/la026032copenalex-snapshot

Novel Plasma Approach for the Synthesis of Highly Fluorinated Thin Surface Layers

inferredcites →https://doi.org/10.1021/la701126topenalex-snapshot

Determination of Amine and Aldehyde Surface Densities: Application to the Study of Aged Plasma Treated Polyethylene Films

inferredcites →https://doi.org/10.1021/la980996fopenalex-snapshot

Surface Modification of Polyethylene through Bromination

inferredcites →https://doi.org/10.1021/ma00193a084openalex-snapshot

Functionalization of polyolefins: structure of functional groups in polyethylene reacted with ethyl diazoacetate

inferredcites →https://doi.org/10.1021/ma00219a010openalex-snapshot

Kinetics of the gas-phase halogenation of a polyethylene surface as studied with x-ray photoelectron spectroscopy

inferredcites →https://doi.org/10.1021/ma0347621openalex-snapshot

Selective and Mild Oxyfunctionalization of Model Polyolefins

inferredcites →https://doi.org/10.1021/ma050626fopenalex-snapshot

Controlled, Copper-Catalyzed Functionalization of Polyolefins

inferredcites →https://doi.org/10.1021/ma0605088openalex-snapshot

Synthesis and Crystallization of Precision ADMET Polyolefins Containing Halogens

inferredcites →https://doi.org/10.1021/ma401628uopenalex-snapshot

Ester Functionalization of Polypropylene via Controlled Decomposition of Benzoyl Peroxide during Solid-State Shear Pulverization

inferredcites →https://doi.org/10.1021/ma500034gopenalex-snapshot

Transition-Metal-Catalyzed Functional Polyolefin Synthesis: Effecting Control through Chelating Ancillary Ligand Design and Mechanistic Insights

inferredcites →https://doi.org/10.1021/ol4006757openalex-snapshot

Metal-Free Fluorination of C(sp 3 )–H Bonds Using a Catalytic N -Oxyl Radical

inferredcites →https://doi.org/10.1038/nature17651openalex-snapshot

Site-selective and stereoselective functionalization of unactivated C–H bonds

inferredcites →https://doi.org/10.1038/s41570-018-0003-0openalex-snapshot

Designing catalysts for olefin polymerization and copolymerization: beyond electronic and steric tuning

inferredcites →https://doi.org/10.1038/s41570-019-0099-xopenalex-snapshot

Dirhodium tetracarboxylates as catalysts for selective intermolecular C–H functionalization

inferredcites →https://doi.org/10.1039/b311405hopenalex-snapshot

Post-polymerization functionalization of polyolefins

inferredcites →https://doi.org/10.1039/b502120kopenalex-snapshot

Dehydrogenation of aliphatic polyolefins catalyzed by pincer-ligated iridium complexes

inferredcites →https://doi.org/10.1039/c3py00246bopenalex-snapshot

N-Acetoxy-phthalimide (NAPI) as a new H-abstracting agent at high temperature: application to the melt functionalization of polyethylene

inferredcites →https://doi.org/10.1039/c8py00013aopenalex-snapshot

Mild halogenation of polyolefins using an N -haloamide reagent

inferredcites →https://doi.org/10.1039/c8py01344fopenalex-snapshot

Regioselective post-functionalization of isotactic polypropylene by amination in the presence of N -hydroxyphthalimide

inferredcites →https://doi.org/10.1039/c9py00599dopenalex-snapshot

A direct functionalization of polyolefins for blend compatibilization by an insertion of 1,1-bis(phenylsulfonyl)ethylene (BPSE)

inferredcites →https://doi.org/10.1039/c9py00672aopenalex-snapshot

Acyloxyimide derivatives as efficient promoters of polyolefin C–H functionalization: application in the melt grafting of maleic anhydride onto polyethylene

inferredcites →https://doi.org/10.1063/1.1510170openalex-snapshot

Functionalization of graphite, glassy carbon, and polymer surfaces with highly oxidized sulfur species by plasma treatments

inferredcites →https://doi.org/10.1080/00222339009351497openalex-snapshot

Kinetic Study of the Catalytic Effect of Zinc(II) Ion on the Dehydrogenation of Atactic Polypropylene by Sulfur

