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Phototherapeutic anticancer strategies with first-row transition metal complexes: a critical review

https://doi.org/10.1039/d1cs00609f
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inferredcites →https://doi.org/10.1039/c6dt01929copenalex-snapshot
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inferredcites →https://doi.org/10.1039/c8dt00255jopenalex-snapshot
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inferredcites →https://doi.org/10.1142/s1088424621500188openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.ica.2025.122818openalex-snapshot
Photodynamic antibacterial therapy by metal complex mediators: A new promise for eliminating drug-Resistant infectious microorganisms
inferred← citeshttps://doi.org/10.1016/j.inoche.2024.112622openalex-snapshot
Synthesis, structure and in vitro anticancer activity of copper(II) and platinum(II) complexes with pyrrol-appended dipicolylamine ligand
inferred← citeshttps://doi.org/10.1016/j.inoche.2025.114915openalex-snapshot
Cobalt(III) complexes with dihalo-substituted 8-hydroxyquinoline ligands: Synthesis, characterization, and anticancer evaluation
inferred← citeshttps://doi.org/10.1016/j.inoche.2025.115827openalex-snapshot
An octahedral Ni(III)-thiosemicarbazone complex with cytotoxic potential
inferred← citeshttps://doi.org/10.1016/j.inoche.2026.117049openalex-snapshot
Binuclear Cu(II) complex featuring asymmetric μ-chlorido bridges derived from a tridentate thiosemicarbazone ligand: structural insights and cytotoxicity evaluation
inferred← citeshttps://doi.org/10.1016/j.inoche.2026.117594openalex-snapshot
CuAAC-enabled Ferrocenyl TitaniumIV Salan complexes as mitochondria-enriched photosensitizers for ROS-mediated ferroptosis
inferred← citeshttps://doi.org/10.1016/j.jcis.2026.141169openalex-snapshot
Steric hindrance engineering on Iridium(III) photosensitizers: unlocking aggregation-induced emission for enhanced photodynamic therapy
inferred← citeshttps://doi.org/10.1016/j.jclepro.2024.142969openalex-snapshot
Differences in anodizing of two copper-containing coordination compounds by different degradation factors: Experiments and DFT calculations
inferred← citeshttps://doi.org/10.1016/j.jics.2025.102011openalex-snapshot
Novel ditopic Schiff base rhenium(I) metallorectangle: Synthesis, characterization, and chemical sensing of aromatic hydrocarbons (AHCs)
inferred← citeshttps://doi.org/10.1016/j.jiec.2022.04.018openalex-snapshot
Synthesis of transition metal titanium oxide (MTiOx, M = Mn, Fe, Cu) and its application in furazolidone electrochemical sensor
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2022.111881openalex-snapshot
Investigating the antiproliferative activities of new CuII complexes with pyridine hydrazone derivatives of nalidixic acid
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2022.112093openalex-snapshot
Antitumor activity of synthetic three copper(II) complexes with terpyridine ligands
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2023.112197openalex-snapshot
An anticancer Ti(IV) complex increases mitochondrial reactive oxygen species levels in relation with hypoxia and endoplasmic-reticulum stress: A distinct non DNA-related mechanism
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2023.112226openalex-snapshot
Lysosome directed red light photodynamic therapy using glycosylated iron-(III) conjugates of boron-dipyrromethene
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2023.112291openalex-snapshot
Study of the biological activity of photoactive bipyridyl-Ru(II) complexes containing 1,3,5-triaza-7-phosphaadamantane (PTA)
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2023.112330openalex-snapshot
Functional copper complexes with benzofurans tridentate ligand: Synthesis, crystal structure, DNA binding and anticancer studies
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2024.112523openalex-snapshot
Systematic review on antibacterial photodynamic therapeutic effects of transition metals ruthenium and iridium complexes
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2025.112982openalex-snapshot
Near-infrared activation of upconversion platforms for non-redox-dependent release of Pt(II)
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2026.113216openalex-snapshot
Iridium(III) and rhenium(I) complexes containing an IDO inhibitor induce apoptosis and pyroptosis
inferred← citeshttps://doi.org/10.1016/j.jlumin.2024.121005openalex-snapshot
Ultrafast dynamics modulated by the number of central metal protons in 3d-orbitals metal complexes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123044openalex-snapshot
Photodynamic antimicrobial activity against S. aureus of metallic Iridium(III) complexes with Helicin pendant
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123346openalex-snapshot
Pincer-metal complexes possessing pyrrolidine: synthesis, structural characterization, and cytotoxicity
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2025.123952openalex-snapshot
2-nitroethenyl ferrocene as a photosensitizer: Evaluation of its photodynamic antitumor properties
inferred← citeshttps://doi.org/10.1016/j.jphotobiol.2025.113203openalex-snapshot
Soranjidiol as a photosensitizer: Mechanistic insights into its photochemistry and photoinduced tautomerization
inferred← citeshttps://doi.org/10.1016/j.jphotochem.2024.115574openalex-snapshot
Copper(I) photosensitizer-silica nanoparticle assembly towards enhanced aqueous photoluminescence
inferred← citeshttps://doi.org/10.1016/j.molstruc.2024.137497openalex-snapshot
Synthesis of asymmetric cationic zinc porphyrin photosensitizer containing thiophene group for photodynamic therapy in vitro and theoretical calculation of DFT
inferred← citeshttps://doi.org/10.1016/j.molstruc.2024.138836openalex-snapshot
Synthesis and anti-cancer investigations of copper(II) complexes based on adenine
inferred← citeshttps://doi.org/10.1016/j.molstruc.2024.140487openalex-snapshot
Novel cyanide-containing porphyrins: Unleashing in vitro photodynamic therapy potential
inferred← citeshttps://doi.org/10.1016/j.molstruc.2024.140940openalex-snapshot
Anticancer drug design of potassium ion (K+) assisted self-assembled Cu(II) Schiff base complex and its Ni(II) and Zn(II) analogues (3d-4s): A comparative study of DNA/protein (BSA) interactions and cytotoxicity
inferred← citeshttps://doi.org/10.1016/j.molstruc.2025.144996openalex-snapshot
A phenoxy-oxygen bridged cadmium (II) complex: synthesis, structural characterization and enhanced biological activities
inferred← citeshttps://doi.org/10.1016/j.molstruc.2026.145973openalex-snapshot
Regulation of the binding and stability of triple helix RNA by enantiomers of ruthenium(II) polypyridyl complexes
inferred← citeshttps://doi.org/10.1016/j.molstruc.2026.147622openalex-snapshot
Synthesis, structure, DFT calculation, and anticancer activity of quinoline-functionalized N-heterocyclic carbene arene Ru(II) complexes
inferred← citeshttps://doi.org/10.1016/j.poly.2023.116656openalex-snapshot
Cobalt(III) dibromo-BODIPY-8-hydroxyquinolinate for mitochondria-targeted red light photodynamic therapy
inferred← citeshttps://doi.org/10.1016/j.poly.2023.116778openalex-snapshot
Recent advances on the photo-chemotherapeutic potential of manganese carbonyl complexes
inferred← citeshttps://doi.org/10.1016/j.poly.2023.116793openalex-snapshot
New hyaluronan-terpyridine conjugate: Metal complexes and their biological activity
inferred← citeshttps://doi.org/10.1021/acs.bioconjchem.5c00449openalex-snapshot
Covalently Platinated DNA Oligonucleotides as Ratiometric Dioxygen Sensors
inferred← citeshttps://doi.org/10.1021/acs.chemrev.3c00161openalex-snapshot
Metal-Based Photosensitizers as Inducers of Regulated Cell Death Mechanisms
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c02737openalex-snapshot
Hydrolytically Stable and Cytotoxic [ONON]2Ti(IV)-Type Octahedral Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c03232openalex-snapshot
Photophysical Exploration of Zn(II) Polypyridine Photosensitizers in Two-Photon Photodynamic Therapy: Insights from Theory
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c04407openalex-snapshot