inferredcites →https://doi.org/10.1080/00319100600757417openalex-snapshot

Determination of three-dimensional solubility parameters of chlorinated polypropylene by ultrasonic degradation

inferredcites →https://doi.org/10.1080/10601329008544724openalex-snapshot

Kinetic Study of the Catalytic Effect of Zinc(Ii) Ion On the Dehydrogenation of Atactic Polypropylene by Sulfur

inferredcites →https://doi.org/10.1080/15421400802463753openalex-snapshot

Photochemical Surface Modification of Polyethylene Films by New Azidobenzenesulfonamides

inferredcites →https://doi.org/10.1081/mc-100107860openalex-snapshot

THE CHEMISTRY OF POLYETHYLENE*

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Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions

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Thermal, Catalytic, Regiospecific Functionalization of Alkanes

inferredcites →https://doi.org/10.1126/science.aat9750openalex-snapshot

Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis

inferredcites →https://doi.org/10.1126/science.aay6230openalex-snapshot

A broadly applicable cross-linker for aliphatic polymers containing C–H bonds

inferredcites →https://doi.org/10.1134/s1070427210010192openalex-snapshot

Composition, properties, and application of products formed in oxidation of polyethylene by nitric acid

inferredcites →https://doi.org/10.3139/217.2039openalex-snapshot

Functionalization of PP with Sulfonyl Azide through Reactive Processing

inferredcites →https://doi.org/10.3144/expresspolymlett.2018.35openalex-snapshot

Polypropylene-based graft copolymers via CuAAC click chemistry

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Polyethylene Surface Modification by Benzoic Acid Grafting

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C−H Functionalization and Allylic Amination for Post‐Polymerization Modification of Polynorbornenes

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A Cleavable Crosslinking Strategy for Commodity Polymer Functionalization and Generation of Reprocessable Thermosets

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Hydroaminoalkylation for Amine Functionalization of Vinyl‐Terminated Polyethylene Enables Direct Access to Responsive Functional Materials

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Iron(III)‐Catalyzed C─H Hydroxylation of Low‐Density Polyethylene Coupled with Short Chain Branching Growth

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C─H Amination of Polypropylene with Sodium N ‐Chloro‐Amides

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Functionalization of Polyolefins via Catalytic Nitrene Addition

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Spotting Trends in Organocatalyzed and Other Organomediated (De)polymerizations and Polymer Functionalizations

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Circular Upcycling of Bottlebrush Thermosets

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C−H Functionalization and Allylic Amination for Post‐Polymerization Modification of Polynorbornenes

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A Cleavable Crosslinking Strategy for Commodity Polymer Functionalization and Generation of Reprocessable Thermosets

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Hydroaminoalkylation for Amine Functionalization of Vinyl‐Terminated Polyethylene Enables Direct Access to Responsive Functional Materials

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Iron(III)‐Catalyzed C─H Hydroxylation of Low‐Density Polyethylene Coupled with Short Chain Branching Growth

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C─H Amination of Polypropylene with Sodium N ‐Chloro‐Amides

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Functionalization of Polyolefins via Catalytic Nitrene Addition

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Functionalizations of C─H and C═C Bonds in Polyolefins Catalyzed by Transition‐Metal Complexes

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Upcycling of Polypropylene Wastes via Catalytically C−H Modification with Polar Olefins

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Cobalt‐Catalyzed C─H Oxidation of Alkanes and Postfunctionalization of Polyolefin Elastomers

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Photocatalytic Metal‐Free Radical Hydrosilylation for Polymer Functionalization†

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Epoxidation of Commodity Polydienes: An Operationally Simple and Acid-Free Platform for Generating Halohydrin-Containing Polymers with Tunable Properties

inferred← citeshttps://doi.org/10.1021/acs.macromol.5c03595openalex-snapshot

Synthesis of Crystalline Syndiotactic Polystyrene Containing Vinyl Groups and Its Functionalization

inferred← citeshttps://doi.org/10.1021/acs.macromol.6c00871openalex-snapshot

Diverse Functionalization of Nonpolar Polyolefins through Late-Stage Incorporation of Alkyl Bromides

inferred← citeshttps://doi.org/10.1021/acsapm.1c01301openalex-snapshot

Influence of Topical Cross-Linking on Mechanical and Ballistic Performance of a Woven Ultra-High-Molecular-Weight Polyethylene Fabric Used in Soft Body Armor

inferred← citeshttps://doi.org/10.1021/acsapm.2c00253openalex-snapshot

Dynamically Cross-Linked Polyolefins via Hydrogen Bonds: Tough yet Soft Thermoplastic Elastomers with High Elastic Recovery

inferred← citeshttps://doi.org/10.1021/acscatal.4c00775openalex-snapshot

Solvent-Free Hydroxylation of Unactivated C–H Bonds in Small Molecules and Macromolecules by a Fe Complex

inferred← citeshttps://doi.org/10.1021/acsmacrolett.0c00789openalex-snapshot

100th Anniversary of Macromolecular Science Viewpoint: Redefining Sustainable Polymers

inferred← citeshttps://doi.org/10.1021/acsmacrolett.1c00519openalex-snapshot

Commodity Polymers to Functional Aminated Materials: Single-Step and Atom-Economic Synthesis by Hydroaminoalkylation

inferred← citeshttps://doi.org/10.1021/acsmacrolett.1c00689openalex-snapshot

Repurposing Mitsunobu Reactions as a Generic Approach toward Polyethylene Derivatives

inferred← citeshttps://doi.org/10.1021/acsmacrolett.5c00368openalex-snapshot

Commodity Polymer Functionalization by a Combination of Hydrogen Atom Transfer Reversible Addition–Fragmentation Chain Transfer Polymerization and Pentafluorophenyl-Ester-Ligation Chemistry

inferred← citeshttps://doi.org/10.1021/acsmaterialslett.1c00490openalex-snapshot

Polyolefins and Polystyrene as Chemical Resources for a Sustainable Future: Challenges, Advances, and Prospects

inferred← citeshttps://doi.org/10.1021/acspolymersau.2c00026openalex-snapshot

Ionic Compatibilization of Polymers

inferred← citeshttps://doi.org/10.1021/acspolymersau.5c00146openalex-snapshot

Decarboxylation-Triggered Polymer Deconstruction

inferred← citeshttps://doi.org/10.1021/jacs.3c07186openalex-snapshot

Chemical Modification of Oxidized Polyethylene Enables Access to Functional Polyethylenes with Greater Reuse

inferred← citeshttps://doi.org/10.1021/jacs.3c07564openalex-snapshot

Amine-Functionalized Polybutadiene Synthesis by Tunable Postpolymerization Hydroaminoalkylation

inferred← citeshttps://doi.org/10.1021/jacs.4c06924openalex-snapshot

Direct Functionalization of Polyethylene Surfaces with High-Density Polymer Brushes

inferred← citeshttps://doi.org/10.1021/jacs.4c10588openalex-snapshot

Polyalkenamers as Drop-In Additives for Ring-Opening Metathesis Polymerization: A Promising Upcycling Paradigm

inferred← citeshttps://doi.org/10.1021/jacs.5c03869openalex-snapshot

One-Step Radical-Induced Synthesis of Graft Copolymers for Effective Compatibilization of Polyethylene and Polypropylene

inferred← citeshttps://doi.org/10.1021/jacs.5c20451openalex-snapshot

Compatibilization of Polyolefin Blends through Acid–Base Interactions

inferred← citeshttps://doi.org/10.1038/s41586-021-04350-0openalex-snapshot

Critical advances and future opportunities in upcycling commodity polymers

inferred← citeshttps://doi.org/10.1039/d1py01140eopenalex-snapshot

Highly efficient terpolymerizations of ethylene/propylene/ENB with a half-titanocene catalytic system

inferred← citeshttps://doi.org/10.1039/d1py01604kopenalex-snapshot

A multi-functional chromone-modified polyethylene obtained by metal-free C–H activation

inferred← citeshttps://doi.org/10.1039/d2py00687aopenalex-snapshot

Electronically optimized diazirine-based polymer crosslinkers

inferred← citeshttps://doi.org/10.1039/d2py01123aopenalex-snapshot

Towards degradable polyethylene: end-functionalised polyethylene (PE-X) and PE-I/LDPE blends from iron-catalysed chain growth of ZnEt 2 with ethylene