Electronic Structure and Geometry of the Lowest 2LMCT State of Fe(III) Potential Fluorescent Emitters
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c02364openalex-snapshot
Iridium(III)-Based Infrared Two-Photon Photosensitizers: Systematic Regulation of Their Photodynamic Therapy Efficacy
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c04282openalex-snapshot
Dinuclear Dicationic Iridium Complexes for Highly Synergistic Photodynamic and Photothermal Therapy to Chemoresistant Cancer
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c00733openalex-snapshot
Synthesis and Characterization of Copper(I) Halide Heteroleptic Complexes with Thermally Activated Delayed Fluorescence
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c03185openalex-snapshot
Synthesis, Characterization, and Biological Evaluation of Iron(III)-N-Heterocyclic Carbene Complexes as Photosensitizers for Photodynamic Therapy and Chemotherapeutics against Cancer
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c03244openalex-snapshot
Estrogen-Functionalized Ru(II) Polypyridyl Complexes Self-Assemble into Aggregates and Exhibit Selective Phototoxicity against Breast Cancer Cells
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c03265openalex-snapshot
Cyclometalated Iridium(III) Complexes with Optimally Allocated Excited-State Energy for Near-Infrared Photodynamic and Photothermal Therapy
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c04486openalex-snapshot
Mononuclear Nonoxido vs Dinuclear Oxido V IV Metallodrugs: Solution Behavior, Biomolecular Binding, Cytotoxicity, and Internalization in Cells
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c05201openalex-snapshot
Binding of Aqueous-Stable, Lipophilic, Hemocompatible Anticancer V V O 2 Metallodrugs with Biological Molecules: X-ray Structures of the Adduct of the V V –hydrazonato Complex with Hen Egg White Lysozyme
inferred← citeshttps://doi.org/10.1021/acs.jchemed.4c01259openalex-snapshot
Mechanochemistry in Senior Undergraduate Laboratory: NHC Complexes, Catalysis, and Sonogashira Cross-Coupling
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.2c02000openalex-snapshot
Photoacidolysis-Mediated Iridium(III) Complex for Photoactive Antibacterial Therapy
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.3c00189openalex-snapshot
Exploring Structure–Activity Relationships in Photodynamic Therapy Anticancer Agents Based on Ir(III)-COUPY Conjugates
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.4c01671openalex-snapshot
Enhanced Sonodynamic Therapy for Deep Tumors Using a Self-Assembled Organoplatinum(II) Sonosensitizer
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.4c01680openalex-snapshot
Tailored Metal-Based Catalysts: A New Platform for Targeted Anticancer Therapies
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.5c01372openalex-snapshot
Trimodal Ni(II) Complex of Natural Coumarin: Enhanced Lung Cancer Therapy through Chemo, Photodynamic, and Photothermal Approaches under Red and NIR Light
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.5c01612openalex-snapshot
Redox-Inactive Terpyridine Zn(II)–Azide Complexes for Photodynamic and Photoactivatable Chemotherapy
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.5c03731openalex-snapshot
Phenolato Ti IV Complexes as Bifunctional Antitumor Agents: Synergistic Photodynamic Therapy, In Situ Ti III -Mediated Cytotoxicity, and Immune Activation
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.6c00856openalex-snapshot
A Mitochondria-Targeted Iridium(III) Complex as a Potent Type-I/II Photosensitizer for Pyroptosis-Based Breast Cancer Therapy
inferred← citeshttps://doi.org/10.1021/acs.jmedchem.6c01764openalex-snapshot
A Vanadium(II) Photosensitizer Delivered by Human Serum Albumin for Photodynamic Therapy
inferred← citeshttps://doi.org/10.1021/acs.jpca.2c03950openalex-snapshot
Chalcogen Effects in the Photophysical Properties of Dimethylamino-1,8-naphthalimide Dyes Revealed by DFT Investigation
inferred← citeshttps://doi.org/10.1021/acs.jpca.5c06391openalex-snapshot
Benchmarking Structures and UV–Vis Spectra of Iron Complexes Against Experimental Data
inferred← citeshttps://doi.org/10.1021/acs.jpcb.3c02382openalex-snapshot
Density Functional Theory-Guided Photo-Triggered Anticancer Activity of Curcumin-Based Zinc(II) Complexes
inferred← citeshttps://doi.org/10.1021/acs.jpclett.4c00588openalex-snapshot
CuCl 2 /FeCl 3 Bimetallic Photocatalyst for Sustainable Ethylene Production from Ethanol via Recoverable Redox Cycles
inferred← citeshttps://doi.org/10.1021/acs.nanolett.6c02643openalex-snapshot
Aggregation-Enhanced Photocatalysis Powers Next-Generation Phototherapeutics
inferred← citeshttps://doi.org/10.1021/acsabm.5c00884openalex-snapshot
Acid-Responsive Thiocarbonylated Coumarin Photosensitizer for Hypoxia-Tolerant Photodynamic Therapy
inferred← citeshttps://doi.org/10.1021/acsami.2c09281openalex-snapshot
Modulating Resonance Energy Transfer with Supramolecular Control in a Layered Hybrid Perovskite and Chromium Photosensitizer Assembly
inferred← citeshttps://doi.org/10.1021/acsami.4c04138openalex-snapshot
Synthesis, Photo-Characterizations, and Pre-Clinical Studies on Advanced Cellular and Animal Models of Zinc(II) and Platinum(II) Sulfonyl-Substituted Phthalocyanines for Enhanced Vascular-Targeted Photodynamic Therapy
inferred← citeshttps://doi.org/10.1021/acsami.4c05181openalex-snapshot
A Nanoencapsulated Ir(III)-Phthalocyanine Conjugate as a Promising Photodynamic Therapy Anticancer Agent
inferred← citeshttps://doi.org/10.1021/acsami.4c22606openalex-snapshot
Photostable Mn(II) Complex of Curcumin for Effective Photodynamic Therapy and Precise Three-Dimensional In Vivo Tumor Imaging
inferred← citeshttps://doi.org/10.1021/acsami.5c01443openalex-snapshot
Theranostic Rhenium Complexes as Suborganelle-Targeted Copper Ionophores To Stimulate Cuproptosis for Cancer Immunotherapy
inferred← citeshttps://doi.org/10.1021/acsmaterialslett.2c01136openalex-snapshot
Chromium Nanoparticles Improve Macrophage and T Cell Infiltration for Cancer Immunotherapy
inferred← citeshttps://doi.org/10.1021/acsomega.5c04204openalex-snapshot
A New Organophosphorus Schiff Base-Titanium(IV) Complex: Synthesis, Structural Insights (XRD/Docking), and Antibacterial Activity
inferred← citeshttps://doi.org/10.1021/acssuschemeng.3c04782openalex-snapshot
Fabrication of Hollow Mesoporous Copper Sulfide Nanocapsules Loaded with Natural Photoactivated Pesticides for Sustainable Plant Disease Management
inferred← citeshttps://doi.org/10.1021/jacs.2c03437openalex-snapshot
Luminescent and Photofunctional Transition Metal Complexes: From Molecular Design to Diagnostic and Therapeutic Applications
inferred← citeshttps://doi.org/10.1021/jacs.2c04465openalex-snapshot
Shedding Light on the Oxidizing Properties of Spin-Flip Excited States in a Cr III Polypyridine Complex and Their Use in Photoredox Catalysis
inferred← citeshttps://doi.org/10.1021/jacs.3c04414openalex-snapshot
Hint from an Enzymatic Reaction: Superoxide Dismutase Models Efficiently Suppress Colorectal Cancer Cell Proliferation
inferred← citeshttps://doi.org/10.1021/jacs.3c08181openalex-snapshot
Nickel(II) Phototheranostics: A Case Study in Photoactivated H2O2-Enhanced Immunotherapy
inferred← citeshttps://doi.org/10.1021/jacs.3c13224openalex-snapshot
Augmenting Cancer Therapy with a Supramolecular Immunogenic Cell Death Inducer: A Lysosome-Targeted NIR-Light-Activated Ruthenium(II) Metallacycle
inferred← citeshttps://doi.org/10.1021/jacs.4c02748openalex-snapshot
Time-Resolved X-ray Emission Spectroscopy and Synthetic High-Spin Model Complexes Resolve Ambiguities in Excited-State Assignments of Transition-Metal Chromophores: A Case Study of Fe-Amido Complexes
inferred← citeshttps://doi.org/10.1021/jacs.4c15036openalex-snapshot
Ruthenium(II) Polypyridyl Complexes Containing COUBPY Ligands as Potent Photosensitizers for the Efficient Phototherapy of Hypoxic Tumors
inferred← citeshttps://doi.org/10.1021/jacs.5c10403openalex-snapshot
Quadrupolar Ligand-to-Metal Charge Transfer Excited States in Octahedral Zr(IV) Complexes
inferred← citeshttps://doi.org/10.1021/jacs.5c14960openalex-snapshot