inferred← citeshttps://doi.org/10.1039/d2py01274jopenalex-snapshot

Vinyl boronate polymers with dynamic exchange properties

inferred← citeshttps://doi.org/10.1039/d2sc03492aopenalex-snapshot

Exhaustive Baeyer–Villiger oxidation: a tailor-made post-polymerization modification to access challenging poly(vinyl acetate) copolymers

inferred← citeshttps://doi.org/10.1039/d3gc00011gopenalex-snapshot

Accessing secondary amine containing fine chemicals and polymers with an earth-abundant hydroaminoalkylation catalyst

inferred← citeshttps://doi.org/10.1039/d3sc03252copenalex-snapshot

Photoinduced iron-catalyzed C–H alkylation of polyolefins

inferred← citeshttps://doi.org/10.1039/d4py01310gopenalex-snapshot

Functionalized cyclic olefin copolymers: chemoselective polymerization of a cyclopropane-containing norbornadiene dimer using a titanium catalyst and post-polymerization modification

inferred← citeshttps://doi.org/10.1039/d5gc02799copenalex-snapshot

Sustainable upcycling of polyethylene waste to compatibilizers and valuable chemicals

inferred← citeshttps://doi.org/10.1039/d5gc05344gopenalex-snapshot

Chemically recyclable, fully biobased polyolefins with performance parity to low-density polyethylene

inferred← citeshttps://doi.org/10.1039/d5sc02684aopenalex-snapshot

Backbone editing and deconstruction of polyethylene by Beckmann rearrangement and hydrogenolysis

inferred← citeshttps://doi.org/10.1126/science.abh4308openalex-snapshot

Diversification of aliphatic C–H bonds in small molecules and polyolefins through radical chain transfer

inferred← citeshttps://doi.org/10.1126/science.adg6093openalex-snapshot

Diverse functional polyethylenes by catalytic amination

inferred← citeshttps://doi.org/10.1155/ijps/6773209openalex-snapshot

Synergistic Effects of Plasma Treatment and Prooxidants on PE/PCL Blend Biodegradation

inferred← citeshttps://doi.org/10.1360/ssc-2025-0295openalex-snapshot

Thermo-chemical upgrading of waste polyethylene and polypropylene plastics

inferred← citeshttps://doi.org/10.21203/rs.3.rs-4011863/v1openalex-snapshot

Amphiphilic Fibers Based on Polypropylene-G-Poly(Acrylic Acid) by Sequential Photo-Induced Metal-Free Atrp and Electrospinning

inferred← citeshttps://doi.org/10.2139/ssrn.5960273openalex-snapshot

Systematic Comparison of Steric and Electronic Substituent Effects on α-Diimine Nickel-Catalyzed Ethylene-Methyl Acrylate Copolymerization

inferred← citeshttps://doi.org/10.26434/chemrxiv-2024-7f3dropenalex-snapshot

Solvent-free Hydroxylation of C-H bonds by Fe-complex: A Green Approach for Activation of Small Molecules and Macromolecules

inferred← citeshttps://doi.org/10.26434/chemrxiv.14778324openalex-snapshot

“Exhaustive” Baeyer-Villiger Oxidation of Poly(Methyl Vinyl Ketone) and Its Copolymers

inferred← citeshttps://doi.org/10.26434/chemrxiv.14778324.v1openalex-snapshot

“Exhaustive” Baeyer-Villiger Oxidation of Poly(Methyl Vinyl Ketone) and Its Copolymers

inferred← citeshttps://doi.org/10.32743/unichem.2024.121.7openalex-snapshot

inferred← citeshttps://doi.org/10.3390/engproc2025117040openalex-snapshot

Hydrophobic-to-Hydrophilic Transition of Polyethylene Surface via Salicylic Acid Grafting

inferred← citeshttps://doi.org/10.3390/polym13142349openalex-snapshot

Role of the Anilinium Ion on the Selective Polymerization of Anilinium 2-Acrylamide-2-methyl-1-propanesulfonate

inferred← citeshttps://doi.org/10.6023/a23050244openalex-snapshot

Recent Advance of Diazo Compounds in Polymer Synthesis★

inferred← citeshttps://doi.org/10.70675/109edc76zf0abz4d0ezafe4z0f0ce1d3a219openalex-snapshot

Reactive processing of polymeric materials : application to the upcycling of polyolefin blends

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