An O 2 -Independent Copper(II) Phototherapeutic Agent for Photoactivating H 2 O 2 to Enhance Antitumor Immunotherapy
inferred← citeshttps://doi.org/10.1021/jacsau.5c00867openalex-snapshot
Ru(II) Complex-Mediated Phase Separation Amplifies Photocatalytic RNA Damage to Stimulate RIG-I Immunotherapy
inferred← citeshttps://doi.org/10.1038/s41598-023-41315-xopenalex-snapshot
AIEgen orthopalladated hybrid polymers for efficient inactivation of the total coliforms in urban wastewater
inferred← citeshttps://doi.org/10.1039/9781837677061-00068openalex-snapshot
Recent Development of Ruthenium Complexes for Photochemotherapy (PCT) Applications
inferred← citeshttps://doi.org/10.1039/9781837677061-00108openalex-snapshot
Luminescent Transition Metal Complexes for Biological Sensing and Labelling
inferred← citeshttps://doi.org/10.1039/bk9781837672301-00194openalex-snapshot
Photophysics of transition metal complexes (2021–2022)
inferred← citeshttps://doi.org/10.1039/d1cs01079dopenalex-snapshot
New guidelines and definitions for type I photodynamic therapy
inferred← citeshttps://doi.org/10.1039/d2cc06721hopenalex-snapshot
Axisymmetric bis-tridentate Ir( iii ) photoredox catalysts for anticancer phototherapy under hypoxia
inferred← citeshttps://doi.org/10.1039/d2cc06987copenalex-snapshot
Visible-light-induced protein labeling in live cells with aryl azides
inferred← citeshttps://doi.org/10.1039/d2cs00407kopenalex-snapshot
Medicinal inorganic chemistry – challenges, opportunities and guidelines to develop the next generation of radioactive, photoactivated and active site inhibiting metal-based medicines
inferred← citeshttps://doi.org/10.1039/d2dt01237eopenalex-snapshot
Balancing the interplay between ligand ejection and therapeutic window light absorption in ruthenium polypyridyl complexes
inferred← citeshttps://doi.org/10.1039/d2dt02157aopenalex-snapshot
Synthesis and anti-microbial activity of a new series of bis(diphosphine) rhenium( v ) dioxo complexes
inferred← citeshttps://doi.org/10.1039/d2dt03317hopenalex-snapshot
In vitro and in vivo antitumor activity of novel half-sandwich ruthenium complexes containing quinoline derivative ligands
inferred← citeshttps://doi.org/10.1039/d2sc06445fopenalex-snapshot
Unveiling upsurge of photogenerated ROS: control of intersystem crossing through tuning aggregation patterns
inferred← citeshttps://doi.org/10.1039/d2sc06675kopenalex-snapshot
A mitochondria-localized iridium( iii ) photosensitizer for two-photon photodynamic immunotherapy against melanoma
inferred← citeshttps://doi.org/10.1039/d3cs00227fopenalex-snapshot
Near-infrared metal agents assisting precision medicine: from strategic design to bioimaging and therapeutic applications
inferred← citeshttps://doi.org/10.1039/d3cs00343dopenalex-snapshot
Click-derived multifunctional metal complexes for diverse applications
inferred← citeshttps://doi.org/10.1039/d3dt00317eopenalex-snapshot
A Cu( i )-based Fenton-like agent inducing mitochondrial damage for photo-assisted enhanced chemodynamic therapy
inferred← citeshttps://doi.org/10.1039/d3dt01750hopenalex-snapshot
Hydrazylpyridine salicylaldehyde–copper( ii )–1,10-phenanthroline complexes as potential anticancer agents: synthesis, characterization and anticancer evaluation
inferred← citeshttps://doi.org/10.1039/d3dt02663aopenalex-snapshot
Cu( ii ) flavonoids as potential photochemotherapeutic agents
inferred← citeshttps://doi.org/10.1039/d3dt03581fopenalex-snapshot
Folate-assisted targeted photocytotoxicity of red-light-activable iron( iii ) complex co-functionalized gold nanoconjugates (Fe@FA-AuNPs) against HeLa and triple-negative MDA-MB-231 cancer cells
inferred← citeshttps://doi.org/10.1039/d3dt04045copenalex-snapshot
Synthesis, characterization, and cancer cell-selective cytotoxicity of mixed-ligand cobalt( iii ) complexes of 8-hydroxyquinolines and phenanthroline bases
inferred← citeshttps://doi.org/10.1039/d3nj05613aopenalex-snapshot
A new iron( iii ) complex-functionalized selenium nanowires (Fe@SeNWs) for potential phototherapeutic applications with red light
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